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1. 发明授权

US4307195A Immobilized enzyme membrane 失效
标题翻译：固定酶膜
公开(公告)号：US4307195A
公开(公告)日：1981-12-22
申请号：US80026
申请日：1979-09-28
申请人： Yoshiharu Karasawa , Hisashi Kohkame
发明人： Yoshiharu Karasawa , Hisashi Kohkame
IPC分类号： C12N11/08 , B01D57/00 , B01D69/02 , B32B5/18 , C12M1/34 , C12N11/00 , C12N11/02 , C12N11/04 , C12N11/12 , C12Q1/00 , G01N27/333 , G01N27/40 , C12M1/40
CPC分类号： B01D69/144 , C12N11/02 , C12Q1/002 , G01N27/3271
摘要： An immobilized enzyme membrane for use at the working face of an electrochemical electrode is prepared which comprises an asymmetrical membrane integrally formed from a skin layer substantially incapable of permeating an enzyme therethrough but capable of permeating a gas and a liquid, and a sponge layer having pores containing an enzyme immobilized therein by crosslinking and which pores intercommunicate with one another throughout the sponge layer and provide sufficient porosity for retaining a necessary amount of the enzyme. The immobilized enzyme membrane contains a large amount of enzyme, has good diffusion and permeability, and has stabilized enzyme activity for a prolonged period of time. Additionally, there is obtained a quick response time and good analytical precision when the immobilized enzyme membrane is used at the working face of an electrode of electrochemical measuring instruments.
摘要翻译：制备用于电化学电极工作面的固定化酶膜，其包括由基本上不能透过酶穿透其中但能渗透气体和液体的皮肤层整体形成的不对称膜，以及具有孔隙的海绵层含有通过交联固定在其中的酶，并且这些孔在整个海绵层中彼此相通，并提供足够的孔隙以保持必需量的酶。固定化酶膜含有大量的酶，具有良好的扩散和渗透性，并且在长时间内具有稳定的酶活性。另外，当在电化学测量仪器的电极的工作面上使用固定化酶膜时，获得了快速的响应时间和良好的分析精度。

2. 发明授权

US4129554A Thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate stabilized by incorporating an organic electron acceptor 失效
标题翻译：可热固化的可聚合树脂组合物，其包含聚环氧化物和通过掺入有机电子受体而稳定的多异氰酸酯
公开(公告)号：US4129554A
公开(公告)日：1978-12-12
申请号：US797429
申请日：1977-05-16
申请人： Yoshiharu Karasawa , Tohru Koyama , Toshikazu Narahara
发明人： Yoshiharu Karasawa , Tohru Koyama , Toshikazu Narahara
IPC分类号： C08G18/00 , C08G18/08 , C08G18/09 , C08L63/00
CPC分类号： C08G18/00 , C08G18/003 , C08G18/089 , C08G18/09
摘要： A thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate which is normally catalyzed by a basic curing catalyst for forming oxazolidone rings and isocyanurate rings or uredione rings is remarkably stabilized at low temperatures by incorporating a small amount of an organic electron acceptor, such as, picric acid, quinone, chloranil, or cyanoacetate ester into the composition. Since the specific electron acceptors effectively inhibit the polymerization of the reactive components in the composition at low temperatures, a shelf life of the composition is remarkably prolonged.
摘要翻译：包含聚环氧化物和多异氰酸酯的热固性可聚合树脂组合物通常通过用于形成恶唑烷酮环和异氰脲酸酯环和脲基环的碱性固化催化剂通常催化，在低温下通过引入少量有机电子受体（例如，苦味酸，醌，氯醌或氰基乙酸酯加入到组合物中。由于特定的电子受体在低温下有效地抑制组合物中反应性组分的聚合，所以组合物的保质期显着延长。

