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1. 发明授权

US6072024A Production process of cross-linked polyaspartic acid resin 失效
标题翻译：交联聚天冬氨酸树脂的生产工艺
公开(公告)号：US6072024A
公开(公告)日：2000-06-06
申请号：US42942
申请日：1998-03-17
申请人： Yoshihiro Irizato , Makoto Sukegawa , Toshio Katoh , Hiroaki Tamatani , Akinori Nagatomo , Masaru Wada
发明人： Yoshihiro Irizato , Makoto Sukegawa , Toshio Katoh , Hiroaki Tamatani , Akinori Nagatomo , Masaru Wada
IPC分类号： C08G73/10 , C08G69/10
CPC分类号： C08G73/1092
摘要： A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced. The process may also include one or both of the following steps as needed: (d) a gel of the cross-linked polyaspartic acid resin is washed with water and/or a water-miscible organic solvent; and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking agent.
摘要翻译：公开了一种具有生物降解性和高吸水性的交联聚天冬氨酸树脂以高生产率生产的方法。该方法包括以下步骤之一：（a）已经通过分散剂进入分散状态的聚琥珀酰亚胺和交联剂反应生成交联聚天冬氨酸树脂; （b）交联聚琥珀酰亚胺的酰亚胺环进行水解反应同时控制所得凝胶的溶胀度，从而制得交联聚天冬氨酸树脂; 和（c）通过使交联剂与聚琥珀酰亚胺在有机溶剂中的溶液反应而获得的交联聚琥珀酰亚胺的凝胶被分解以使交联的聚琥珀酰亚胺的酰亚胺环进行水解反应，制成交联聚天冬氨酸树脂。该方法还可以根据需要包括以下步骤中的一种或两种：（d）用水和/或水混溶性有机溶剂洗涤交联聚天冬氨酸树脂的凝胶; 和（e）使用碱性氨基酸作为交联剂制备聚琥珀酰亚胺。

2. 发明授权

US06346569B1 Production process of cross-linked polysuccinimide resin 有权
标题翻译：交联聚琥珀酰亚胺树脂的生产工艺
公开(公告)号：US06346569B1
公开(公告)日：2002-02-12
申请号：US09514954
申请日：2000-02-28
申请人： Yoshihiro Irizato , Makoto Sukegawa , Toshio Katoh , Hiroaki Tamatani , Akinori Nagatomo , Masaru Wada
发明人： Yoshihiro Irizato , Makoto Sukegawa , Toshio Katoh , Hiroaki Tamatani , Akinori Nagatomo , Masaru Wada
IPC分类号： C08J324
CPC分类号： C08G73/1092
摘要： A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced. The process may also include one or both of the following steps as needed: (d) a gel of the cross-linked polyaspartic acid resin is washed with water and/or a water-miscible organic solvent; and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking agent.
摘要翻译：公开了一种具有生物降解性和高吸水性的交联聚天冬氨酸树脂以高生产率生产的方法。该方法包括以下步骤之一：（a）已经通过分散剂进入分散状态的聚琥珀酰亚胺和交联剂反应生成交联聚天冬氨酸树脂; （b）交联聚琥珀酰亚胺的酰亚胺环进行水解反应同时控制所得凝胶的溶胀度，从而制得交联聚天冬氨酸树脂; 和（c）通过使交联剂与聚琥珀酰亚胺在有机溶剂中的溶液反应而获得的交联聚琥珀酰亚胺的凝胶被分解以使交联的聚琥珀酰亚胺的酰亚胺环进行水解反应，制成交联聚天冬氨酸树脂。该方法还可以根据需要包括以下步骤中的一种或两种：（d）用水和/或水混溶性有机溶剂洗涤交联聚天冬氨酸树脂的凝胶; 和（e）使用碱性氨基酸作为交联剂制备聚琥珀酰亚胺。

3. 发明授权

US5986042A Cross-linked polymer 失效
标题翻译：交联聚合物
公开(公告)号：US5986042A
公开(公告)日：1999-11-16
申请号：US14421
申请日：1998-01-27
申请人： Yoshihiro Irizato , Makoto Sukegawa , Toshio Katoh , Hiroaki Tamatani
发明人： Yoshihiro Irizato , Makoto Sukegawa , Toshio Katoh , Hiroaki Tamatani
IPC分类号： C08G69/48 , C08G73/02 , C08G69/10
CPC分类号： C08G69/48 , C08G73/028 , C08G73/0293
摘要： A cross-linked polymer containing, in its molecule, recurring units represented by the following formula (1), and having biodegradability and high water-absorbency: ##STR1## wherein R.sub.1 is a pendant group having at least one functional group selected from the group consisting of acidic groups and salts thereof, a glycino group and salts thereof, cationic groups and betaine groups; X.sub.1 is NH, NR.sub.1 ', R.sub.1 ' being an alkyl, aralkyl or aryl group, O or S; and n.sub.1 is 1 or 2.
摘要翻译：在其分子中含有由下式（1）表示的重复单元并且具有生物降解性和高吸水性的交联聚合物：其中R1是具有至少一个选自酸性的官能团的侧基基团和盐，缩水甘油基及其盐，阳离子基团和甜菜碱基团; X1是NH，NR1'，R1'是烷基，芳烷基或芳基，O或S; n1为1或2。

