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    • 1. 发明申请
    • RADIATION-CURABLE RESIN COMPOSITION, RADIATION-CURABLE COATING MATERIAL, AND METHOD FOR FORMING PROTECTIVE LAYER
    • 可辐射固化树脂组合物,可辐射固化涂料和形成保护层的方法
    • US20100104765A1
    • 2010-04-29
    • US12530070
    • 2008-03-04
    • Yohzoh YamashinaHiroyuki TokudaYouichi Tanimoto(none) DavidNobuyuki Koike
    • Yohzoh YamashinaHiroyuki TokudaYouichi Tanimoto(none) DavidNobuyuki Koike
    • C08L77/00C08F20/00C08G18/67C08J7/04
    • C09D175/16B05D3/067C08G18/3853C08G18/672C08G18/8125
    • An object of the present invention is to provide a radiation-curable coating material which forms a cured coating film having high hardness and low curing shrinkage, a radiation-curable resin composition for obtaining the radiation-curable coating material, and a method for forming a protective layer using the radiation-curable coating material. The present invention provides a radiation-curable resin composition including an urethane (meth)acrylate (A), which is obtained by reacting a bicyclo ring-containing polyisocyanate compound (a1), a hydroxyl group-containing, trifunctional or higher polyfunctional (meth)acrylate (a2) and a tris(2-hydroxyalkyl)isocyanurate di(meth)acrylate (a3); a radiation-curable coating material including the above resin composition; and a method for forming a protective layer, which includes: applying the above radiation-curable coating material onto a support to form a layer of the radiation-curable coating material thereon; and irradiating the layer of the coating material with radiation thereby curing the layer of the coating material to form a protective layer.
    • 本发明的目的是提供一种形成具有高硬度和低固化收缩率的固化涂膜的可辐射固化涂料,用于获得可辐射固化涂料的辐射固化树脂组合物,以及用于形成 使用可辐射固化涂层材料的保护层。 本发明提供一种含有双环环的多异氰酸酯化合物(a1),含羟基的三官能以上的多官能(甲基)丙烯酸酯化合物(甲基)丙烯酸酯(A) 丙烯酸酯(a2)和三(2-羟烷基)异氰脲酸酯二(甲基)丙烯酸酯(a3); 包含上述树脂组合物的可辐射固化涂料; 以及形成保护层的方法,其包括:将上述可辐射固化涂层材料施加到支撑体上以在其上形成可辐射固化涂层材料层; 并且用辐射照射涂层材料层,从而固化涂层材料层以形成保护层。