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1. 发明授权

US07247598B2 Nano-scale magnetic solid base catalyst and its preparation method 失效
标题翻译：纳米磁性固体碱催化剂及其制备方法
公开(公告)号：US07247598B2
公开(公告)日：2007-07-24
申请号：US11040408
申请日：2005-01-21
申请人： Xue Duan , Hui Zhang , Rong Qi
发明人： Xue Duan , Hui Zhang , Rong Qi
IPC分类号： B01J23/00
CPC分类号： B01J37/03 , B01J23/002 , B01J23/74 , B01J35/0013 , B01J35/0033 , B01J37/0036 , B01J2523/00 , Y10S502/524 , Y10T428/2993 , B01J2523/22 , B01J2523/31 , B01J2523/842 , B01J2523/847 , B01J2523/27
摘要： This invention describes a nano-scale magnetic solid base catalyst and its preparation method. The catalyst involves a magnetic core coated with a solid base active layer. The synthesis of the nano-scale magnetic cores was first carried out using a rapid nucleation method in a colloid mill reactor using a liquid-liquid reaction. The nano-scale magnetic cores were mixed with a mixed salt solution. The LDH-containing magnetic cores were prepared in a colloid mill reactor by a rapid nucleation method, and subsequently calcined to give a solid base mixed oxides coated on magnetic cores. The characteristics of this catalyst are: nano-scale, high surface area and high activity and selectivity in base-catalyzed reactions. The highly dispersed catalyst can be easily reclaimed using an external magnetic field because of its magnetism. The catalyst can be utilized in base catalysis in organic reactions such as glycol ether synthesis, ester exchange, aldol condensation, etc.
摘要翻译：本发明描述了一种纳米级磁性固体碱催化剂及其制备方法。催化剂包括涂覆有固体碱性活性层的磁芯。首先使用液 - 液反应在胶体磨反应器中使用快速成核法进行纳米级磁芯的合成。将纳米级磁芯与混合盐溶液混合。通过快速成核法在胶体磨反应器中制备含LDH的磁芯，随后煅烧，得到涂覆在磁芯上的固体基础混合氧化物。该催化剂的特征是：纳米级，高表面积，碱催化反应中的高活性和选择性。高度分散的催化剂由于其磁性而可以使用外部磁场容易地回收。催化剂可用于有机反应的碱催化，如二醇醚合成，酯交换，醛醇缩合等。

2. 发明申请

US20050130838A1 Nano-scale magnetic solid base catalyst and its preparatiion method 失效
标题翻译：纳米级磁性固体碱催化剂及其制备方法
公开(公告)号：US20050130838A1
公开(公告)日：2005-06-16
申请号：US11040408
申请日：2005-01-21
申请人： Xue Duan , Hui Zhang , Rong Qi
发明人： Xue Duan , Hui Zhang , Rong Qi
IPC分类号： B01J23/00 , B01J23/74 , B01J35/00 , B01J37/00 , B01J37/03 , B01J23/78
CPC分类号： B01J37/03 , B01J23/002 , B01J23/74 , B01J35/0013 , B01J35/0033 , B01J37/0036 , B01J2523/00 , Y10S502/524 , Y10T428/2993 , B01J2523/22 , B01J2523/31 , B01J2523/842 , B01J2523/847 , B01J2523/27
摘要： This invention describes a nano-scale magnetic solid base catalyst and its preparation method. The catalyst involves a magnetic core coated with a solid base active layer. The synthesis of the nano-scale magnetic cores was first carried out using a rapid nucleation method in a colloid mill reactor using a liquid-liquid reaction. The nano-scale magnetic cores were mixed with a mixed salt solution. The LDH-containing magnetic cores were prepared in a colloid mill reactor by a rapid nucleation method, and subsequently calcined to give a solid base mixed oxides coated on magnetic cores. The characteristics of this catalyst are: nano-scale, high surface area and high activity and selectivity in base-catalyzed reactions. The highly dispersed catalyst can be easily reclaimed using an external magnetic field because of its magnetism. The catalyst can be utilized in base catalysis in organic reactions such as glycol ether synthesis, ester exchange, aldol condensation, etc.
摘要翻译：本发明描述了一种纳米级磁性固体碱催化剂及其制备方法。催化剂包括涂覆有固体碱性活性层的磁芯。首先使用液 - 液反应在胶体磨反应器中使用快速成核法进行纳米级磁芯的合成。将纳米级磁芯与混合盐溶液混合。通过快速成核法在胶体磨反应器中制备含LDH的磁芯，随后煅烧，得到涂覆在磁芯上的固体基础混合氧化物。该催化剂的特征是：纳米级，高表面积，碱催化反应中的高活性和选择性。高度分散的催化剂由于其磁性而可以使用外部磁场容易地回收。催化剂可用于有机反应的碱催化，如二醇醚合成，酯交换，醛醇缩合等。

