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1. 发明授权

US06468487B1 Nitration or carboxylation catalysts 失效
标题翻译：硝化或羧化催化剂
公开(公告)号：US06468487B1
公开(公告)日：2002-10-22
申请号：US09142089
申请日：1999-02-19
申请人： Yasutaka Ishii , Tatsuya Nakano , Satoshi Sakaguchi
发明人： Yasutaka Ishii , Tatsuya Nakano , Satoshi Sakaguchi
IPC分类号： B01J800
CPC分类号： C07C45/36 , B01J31/006 , B01J31/0247 , B01J31/2208 , B01J2231/70 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07B41/08 , C07B43/02 , C07C51/10 , C07C67/12 , C07C69/757 , C07C205/04 , C07C205/05 , C07C205/06 , C07C205/18 , C07C205/55 , C07C211/35 , C07C211/37 , C07C215/42 , C07C229/50 , C07C233/10 , C07C233/14 , C07C233/23 , C07C233/41 , C07C233/52 , C07C233/58 , C07C233/62 , C07C235/40 , C07C235/82 , C07C237/24 , C07C265/10 , C07C271/24 , C07C2603/74 , C07C49/78 , C07C61/29 , C07C61/135
摘要： In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the following formula (1): wherein R1 and R2 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group and a cycloalkyl group, and R1 and R2 may bond together to form a double bond, or an aromatic or non-aromatic ring, and Y is an O or OH, and n denotes 1 to 3; a substrate is allowed to contact with at least one reactant selected from (i) a nitrogen oxide and (ii) a mixture of carbon monoxide and oxygen to be introduced with at least one functional group selected from a nitro group and a carboxyl group. The nitrogen oxide includes, for example, a compound represented by the formula NxOy (e.g., N2O3, NO2). The substrate includes, for example, a compound having a methine carbon atom (e.g., adamantane), a compound having a methyl group or a methylene group at an adjacent moiety of an aromatic ring. According to such reaction, the substrate can be efficiently nitrated or carboxylated even in a mild or moderate condition.
摘要翻译：在下式（1）所示的酰亚胺化合物（例如，N-羟基邻苯二甲酰亚胺）存在下，其中R 1和R 2表示氢原子，卤素原子，烷基，芳基和环烷基，R 1 并且R 2可以键合在一起形成双键，或芳族或非芳香族环，Y是O或OH，n表示1至3;使底物与至少一种选自（i ）氮氧化物和（ii）一氧化碳和氧气的混合物与至少一种选自硝基和羧基的官能团一起引入。氮氧化物包括例如由式N x O y表示的化合物（例如，N 2 O 3，NO 2）。底物包括例如具有次甲基碳原子的化合物（例如金刚烷），在芳环的相邻部分具有甲基或亚甲基的化合物。根据这种反应，即使在温和或中等条件下，底物也能被有效地硝化或羧化。

2. 发明授权

US5956657A Method for producing nitro compounds 失效
标题翻译：硝基化合物的制备方法
公开(公告)号：US5956657A
公开(公告)日：1999-09-21
申请号：US997585
申请日：1997-12-23
申请人： Tatsuya Nakano , Satoshi Sakaguchi , Yasutaka Ishii
发明人： Tatsuya Nakano , Satoshi Sakaguchi , Yasutaka Ishii
IPC分类号： C07B43/02 , C07C201/08 , C07C205/04 , C07C205/05 , C07C205/00
CPC分类号： C07B43/02 , C07C201/08 , C07C2103/74
摘要： The method provides nitro compounds at a high conversion and selectivity by nitrating substrates under comparatively mild conditions in the absence of catalysts. Organic substrates are nitrated using no catalysts or ozone, but using (1) at least one nitrogen compound selected from N.sub.2 O or NO and oxygen. It is advantageous for the nitration reaction to employ a nitrogen compound obtained by a reaction of the nitrogen compound with oxygen, particularly a nitrogen oxide comprising N.sub.2 O.sub.3 as a main component. Additionally, organic substrates are nitrated using (2) NO.sub.2. The substrates include a compound having a methine-carbon atom, and a compound having a methyl group or methylene group in an adjacent position to an aromatic ring.
摘要翻译：该方法通过在不存在催化剂的情况下在相对温和的条件下硝化底物以高转化率和选择性提供硝基化合物。使用没有催化剂或臭氧的有机底物进行硝化，但使用（1）至少一种选自N 2 O或NO的氮化合物和氧气。硝化反应采用氮化合物与氧反应获得的氮化合物，特别是以N 2 O 3为主要成分的氮氧化物是有利的。另外，使用（2）NO2对有机底物进行硝化。底物包括具有次甲基 - 碳原子的化合物和在芳香环相邻位置具有甲基或亚甲基的化合物。

