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    • 5. 发明授权
    • Method of preparing disilanol compound and method of storing disilanol compound
    • 制备二硅烷醇化合物的方法和二硅烷醇化合物的储存方法
    • US08247592B2
    • 2012-08-21
    • US13111647
    • 2011-05-19
    • Yasunori SakanoTakashi MatsudaNoriyuki Koike
    • Yasunori SakanoTakashi MatsudaNoriyuki Koike
    • C07F7/08
    • C07F7/0836C08G65/007C08G65/336
    • Disclosed is a method of storing a fluorine-containing disilanol compound represented by the following formula (3) in the presence of a tertiary amine in such an amount that a molar ratio of the tertiary amine to a silanol group of the fluorine-containing disilanol compound ranges from 0.001 to 20, HO—Z—R1—Rf—R1—Z—OH  (3) wherein Rf is a divalent fluorinated hydrocarbon group or a divalent fluorinated polyether group, R1 may be the same with or different from each other and is a substituted or unsubstituted divalent hydrocarbon group which may have at least one atom selected from the group consisting of oxygen, nitrogen, silicon, and sulfur atoms, and Z is a group represented by the following formula (2) —SiR2R3—  (2) wherein R2 and R3 may be the same with or different from each other and are monovalent organic groups.
    • 本发明公开了一种在叔胺存在下,使下式(3)表示的含氟二硅烷醇化合物的存在量使得含氟二硅烷醇化合物的叔胺与硅烷醇基的摩尔比 范围为0.001〜20,HO-Z-R1-Rf-R1-Z-OH(3)其中Rf为二价氟化烃基或二价氟化聚醚基,R 1可以相同或不同, 可以具有选自氧,氮,硅和硫原子中的至少一个原子的取代或未取代的二价烃基,Z是由下式(2)-SiR 2 R 3 - (2)表示的基团,其中 R2和R3可以彼此相同或不同,并且是一价有机基团。
    • 8. 发明授权
    • Fluorine-containing curable composition
    • 含氟可固化组合物
    • US08236195B2
    • 2012-08-07
    • US12351651
    • 2009-01-09
    • Yasunori SakanoNoriyuki Koike
    • Yasunori SakanoNoriyuki Koike
    • C09K3/00C08G59/00C08G59/40C08G59/50C08G59/62
    • C08G65/007C08G59/504C08G65/33317C08G2650/48C08L63/00C08L71/02C08L2666/22
    • A fluorine-containing curable composition containing (A) A fluorine-containing amino compound having primary or secondary amino groups at both ends, said compound being represented by the formula (1): Y-Q-Rf—(X—Rf)n-Q-Y  (1) wherein Rf is a divalent perfluorooxyalkylene group, each Q is independently a divalent organic group having 1 to 20 carbon atoms and, optionally, containing an oxygen atom and/or a nitrogen atom, X is a divalent organic group having 1 to 20 carbon atoms and, optionally, containing an oxygen atom and/or a nitrogen atom, Y is an organic group having a primary or secondary amino group and 1 to 20 carbon atoms and, optionally, containing an oxygen atom, and n is an integer of from 1 to 20, (B) An epoxy compound having at least two epoxy groups in a molecule, in an amount such that the amount of the epoxy groups is 0.1 to 10 moles per mole of the amino groups of component (A), and (C) At least one alcohol containing fluorine atoms and represented by the following formula (2) in an amount such that the amount of the alcoholic hydroxyl group is 0.001 to 0.5 mole per mole of the amino groups of component (A): Rf′(CH2OH)m (2), wherein m is an integer of 1 or 2, Rf′ is a monovalent or divalent group containing 2 to 300 fluorine atoms, and at least one fluorine atom or at least one trifluoromethyl group is bonded to a carbon atom to which site the methylol group is bonded.
    • 一种含有(A)在两端具有伯氨基或仲氨基的含氟氨基化合物的含氟可固化组合物,所述化合物由式(1)表示:YQ-Rf-(X-Rf)nQY(1) 其中Rf是二价全氟氧化烯基,每个Q独立地是具有1至20个碳原子的二价有机基团,并且任选地含有氧原子和/或氮原子,X是具有1至20个碳原子的二价有机基团, ,任选地含有氧原子和/或氮原子,Y是具有伯或仲氨基和1至20个碳原子的有机基团,并且任选地含有氧原子,n是1至 20,(B)分子中具有至少两个环氧基的环氧化合物,其量使得每摩尔组分(A)的氨基的环氧基的量为0.1-10摩尔,和(C) 至少含有一个含氟原子的醇,由以下代表 (2)的量,使得醇羟基的量相对于组分(A)的每摩尔摩尔数为0.001至0.5摩尔:Rf'(CH 2 OH)m(2),其中m为 1或2中,Rf'是含有2〜300个氟原子的一价或二价基团,并且至少一个氟原子或至少一个三氟甲基与键合有羟甲基的位置的碳原子键合。