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    • 5. 发明授权
    • Method for producing polyamide masterbatch
    • 聚酰胺母料生产方法
    • US07960451B2
    • 2011-06-14
    • US12296452
    • 2007-04-10
    • Masaaki Aramaki
    • Masaaki Aramaki
    • C08J3/20
    • C08J3/226C08J2377/00C08J2477/00C08K3/08C08L77/00C08L2205/02C08L2666/20
    • A polyamide masterbatch free from metal copper deposition and metal corrosion in an extruder or a molding machine, deterioration in mechanical physical properties of the product, and a color change of appearance due to water absorption and having improved heat aging resistance is produced by mixing, by melt kneading, a) 100 parts by weight of a polyamide having a water content of from 0.05 to 2.0 wt. %, b) from 0.1 to 10 parts by weight of an organic compound having at least one amide group, c) from 0.1 to 5 parts by weight of a copper compound having a maximum particle size of 50 μm or less, and d) from 1 to 50 parts by weight of a halogen compound (with the proviso that a copper halide is excluded) having a maximum particle size of 50 μm or less.
    • 在挤出机或成型机中不含金属铜沉积和金属腐蚀的聚酰胺母料,产品的机械物理性能的劣化以及由吸水引起的外观颜色变化并具有改善的耐热老化性,是通过 熔融捏合,a)100重量份的水含量为0.05-2.0重量%的聚酰胺。 %,b)0.1〜10重量份具有至少一个酰胺基的有机化合物,c)0.1至5重量份最大粒度为50μm或更小的铜化合物,以及d) 1〜50重量份最大粒径为50μm以下的卤素化合物(不含卤化铜)。
    • 6. 发明申请
    • Polyamide composition
    • 聚酰胺组合物
    • US20060142443A1
    • 2006-06-29
    • US10520629
    • 2003-07-09
    • Masaaki AramakiAsami Ohashi
    • Masaaki AramakiAsami Ohashi
    • C08K5/49C04B26/06
    • C08K3/32C08L77/00
    • A polyamide composition has (a) a polyamide, (b) at least one phosphorus compound selected from the group consisting of phosphoric acids, phosphorous acids, hypophosphorous acids, metal phosphates, metal phosphites, metal hypophosphites, phosphoric esters, and phosphorous esters, and (c) a soluble metal aluminate compound represented by the general formula (M2O)x(Al2O3)y (wherein X+Y=1 and M is a Group 1 metal of the Periodic Table), wherein the molar ratio of polyvalent metal to monovalent metal in the composition (polyvalent metal/monovalent metal) is from 0.25 to 1.0.
    • 聚酰胺组合物具有(a)聚酰胺,(b)至少一种选自磷酸,亚磷酸,次磷酸,金属磷酸盐,金属亚磷酸盐,金属次磷酸盐,磷酸酯和磷酸酯的磷化合物,以及 (c)由通式(M 2 O 2)x(Al 2 O 3)3表示的可溶性金属铝酸盐化合物, (其中X + Y = 1,M是元素周期表的第1族金属),其中组成中的多价金属与一价金属的摩尔比(多价金属/一价金属 )为0.25〜1.0。
    • 7. 发明授权
    • Polyamide resin composition and process for producing the same
    • 聚酰胺树脂组合物及其制造方法
    • US06506826B1
    • 2003-01-14
    • US09529965
    • 2000-04-24
    • Masaaki AramakiKatsushi Watanabe
    • Masaaki AramakiKatsushi Watanabe
    • C08K332
    • C08K3/32C08L77/00
    • A polyamide resin composition which contains 0.5 to 50 wt. % of an apatite type compound and which, when eluted with a phenol solvent and filtered, leaves 1 to 100 parts by weight of residual organic substances per 100 parts by weight of the apatite type compound has high strength and rigidity and is excellent in toughness. Moreover, the composition is reduced in water absorption and warpage and is excellent in rigidity upon water absorption, heat resistance, creep resistance, dimensional stability and moldability. Thus, the composition is suitable for use as an industrial material for producing mechanical parts, electrical/electronic parts, etc.