3. 发明授权

US06548713B2 Process for the preparation of organic compounds with manganese catalysts or the like 失效
标题翻译：用锰催化剂等制备有机化合物的方法
公开(公告)号：US06548713B2
公开(公告)日：2003-04-15
申请号：US09959843
申请日：2001-11-09
申请人： Yasutaka Ishii , Takahiro Iwahama , Satoshi Sakaguchi , Tatsuya Nakano
发明人： Yasutaka Ishii , Takahiro Iwahama , Satoshi Sakaguchi , Tatsuya Nakano
IPC分类号： C07C4532
CPC分类号： C07C403/02 , C07C45/33 , C07C45/69 , C07C51/56 , C07C67/347 , C07C253/30 , C07C2601/14 , C07D307/20 , C07D307/33 , C07D307/83 , C07D313/04 , C07C49/413 , C07C49/403 , C07C49/395 , C07C49/82 , C07C49/683 , C07C49/04 , C07C55/21 , C07C69/708 , C07C69/34 , C07C69/716 , C07C255/04
摘要： The process of this invention efficiently produces a compound having an alkyl group or alkenyl group bonded at the alpha position of an electron attractive group, or a derivative thereof, by catalytic radical addition reaction. The process reacts a compound containing an electron attractive group of Formula (1) as defined in the specification with a compound containing an unsaturated carbon-carbon bond of Formula (2) or (7) as defined in the specification to produce a compound of Formula (3) or (8) as defined in the specification. The invention is characterized by carrying out the reaction in the presence of oxygen and a catalytic compound of a Group 7, 8, or 9 element of the Periodic Table of Elements.
摘要翻译：本发明的方法通过催化自由基加成反应有效地生成具有与吸电子基团的α位相连的烷基或链烯基的化合物或其衍生物。该方法将含有本说明书中定义的式（1）的吸电子基团的化合物与含有本说明书中定义的式（2）或（7）的不饱和碳 - 碳键的化合物反应，生成式（3）或（8）。本发明的特征在于在氧的存在下进行反应和元素周期表第7,8或9族元素的催化化合物。

4. 发明授权

US07414160B2 Process for producing aromatic compounds 失效
标题翻译：芳香族化合物的制备方法
公开(公告)号：US07414160B2
公开(公告)日：2008-08-19
申请号：US11311333
申请日：2005-12-20
申请人： Yasutaka Ishii , Tatsuya Nakano
发明人： Yasutaka Ishii , Tatsuya Nakano
IPC分类号： C07C39/205 , C07C39/21 , C07C39/215 , C07C39/225
CPC分类号： C07C37/58 , C07B37/04 , C07C2/76 , C07C41/30 , C07C45/69 , C07C51/367 , C07C67/31 , C07C67/343 , C07C253/30 , C07C2523/44 , C07C2527/19 , C07D307/54 , C07D333/24 , C07C39/04 , C07C39/07 , C07C43/275 , C07C43/2055 , C07C69/84 , C07C69/76 , C07C69/618 , C07C69/65 , C07C255/34 , C07C15/14 , C07C15/52 , C07C65/03 , C07C49/223
摘要： A process produces an aromatic compound by bringing an aromatic compound (B) into contact with molecular oxygen (C) in the presence of a catalyst (A) comprising at least one of (A1) a heteropolyacid and/or a salt thereof, and (A2) a mixture of oxoacids and/or salts thereof containing, as a whole, one of P and Si and at least one selected from V, Mo and W to thereby yield another aromatic compound (G) than the aromatic compound (B). The process can produce, for example, a corresponding aromatic hydroxy compound (G1) by allowing the aromatic compound (B) to react with the molecular oxygen (C) further in the presence of a reducing agent (D).
摘要翻译：一种方法是在芳族化合物（B）与分子氧（C）接触的情况下，在包含（A1）杂多酸和/或其盐中的至少一种的催化剂（A）存在下，和（ A2）含有氧和/或其盐的混合物，其总体上含有P和Si中的一种以及选自V，Mo和W中的至少一种，从而得到除芳香族化合物（B）以外的其它芳香族化合物（G）。该方法可以通过在还原剂（D）的存在下使芳族化合物（B）与分子氧（C）进一步反应而生成相应的芳香族羟基化合物（G1）。

