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    • 6. 发明授权
    • Method for surface modification and apparatus therefor
    • 表面改性方法及其设备
    • US5246741A
    • 1993-09-21
    • US630858
    • 1990-12-20
    • Koukichi OuhataKenichi Natsui
    • Koukichi OuhataKenichi Natsui
    • C01F7/02C04B35/10C04B41/00C04B41/80C23C14/22C23C14/48
    • C04B41/009C04B41/0027C04B41/80C23C14/22C23C14/48
    • A substrate to be modified is placed in a vacuum vessel, a reducing atmosphere is provided over the substrate and simultaneously therewith the substrate is irradiated with accelerated ions, whereby oxygen which bonds to the substrate is freed from the substrate, the oxygen bonds to a material which forms the reducing atmosphere and the surface of the substrate is modified by the accelerated ion. The surface of the substrate can be thus efficiently modifed at relatively low temperatures. Furthermore, by evaporating carbon for an alumina substrate or alumina powder or providing hydrocarbon gas over the alumina substrate or alumina powder in a vacuum vessel, the alumina substrate or alumina powder is providing in the reducing atmosphere and the alumina substrate or alumina powder is irradiated with accelerated nitrogen ions from an ion source, whereby aluminum and oxygen which constitute the alumina substrate or alumina powder are cut off from each other by irradiation with the accelerated nitrogen ions. The oxygen reacts with carbon or hydrocarbon gas which forms the reducing atmosphere to form carbon monoxide or carbon dioxide, which is evacuated. On the other hand, the aluminum is modified to aluminum nitride by the accelerated nitrogen ions or nitrogen particles. That is, the surface of the alumina substrate or alumina powder can be efficiently modifed at relatively low temperatures.
    • 将待改性的基板放置在真空容器中,在基板上设置还原气氛,同时衬底被加速离子照射,由此与基板结合的氧离开基板,氧键连接到材料 其形成还原气氛,并且基板的表面被加速离子改性。 因此,可以在较低温度下有效地修改基板的表面。 此外,通过蒸发氧化铝基体或氧化铝粉末的碳或在真空容器中的氧化铝基体或氧化铝粉末上提供烃气体,在还原气氛中提供氧化铝基体或氧化铝粉末,并且将氧化铝基体或氧化铝粉末照射 从离子源加速氮离子,由此通过加速的氮离子的照射将构成氧化铝基体或氧化铝粉末的铝和氧彼此切断。 氧气与形成还原气氛的碳或烃气体反应形成一氧化碳或二氧化碳,其被排空。 另一方面,通过加速的氮离子或氮颗粒将铝改性成氮化铝。 也就是说,氧化铝基底或氧化铝粉末的表面可以在相对低的温度下被有效地修饰。