    • 一种聚酰胺树脂组合物,其含有0.5〜50重量% 磷灰石型化合物的%,当用苯酚溶剂洗脱并过滤时,每100重量份的磷灰石型化合物留下1〜100重量份的残留有机物质,其强度和刚性高,韧性优异。 此外,组合物的吸水性和翘曲性降低,并且在吸水性,耐热性,耐蠕变性,尺寸稳定性和成型性方面的刚性优异。 因此,该组合物适合用作生产机械部件,电气/电子部件等的工业材料。
    • 8. 发明申请
    • METHOD FOR PRODUCING POLYAMIDE MASTERBATCH
    • 生产聚酰胺主板的方法
    • US20090281210A1
    • 2009-11-12
    • US12296452
    • 2007-04-10
    • Masaaki Aramaki
    • Masaaki Aramaki
    • C08J3/22C08K3/10
    • C08J3/226C08J2377/00C08J2477/00C08K3/08C08L77/00C08L2205/02C08L2666/20
    • A polyamide masterbatch free from metal copper deposition and metal corrosion in an extruder or a molding machine, deterioration in mechanical physical properties of the product, and a color change of appearance due to water absorption and having improved heat aging resistance is produced by mixing, by melt kneading, a) 100 parts by weight of a polyamide having a water content of from 0.05 to 2.0 wt. %, b) from 0.1 to 10 parts by weight of an organic compound having at least one amide group, c) from 0.1 to 5 parts by weight of a copper compound having a maximum particle size of 50 μm or less, and d) from 1 to 50 parts by weight of a halogen compound (with the proviso that a copper halide is excluded) having a maximum particle size of 50 μm or less.
    • 在挤出机或成型机中不含金属铜沉积和金属腐蚀的聚酰胺母料,产品的机械物理性能的劣化以及由吸水引起的外观颜色变化并具有改善的耐热老化性,是通过 熔融捏合,a)100重量份的水含量为0.05-2.0重量%的聚酰胺。 %,b)0.1〜10重量份具有至少一个酰胺基的有机化合物,c)0.1至5重量份最大粒径为50微米或更小的铜化合物,和d) 1〜50重量份最大粒径为50μm以下的卤素化合物(不含卤化铜)。
    • 10. 发明授权
    • Polyamide resin composition
    • 聚酰胺树脂组合物
    • US06890984B2
    • 2005-05-10
    • US09958982
    • 2001-02-15
    • Masaaki AramakiKatsushi WatanabeIkutoshi Nakashima
    • Masaaki AramakiKatsushi WatanabeIkutoshi Nakashima
    • C08K3/32C08K5/098
    • C08K3/32C08K5/098C08L77/00
    • The present invention provides a polyamide resin composition suitable as industrial materials such as automobile parts, electronic or electrical parts, and industrial machine parts, and excellent in various mechanical properties such as various kinds of moldability, rigidity, and strength, and durability such as heat-resistant aging property.Namely, the invention relates to a polyamide resin composition comprising (A) a polyamide, (B) an apatite type compound, and (C) (i) a higher fatty acid metal salt and/or (ii) a mixture of a metal halide and a copper compound, wherein the polyamide resin composition is obtainable by adding component (C) after the formation of the apatite type compound.
    • 本发明提供一种适合作为汽车部件,电子部件,工业机械部件等工业材料的聚酰胺树脂组合物,各种成形性,刚性和强度等各种机械性能以及耐热性 耐老化性能。 即,本发明涉及一种聚酰胺树脂组合物,其包含(A)聚酰胺,(B)磷灰石型化合物和(C)(i)高级脂肪酸金属盐和/或(ii)金属卤化物 和铜化合物,其中聚酰胺树脂组合物可以通过在形成磷灰石型化合物之后添加组分(C)而获得。