5. 发明授权

US07304184B2 Process for producing allyl-containing compounds 失效
标题翻译：生产含烯丙基化合物的方法
公开(公告)号：US07304184B2
公开(公告)日：2007-12-04
申请号：US10786104
申请日：2004-02-26
申请人： Yasutaka Ishii , Takahiro Iwahama , Tatsuya Nakano
发明人： Yasutaka Ishii , Takahiro Iwahama , Tatsuya Nakano
IPC分类号： C07C41/00 , C07C319/00
CPC分类号： C07C41/16 , C07C67/10 , C07C319/14 , C07C2603/74 , C07C69/78 , C07C321/18 , C07C43/15 , C07C43/178 , C07C43/188 , C07C43/215 , C07C43/166
摘要： An allyl-containing compound represented by following Formula (3): wherein R2, R3, R4, R5 and R6 may be the same as or different from one another and each represent hydrogen atom or an organic group; R7 represents an organic group; and Y represents oxygen atom or sulfur atom, is produced by reacting an allyl ester compound represented by following Formula (1): wherein R1 represents hydrogen atom or an organic group; and R2, R3, R4, R5 and R6 are as defined above, with a compound represented by following Formula (2): R7—Y—H (2) wherein R7 is an organic group; and Y is as defined above, in the presence of at least one transition element compound.
摘要翻译：由下式（3）表示的含烯丙基的化合物：

6. 发明授权

US07271285B2 Process for producing aromatic carboxylic acids 失效
标题翻译：芳香族羧酸的制造方法
公开(公告)号：US07271285B2
公开(公告)日：2007-09-18
申请号：US10785982
申请日：2004-02-26
申请人： Yasutaka Ishii , Tatsuya Nakano
发明人： Yasutaka Ishii , Tatsuya Nakano
IPC分类号： C07C51/00 , C07C51/16
CPC分类号： C07C51/145 , B01J23/002 , B01J23/44 , B01J27/199 , B01J2523/00 , C07C65/21 , C07C63/04 , B01J2523/51 , B01J2523/55 , B01J2523/68 , B01J2523/824
摘要： An aromatic compound (C) is reacted with carbon monoxide (D) and molecular oxygen (E) in the presence of a palladium compound catalyst (A) and a catalyst (B) and thereby yields a aromatic carboxylic acid corresponding to the aromatic compound (C) except with one or more carboxyl groups bonded to its aromatic ring. The catalyst (B) contains a heteropolyacid or a salt thereof (B1) or a mixture of oxo acids and/or salts thereof (B2), and the mixture (B2) contains, as a whole, one of P and Si and at least one selected from V, Mo and W.
摘要翻译：在钯化合物催化剂（A）和催化剂（B）的存在下，芳香族化合物（C）与一氧化碳（D）和分子氧（E）反应，得到对应于芳香族化合物的芳香族羧酸（ C），除了一个或多个与其芳香环键合的羧基。催化剂（B）含有杂多酸或其盐（B 1）或其含氧酸和/或其盐的混合物（B 2），并且混合物（B 2）总体上含有P和Si 和选自V，Mo和W中的至少一种。

7. 发明申请

US20060106261A1 Process for producing aromatic compounds 失效
公开(公告)号：US20060106261A1
公开(公告)日：2006-05-18
申请号：US11311333
申请日：2005-12-20
申请人： Yasutaka Ishii , Tatsuya Nakano
发明人： Yasutaka Ishii , Tatsuya Nakano
IPC分类号： C07C37/58
CPC分类号： C07C37/58 , C07B37/04 , C07C2/76 , C07C41/30 , C07C45/69 , C07C51/367 , C07C67/31 , C07C67/343 , C07C253/30 , C07C2523/44 , C07C2527/19 , C07D307/54 , C07D333/24 , C07C39/04 , C07C39/07 , C07C43/275 , C07C43/2055 , C07C69/84 , C07C69/76 , C07C69/618 , C07C69/65 , C07C255/34 , C07C15/14 , C07C15/52 , C07C65/03 , C07C49/223
摘要： A process produces an aromatic compound by bringing an aromatic compound (B) into contact with molecular oxygen (C) in the presence of a catalyst (A) comprising at least one of (A1) a heteropolyacid and/or a salt thereof, and (A2) a mixture of oxoacids and/or salts thereof containing, as a whole, one of P and Si and at least one selected from V, Mo and W to thereby yield another aromatic compound (G) than the aromatic compound (B). The process can produce, for example, a corresponding aromatic hydroxy compound (G1) by allowing the aromatic compound (B) to react with the molecular oxygen (C) further in the presence of a reducing agent (D).

