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    • 3. 发明授权
    • Process for producing low-oxygen iron-base metallic powder
    • 生产低氧铁基金属粉末的方法
    • US4209320A
    • 1980-06-24
    • US942023
    • 1978-09-13
    • Yoshihiro KajinagaMinoru NittaIchio SakuradaShunji Ito
    • Yoshihiro KajinagaMinoru NittaIchio SakuradaShunji Ito
    • B22F9/20C22C33/02B22F9/00
    • C22C33/0235B22F9/20
    • A process for producing low-oxygen iron-base metallic powder are disclosed. The low-oxygen iron-base metallic powder is produced in a shaft-type apparatus comprising a preheating zone and an induction heating zone by alloying and/or admixing iron-base metallic raw powder to be subjected to a final reduction, which has an apparent density corresponding to 16 to 57% of theoretical true density, an oxygen content of not more than 6% by weight and a particle size of not more than 1 mm, with carbon or carbonaceous granule in an amount corresponding to not more than a target alloying carbon content of a final product (% by weight)+ an oxygen content of the powder just before the final reduction (% by weight).times. 1.35 to form a starting powder, preheating the starting powder at a temperature of 780.degree. to 1,200.degree. C. in a non-oxidizing atmosphere having a thermodynamically calculated oxygen partial pressure of not more than 2.1.times.10.sup.-1 mmHg and a dew point of not more than +5.degree. C. in the preheating zone to form a preheated and sintered cake (P-cake) with cylindrically sintered shell layer wherein the volume ratio of the shell layer is at least 20%, induction heating the P-cake at a temperature of 850.degree. to 1,400.degree. C. in the same atmosphere by applying an alternating power of 50 Hz to 500 kHz from power supply to effect deoxidation and decarburization to form an induction heated cake (I-cake), and then cooling and pulverizing the I-cake.
    • 公开了一种生产低氧铁基金属粉末的方法。 低氧铁基金属粉末是通过合金化和/或混合铁基金属原料粉末进行最终还原而形成的预热区域和感应加热区域的轴型设备中生产的,其具有明显的 密度对应于理论真密度的16〜57%,氧含量不超过6重量%,粒径不大于1mm,碳或碳质颗粒的量不大于目标合金化 最终产品的碳含量(重量%)+最终还原前的粉末的氧含量(重量%)×1.35,形成起始粉末,在780〜1200℃的温度下预热起始粉末 在预热区内具有不大于2.1×10-1mmHg的热力学计算的氧分压和不高于+5℃的露点的非氧化性气氛中,以形成预热和烧结的饼(P- 蛋糕) 壳层的体积比至少为20%,通过施加50Hz至500kHz的交流功率,在相同气氛中在850℃至1400℃的温度下感应加热P饼 电源进行脱氧脱碳,形成感应加热饼(I饼),然后冷却粉碎I饼。
    • 6. 发明授权
    • Apparatus for producing low-oxygen iron-base metallic powder
    • 低氧铁基金属粉末生产设备
    • US4234168A
    • 1980-11-18
    • US942374
    • 1978-09-14
    • Yoshihiro KajinagaMinoru NittaIchio SakuradaShunji Ito
    • Yoshihiro KajinagaMinoru NittaIchio SakuradaShunji Ito
    • C22B5/10B22F1/00B22F9/20C22C33/02C21D1/40C21D1/42
    • B22F9/20C22C33/0235
    • A process and an apparatus for producing low-oxygen iron-base metallic powder are disclosed. The low-oxygen iron-base metallic powder is produced by alloying and/or admixing iron-base metallic raw powder to be subjected to a final reduction, which has an apparent density in filled state corresponding to 16-57% of theoretical true density, an oxygen content of not more than 6% by weight and a particle size of not more than 1 mm, with carbon or carbonaceous granule in an amount corresponding to not more than an target alloying carbon content of a final product (% by weight) + an oxygen content of the powder just before the final reduction (% by weight) .times. 1.35 to form a starting powder, preheating the starting powder at a temperature of 780.degree.-1,130.degree. C. in a non-oxidizing atmosphere having a theoretical oxygen partial pressure of not more than 2.1.times.10.sup.-1 mmHg and a dew point of not more than +5.degree. C. to form a preheated and sintered cake (P-cake), induction heating the P-cake at a temperature of 850.degree.-1,400.degree. C. in the same atmosphere by applying an alternating power of 50 Hz to 500 kHz from power supply to effect deoxidation and decarburization to form an induction heated cake (I-cake), and then cooling and pulverizing the I-cake.