3. 发明授权

US08765632B2 Process for preparing catalyst comprising palladium supported on carrier with high dispersion 有权
标题翻译：制备催化剂的方法，所述催化剂包含负载在高分散体载体上的钯
公开(公告)号：US08765632B2
公开(公告)日：2014-07-01
申请号：US13128546
申请日：2009-06-25
申请人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
发明人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
IPC分类号： B01J23/00 , B01J23/02 , B01J23/08 , B01J23/40 , B01J23/42 , B01J23/44 , B01J20/00 , B01J21/04 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： B01J23/007 , B01J23/44 , B01J23/58 , B01J23/892 , B01J23/8926 , B01J35/008 , B01J37/0201 , B01J37/18 , C01F7/005 , C01P2002/22 , C07C67/303 , C07C2601/14 , C07C69/75
摘要： A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of A12O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later. The process has the advantages of improving the catalytic performance of the catalyst, enhancing the stability of the catalyst, and achieving the object of reducing the consumption of the precious metal-palladium.
摘要翻译：一种制备催化剂的方法，所述催化剂包含通过层状前体负载在载体上的钯，其包括以下步骤：（1）合成水滑石层状前体，其包括在A12O3微球载体的表面上促进金属元素和铝，由于水滑石晶体的晶格定位效应，促进金属和铝彼此高度分散并牢固地结合到载体上; （2）通过浸渍将钯引入载体; （3）干燥; 和（4）用H 2煅烧和还原，水滑石层状前体被转化为由促进金属和铝的氧化物组成的复合氧化物，并且促进金属元素和铝彼此高度分散，并且能够分离和分散稍后加载的主要活性钯元素。该方法具有提高催化剂的催化性能，提高催化剂稳定性，降低贵金属钯的消耗量的优点。

4. 发明申请

US20110237430A1 PROCESS FOR PREPARING CATALYST COMPRISING PALLADIUM SUPPORTED ON CARRIER WITH HIGH DISPERSION 有权
标题翻译：用于制备包含支持高分散载体的钯催化剂的方法
公开(公告)号：US20110237430A1
公开(公告)日：2011-09-29
申请号：US13128546
申请日：2009-06-25
申请人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
发明人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
IPC分类号： B01J21/04 , B01J37/06 , B01J37/18 , B01J37/08 , B01J35/02 , B01J21/10
CPC分类号： B01J23/007 , B01J23/44 , B01J23/58 , B01J23/892 , B01J23/8926 , B01J35/008 , B01J37/0201 , B01J37/18 , C01F7/005 , C01P2002/22 , C07C67/303 , C07C2601/14 , C07C69/75
摘要： A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of Al2O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later. The process has the advantages of improving the catalytic performance of the catalyst, enhancing the stability of the catalyst, and achieving the object of reducing the consumption of the precious metal-palladium.
摘要翻译：一种制备催化剂的方法，所述催化剂包含通过层状前体负载在载体上的钯，其包括以下步骤：（1）合成水滑石层状前体，其包括在Al 2 O 3微球载体的表面上促进金属元素和铝，由于水滑石晶体的晶格定位效应，促进金属和铝彼此高度分散并牢固地结合到载体上; （2）通过浸渍将钯引入载体; （3）干燥; 和（4）用H 2煅烧和还原，水滑石层状前体被转化为由促进金属和铝的氧化物组成的复合氧化物，并且促进金属元素和铝彼此高度分散，并且能够分离和分散稍后加载的主要活性钯元素。该方法具有提高催化剂的催化性能，提高催化剂稳定性，降低贵金属钯的消耗量的优点。

