专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4789709A Process for the production of heat resistant thermoplastic copolymer 失效
标题翻译：生产耐热性热塑性共聚物的方法
公开(公告)号：US4789709A
公开(公告)日：1988-12-06
申请号：US924752
申请日：1986-10-30
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Hideaki Matsuura , Susumu Iijima , Tsuyoshi Hashimoto
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Hideaki Matsuura , Susumu Iijima , Tsuyoshi Hashimoto
IPC分类号： C08F8/48
CPC分类号： C08F8/48
摘要： A process for the production of a thermoplastic copolymer having excellent heat distortion resistance is disclosed. The process includes heat-treating a raw copolymer comprising a vinyl monomer unit including methacrylic and/or acrylic acid units in the presence of a specific ring-closing promoter selected from basic compounds, whereby the methacrylic and/or acrylic acid unit is converted into six-membered cyclic anhydride unit. The copolymer has excellent heat distortion resistance, transparency, mechanical properties and processability, and can produce a formed product without splash on the surface. The copolymer is useful for the production of various parts, such as automobile parts, electrical parts, industrial parts, and miscellaneous goods.
摘要翻译：公开了一种制造具有优异耐热变形性的热塑性共聚物的方法。该方法包括在选自碱性化合物的特定闭环促进剂存在下热处理包含乙烯基单体单元（包括甲基丙烯酸和/或丙烯酸单元）的原料共聚物，由此将甲基丙烯酸和/或丙烯酸单元转化为六环状酸酐单元。该共聚物具有优异的耐热变形性，透明性，机械性能和加工性，并且可以在表面上产生无飞溅的成形产品。该共聚物可用于生产汽车部件，电气部件，工业部件和杂项等各种部件。

2. 发明授权

US4661571A Process for the production of heat resistant methacrylic resin 失效
标题翻译：生产耐热甲基丙烯酸树脂的方法
公开(公告)号：US4661571A
公开(公告)日：1987-04-28
申请号：US780903
申请日：1985-09-27
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Susumu Iijima
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Susumu Iijima
IPC分类号： C08F2/38 , C08F20/14 , C08F2/00
CPC分类号： C08F20/14
摘要： An improved process for the production of a methacrylic polymer having excellent heat resistance, which comprises radical-polymerizing a monomer or monomer mixture consisting of 80 to 100% by weight of methyl methacrylate and 0 to 20% by weight of a copolymerizable vinyl monomer in the presence of a polymerization initiator and one or more of specific chain transfer agents selected from the group consisting of(A) 2-mercaptoethyl alkanecarboxylate of the formula: ##STR1## wherein R is an alkyl having 4 to 12 carbon atoms,(B) alkyl 3-mercaptopropionate of the formula: ##STR2## wherein R is an alkyl having 4 to 18 atoms. The methacrylic resin prepared by this invention has excellent heat resistance and can give formed products having excellent heat resistance (high heat distortion temperature) without increase of monomer content processing thereof.
摘要翻译：一种用于制备具有优异耐热性的甲基丙烯酸类聚合物的改进方法，其包括使由80至100重量％的甲基丙烯酸甲酯和0至20重量％的可共聚乙烯基单体组成的单体或单体混合物自由基聚合存在聚合引发剂和一种或多种选自（A）下式的（A）2-巯基乙基链烷羧酸酯的特定链转移剂：其中R是具有4至12个碳原子的烷基（1） B）下式的3-巯基丙酸烷基酯：其中R是具有4-18个原子的烷基。通过本发明制备的甲基丙烯酸树脂具有优异的耐热性，并且可以提供具有优异的耐热性（高热变形温度）的成型产品，而不增加其单体含量处理。

3. 发明授权

US4699964A Antistatic acrylic resin composition and method for the production thereof 失效
标题翻译：抗静电丙烯酸树脂组合物及其制备方法
公开(公告)号：US4699964A
公开(公告)日：1987-10-13
申请号：US860480
申请日：1986-05-07
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
IPC分类号： C08F220/14 , C08F2/00
CPC分类号： C08F220/14
摘要： An acrylic resin composition having excellent permanent antistatic properties, which comprises a copolymer of an acrylic monomer comprising predominantly methyl methacrylate with a specific sulfonate and optionally a specific alkylene oxide and/or acidic phosphate, and a method for the production thereof. The acrylic resin composition of the invention shows excellent antistatic properties without losing the excellent properties of methacrylic resin, such as excellent transparency, mechanical properties, heat resistance, etc., and is useful for various utilities, such as preparation of advertising display, lighting fixtures, covers, nameplate, and various decoratings.