    • 公开了一种生产低氧铁基金属粉末的方法和设备。 低氧铁基金属粉末是通过将铁基金属原料粉末进行合金化和/或混合来进行最终还原而制备的,该粉末的填充状态的表观密度对应于理论真密度的16-57% 氧含量不超过6重量%且粒径不大于1mm,碳或碳质颗粒的量不大于最终产品的目标合金碳含量(重量%)+ 在最终还原(重量%)之前的粉末的氧含量×1.35以形成起始粉末,在具有理论氧部分的非氧化性气氛中在780℃-130℃的温度下预热起始粉末 压力不大于2.1×10-1mmHg,露点不超过+5℃,形成预热烧结块(P饼),在850℃-140℃的温度下感应加热P-饼 在相同的气氛中通过施加交替的力量 从电源50 Hz到500 kHz,进行脱氧脱碳,形成感应加热饼(I饼),然后冷却和粉碎I-饼。
    • 8. 发明授权
    • Corrosion-resistant sintered alloy steels and method for making same
    • 耐腐蚀烧结合金钢及其制造方法
    • US5108492A
    • 1992-04-28
    • US465192
    • 1990-02-22
    • Yoshisato KiyotaHiroshi OhtsuboJunichi OhtaMasakazu MatsushitaIchio Sakurada
    • Yoshisato KiyotaHiroshi OhtsuboJunichi OhtaMasakazu MatsushitaIchio Sakurada
    • B22F3/10C22C33/02C22C38/00C22C38/40
    • C22C33/02B22F3/101C22C33/0285
    • It is provided a method for the manufacture of a corrosion-resistant sintered alloy steel, which comprises providing a stainless steel powder; adding a binder to said steel powder; molding the mixture; and carrying out the steps of (1) heating the resultant molding to remove the binder therefrom, (2) sintering the thus debound molding under reduced pressure up to 30 Torr, and (3) further sintering at a higher temperature than those of steps (1) and (2) in a non-oxidative atmosphere under substantially atmospheric pressure. It is also provided a corrosion-resistant sintered alloy steel which comprises a stainless steel, said alloy steel having a density ratio of not less than 92%, a maximum diametric of pore present in the structure of not larger than 20 .mu.m, and a content of Cr at the surface of the steel as being sintered which is not less than 80% of a content of Cr in the inside thereof.
    • PCT No.PCT / JP89 / 00633 Sec。 371日期1990年2月22日 102(e)日期1990年2月22日PCT提交1989年6月27日PCT公布。 公开号WO90 / 00207 日本1990年1月11日提供了一种制造耐腐蚀烧结合金钢的方法,其包括提供不锈钢粉末; 向所述钢粉末添加粘合剂; 成型混合物; (1)加热所得到的模制品以除去粘合剂,(2)在减压下将脱模成型体烧结至30托,和(3)在比步骤(TM)高的温度下进一步烧结( 1)和(2)在非氧化性气氛中在大气压下进行。 还提供了一种耐腐蚀的烧结合金钢,其包括不锈钢,所述合金钢的密度比不小于92%,结构中存在的孔的最大直径不大于20μm, 在烧结的钢表面的Cr含量不低于其内部的Cr含量的80%。
    • 9. 发明授权
    • Composite alloy steel powder and sintered alloy steel
    • 复合合金钢粉末和烧结合金钢
    • US4954171A
    • 1990-09-04
    • US381652
    • 1989-07-14
    • Shigeaki TakajoOsamu FurukimiKuniaki OguraKeiichi MarutaTeruyoshi AbeIchio Sakurada
    • Shigeaki TakajoOsamu FurukimiKuniaki OguraKeiichi MarutaTeruyoshi AbeIchio Sakurada
    • C22C33/02
    • C22C33/0264C22C33/0207C22C33/0257Y10T428/12181
    • Provided herein are high-strength high-toughness sintered alloy steel and composite alloy steel powder useful for the production thereof. The sintered alloy steel contains, as the alloy components in the final product, Ni, Mo, and/or W, and C, if necessary, said alloy being composed of 0.50-3.50 wt % of Ni, 0.65-3.50 wt % of Mo+1/2W, (and 0.3-0.8 wt % of C, if necessary), and the remainder of Fe and inevitable impurities, and has a density higher than 7.0 g/cm.sup.3 and a tensile strength higher than 130 kgf/mm.sup.2 after quenching and tempering. The composite alloy steel powder is composed of iron powder particles and powdery alloy components attached by diffusion to part of the surface of the iron powder particles, with the content of Ni and the content of Mo+1/2W in the steel powder of particle diameter smaller than 45 .infin.m being in the range of 2.0-4.2 times the average content in the entire steel powder. The sintered alloy steel has high strength and high toughness despites its comparatively low alloy composition and can be produced without any special equipment. The heat-treated sintered steel meets the requirements for automotive parts and the like.
    • PCT No.PCT / JP88 / 01007 Sec。 371日期:1989年7月14日 102(e)日期1989年7月14日PCT提交1988年9月30日PCT公布。 公开号WO89 / 02802 日本1989年4月6日。这里提出了用于制造高强度高韧性烧结合金钢和复合合金钢粉末。 烧结合金钢作为最终产品中的合金成分含有Ni,Mo和/或W和C,如果需要,所述合金由0.50-3.50wt%的Ni,0.65-3.50wt%的Mo + 1 / 2W,(如果需要,为0.3〜0.8重量%的C),余量为Fe和不可避免的杂质,并且在淬火后具有高于7.0g / cm 3的密度和高于130kgf / mm 2的拉伸强度 并回火。 复合合金钢粉末由铁粉颗粒和粉末状合金组分组成,通过扩散到铁粉颗粒表面的一部分,其中Ni含量和Mo + 1 / 2W含量在钢粉中的粒径 小于45的INFINITY m在整个钢粉末的平均含量的2.0-4.2倍的范围内。 烧结合金钢具有较高的强度和高韧性,可以使其相对低的合金组成不受任何特殊的设备制造。 热处理烧结钢满足汽车部件等的要求。