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    • 5. 发明申请
    • COPOLYMER POLYAMIDE
    • 共聚聚酰胺
    • US20130261256A1
    • 2013-10-03
    • US13990937
    • 2012-01-06
    • Shinji IedaKazunori TeradaYu Nitto
    • Shinji IedaKazunori TeradaYu Nitto
    • C08G69/26C08G69/08
    • C08G69/26C08G69/08C08G69/265C08G69/36C08L77/06
    • An object of the present invention is to provide a copolymer polyamide which has excellent strength, high-temperature strength, low water absorbance, low blocking properties, releasability and plasticizing time stability, and a copolymer polyamide composition which has excellent vibration fatigue characteristics, surface appearance and continuous productivity. A copolymer polyamide of the present invention is obtained by polymerizing (a) at least one alicyclic dicarboxylic acid, (b) one diamine having 8 or more carbon atoms, and (c) at least one copolymer component selected from the group consisting of the following (c-1) to (c-3): a (c-1) dicarboxylic acid other than the alicyclic dicarboxylic acid; a (c-2) diamine having fewer carbon atoms than the (b) diamine; and a (c-3) lactam and/or aminocarboxylic acid, and the copolymer polyamide satisfies specific conditions.
    • 本发明的目的是提供一种具有优异的强度,高温强度,低吸水率,低粘连性,脱模性和塑化时间稳定性的共聚物聚酰胺,以及具有优异的振动疲劳特性,表面外观的共聚物聚酰胺组合物 并持续生产力。 通过聚合(a)至少一种脂环族二羧酸,(b)一种具有8个或更多个碳原子的二胺和(c)至少一种选自以下的共聚物组分,获得本发明的共聚物聚酰胺 (c-1)〜(c-3):除脂环族二羧酸以外的(c-1)二羧酸; 具有比(b)二胺更少碳原子的(c-2)二胺; 和(c-3)内酰胺和/或氨基羧酸,共聚物聚酰胺满足特定条件。
    • 9. 发明授权
    • Olefin polymerization catalyst
    • 烯烃聚合催化剂
    • US06214954B1
    • 2001-04-10
    • US08849835
    • 1997-06-12
    • Yu NittoTokitaka KaneshimaToshiya Aoki
    • Yu NittoTokitaka KaneshimaToshiya Aoki
    • C08F442
    • C08F10/00C08F4/65908C08F4/65912C08F4/6592Y10S526/943
    • Disclosed is an olefin polymerization catalyst comprising: a transition metal compound comprising one transition metal selected from the group consisting of Ti, Zr and Hf, and at least two ligands, wherein one ligand is a group having a cyclopentadienyl skeleton, and the remaining at least one ligand is a monovalent, bidentate, anionic chelating ligand having two coordinating atoms each coordinated to the transition metal, one of which atoms is selected from the group consisting of O, S, Se and Te, and the other of which atoms is selected from the group consisting of N, S, Se and Te, and wherein one of the remaining at least one ligand is optionally bonded to the group having a cyclopentadienyl skeleton through a bridging group. Also disclosed is a method for efficiently producing an olefin homopolymer or olefin copolymer by using this catalyst. By polymerizing an olefin using the olefin polymerization catalyst of the present invention, there can be advantageously produced an olefin homopolymer having a narrow molecular weight distribution or an olefin copolymer having not only a narrow molecular weight distribution but also a uniform copolymerization distribution. The produced polymer has high impact strength, high resistance to stress cracking, high transparency, excellent heat sealing properties at low temperatures, high blocking resistance, low tackiness, low extractability and the like.
    • 公开了一种烯烃聚合催化剂,其包括:包含一种选自Ti,Zr和Hf的过渡金属的过渡金属化合物和至少两个配体,其中一个配体是具有环戊二烯基骨架的基团,其余至少 一个配位体是具有两个与过渡金属配位的两个配位原子的单价二齿阴离子螯合配体,其中一个原子选自O,S,Se和Te,其中原子选自 由N,S,Se和Te组成的组,并且其中剩余的至少一种配体之一任选地通过桥连基团与具有环戊二烯基骨架的基团键合。 还公开了通过使用该催化剂有效地制备烯烃均聚物或烯烃共聚物的方法。 通过使用本发明的烯烃聚合催化剂聚合烯烃,可以有利地制备具有窄分子量分布的烯烃均聚物或不仅具有窄分子量分布而且具有均匀共聚分布的烯烃共聚物。 所生产的聚合物具有高冲击强度,高抗应力开裂性,高透明性,低温下的热封性优异性,耐粘连性,低粘性,低萃取性等优异性。