4. 发明授权

US4717756A Process for preparing methacrylate polymer 失效
标题翻译：制备甲基丙烯酸酯聚合物的方法
公开(公告)号：US4717756A
公开(公告)日：1988-01-05
申请号：US46983
申请日：1987-04-06
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08F4/00 , C08F2/02 , C08F4/10 , C08F4/28 , C08F4/32 , C08F4/40 , C08F4/42 , C08F4/50 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/14 , C08F220/10 , C08F220/14 , C08F220/20 , C08F265/06
CPC分类号： C08F220/14 , C08F20/14 , C08F265/06
摘要： A polymerization can be carried out rapidly by polymerizing a methacrylate ester or a mixture of unsaturated monomers comprising the methacrylate ester as a main component in the presence of (1) a hydroperoxide polymerization initiator, (2) a reductant containing sulfur in a molecule, (3) a hydrogen halogenide salt of amine or a quarternary halogenide and (4) a copper-containing compound.
摘要翻译： PCT No.PCT / JP86 / 00400 Sec。 371日期1987年4月6日 102（e）日期1987年4月6日PCT申请日1986年8月4日PCT公布。公开号WO87 / 00842 日本1987年2月12日。聚合可以通过在（1）氢过氧化物聚合引发剂存在下，使甲基丙烯酸酯或包含甲基丙烯酸酯作为主要成分的不饱和单体的混合物进行聚合，（2）还原剂（3）胺或卤化四氯化氢的卤化氢盐和（4）含铜化合物。

5. 发明授权

US4604414A Antistatic acrylic resin composition and method for the production thereof 失效
标题翻译：抗静电丙烯酸树脂组合物及其制备方法
公开(公告)号：US4604414A
公开(公告)日：1986-08-05
申请号：US591853
申请日：1984-03-21
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
IPC分类号： C08F220/14
CPC分类号： C08F220/14
摘要： An acrylic resin composition having excellent permanent antistatic properties, which comprises a copolymer of an acrylic monomer comprising predominantly methyl methacrylate with a specific sulfonate and optionally a specific alkylene oxide and/or acidic phosphate, and a method for the production thereof. The acrylic resin composition of the invention shows excellent antistatic properties without losing the excellent properties of methacrylic resin, such as excellent transparency, mechanical properties, heat resistance, etc., and is useful for various utilities, such as preparation of advertising displays, lighting fixtures, covers, nameplates, and various decorations.
摘要翻译：具有优异永久抗静电性能的丙烯酸树脂组合物及其制备方法，其包含主要包含甲基丙烯酸甲酯与特定磺酸盐和任选的特定环氧烷和/或酸性磷酸盐的丙烯酸单体的共聚物。本发明的丙烯酸树脂组合物显示出优异的抗静电性能，而不会失去甲基丙烯酸树脂的优异性能，例如优异的透明性，机械性能，耐热性等，并且可用于各种用途，例如制备广告显示器，照明器具，盖板，铭牌和各种装饰品。

6. 发明授权

US4837286A Method for the production of polymethacrylates 失效
标题翻译：生产聚甲基丙烯酸酯的方法
公开(公告)号：US4837286A
公开(公告)日：1989-06-06
申请号：US901363
申请日：1986-08-28
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08G63/00 , B29C39/00 , B29C39/42 , B29C39/44 , B29C67/24 , B29K33/04 , B29L11/00 , C08F2/00 , C08F2/02 , C08F2/38 , C08F2/44 , C08F4/28 , C08F4/34 , C08F4/40 , C08F18/00 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/18 , C08G63/66 , C08K5/17 , C08L33/10
CPC分类号： B29C67/246 , C08F2/02 , C08F2/38 , C08F20/10 , C08F20/12
摘要： Improved method for the production of polymethacrylates by a rapid polymerization, which comprises polymerizing an unsaturated monomer selected from a methacrylate and a monomer mixture comprising predominantly a methacrylate which may partially contain a polymer of the monomer (i.e. a syrup of the monomer or monomer mixture) in the presence of a radical polymerization initiator, a reducing compound containing sulfur in the molecule thereof, a copper-containing compound and a specific tertiary amine hydrohalogenate or a quaternary ammonium halide. Said polymethacrylates can give molded products having excellent mold release characteristics and are useful particularly for the production of optical parts such as conventional lenses, Fresnel's lens, optical recording disc media, prisms, mirrors, etc.
摘要翻译：通过快速聚合制备聚甲基丙烯酸酯的改进方法包括聚合选自甲基丙烯酸酯的不饱和单体和主要包含可部分含有单体聚合物（即单体或单体混合物的浆料）的甲基丙烯酸酯的单体混合物，在自由基聚合引发剂的存在下，分子中含有硫的还原性化合物，含铜化合物和特定的叔胺氢卤酸盐或季铵卤化物。所述聚甲基丙烯酸酯可以得到具有优异的脱模特性的成型产品，并且特别用于生产诸如常规透镜，菲涅耳透镜，光记录盘介质，棱镜，反射镜等的光学部件。

