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    • 1. 发明授权
    • Dielectric ceramic composition and electronic device
    • 介电陶瓷组合物和电子器件
    • US06559084B1
    • 2003-05-06
    • US09618219
    • 2000-07-18
    • Yoshinori FujikawaYoshihiro TeradaShigeki Sato
    • Yoshinori FujikawaYoshihiro TeradaShigeki Sato
    • H01G412
    • H01G4/1227C04B35/4682C04B35/803
    • A dielectric ceramic composition comprising a main component of BaTiO3, a first subcomponent including at least one compound selected from MgO, CaO, BaO, SrO and Cr2O3, a second subcomponent of (Ba, Ca)xSiO2+x (where, x=0.8 to 1.2), a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3, and a fourth subcomponent including an oxide of R1 (where R1 is at least one element selected from Sc, Er, Tm, Yb, and Lu), a fifth subcomponent including an oxide of R2 (where R2 is at least one element selected from Y, Dy, Ho, Tb, Gb and Eu), wherein the ratios of the subcomponents to 100 moles of the main component of BaTiO3 are first subcomponent of 0.1 to 3 moles, second subcomponent of 2 to 10 moles, third subcomponent of 0.01 to 0.5 mole, fourth subcomponent of 0.5 to 7 moles, and fifth subcomponent of 2 to 9 moles (where the number of moles of the fourth and fifth subcomponents are respectively the ratio of R1 and R2 alone).
    • 一种包含BaTiO 3的主要组分的介电陶瓷组合物,包含至少一种选自MgO,CaO,BaO,SrO和Cr 2 O 3的化合物的第一副成分,(Ba,Ca)xSiO 2 + x的第二副成分(其中x = 0.8至 1.2),包含至少一种选自V 2 O 5,MoO 3和WO 3的化合物的第三副成分和包含R 1的氧化物(其中R 1为选自Sc,Er,Tm,Yb和Lu中的至少一种元素)的第四副成分, ,其中包含R2的氧化物(其中R2是选自Y,Dy,Ho,Tb,Gb和Eu中的至少一种元素)的第五副成分,其中副成分与BaTiO 3的主成分100摩尔的比率是第一次要成分 为0.1〜3摩尔,第2副成分为2〜10摩尔,第3副成分为0.01〜0.5摩尔,第4副成分为0.5〜7摩尔,第5副成分为2〜9摩尔(第4副产物和第5副成分的摩尔数 分别是R1和R2的比率)。
    • 2. 发明授权
    • Dielectric ceramic composition and electronic device
    • 介电陶瓷组合物和电子器件
    • US06699809B2
    • 2004-03-02
    • US10368650
    • 2003-02-20
    • Yoshinori FujikawaYoshihiro TeradaShigeki Sato
    • Yoshinori FujikawaYoshihiro TeradaShigeki Sato
    • H01G412
    • H01G4/1227C04B35/4682C04B35/803
    • A dielectric ceramic composition including a dielectric base phase containing BaTiO3 as a main component, and plate-shaped or acicula deposition phase existing together in the dielectric base phase. Preferably, the dielectric ceramic composition includes a main component of BaTiO3, a first subcomponent including at least one compound selected from MgO, CaG, BaG, SrO and Cr2O3, a second subcomponent of (Ba, Ca)xSiO2+x (where, x=0.8 to 1.2), a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3, and a fourth subcomponent including an oxide of R1 (where R1 is at least one element selected from Sc, Er, Tm, Yb, and Lu), a fifth subcomponent including an oxide of R2 (where R2 is at least one element selected from Y, Dy, Ho, Tb, Gb and Eu), wherein the ratios of the subcomponents to 100 moles of the main component of BaTiO3 are first subcomponent of 0.1 to 3 moles, second subcomponent of 2 to 10 moles, third subcomponent of 0.01 to 0.5 mole, fourth subcomponent of 0.5 to 7 moles, and fifth subcomponent of 2 to 9 moles (where the number of moles of the fourth and fifth subcomponents are respectively the ratio of R1 and R2 alone).