4. 发明授权

US06657041B1 Production process of polysuccinimide 有权
标题翻译：聚琥珀酰亚胺的生产工艺
公开(公告)号：US06657041B1
公开(公告)日：2003-12-02
申请号：US09868498
申请日：2001-06-18
申请人： Katsuhiko Machida , Susumu Fukawa , Shinji Ogawa , Toshio Katoh , Makoto Sukegawa , Yoshihiro Irizato
发明人： Katsuhiko Machida , Susumu Fukawa , Shinji Ogawa , Toshio Katoh , Makoto Sukegawa , Yoshihiro Irizato
IPC分类号： C08G6910
CPC分类号： C08G73/1092 , C08G69/10
摘要： A production process of high molecular weight polysuccinimide having a weight average molecular weight of 40,000 or higher is disclosed, which comprises the following steps: 1) mixing and heating aspartic acid and an acidic catalyst to produce a liquid, low molecular weight polymer mixture, 2) separating the acidic catalyst to appropriate extent from the liquid, low molecular weight polymer mixture, thereby directly changing a polymer-containing phase from a liquid phase into a solid phase to produce a solid, low molecular weight polymer mixture, and 3) conducting solid-state polymerization on the thus-obtained solid, low molecular weight polymer mixture. This process can be practiced in a simple apparatus, and is free of problems such as formation of a highly viscous phase, excessive formation of foam, and formation of a reaction mixture into coherent mass.
摘要翻译：公开了重均分子量为40,000以上的高分子量聚琥珀酰亚胺的生产方法，其包括以下步骤：1）将天冬氨酸和酸性催化剂混合加热以制备液体低分子量聚合物混合物2 ）将酸性催化剂从液态低分子量聚合物混合物中分离出适当的程度，由此直接将含聚合物的相从液相转变为固相以产生固体低分子量聚合物混合物，和3）导电固体在这样得到的固体低分子量聚合物混合物上进行状态聚合。该方法可以在简单的装置中实施，并且没有诸如高粘性相的形成，泡沫过度形成以及反应混合物形成连续质量的问题。

5. 发明授权

US5545751A Process for the preparation of 4-methoxy-2,2',6'-Trimethyldiphenylamine 失效
标题翻译： 4-甲氧基-2,2'，6'-三甲基二苯胺的制备方法
公开(公告)号：US5545751A
公开(公告)日：1996-08-13
申请号：US358566
申请日：1994-12-14
申请人： Chiyuki Kusuda , Masayuki Furuya , Masaru Wada , Yoshihiro Irizato , Hiroshi Naruse , Teruyuki Nagata
发明人： Chiyuki Kusuda , Masayuki Furuya , Masaru Wada , Yoshihiro Irizato , Hiroshi Naruse , Teruyuki Nagata
IPC分类号： C07C213/00 , C07C217/92 , C07C209/22
CPC分类号： C07C213/00 , C07C217/92
摘要： A process for the preparation of 4-methoxy-2,2',6-trimethyldiphenylamine, which comprises heating and reacting 2,6-dimethylcyclohexanone and 2-methyl-4-methoxyaniline in the presence of a dehydrogenation catalyst while removing the resultant hydrogen and water from the reaction system.
摘要翻译：一种制备4-甲氧基-2,2'，6-三甲基二苯胺的方法，该方法包括在脱氢催化剂的存在下加热和反应2,6-二甲基环己酮和2-甲基-4-甲氧基苯胺，同时除去所得氢气，来自反应体系的水。

6. 发明授权

US5182409A Preparation process of bis(1,2-diaryl-1,2-ethyolenedithiolato)nickel-based complex 失效
标题翻译： BIS（1,2-二元-1,2-乙二醇二醇）基于镍的复合物的制备方法
公开(公告)号：US5182409A
公开(公告)日：1993-01-26
申请号：US613554
申请日：1990-11-15
申请人： Keisuke Takuma , Yoshihiro Irizato , Kimitoshi Katho
发明人： Keisuke Takuma , Yoshihiro Irizato , Kimitoshi Katho
IPC分类号： C07C319/02 , C07C321/10 , C07F15/04
CPC分类号： C07C321/10 , C07C319/02 , C07F15/045
摘要： The present invention is a process for the preparation of bis(1,2-diaryl-1,2-ethylenedithiolato)-nickel-based complex which is characterized by reacting a benzil-based compound or a benzoin-based compound with phosphorus pentasulfide in 1,3-dimethyl-2-imidazolidinone and successively reacting with nickel chloride.
摘要翻译： PCT No.PCT / JP90 / 00452 Sec。 371日期1990年11月15日 102（e）1990年11月15日日期PCT提交1990年4月4日PCT公布。出版物WO90 / 12019 日期：1990年10月18日。本发明是制备双（1,2-二芳基-1,2-亚乙基二硫醇） - 镍基复合物的方法，其特征在于使苯偶酰基化合物或苯偶姻 - 与1,3-二甲基-2-咪唑啉酮中的五硫化二磷化合物反应，然后与氯化镍反应。