3. 发明授权

US4070416A Novel thermosetting resin and a process for producing same 失效
标题翻译：新型热固性树脂及其制备方法
公开(公告)号：US4070416A
公开(公告)日：1978-01-24
申请号：US605324
申请日：1975-08-18
申请人： Toshikazu Narahara , Katuo Sugawara , Yoshiharu Karasawa , Hitoshi Yokono , Junji Mukai , Tadashi Muroi
发明人： Toshikazu Narahara , Katuo Sugawara , Yoshiharu Karasawa , Hitoshi Yokono , Junji Mukai , Tadashi Muroi
IPC分类号： C08G18/00 , C08G18/79 , C08G59/40 , C08G69/06 , C08L63/00
CPC分类号： C08G18/791 , C08G18/003 , C08G59/4028 , C08G69/06 , C08G2105/02
摘要： A novel thermosetting resin can be obtained by mixing 1 equivalent or more of a polyfunctional isocyanate per 1 equivalent of a polyfunctional epoxide and then carrying out a polymerization reaction of the mixture in the presence of the catalyst which forms isocyanurate rings and oxazolidone rings so as to enable the mixture to form 2 or more isocyanurate rings directly connected with oxazolidone rings through an isocyanate residues.The resulting thermosetting resin has excellent electrical, chemical and impact resistances and excellent self-extinguishing properties. Said resin is used as an electric insulating material.
摘要翻译：可以通过将1当量或更多个多官能异氰酸酯/ 1当量多官能环氧化物混合，然后在形成异氰脲酸酯环和恶唑烷酮环的催化剂存在下进行混合物的聚合反应，得到新的热固性树脂，以便使得混合物通过异氰酸酯残基形成与恶唑烷酮环直接连接的2个或更多个异氰脲酸酯环。

4. 发明授权

US4547280A Maltose sensor 失效
标题翻译：麦芽糖传感器
公开(公告)号：US4547280A
公开(公告)日：1985-10-15
申请号：US674693
申请日：1984-11-26
申请人： Yoshiharu Karasawa , Yoshinori Takata
发明人： Yoshiharu Karasawa , Yoshinori Takata
IPC分类号： G01N27/327 , C12Q1/00 , C12Q1/26 , C12Q1/40 , C12Q1/54
CPC分类号： C12Q1/005 , Y10S435/817
摘要： In a method for assaying maltose to quantitatively determine amylase, which comprises an enzyme membrane having immobilized .alpha.-glucosidase and glucose oxidase, the present invention is an improvement of the enzyme electrode for assaying maltose, where a hydrogen peroxide electrode provided with a palladium cathode is used.
摘要翻译：本发明是用于测定麦芽糖以定量测定淀粉酶的方法，该淀粉酶包含具有固定的α-葡糖苷酶和葡萄糖氧化酶的酶膜，本发明是用于测定麦芽糖的酶电极的改进，其中提供有钯阴极的过氧化氢电极为用过的。

5. 发明授权

US4476005A Urease-immobilized urea electrode and process for preparing the same 失效
标题翻译：尿素酶固定尿素电极及其制备方法
公开(公告)号：US4476005A
公开(公告)日：1984-10-09
申请号：US537511
申请日：1983-09-30
申请人： Daizo Tokinaga , Teruaki Kobayashi , Akiko Katori , Yoshiharu Karasawa
发明人： Daizo Tokinaga , Teruaki Kobayashi , Akiko Katori , Yoshiharu Karasawa
IPC分类号： G01N27/327 , C12Q1/00 , G01N27/30 , C12Q1/58
CPC分类号： C12Q1/002 , C12Q1/005 , Y10S435/817
摘要： Urea electrode comprises a urease-immobilized membrane having added amino groups prepared by dipping an immobilized membrane in an aqueous solution of ethylenediamine or polylysine and an electrode for quantitative determination of ammonium ions. The electrode has a shorter measurement time with a larger electrode output.
摘要翻译：尿素电极包括固定有脲酶的膜，其具有通过将固定化膜浸渍在乙二胺或聚赖氨酸的水溶液中的添加的氨基和用于定量测定铵离子的电极。电极具有较短的测量时间，较大的电极输出。

6. 发明授权

US4128531A Thermosetting resin composition 失效
标题翻译：热固性树脂组合物
公开(公告)号：US4128531A
公开(公告)日：1978-12-05
申请号：US843205
申请日：1977-10-18
申请人： Shinichi Toyoda , Masahiko Sakai , Kazuo Goto , Toshikazu Narahara , Yoshiharu Karasawa
发明人： Shinichi Toyoda , Masahiko Sakai , Kazuo Goto , Toshikazu Narahara , Yoshiharu Karasawa
IPC分类号： C08G18/00 , C08G18/58 , C08G18/69 , C08G18/79 , C08L63/00 , H01B3/30
CPC分类号： C08G18/791 , C08G18/003 , C08G18/69 , C08L63/00
摘要： A thermosetting resin composition comprising a polyfunctional epoxy compound such as diglycidyl ether of bisphenol A, a polyfunctional isocyanate such as diphenylmethane diisocyanate, a curing agent and polybutadiene type polymer having terminal hydroxyl groups can produce cured articles excellent in heat resistance and crack resistance.
摘要翻译：包含双酚A的多官能环氧化合物如二苯基甲烷二异氰酸酯的多官能异氰酸酯，具有末端羟基的固化剂和聚丁二烯型聚合物的热固性树脂组合物可以产生耐热性和抗裂性优异的固化体。

