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1. 发明申请

US20120077041A1 FLUOROOXYALKYLENE GROUP-CONTAINING POLYMER COMPOSITION, A SURFACE TREATMENT AGENT COMPRISING THE SAME AND AN ARTICLE TREATED WITH THE AGENT 有权
标题翻译：包含含氟聚合物的含聚合物组合物，包含该聚合物组合物的表面处理剂和与该试剂一起处理的物品
公开(公告)号：US20120077041A1
公开(公告)日：2012-03-29
申请号：US13226987
申请日：2011-09-07
申请人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
发明人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C08L71/00 , C08L67/00 , B32B27/32 , C09D171/00
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

2. 发明授权

US08900711B2 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译：含有含氟氧化烯基的聚合物组合物，包含该组合物的表面处理剂和用该试剂处理的制品
公开(公告)号：US08900711B2
公开(公告)日：2014-12-02
申请号：US13226987
申请日：2011-09-07
申请人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
发明人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C08L71/00 , C08G65/336 , C08G65/00 , C08G77/24 , C08G77/46 , C09D171/02
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

3. 发明申请

US20100317875A1 PERFLUOROPOLYETHER GROUP-CONTAINING ACRYLATE COMPOUND 有权
标题翻译：全氟聚醚基团含丙烯酸酯化合物
公开(公告)号：US20100317875A1
公开(公告)日：2010-12-16
申请号：US12797103
申请日：2010-06-09
申请人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07D307/04 , C07F7/10
CPC分类号： C08G77/50 , C07F7/21 , C08F230/08 , C08G77/388 , C08G77/46 , C09D183/12 , C09D183/14
摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1 (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.
摘要翻译：本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

4. 发明授权

US08283480B2 Perfluoropolyether group-containing acrylate compound 有权
标题翻译：含全氟聚醚基团的丙烯酸酯化合物
公开(公告)号：US08283480B2
公开(公告)日：2012-10-09
申请号：US12797103
申请日：2010-06-09
申请人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07F7/21 , C07F7/08 , C07F7/10
CPC分类号： C08G77/50 , C07F7/21 , C08F230/08 , C08G77/388 , C08G77/46 , C09D183/12 , C09D183/14
摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1 (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.
摘要翻译：本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

5. 发明授权

US06552152B2 Curable fluoropolyether rubber compositions 有权
公开(公告)号：US06552152B2
公开(公告)日：2003-04-22
申请号：US09893603
申请日：2001-06-29
申请人： Yasunori Sakano , Shinichi Sato , Koichi Yamaguchi , Noriyuki Koike , Masatoshi Arai , Hirofumi Kishita
发明人： Yasunori Sakano , Shinichi Sato , Koichi Yamaguchi , Noriyuki Koike , Masatoshi Arai , Hirofumi Kishita
IPC分类号： C08G7712
CPC分类号： C08G65/336 , C08G65/007
摘要： A curable fluoropolyether rubber composition comprising (A) a straight-chain fluoropolyether compound having at least two alkenyl groups and a perfluoropolyether structure backbone, (B) an organosilicon compound having at least two silicon atom-bonded hydrogen atoms, which all form H—SiCH2— structures, and (C) a hydrosilylation catalyst cures into parts which have good heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency and weather resistance as well as improved acid and alkali resistance and are useful as sealants.

6. 发明申请

US20070149746A1 Fluorine-containing organopolysiloxane, a surface treatment composition comprising the same and an article treated with the composition 有权
公开(公告)号：US20070149746A1
公开(公告)日：2007-06-28
申请号：US11643988
申请日：2006-12-22
申请人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
发明人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/24
CPC分类号： C08G77/385 , C07F7/21 , C08G77/50 , Y10T428/31663
摘要： An organopolysiloxane represented by the following general formula (A), (B) or (C) SinR12n+2On−1 (A) SinR12nOn (B) SinR12n+2R2kOn−k (C) wherein R1 may be the same with or different from each other and is a hydrogen atom or a monovalent organic group, R2 is an alkylene group having 2 to 6 carbon atoms, n is an integer of from 2 to 40 and k is an integer of 1 to 3, characterized in that at least two R1's are represented by the following formula (i): wherein X is a hydrolyzable group, R3 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, y is an integer of from 1 to 5 and a is 2 or 3; and one SiR1 bond is represented by the following formula (ii) or one SiOSi bond is replaced with a bond represented by the following formula (iii): SiQRf1 (ii) SiQRf2QSi (iii) wherein Rf1 is a monovalent group containing a perfluoroether residue, Rf is a divalent group containing a perfluoroether residue, and Q is a divalent organic group.