7. 发明授权

US4885125A Method for in-mold polymerization of unsaturated compound 失效
标题翻译：不饱和化合物的模内聚合方法
公开(公告)号：US4885125A
公开(公告)日：1989-12-05
申请号：US900974
申请日：1986-08-27
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08G63/00 , B29C39/00 , B29C39/42 , B29C39/44 , B29C67/24 , B29K33/04 , B29L11/00 , C08F2/00 , C08F2/02 , C08F2/38 , C08F2/44 , C08F4/28 , C08F4/34 , C08F4/40 , C08F18/00 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/18 , C08G63/66 , C08K5/17 , C08L33/10
CPC分类号： B29C67/246 , C08F2/02 , C08F2/38 , C08F20/10 , C08F20/12
摘要： An unsaturated compound having a vinyl or vinylidene group is rapidly in-mold polymerized by mixing the unsaturated compound containing a polymerization initiator and the unsaturated compound containing a polymerization accelerator, pouring the mixture into a mold cavity and polymerizing the monomer for not longer than 30 minutes.
摘要翻译：具有乙烯基或亚乙烯基的不饱和化合物通过混合含有聚合引发剂的不饱和化合物和含有聚合促进剂的不饱和化合物而快速模内聚合，将混合物倒入模腔中并使单体聚合不超过30分钟。

8. 发明授权

US4859750A Method for the production of polymethyl methacrylate 失效
标题翻译：生产聚甲基丙烯酸甲酯的方法
公开(公告)号：US4859750A
公开(公告)日：1989-08-22
申请号：US898514
申请日：1986-08-21
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08F4/00 , C08F2/02 , C08F4/10 , C08F4/28 , C08F4/32 , C08F4/40 , C08F4/42 , C08F4/50 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/14 , C08F220/10 , C08F220/14 , C08F220/20 , C08F265/06
CPC分类号： C08F220/14 , C08F20/14 , C08F265/06
摘要： Improved method for the production of a polymer of a monofunctional (unsaturated) monomer, particularly polymethyl methacrylate, by a rapid crosslinking polymerization, which comprises polymerizing a mixture of a monofunctional (unsaturated) monomers, selected from methyl methacrylate and a monomer mixture comprising predominantly methyl methacrylate which may partially contain a polymer of the monomer (i.e. a syrup of the monomer or monomer mixture), and a polyfunctional (unsaturated) monomer in the presence of (1) a radical polymerization initiator, (2) a reducing compound containing sulfur in the molecule thereof, (3) an amine hydrohalogenate or a quaternary ammonium halide and (4) a copper-containing compound. Said polymer has high mechanical properties and excellent transparency and is useful particularly for the production of optical parts such as conventional lenses, Fresnel's lens, optical recording disc media, prisms, mirrors, etc.
摘要翻译：用于通过快速交联聚合制备单官能（不饱和）单体，特别是聚甲基丙烯酸甲酯的聚合物的改进方法，其包括聚合选自甲基丙烯酸甲酯和单体混合物的混合物，所述单体混合物主要包含甲基在（1）自由基聚合引发剂存在下，可以部分含有单体的聚合物（即单体或单体混合物的浆料）和多官能（不饱和的）单体的甲基丙烯酸酯，（2）含硫的还原化合物其分子，（3）氢卤酸胺或季铵卤化物和（4）含铜化合物。所述聚合物具有高机械性能和优异的透明度，并且特别用于制造诸如常规透镜，菲涅尔透镜，光记录盘介质，棱镜，反射镜等的光学部件。