    • 包含以BaTiO 3为主要成分的介电基底相的电介质陶瓷组合物和介电基体相中一起存在的板状或者acicula沉积相。 优选地,电介质陶瓷组合物包括主要组分BaTiO 3,第一副成分包括至少一种选自MgO,CaG,BaG,SrO和Cr2O3的化合物,第二副成分(Ba,Ca)xSiO 2 + x(其中x = 0.8〜1.2),包含至少一种选自V 2 O 5,MoO 3和WO 3的化合物的第三副成分和包含R1的氧化物的第四副成分(其中,R 1为选自Sc,Er,Tm,Yb和 Lu),其中包含R2的氧化物(其中R2是选自Y,Dy,Ho,Tb,Gb和Eu中的至少一种元素)的第五副成分,其中副成分与BaTiO 3的主要成分的100摩尔比为 第一副成分为0.1〜3摩尔,第二副成分为2〜10摩尔,第3副成分为0.01〜0.5摩尔,第4副成分为0.5〜7摩尔,第5副成分为2〜9摩尔(第4副成分 第五个子部件分别是R1和R2的比率)。
    • 3. 发明授权
    • Dielectric ceramic composition and electronic device
    • 介电陶瓷组合物和电子器件
    • US06403513B1
    • 2002-06-11
    • US09689707
    • 2000-10-13
    • Shigeki SatoYoshinori FujikawaYoshihiro Terada
    • Shigeki SatoYoshinori FujikawaYoshihiro Terada
    • H01G410
    • H01G4/1227C04B35/468
    • A dielectric ceramic composition comprising a main component of composed mainly of barium titanate, a first subcomponent including at least one compound selected from MgO, CaO, BaO, SrO and Cr2O3, a second subcomponent containing silicone oxide as a main composition, a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3, a fourth subcomponent including an oxide of R1 (where R1 is at least one element selected from Sc, Er, Tm, Yb, and Lu), and a fifth subcomponent including CaZrO3 or CaO+ZrO2, wherein the ratios of the subcomponents to 100 moles of the main component of composed mainly of barium titanate are the first subcomponent of 0.1 to 3 moles, the second subcomponent of 2 to 10 moles, the third subcomponent of 0.01 to 0.5 moles, the fourth subcomponent of 0.5 to 7 moles (where the number of moles of the fourth subcomponent is the ratio of R1 alone), and the fifth subcomponent of 0
    • 一种包含主要由钛酸钡组成的主要成分的电介质陶瓷组合物,包含至少一种选自MgO,CaO,BaO,SrO和Cr 2 O 3的化合物的第一副成分,含有氧化硅作为主要成分的第二副成分,第三副成分, 至少一种选自V 2 O 5,MoO 3和WO 3的化合物,包含R 1的氧化物(其中R 1为选自Sc,Er,Tm,Yb和Lu中的至少一种元素)的第四副成分,以及包含CaZrO 3的第五副成分或 CaO + ZrO 2,其中副成分与100摩尔主要由钛酸钡组成的主成分的比例为0.1〜3摩尔的第1副成分,2〜10摩尔的第2副成分,第2副成分为0.01〜0.5摩尔 ,第四副成分为0.5〜7摩尔(其中第四副成分的摩尔数为单独的R1的比例),第五副成分为0 <第五副成分<= 5摩尔。 根据介电陶瓷组合物,介电常数高,电容温度特性可以达到EIA标准的X8R特性(-55〜150℃,DELTAC =±15%),在 减少的气氛是可能的。
    • 5. 发明授权
    • Manufacture method of dielectric ceramic composition
    • 电介质陶瓷组合物的制造方法
    • US06544916B1
    • 2003-04-08
    • US09857413
    • 2001-06-04
    • Shigeki SatoYoshihiro TeradaYoshinori Fujikawa
    • Shigeki SatoYoshihiro TeradaYoshinori Fujikawa
    • C04B35468
    • C04B35/4682H01G4/1227
    • A method of manufacturing a dielectric ceramic composition comprising at least BaTiO3 as a main component, a second subcomponent having SiO2 as a main component and at least one type selected from MO (note that M is at least one type of element selected from Ba, Ca, Sr and Mg), Li2O and B2O3 and other subcomponents, comprising the steps of mixing in the main component at least part of other subcomponents except for the second subcomponent to prepare a pre-calcination powder, calcining said pre-calcination powder to prepare a calcined powder, and mixing at least said second subcomponent in said calcined powder to obtain a dielectric ceramic composition having ratios of the subcomponents to BaTiO3 as the main component of predetermined molar ratios.
    • 一种制造包含至少BaTiO 3作为主要成分的电介质陶瓷组合物的方法,具有SiO 2作为主要成分的第二次要成分和选自MO的至少一种类型(注意,M是选自Ba,Ca中的至少一种元素 ,Sr和Mg),Li 2 O和B 2 O 3等副成分,包括以下步骤:在主成分中除了第二副成分以外的至少一部分其他副成分混合以制备预煅烧粉末,煅烧所述预煅烧粉末以制备 煅烧粉末,并在所述煅烧粉末中混合至少所述第二次要组分,以获得具有作为主要组分的预定摩尔比的亚组分与BaTiO 3的比例的介电陶瓷组合物。