5. 发明授权

US08298618B2 Preparation method of composite luminescent thin film of sulfonated poly (p-phenylene) and layered double hydroxides 失效
标题翻译：磺化聚（对亚苯基）和层状双氢氧化物复合发光薄膜的制备方法
公开(公告)号：US08298618B2
公开(公告)日：2012-10-30
申请号：US12459795
申请日：2009-07-07
申请人： Dongpeng Yan , Jun Lu , Min Wei , Xue Duan
发明人： Dongpeng Yan , Jun Lu , Min Wei , Xue Duan
IPC分类号： B05D5/00 , B05D7/24 , B05D1/18 , B05D1/38
CPC分类号： C09K11/06 , C09K2211/1408 , H01L51/0038 , H01L51/5032 , H01L51/5278 , H05B33/10
摘要： A preparation method of composite blue luminescent thin film of sulfonated poly(p-phenylene) (i.e. poly[2,5-bis(3-sulfonatopropoxy)-1,4-phenylene-alt-1,4-phenylene]) and LDHs (Layered Double Hydroxides) is disclosed. The preparation method comprises the following steps: preparing delaminated LDHs colloidal solution using formamide solvent, preparing sulfonated poly(p-phenylene) aqueous solution, and performing alternate assembling on hydrophilically treated substrate in the two solutions to give the composite thin film of sulfonated poly(p-phenylene)/LDHs multilayer. The preparation method has the advantages of simple preparation process, and film thickness controllable at nanoscale precision, in addition, this method also achieves the immobilization of luminescent polymer via restricted space among LDHs layers and host-guest interaction, effectively improves thermal stability, and reduces fluorescence quenching caused by aggregation.
摘要翻译：磺化聚（对亚苯基）（即聚[2,5-双（3-磺基丙氧基）-1,4-亚苯基 - 邻-1,4-亚苯基]）和LDHs的复合蓝色发光薄膜的制备方法分层双氢氧化物）。制备方法包括以下步骤：使用甲酰胺溶剂制备分层的LDHs胶体溶液，制备磺化聚（对亚苯基）水溶液，并在两种溶液中对亲水处理的基材进行交替组装，得到磺化聚（对亚苯基）/ LDHs多层。该制备方法制备工艺简单，膜厚可控于纳米级精度，此外，该方法还通过LDH层间的空间限制和主 - 客体相互作用实现了发光聚合物的固定，有效提高了热稳定性，降低了由聚集引起的荧光猝灭。

6. 发明申请

US20100219378A1 Preparation method of composite luminescent thin film of sulfonated poly (p-phenylene) and layered double hydroxides 失效
标题翻译：磺化聚（对亚苯基）和层状双氢氧化物复合发光薄膜的制备方法
公开(公告)号：US20100219378A1
公开(公告)日：2010-09-02
申请号：US12459795
申请日：2009-07-07
申请人： Dongpeng Yan , Jun Lu , Min Wei , Xue Duan
发明人： Dongpeng Yan , Jun Lu , Min Wei , Xue Duan
IPC分类号： C09K11/06
CPC分类号： C09K11/06 , C09K2211/1408 , H01L51/0038 , H01L51/5032 , H01L51/5278 , H05B33/10
摘要： The present invention provide a preparation method of composite blue luminescent thin film of sulfonated poly(p-phenylene) (i.e. poly[2,5-bis(3-sulfonatopropoxy)-1,4-phenylene-alt-1,4-phenylene]) and LDHs (Layered Double Hydroxides). The preparation method comprises following steps: preparing delaminated LDHs colloidal solution using formamide solvent, preparing sulfonated poly(p-phenylene) aqueous solution, performing alternate assembling on hydrophilically treated substrate in the two solutions to give the composite thin film of sulfonated poly(p-phenylene)/LDHs multilayer. The present invention has the advantages of simple preparation process, and film thickness controllable at nanoscale precision; the invention also achieves the immobilization of luminescent polymer via restricted space among LDHs layers and host-guest interaction, effectively improves thermal stability, and reduces fluorescence quenching caused by aggregation.
摘要翻译：本发明提供磺化聚（对亚苯基）（即聚[2,5-双（3-磺酰丙氧基）-1,4-亚苯基 - 邻-1,4-亚苯基]亚磺酰基的复合蓝色发光薄膜的制备方法，）和LDH（层状双氢氧化物）。制备方法包括以下步骤：使用甲酰胺溶剂制备分层的LDHs胶体溶液，制备磺化聚（对亚苯基）水溶液，在两种溶液中对亲水处理的基材进行交替组装，得到磺化聚（对 - 亚苯基）/ LDH多层。本发明具有制备工艺简单，膜厚可控纳米精度的优点; 本发明还通过LDH层之间的限制空间和主客体相互作用实现了发光聚合物的固定，有效地提高了热稳定性，并且减少了聚集引起的荧光猝灭。