7. 发明授权

US08420763B2 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译：含有含氟氧化烯基的聚合物组合物，包含该组合物的表面处理剂和用该试剂处理的制品
公开(公告)号：US08420763B2
公开(公告)日：2013-04-16
申请号：US12911890
申请日：2010-10-26
申请人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
发明人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C08G77/24
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.
摘要翻译：本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性，良好的耐污染性，并提供包含该表面处理剂的表面处理剂。本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

8. 发明授权

US08362186B2 Coating composition and a coating therefrom having waterdrop sliding property 有权
标题翻译：涂料组合物及其具有水滑滑性的涂层
公开(公告)号：US08362186B2
公开(公告)日：2013-01-29
申请号：US12167873
申请日：2008-07-03
申请人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
发明人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/24
CPC分类号： C08L83/12 , C09D183/12 , Y10T428/31663
摘要： A coating composition comprising a fluorine-containing silicon compound represented by the following formula (1) wherein Z is a linear or branched divalent polyorganosiloxane residue having 1 to 40 siloxane units, R is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, Q is a C2-12 divalent connecting group, a is an integer of 2 or 3, b is an integer of from 1 to 10, y is an integer of 1 to 5, and Rf is a group represented by the following formula (2) -Rf1-(Q-W-Q-Rf1)q- (2) wherein Rf1 is a perfluoropolyether residue, W is an organopolysiloxane residue having 1 to 40 siloxane units and Q is as defined above and may be the same with or different from each other, and q is an integer of from 0 to 3, and at least one solvent selected from the group consisting of alcohols, esters, ethers, ketones, and perfluoroethers. The coating prepared from the composition is oil-repellent, water-repellent and has water sliding property.
摘要翻译：一种涂料组合物，其包含由下式（1）表示的含氟硅化合物，其中Z为具有1至40个硅氧烷单元的直链或支链二价聚有机硅氧烷残基，R为具有1至4个碳原子的烷基或苯基 X为水解性基团，Q为C2-12二价连接基团，a为2或3的整数，b为1〜10的整数，y为1〜5的整数，Rf为基团由下式（2）-Rf1-（QWQ-Rf1）q-（2）表示，其中Rf1是全氟聚醚残基，W是具有1至40个硅氧烷单元的有机聚硅氧烷残基，Q如上定义并且可以相同 q为0〜3的整数，以及选自醇，酯，醚，酮，全氟醚中的至少一种溶剂。由该组合物制备的涂料具有防油，防水，具有水滑动性。

9. 发明申请

US20110098402A1 FLUOROOXYALKYLENE GROUP-CONTAINING POLYMER COMPOSITION, A SURFACE TREATMENT AGENT COMPRISING THE SAME AND AN ARTICLE TREATED WITH THE AGENT 有权
标题翻译：包含含氟聚合物的含聚合物组合物，包含该聚合物组合物的表面处理剂和与该试剂一起处理的物品
公开(公告)号：US20110098402A1
公开(公告)日：2011-04-28
申请号：US12911890
申请日：2010-10-26
申请人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
发明人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C09D127/12
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.
摘要翻译：本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性，良好的耐污染性，并提供包含该表面处理剂的表面处理剂。本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

10. 发明授权

US07794843B2 Fluorine-containing organopolysiloxane, a surface treatment composition comprising the same and an article treated with the composition 有权
标题翻译：含氟有机聚硅氧烷，包含其的表面处理组合物和用该组合物处理的制品
公开(公告)号：US07794843B2
公开(公告)日：2010-09-14
申请号：US11643988
申请日：2006-12-22
申请人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
发明人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/46
CPC分类号： C08G77/385 , C07F7/21 , C08G77/50 , Y10T428/31663
摘要： An organopolysiloxane represented by the following general formula (A), (B) or(C) SinR12n+2On−1 (A) SinR12nOn (B) SinR12n+2R2kOn−k (C) wherein R1 may be the same with or different from each other and is a hydrogen atom or a monovalent organic group, R2 is an alkylene group having 2 to 6 carbon atoms, n is an integer of from 2 to 40 and k is an integer of 1 to 3, characterized in that at least two R1's are represented by the following formula (i): wherein X is a hydrolyzable group, R3 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, y is an integer of from 1 to 5 and a is 2 or 3; and one SiOSi bond is replaced with a bond represented by the following formula (iii): SiQRf2QSi (iii) wherein Rf1 is a monovalent group containing a perfluoroether residue, Rf2 is a divalent group containing a perfluoroether residue, and Q is a divalent organic group.
摘要翻译：由以下通式（A），（B）或（C）表示的有机聚硅氧烷SinR12n + 2On-1（A）SinR12nOn（B）SinR12n + 2R2kOn-k（C）其中R1可以相同或不同另一个是氢原子或一价有机基团，R 2是具有2至6个碳原子的亚烷基，n是2至40的整数，k是1至3的整数，其特征在于，至少两个R 1的由下式（i）表示：其中X是可水解基团，R 3是具有1至4个碳原子的烷基或苯基，y是1至5的整数，a是2或3; 并且一个SiOSi键用下式（ⅲ）表示的键代替：SiQRf2QSi（ⅲ）其中Rf1是含有全氟醚残基的一价基团，Rf2是含有全氟醚残基的二价基团，Q是二价有机基团。

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