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1. 发明授权

US08765632B2 Process for preparing catalyst comprising palladium supported on carrier with high dispersion 有权
标题翻译：制备催化剂的方法，所述催化剂包含负载在高分散体载体上的钯
公开(公告)号：US08765632B2
公开(公告)日：2014-07-01
申请号：US13128546
申请日：2009-06-25
申请人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
发明人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
IPC分类号： B01J23/00 , B01J23/02 , B01J23/08 , B01J23/40 , B01J23/42 , B01J23/44 , B01J20/00 , B01J21/04 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： B01J23/007 , B01J23/44 , B01J23/58 , B01J23/892 , B01J23/8926 , B01J35/008 , B01J37/0201 , B01J37/18 , C01F7/005 , C01P2002/22 , C07C67/303 , C07C2601/14 , C07C69/75
摘要： A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of A12O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later. The process has the advantages of improving the catalytic performance of the catalyst, enhancing the stability of the catalyst, and achieving the object of reducing the consumption of the precious metal-palladium.
摘要翻译：一种制备催化剂的方法，所述催化剂包含通过层状前体负载在载体上的钯，其包括以下步骤：（1）合成水滑石层状前体，其包括在A12O3微球载体的表面上促进金属元素和铝，由于水滑石晶体的晶格定位效应，促进金属和铝彼此高度分散并牢固地结合到载体上; （2）通过浸渍将钯引入载体; （3）干燥; 和（4）用H 2煅烧和还原，水滑石层状前体被转化为由促进金属和铝的氧化物组成的复合氧化物，并且促进金属元素和铝彼此高度分散，并且能够分离和分散稍后加载的主要活性钯元素。该方法具有提高催化剂的催化性能，提高催化剂稳定性，降低贵金属钯的消耗量的优点。

2. 发明申请

US20110237430A1 PROCESS FOR PREPARING CATALYST COMPRISING PALLADIUM SUPPORTED ON CARRIER WITH HIGH DISPERSION 有权
标题翻译：用于制备包含支持高分散载体的钯催化剂的方法
公开(公告)号：US20110237430A1
公开(公告)日：2011-09-29
申请号：US13128546
申请日：2009-06-25
申请人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
发明人： Fazhi Zhang , Peng Chen , Rong Hou , Jiali Chen , Chao Gao , Hui Zhang , Dianqing Li , Feng Li , Xue Duan
IPC分类号： B01J21/04 , B01J37/06 , B01J37/18 , B01J37/08 , B01J35/02 , B01J21/10
CPC分类号： B01J23/007 , B01J23/44 , B01J23/58 , B01J23/892 , B01J23/8926 , B01J35/008 , B01J37/0201 , B01J37/18 , C01F7/005 , C01P2002/22 , C07C67/303 , C07C2601/14 , C07C69/75
摘要： A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of Al2O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later. The process has the advantages of improving the catalytic performance of the catalyst, enhancing the stability of the catalyst, and achieving the object of reducing the consumption of the precious metal-palladium.
摘要翻译：一种制备催化剂的方法，所述催化剂包含通过层状前体负载在载体上的钯，其包括以下步骤：（1）合成水滑石层状前体，其包括在Al 2 O 3微球载体的表面上促进金属元素和铝，由于水滑石晶体的晶格定位效应，促进金属和铝彼此高度分散并牢固地结合到载体上; （2）通过浸渍将钯引入载体; （3）干燥; 和（4）用H 2煅烧和还原，水滑石层状前体被转化为由促进金属和铝的氧化物组成的复合氧化物，并且促进金属元素和铝彼此高度分散，并且能够分离和分散稍后加载的主要活性钯元素。该方法具有提高催化剂的催化性能，提高催化剂稳定性，降低贵金属钯的消耗量的优点。