7. 发明申请

US20140154165A1 METHOD FOR PREPARING GRAPHENE BY USING TWO-DIMENSIONAL CONFINED SPACE BETWEEN THE LAYERS OF INORGANIC LAYERED MATERIALS 有权
标题翻译：通过在无机层材料层之间使用两维限定空间来制备石墨的方法
公开(公告)号：US20140154165A1
公开(公告)日：2014-06-05
申请号：US13980715
申请日：2012-03-27
申请人： Wensheng Yang , Jie Sun , Haimei Liu , Xu Chen , Xue Duan
发明人： Wensheng Yang , Jie Sun , Haimei Liu , Xu Chen , Xue Duan
IPC分类号： C01B31/04
CPC分类号： C01B31/0446 , C01B32/192 , C01B32/22 , Y10S977/789
摘要： The present invention relates to a method for preparing graphene using the two-dimensional confined space between the layers of inorganic layered materials. Such method comprises the following steps: mix a soluble salt of a divalent metal ion M2+, a soluble salt of a trivalent metal ion M′3+, a soluble salt of a chain alkyl anion A− and a carbon source molecule C and dissolve them in deionized and CO2-eliminated water to prepare a mixed salt solution; mix the mixed salt solution with an alkali solution under nitrogen protection and subject them to reaction and crystallization under nitrogen, and filter the suspension obtained thereafter and wash the filter cake with deionized water until the pH of the filtrate is 7 to 7.5, and then dry the filter cake to obtain layered double hydroxides with an intercalated structure; under an inert atmosphere or a reducing atmosphere, calcinate the layered double hydroxides with an intercalated structure to provide a calcinated product; add the calcinated product into a hydrochloric acid solution for ultrasonic treatment, and separate the solution by centrifugation and wash the precipitate obtained by centrifugation with deionized water until the pH of the filtrate is 6.5 to 7 to obtain the graphene.
摘要翻译：本发明涉及使用无机层状材料层之间的二维密闭空间来制备石墨烯的方法。该方法包括以下步骤：将二价金属离子M2 +的可溶性盐，三价金属离子M'3 +的可溶性盐，链烷基阴离子A的可溶性盐和碳源分子C混合并溶解在去离子水和二氧化碳消除的水中制备混合盐溶液; 在氮气保护下将混合盐溶液与碱溶液混合，并在氮气下进行反应和结晶，过滤后得到的悬浮液，用去离子水洗涤滤饼直到滤液的pH为7至7.5，然后干燥滤饼得到具有插层结构的层状双氢氧化物; 在惰性气氛或还原气氛下，以层间结构煅烧层状双氢氧化物，得到煅烧产物; 将煅烧后的产物加入到盐酸溶液中进行超声波处理，离心分离溶液，用去离子水离心洗涤沉淀，直到滤液的pH值达到6.5〜7，得到石墨烯。

8. 发明申请

US20110268646A1 PREPARATION METHOD OF CARBON NANOTUBE BY DECOMPOSING THE POLYMER WITH HYDROTALCITE AS A CATALYST 失效
标题翻译：通过用聚合物作为催化剂分解聚合物制备碳纳米管的方法
公开(公告)号：US20110268646A1
公开(公告)日：2011-11-03
申请号：US13144246
申请日：2010-01-12
申请人： Fazhi Zhang , Lixia Zhang , Xiaodong Lei , Rushi Li , Sailong Xu , Xue Duan
发明人： Fazhi Zhang , Lixia Zhang , Xiaodong Lei , Rushi Li , Sailong Xu , Xue Duan
IPC分类号： D01F9/12 , B82Y40/00
CPC分类号： B82Y40/00 , B01J23/007 , B01J23/755 , B01J37/031 , B82Y30/00 , C01B32/162 , C01B2202/36
摘要： The present invention discloses a preparation method of carbon nanotube by decomposing the polymer with hydrotalcite as a catalyst, which belongs to the field of preparation technology of carbon nanotube (CNT). The technical solution of the present invention are as below: firstly, the hydrotalcite with the particle size at nanometer or sub-micron level is prepared, and then is added into the polymer. After the calcination process at high temperature and a treatment with acid, the nano-scale CNT can be obtained. The CNTs prepared by the method supplied in this invention not only have the advantages including high yield, uniform diameter, few structural defects, low impurity content, low cost and simple preparation process, which is suitable for large-scale industrial production, but also can solve the problem of recirculation of waste plastics and utilization of the resource.
摘要翻译：本发明公开了一种碳纳米管的制备方法，该方法属于碳纳米管（CNT）制备技术领域，以水滑石作催化剂分解聚合物。本发明的技术方案如下：首先制备粒径为纳米或亚微米级的水滑石，然后加入到聚合物中。在高温煅烧和酸处理后，可以得到纳米级的CNT。通过本发明提供的方法制备的CNT不仅具有产量高，直径均匀，结构缺陷少，杂质含量低，成本低，制备工艺简单，适用于大规模工业化生产的优点，而且可以解决废塑料再循环和资源利用问题。