8. 发明授权

US06489504B2 Malic acid and oxalacetic acid derivatives 失效
标题翻译：苹果酸和草乙酸衍生物
公开(公告)号：US06489504B2
公开(公告)日：2002-12-03
申请号：US09801648
申请日：2001-03-09
申请人： Yasutaka Ishii , Tatsuya Nakano
发明人： Yasutaka Ishii , Tatsuya Nakano
IPC分类号： C07C6521
CPC分类号： C07C69/716 , C07C69/675 , C07C2603/00 , C07C2603/74
摘要： A malic acid or oxalacetic acid derivative is represented by the following formula (1): wherein ring Z is an alicyclic carbon ring; each of Ra and Rb is independently a hydrogen atom, a metal atom, or an organic group; and Y is a hydroxyl group or an oxygen atom, where ring Z is a bridged carbon ring or a monocyclic carbon ring having eight or more members when Y is an oxygen atom. The alicyclic carbon ring includes, for example, cyclooctane ring and adamantane ring. This compound is a novel malic acid derivative having an alicyclic group bonded to a carbon atom at the 3-position, or a novel oxalacetic acid derivative having a specific alicyclic group bonded to a carbon atom at the 3-position.
摘要翻译：苹果酸或草乙酸衍生物由下式（1）表示：其中环Z是脂环碳环; Ra和Rb各自独立地为氢原子，金属原子或有机基团; Y为羟基或氧原子，当Y为氧原子时，其中环Z为桥碳环或具有8个以上成员的单环碳环。脂环碳环包括例如环辛烷环和金刚烷环。该化合物是具有与3-位上的碳原子键合的脂环基的新型苹果酸衍生物，或具有与3-位上的碳原子键合的特定脂环基的新型草乙酸衍生物。

9. 发明授权

US06235851B1 Polymerizable adamantane derivatives and process for producing the same 失效
标题翻译：可聚合的金刚烷衍生物及其制备方法
公开(公告)号：US06235851B1
公开(公告)日：2001-05-22
申请号：US09214724
申请日：1999-01-11
申请人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
IPC分类号： C08F2000
CPC分类号： C07C67/03 , C07C2603/74 , C07C69/54
摘要： A compound shown by the following formula: wherein each of R1a, R2a, R3a and R4a represents a substituent selected from a non-reactive atom, a non-reactive group, a hydroxyl group and an amino group, and at least two members selected from R1a, R2a, R3a and R4a are a hydroxyl group, a carboxyl group or an amino group; is subjected to an esterification reaction or an amidation reaction with a polymerizable unsaturated compound (e.g., an alcohol, a carboxylic acid, an amine) in the presence of a catalyst comprising an element selected from the Group 3 elements, such as a samarium compound, to obtain a polymerizable adamantane derivative having at least one polymerizable unsaturated group in high yield.
摘要翻译：下式表示的化合物：其中R1a，R2a，R3a和R4a各自表示选自非反应性原子，非反应性基团，羟基和氨基的取代基，以及选自以下的至少两种： R1a，R2a，R3a和R4a是羟基，羧基或氨基; 在包含选自第3族元素的元素如钐化合物的催化剂存在下，与可聚合不饱和化合物（例如醇，羧酸，胺）进行酯化反应或酰胺化反应，以高收率得到具有至少一个聚合性不饱和基团的聚合性金刚烷衍生物。

10. 发明授权

US07741514B2 Catalyst comprising N-substituted cyclic imide compound and process for producing organic compound using the catalyst 失效
标题翻译：包含N-取代的环状酰亚胺化合物的催化剂和使用该催化剂制备有机化合物的方法
公开(公告)号：US07741514B2
公开(公告)日：2010-06-22
申请号：US11504019
申请日：2006-08-15
申请人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
IPC分类号： C07C63/00 , C07C51/16 , C07C51/00 , C07D207/00
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

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