9. 发明授权

US4978702A Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US4978702A
公开(公告)日：1990-12-18
申请号：US237690
申请日：1988-08-26
申请人： Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
发明人： Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
IPC分类号： C09D183/00 , C09D183/04
CPC分类号： C09D183/04
摘要： A coating composition is disclosed which includes(A) 15 to 65% by weight (calculated as SiO.sub.2) of colloidal silica,a partially hydrolyzed and partially co-condensed product of the following component (B) and component (C):(B) 10 to 80% by weight (calculated as R.sup.1 Si(OH).sub.3) of a trialkoxysilane of the formula: R.sup.1 Si(OR.sup.2).sub.3 wherein the group R.sup.1 is methyl or vinyl and the group R.sup.2 is alkyl having 1 to 4 carbon atoms,(C) 1 to 50% by weight (calculated as R.sup.3.sub.n Si(OH).sub.4-n) of an acetoxysilane of the formula: R.sup.3.sub.n Si(OCOCH.sub.3).sub.4-n wherein the group R.sup.3 is alkyl having 1 to 3 carbon atoms, vinyl, phenyl, or mercaptoalkyl having 1 to 3 carbon atoms, and n is an integer of 0 to 2, provided that the total amount of the component (B) wherein the group R.sup.1 is methyl and the component (C) wherein the group R.sup.3 is methyl and n is 1 is in the range of from 10% by weight to less than 70% by weight based on the whole amount of the components (B) and (C), and(D) a solvent.The composition is useful for coating plastic articles and metallic articles to improve their surface properties such as surface hardness, chemical resistance, etc.
摘要翻译：公开了一种涂料组合物，其包含（A）15至65重量％（以SiO 2计）胶体二氧化硅，部分水解和部分共缩合的下列组分（B）和组分（C）的产物：（B） 10〜80重量％（以R1Si（OH）3表示）下式的三烷氧基硅烷：R1Si（OR2）3，其中R1为甲基或乙烯基，R2为碳原子数1〜4的烷基，（C ）1至50重量％（以R3nSi（OH）4-n计算）的下式的酰氧基硅烷：R3nSi（OCOCH3）4-n，其中基团R3为具有1至3个碳原子的烷基，乙烯基，苯基或如果基团R 1为甲基的组分（B）和基团R 3为甲基且n为（C）的组分（C）的总量，则n为0至2的整数，n为0至2的整数。 1相对于成分（B）和（C）的总量为10重量％以下且小于70重量％的范围，（D）溶剂。该组合物可用于涂覆塑料制品和金属制品以改善其表面性能，例如表面硬度，耐化学性等。

10. 发明授权

US4287317A Continuous process for producing rubber-modified methyl methacrylate syrups 失效
标题翻译：生产橡胶改性甲基丙烯酸甲酯糖浆的连续工艺
公开(公告)号：US4287317A
公开(公告)日：1981-09-01
申请号：US142638
申请日：1980-04-22
申请人： Yoshihiko Kitagawa , Yoshimi Hanamura , Masahiro Yuyama , Masahiko Moritani , Akira Sakuramoto , Mikio Suzuki
发明人： Yoshihiko Kitagawa , Yoshimi Hanamura , Masahiro Yuyama , Masahiko Moritani , Akira Sakuramoto , Mikio Suzuki
IPC分类号： C08F291/00 , C08F2/00 , C08F2/02 , C08F291/02 , C08F255/06 , C08F263/04 , C08F265/06 , C08F279/02
CPC分类号： C08F291/02
摘要： A continuous process for producing rubber-modified methyl methacrylate syrups which comprises continuously supplying a material liquor comprising 1 to 20 parts by weight of a rubbery polymer dissolved in 100 parts by weight of a monomer comprising 60 to 100% by weight of methyl methacrylate, and a radical-polymerization initiator to the first reaction zone, continuously polymerizing at such a stationary conversion that the rubber polymer is dispersed in the form of particles form while maintaining the temperature and residence time in the zone so that a steady state is achieved in the zone and the steady-state concentration of the initiator in the zone is 1/2 to 1/1,000 time as much as the concentration of initiator supplied, continuously taking out the resulting reaction mixture from the zone, and passing it through the second reaction zone having a volume of 0 to 5 times as much as that of the first reaction zone, to obtain a stable syrup comprising a disperse phase and a continuous phase, the former phase being substantially a solution of the rubbery polymer in the monomer and the latter one being substantially a solution of the resinous polymer in the monomer, and a process for the production of methyl methacrylate cast sheets and molding materials having an excellent impact resistance from the syrups.
摘要翻译：一种用于生产橡胶改性的甲基丙烯酸甲酯糖浆的连续方法，其包括连续地供给包含1至20重量份的溶解在100重量份的包含60至100重量％的甲基丙烯酸甲酯的单体的橡胶状聚合物的材料液，以及自由基聚合引发剂在第一反应区中，以这样的固定转化率连续聚合，使得橡胶聚合物以颗粒形式分散，同时保持温度和停留时间在区域中，使得在区域中实现稳定状态并且引发剂在该区域中的稳态浓度是所提供的引发剂浓度的1/2至1/1000倍，连续从该区域取出所得的反应混合物，并使其通过具有体积为第一反应区的体积的0至5倍，以获得包含分散相和连续前一相基本上是橡胶状聚合物在单体中的溶液，后者基本上是树脂聚合物在单体中的溶液，以及用于生产具有优异影响的甲基丙烯酸甲酯铸片和成型材料的方法糖浆的抵抗力。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式