7. 发明授权

US5021294A Plastic slides for microscopes 失效
标题翻译：显微镜塑料滑块
公开(公告)号：US5021294A
公开(公告)日：1991-06-04
申请号：US99471
申请日：1987-09-22
申请人： Yoshiharu Karasawa , Ken Hirohashi
发明人： Yoshiharu Karasawa , Ken Hirohashi
IPC分类号： G01N1/28 , G02B21/34
CPC分类号： G02B21/34 , Y10S428/913 , Y10T428/26 , Y10T428/31533 , Y10T428/31536 , Y10T428/31667 , Y10T428/31797 , Y10T428/31917 , Y10T428/3192 , Y10T428/31971
摘要： The present invention is directed to a hydrophilic transparent plastic slide for a microscope and a method for preparing the same. This slide is characterized in that at least one surface of the slide is rendered hydrophilic so that a staining solution which is generally used in microscopic examination may not be repelled thereon. Further, according to the present invention, the plastic slides can be manufactured by providing at least one surface of each slide with a hydrophilic layer of silicon oxide, a polysaccharide or the like.
摘要翻译：本发明涉及用于显微镜的亲水性透明塑料滑块及其制备方法。该载玻片的特征在于滑动件的至少一个表面具有亲水性，使得通常在显微镜检查中使用的染色溶液不能在其上被排斥。此外，根据本发明，可以通过将每个载玻片的至少一个表面提供氧化硅亲水层，多糖等来制造塑料滑块。

8. 发明授权

US4304818A Insulation system for winding of electric rotating machines and process of production thereof 失效
标题翻译：旋转电机绕组绝缘系统及其生产工艺
公开(公告)号：US4304818A
公开(公告)日：1981-12-08
申请号：US103571
申请日：1979-12-14
申请人： Hideyo Hirata , Takeshi Hakamada , Misao Souma , Masao Matsui , Yoshiyuki Suda , Yoshiharu Karasawa , Toshikazu Narahara
发明人： Hideyo Hirata , Takeshi Hakamada , Misao Souma , Masao Matsui , Yoshiyuki Suda , Yoshiharu Karasawa , Toshikazu Narahara
IPC分类号： H02K15/12 , C08G18/00 , C08G59/40 , C08G73/06 , H01B3/30 , H01B3/40 , H02K3/30 , B05D5/12
CPC分类号： C08G73/06 , C08G18/003 , C08G59/4028 , C08G73/0638 , H01B3/302 , H01B3/303 , H01B3/40 , H02K3/30 , Y10T428/2936 , Y10T428/2964 , Y10T428/2969 , Y10T428/2971 , Y10T428/31511 , Y10T428/31533 , Y10T428/31547 , Y10T428/31551 , Y10T428/31562 , Y10T428/31601 , Y10T428/31721 , Y10T428/31725
摘要： An insulation system for winding of electric rotating machines having thermal resistance of class H or more and excellent adhesiveness between a conductor and an insulating layer and resistance to thermal stress can be produced by wrapping a plurality of layers of an insulating tape or sheet having thermal resistance of class H or more around a winding conductor, impregnating the thus treated winding conductor with a solventless varnish consisting essentially of 1 equivalent of an epoxy compound containing at least two vicinal epoxy groups, more than one equivalent of an organic polyisocyanate, and then heating the inpregnated winding conductor at a temperature above 60.degree. C. for a time sufficient to form and cure a resin containing as recurring units at least two isocyanurate rings directly bonded to one another through the residue of the polyisocyanate and two oxazolidone rings directly bonded to each other through the residue of the polyepoxide in the presence of 0.01-10% by weight of a catalyst which forms the isocyanurate rings and oxazolidone rings based on the total amount of the polyepoxide and polyisocyanate.
摘要翻译：用于缠绕具有H级以上的耐热性和导体与绝缘层之间优异的粘合性和耐热应力的电动旋转机械的绝缘系统可以通过包裹多层绝缘带或具有热阻的片材来制造在绕组导体周围的H级以上的等级浸渍在这样处理的绕组导体上，用无溶剂的清漆基本上由1当量的含有至少两个邻位环氧基，多于1当量的有机多异氰酸酯的环氧化合物组成，然后加热浸渍的绕组导体在60℃以上的时间足以形成和固化含有作为重复单元的树脂的树脂，所述树脂通过多异氰酸酯的残基和彼此直接键合的两个直接键合的至少两个异氰脲酸酯环直接键合在0.01-10重量％存在下通过聚环氧化物的残基基于聚环氧化物和多异氰酸酯的总量形成异氰脲酸酯环和恶唑烷酮环的催化剂。

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