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    • 1. 发明授权
    • Flowthrough-type electrolytic cell
    • 流通式电解槽
    • US4576706A
    • 1986-03-18
    • US647483
    • 1984-09-05
    • Yoshinori TakataMamoru Taki
    • Yoshinori TakataMamoru Taki
    • G01N27/28G01N27/42G01N30/64
    • G01N27/42G01N27/28
    • A sample leaving a separation column of liquid chromatograph is led to an electrolytic cell to obtain an electrolytic current corresponding to the amount of an assayed sample component. The electrolytic cell is divided into two compartments by an ion exchange pipe penetrating therethrough at the center. One compartment is a cylindrical working electrode chamber in the pipe, and the other compartment is a cylindrical chamber for a counterelectrode outside the pipe. A working electrode comprising a bundle of electroconductive carbon fibers is provided in the working electrode chamber, and preferably a swellable rod is inserted as a core into the working electrode. In the chamber for the counterelectrode, a cylindrical counterelectrode made of carbon fibers is provided to surround the outside surface of the ion exchange pipe. The inner diameter of the ion exchange pipe is substantially equal to the inner diameter of a tube for introducing the sample. The sample undergoes electrolysis reaction while the sample passes through the carbon fibers of the working electrode.
    • 将离开液相色谱仪的分离柱的样品导入电解槽,以获得与测定的样品组分的量相对应的电解电流。 电解槽被中心穿过的离子交换管分成两个隔室。 一个隔室是管道中的圆柱形工作电极室,另一个隔室是用于管外的反电极的圆柱形室。 在工作电极室中设置包括导电性碳纤维束的工作电极,优选将可膨胀的棒作为芯插入到工作电极中。 在反电极的室中,设置由碳纤维制成的圆柱形对电极以包围离子交换管的外表面。 离子交换管的内径基本上等于用于引入样品的管的内径。 样品经过电解反应,同时样品通过工作电极的碳纤维。
    • 7. 发明授权
    • Apparatus for measuring clinical emergency check items of blood
    • 用于测量血液临床紧急检查项目的装置
    • US4452682A
    • 1984-06-05
    • US200264
    • 1980-10-24
    • Yoshinori TakataHiroyuki MiyagiKunio HirotaYasuhisa ShibataKazuo NidairaFusao Shirato
    • Yoshinori TakataHiroyuki MiyagiKunio HirotaYasuhisa ShibataKazuo NidairaFusao Shirato
    • G01N27/403G01N27/416G01N27/46
    • G01N33/4915G01N33/492
    • An apparatus for electrochemically measuring clinical emergency check items of blood for a short time by flowthrough system, using a small amount of whole blood as a blood sample, which comprises a blood pH/gas component sensor unit, an electrolyte component sensor unit, and/or a biochemical component sensor unit, arranged in series in this order, a sampler and these sensor units being communicated with one another through a blood sample flow passage or channel, each of the sensor units being provided with sensor electrodes and at least one reference electrode as electrochemical sensor means.Detected values from each of the sensor units are transmitted to a computer or calculator through a current amplifier and/or a differential amplifier for a differential voltage from the voltage of the reference electrode to compute pH, pressure, or concentrations from the detected values, and numerically displayed on a display device connected to the computer.
    • 一种用于使用少量全血作为血液样品的流过系统电化学测量血液临时紧急检查项目的装置,其包括血液pH /气体成分传感器单元,电解质成分传感器单元和/ 或生物化学成分传感器单元,其依次排列成一个采样器,并且这些传感器单元通过血液样本流动通道或通道彼此连通,每个传感器单元设置有传感器电极和至少一个参考电极 作为电化学传感器装置。 来自每个传感器单元的检测值通过电流放大器和/或差分放大器传输到计算机或计算器,用于与参考电极的电压的差分电压,以从检测值计算pH,压力或浓度,以及 数字显示在连接到计算机的显示设备上。
    • 10. 发明授权
    • Wet-laid nonwoven fabric for battery separator, its production method
and sealed type secondary battery
    • 用于电池隔膜的湿式无纺布,其制造方法和密封型二次电池
    • US5888916A
    • 1999-03-30
    • US860492
    • 1997-06-27
    • Yoshiyuki TadokoroMasaru UesakaYoshinori TakataFumigo Goto
    • Yoshiyuki TadokoroMasaru UesakaYoshinori TakataFumigo Goto
    • D04H3/10D21H13/10D21H13/26H01M2/16H01M10/30D04H1/00
    • D04H1/54D04H1/49D21H13/10D21H13/26H01M2/162H01M10/30Y10T442/608Y10T442/637Y10T442/641Y10T442/689Y10T442/69
    • An improved wet-laid nonwoven fabric for a battery separator wherein 20 to 95% by weight of thermoplastic staple fibers having a single fiber diameter of 20 .mu.rm, or less are three-dimensionally entangled with hot-melt fibers having a melting point lower by 20.degree. C. than that of the thermoplastic staple fibers so that a mean fiber entangling point interval is 300 .mu.m or less, wherein at least part of the hot-melt fibers are fused to bond the fibers with each other to fix the nonwoven structure. The nonwoven fabric has a basis weight in a range from 10 to 350 g/m.sup.2, a thickness in a range from 30 to 1000 .mu.m and an apparent density in a range from 0.26 to 0.7 g/cm.sup.3, and is excellent in uniformity and mechanical strength. The wet-laid nonwoven fabric is particularly excellent in air permeability, liquid holding capability, liquid retention capability and liquid absorption rate and satisfies the requirement for a battery separator. Therefore, it is useful for the production of a high performance secondary battery having favorable overcharging characteristics and cycle characteristics. The wet-laid nonwoven fabric according to the present invention is prepared by subjecting a wet-laid web of staple fibers having a ratio L/D of a fiber length L to a single diameter D in a range from 0.5.times.10.sup.3 to 2.0.times.10.sup.3 to a hydroentangling treatment while taking care not to leave a mark from a water jet on the web.
    • PCT No.PCT / JP95 / 02737第 371日期:1997年6月27日 102(e)日期1997年6月27日PCT 1995年12月27日PCT PCT。 公开号WO96 / 20505 PCT 日本1996年7月4日改进的用于电池隔膜的湿法无纺布,其中20至95重量%的单纤维直径为20微米或更小的热塑性短纤维与热熔纤维三维缠结,所述热熔纤维具有 熔点比热塑性短纤维的熔点低20℃,平均纤维缠结点间隔为300μm以下,其中至少部分热熔纤维熔合以将纤维彼此粘合 以固定非织造结构。 无纺布的单位面积重量为10〜350g / m 2,厚度为30〜1000μm,表观密度为0.26〜0.7g / cm 3,均匀性优异, 机械强度。 湿式无纺布的透气度,液体保持能力,液体保持能力和液体吸收率特别优异,并且满足电池隔膜的要求。 因此,制造具有良好的过充电特性和循环特性的高性能二次电池是有用的。 根据本发明的湿法无纺布是通过将具有纤维长度L的L / D的比率的湿法成网幅材在0.5×10 3至2.0×10 3的范围内对单丝直径D进行 水力缠结处理,同时注意不要从网络上的喷水头留下痕迹。