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    • 2. 发明授权
    • Radiation-curable resin composition, radiation-curable coating material, and method for forming protective layer
    • 可辐射固化树脂组合物,可辐射固化涂料,以及形成保护层的方法
    • US08414979B2
    • 2013-04-09
    • US12530070
    • 2008-03-04
    • Yohzoh YamashinaHiroyuki TokudaYouichi TanimotoDavidNobuyuki Koike
    • Yohzoh YamashinaHiroyuki TokudaYouichi TanimotoDavidNobuyuki Koike
    • B05D3/06
    • C09D175/16B05D3/067C08G18/3853C08G18/672C08G18/8125
    • An object of the present invention is to provide a radiation-curable coating material which forms a cured coating film having high hardness and low curing shrinkage, a radiation-curable resin composition for obtaining the radiation-curable coating material, and a method for forming a protective layer using the radiation-curable coating material. The present invention provides a radiation-curable resin composition including an urethane (meth)acrylate (A), which is obtained by reacting a bicyclo ring-containing polyisocyanate compound (a1), a hydroxyl group-containing, trifunctional or higher polyfunctional (meth)acrylate (a2) and a tris(2-hydroxyalkyl)isocyanurate di(meth)acrylate (a3); a radiation-curable coating material including the above resin composition; and a method for forming a protective layer, which includes: applying the above radiation-curable coating material onto a support to form a layer of the radiation-curable coating material thereon; and irradiating the layer of the coating material with radiation thereby curing the layer of the coating material to form a protective layer.
    • 本发明的目的是提供一种形成具有高硬度和低固化收缩率的固化涂膜的可辐射固化涂料,用于获得可辐射固化涂料的辐射固化树脂组合物,以及用于形成 使用可辐射固化涂层材料的保护层。 本发明提供一种含有双环环的多异氰酸酯化合物(a1),含羟基的三官能以上的多官能(甲基)丙烯酸酯化合物(甲基)丙烯酸酯(A) 丙烯酸酯(a2)和三(2-羟烷基)异氰脲酸酯二(甲基)丙烯酸酯(a3); 包含上述树脂组合物的可辐射固化涂料; 以及形成保护层的方法,其包括:将上述可辐射固化涂层材料施加到支撑体上以在其上形成可辐射固化涂层材料层; 并且用辐射照射涂层材料层,从而固化涂层材料层以形成保护层。
    • 5. 发明申请
    • RADIATION-CURABLE RESIN COMPOSITION, RADIATION-CURABLE COATING MATERIAL, AND METHOD FOR FORMING PROTECTIVE LAYER
    • 可辐射固化树脂组合物,可辐射固化涂料和形成保护层的方法
    • US20100104765A1
    • 2010-04-29
    • US12530070
    • 2008-03-04
    • Yohzoh YamashinaHiroyuki TokudaYouichi Tanimoto(none) DavidNobuyuki Koike
    • Yohzoh YamashinaHiroyuki TokudaYouichi Tanimoto(none) DavidNobuyuki Koike
    • C08L77/00C08F20/00C08G18/67C08J7/04
    • C09D175/16B05D3/067C08G18/3853C08G18/672C08G18/8125
    • An object of the present invention is to provide a radiation-curable coating material which forms a cured coating film having high hardness and low curing shrinkage, a radiation-curable resin composition for obtaining the radiation-curable coating material, and a method for forming a protective layer using the radiation-curable coating material. The present invention provides a radiation-curable resin composition including an urethane (meth)acrylate (A), which is obtained by reacting a bicyclo ring-containing polyisocyanate compound (a1), a hydroxyl group-containing, trifunctional or higher polyfunctional (meth)acrylate (a2) and a tris(2-hydroxyalkyl)isocyanurate di(meth)acrylate (a3); a radiation-curable coating material including the above resin composition; and a method for forming a protective layer, which includes: applying the above radiation-curable coating material onto a support to form a layer of the radiation-curable coating material thereon; and irradiating the layer of the coating material with radiation thereby curing the layer of the coating material to form a protective layer.
    • 本发明的目的是提供一种形成具有高硬度和低固化收缩率的固化涂膜的可辐射固化涂料,用于获得可辐射固化涂料的辐射固化树脂组合物,以及用于形成 使用可辐射固化涂层材料的保护层。 本发明提供一种含有双环环的多异氰酸酯化合物(a1),含羟基的三官能以上的多官能(甲基)丙烯酸酯化合物(甲基)丙烯酸酯(A) 丙烯酸酯(a2)和三(2-羟烷基)异氰脲酸酯二(甲基)丙烯酸酯(a3); 包含上述树脂组合物的可辐射固化涂料; 以及形成保护层的方法,其包括:将上述可辐射固化涂层材料施加到支撑体上以在其上形成可辐射固化涂层材料层; 并且用辐射照射涂层材料层,从而固化涂层材料层以形成保护层。
    • 9. 发明授权
    • Radiation curable resin composition for fresnel lens and fresnel lens sheet
    • 用于菲涅尔透镜和菲涅耳透镜片的辐射固化树脂组合物
    • US06809889B2
    • 2004-10-26
    • US10270568
    • 2002-10-16
    • Hiroyuki TokudaYasunobu HirotaYasuhiro Doi
    • Hiroyuki TokudaYasunobu HirotaYasuhiro Doi
    • G02B308
    • G02B3/08C08F290/144G02B1/041Y10T428/31511C08L63/00
    • A radiation curable resin composition for a Fresnel lens is provided, which exhibits a high elastic modulus and a high refractive index and is superior in adhesion to the plastic substrate and is superior in transparency. A lens layer exhibits excellent shape retention over a wide temperature range and is less likely to chip and crack due to an external force. A Fresnel lens sheet using the radiation curable resin composition is also provided. The resin composition comprises, as an essential component, an epoxy (meth)acrylate (a) having an epoxy equivalent per weight of 450 g/eq or more, which has a cyclic structure and two or more (meth)acryloyl groups; a specific trifunctional (meth)acrylate (b); a (meth)acrylate (c) having a molecular weight of 700 or less from an aliphatic polyhydric alcohol having an oxypropylene structure; and a monofunctional (meth)acrylate (d) having a cyclic structure.
    • 提供了一种用于菲涅尔透镜的辐射固化树脂组合物,其具有高弹性模量和高折射率,并且与塑料基材的粘合性优异并且透明度优异。 透镜层在宽的温度范围内表现出优异的形状保持性,并且由于外力而不太可能发生切屑和裂纹。 还提供了使用辐射固化树脂组合物的菲涅尔透镜片。 作为必要成分,树脂组合物含有具有环状结构和2个以上(甲基)丙烯酰基的环氧当量(环氧当量)为450g / eq以上的环氧(甲基)丙烯酸酯(a) 特定的三官能(甲基)丙烯酸酯(b); 具有氧化丙烯结构的脂肪族多元醇的分子量为700以下的(甲基)丙烯酸酯(c) 和具有环状结构的单官能(甲基)丙烯酸酯(d)。