7. 发明授权

US5736609A Sulfur-containing urethane-based resin composition, its resin, and optical element and lens comprising resin 失效
标题翻译：含硫氨基甲酸酯类树脂组合物，其树脂和包含树脂的光学元件和透镜
公开(公告)号：US5736609A
公开(公告)日：1998-04-07
申请号：US663734
申请日：1996-06-14
申请人： Yoshihiro Irizato , Shinichi Umeda , Yoshinobu Kanemura , Teruyuki Nagata
发明人： Yoshihiro Irizato , Shinichi Umeda , Yoshinobu Kanemura , Teruyuki Nagata
IPC分类号： C08G18/38 , C08G18/67 , G02B1/04 , C08G18/62
CPC分类号： C08G18/677 , C08G18/3876 , G02B1/041
摘要： The present invention discloses a sulfur-containing urethane-based resin composition of the present invention is directed to a sulfur-containing urethane-based resin composition which comprises a polythiol compound represented by formula (1): ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 each is a hydrogen atom or a mercapto group; x, y and z each is an integer of 0 to 8; and in their combinations, formula (1) has at least two mercapto groups, a polyiso(thio)cyanate compound, and a compound having two or more reactive unsaturated groups in an amount of 30 to 70% by weight based on the total weight of the composition, or a sulfur-containing urethane-based resin composition which comprises the polythiol compound represented by formula (1), the polyiso(thio)cyanate compound, the compound having two or more reactive unsaturated groups in an amount of 10 to 70% by weight based on the total weight, and a photopolymerization catalyst.
摘要翻译：本发明公开了本发明的含硫氨基甲酸酯类树脂组合物，其特征在于，含有由式（1）表示的多硫醇化合物的含硫氨基甲酸酯类树脂组合物：其中X1， X2和X3各自为氢原子或巯基; x，y和z各自为0〜8的整数; 并且在它们的组合中，式（1）具有至少两个巯基，多异（硫代）氰酸酯化合物和具有两个或更多个反应性不饱和基团的化合物，其量为30至70重量％，基于所述组合物，或含有式（1）表示的多硫醇化合物，多异（硫代）氰酸酯化合物，具有10〜70重量％以上的反应性不饱和基团的化合物的含硫氨基甲酸酯类树脂组合物，和基于总重量的光聚合催化剂。

8. 发明授权

US5955206A Polysulfide-based resin composition, polysulfide-based resin, and optical material comprising the resin 失效
标题翻译：聚硫醚系树脂组合物，聚硫醚系树脂，以及包含该树脂的光学材料
公开(公告)号：US5955206A
公开(公告)日：1999-09-21
申请号：US640442
申请日：1996-04-30
申请人： Koju Okazaki , Chitoshi Shimakawa , Mamoru Tanaka , Yoshinobu Kanemura , Teruyuki Nagata , Yoshihiro Irizato , Shinichi Umeda
发明人： Koju Okazaki , Chitoshi Shimakawa , Mamoru Tanaka , Yoshinobu Kanemura , Teruyuki Nagata , Yoshihiro Irizato , Shinichi Umeda
IPC分类号： C08G18/38 , C08G59/66 , G02B1/04 , B29B1/02
CPC分类号： C08G59/66 , C08G18/3876 , G02B1/041
摘要： A composition for polysulfide-based resin comprising a polythiol having 4 or more functional groups and a compound having a reactive unsaturated bond(s) and/or b epoxy group(s) and/or c iso(thio)cyanato group(s) in one molecule (however, a+b+c.gtoreq.2, and a and b are not simultaneously 0). A polysulfide-based resin obtained by curing the composition, an optical material comprising the resin, a lens consisting of the optical material and a method for producing the polysulfide-based resin are also set forth.
摘要翻译：一种用于多硫化物基树脂的组合物，其包含具有4个或更多个官能团的多硫醇和具有一个或多个反应性不饱和键和/或b个环氧基和/或c（硫代）氰基的化合物，一个分子（然而，a + b + c> / = 2，a和b不同时为0）。还提出了通过固化组合物获得的聚硫化物基树脂，包含树脂的光学材料，由光学材料组成的透镜和用于制备多硫化物基树脂的方法。

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