9. 发明申请

US20100130750A1 Benzocarbazole-intercalated layered double hydroxides composite luminescent material and its preparation method 失效
标题翻译：苯并咔唑层间双氢氧化物复合发光材料及其制备方法
公开(公告)号：US20100130750A1
公开(公告)日：2010-05-27
申请号：US12459793
申请日：2009-07-07
申请人： Dongpeng Yan , Jun Lu , Min Wei , Xue Duan
发明人： Dongpeng Yan , Jun Lu , Min Wei , Xue Duan
IPC分类号： C07D209/82
CPC分类号： C09K11/06 , C07D209/82 , C09K2211/1011 , C09K2211/1029 , C09K2211/186
摘要： The present invention discloses a benzocarbazole-intercalated layered double hydroxides (LDHs) composite luminescent material and its preparation method. The detailed procedure comprises preparing divalent and trivalent metal cation solution A and glycol solution B of sodium 2-hydroxy benzo[a]carbazole-3-carboxylate, mixing the solutions A and B to obtain solution C, slowly adding the prepared NaOH solution dropwise into the solution C, regulating pH of the resultant after dropwise addition to obtain slurry D, allowing the slurry D to react under water bath or microwave temperature-controlled heating condition, centrifuging and washing the obtained product, and drying in vacuum to obtain 2-hydroxy benzo[a]carbazole-3-carboxylate anion intercalated LDHs composite material. The method implements the immobilization of sodium 2-hydroxy benzo[a]carbazole-3-carboxylate, effectively improves thermal stability of the luminescent dye molecules, and reduces fluorescence quenching caused by aggregation of the dye molecules.
摘要翻译：本发明公开了苯并咔唑层间双氢氧化物（LDH）复合发光材料及其制备方法。详细的方法包括制备二价和三价金属阳离子溶液A和2-羟基苯并[a]咔唑-3-羧酸钠的乙二醇溶液B，混合溶液A和B，得到溶液C，将制备的NaOH溶液逐滴加入溶液C，在滴加后调节所得物的pH，得到浆料D，使浆料D在水浴或微波温度控制加热条件下反应，离心分离得到的产物，真空干燥，得到2-羟基苯并[a]咔唑-3-羧酸盐阴离子插层的LDHs复合材料。该方法实现了2-羟基苯并[a]咔唑-3-羧酸钠的固定，有效地改善了发光染料分子的热稳定性，并且减少了由染料分子聚集引起的荧光猝灭。

10. 发明授权

US09029167B2 Preparation of an optical PH sensor based on fluorescein and 1-heptanesulfonic acid sodium Co-intercalated layered double hydroxide 有权
标题翻译：基于荧光素和1-庚磺酸钠共插层式双氢氧化物制备光学PH传感器
公开(公告)号：US09029167B2
公开(公告)日：2015-05-12
申请号：US13520694
申请日：2010-03-12
申请人： Min Wei , Wenying Shi , Jun Lu , Xue Duan
发明人： Min Wei , Wenying Shi , Jun Lu , Xue Duan
IPC分类号： G01N21/76 , G01N31/22
CPC分类号： G01N31/221
摘要： This invention relates to the field of preparation technology of optical pH sensor by co-intercalated fluorescein and 1-heptanesulfonic acid sodium into layered double hydroxide. The sensor is composed by conductive materials and the surface LDH films by co-interacted FLU and HES. The synthesis method is: first: synthesis of LDH colloid suspension, subsequently, the FLU and HES co-intercalated LDH colloid solution was prepared following the ion-exchange method, then the thin film of FLU-HES/LDH was spreaded on the surface of the conductive material by electrophoretic deposition, and the oriental pH sensor was synthesized. The advantages of the present invention is: first, the LDH matrix provides chromophore molecules with a confined and stable environment; the novel electrophoretic deposition strategy in this work provides a method for precise control of thickness (ranging from nanometers to micrometers), and the oriental pH sensor show good pH responsive.
摘要翻译：本发明涉及通过共插入荧光素和1-庚烷磺酸钠的光学pH传感器的制备技术领域到层状双氢氧化物中。传感器由导电材料和表面LDH膜共同相互作用的FLU和HES组成。合成方法是：首先合成LDH胶体悬浮液，随后用离子交换法制备FLU和HES共插入LDH胶体溶液，然后将FLU-HES / LDH薄膜铺展在通过电泳沉积导电材料和东方pH传感器。本发明的优点是：首先，LDH基体为发色团分子提供约束和稳定的环境; 该工作中的新型电泳沉积策略提供了一种精确控制厚度（范围从纳米到微米）的方法，东方pH传感器显示出良好的pH响应。

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