3. 发明申请

US20110268646A1 PREPARATION METHOD OF CARBON NANOTUBE BY DECOMPOSING THE POLYMER WITH HYDROTALCITE AS A CATALYST 失效
标题翻译：通过用聚合物作为催化剂分解聚合物制备碳纳米管的方法
公开(公告)号：US20110268646A1
公开(公告)日：2011-11-03
申请号：US13144246
申请日：2010-01-12
申请人： Fazhi Zhang , Lixia Zhang , Xiaodong Lei , Rushi Li , Sailong Xu , Xue Duan
发明人： Fazhi Zhang , Lixia Zhang , Xiaodong Lei , Rushi Li , Sailong Xu , Xue Duan
IPC分类号： D01F9/12 , B82Y40/00
CPC分类号： B82Y40/00 , B01J23/007 , B01J23/755 , B01J37/031 , B82Y30/00 , C01B32/162 , C01B2202/36
摘要： The present invention discloses a preparation method of carbon nanotube by decomposing the polymer with hydrotalcite as a catalyst, which belongs to the field of preparation technology of carbon nanotube (CNT). The technical solution of the present invention are as below: firstly, the hydrotalcite with the particle size at nanometer or sub-micron level is prepared, and then is added into the polymer. After the calcination process at high temperature and a treatment with acid, the nano-scale CNT can be obtained. The CNTs prepared by the method supplied in this invention not only have the advantages including high yield, uniform diameter, few structural defects, low impurity content, low cost and simple preparation process, which is suitable for large-scale industrial production, but also can solve the problem of recirculation of waste plastics and utilization of the resource.
摘要翻译：本发明公开了一种碳纳米管的制备方法，该方法属于碳纳米管（CNT）制备技术领域，以水滑石作催化剂分解聚合物。本发明的技术方案如下：首先制备粒径为纳米或亚微米级的水滑石，然后加入到聚合物中。在高温煅烧和酸处理后，可以得到纳米级的CNT。通过本发明提供的方法制备的CNT不仅具有产量高，直径均匀，结构缺陷少，杂质含量低，成本低，制备工艺简单，适用于大规模工业化生产的优点，而且可以解决废塑料再循环和资源利用问题。

4. 发明授权

US08318123B2 Preparation method of carbon nanotube by decomposing the polymer with hydrotalcite as a catalyst 失效
标题翻译：通过用水滑石作为催化剂分解聚合物制备碳纳米管的方法
公开(公告)号：US08318123B2
公开(公告)日：2012-11-27
申请号：US13144246
申请日：2010-01-12
申请人： Fazhi Zhang , Lixia Zhang , Xiaodong Lei , Rushi Li , Sailong Xu , Xue Duan
发明人： Fazhi Zhang , Lixia Zhang , Xiaodong Lei , Rushi Li , Sailong Xu , Xue Duan
IPC分类号： D01F9/12
CPC分类号： B82Y40/00 , B01J23/007 , B01J23/755 , B01J37/031 , B82Y30/00 , C01B32/162 , C01B2202/36
摘要： The present invention discloses a preparation method of carbon nanotube by decomposing the polymer with hydrotalcite as a catalyst, which belongs to the field of preparation technology of carbon nanotube (CNT). The technical solution of the present invention are as below: firstly, the hydrotalcite with the particle size at nanometer or sub-micron level is prepared, and then is added into the polymer. After the calcination process at high temperature and a treatment with acid, the nano-scale CNT can be obtained. The CNTs prepared by the method supplied in this invention not only have the advantages including high yield, uniform diameter, few structural defects, low impurity content, low cost and simple preparation process, which is suitable for large-scale industrial production, but also can solve the problem of recirculation of waste plastics and utilization of the resource.
摘要翻译：本发明公开了一种碳纳米管的制备方法，该方法属于碳纳米管（CNT）制备技术领域，以水滑石作催化剂分解聚合物。本发明的技术方案如下：首先制备粒径为纳米或亚微米级的水滑石，然后加入到聚合物中。在高温煅烧和酸处理后，可以得到纳米尺度的CNT。通过本发明提供的方法制备的CNT不仅具有产率高，直径均匀，结构缺陷少，杂质含量低，成本低，制备工艺简单，适用于大规模工业化生产的优点，而且可以解决废塑料再循环和资源利用问题。

5. 发明授权

US08088349B2 Clean method for preparing layered double hydroxides 有权
标题翻译：清洁方法制备层状双氢氧化物
公开(公告)号：US08088349B2
公开(公告)日：2012-01-03
申请号：US11853788
申请日：2007-09-11
申请人： Xue Duan , Dianqing Li , Zhi Lv , Yanjun Lin , Xiangyu Xu
发明人： Xue Duan , Dianqing Li , Zhi Lv , Yanjun Lin , Xiangyu Xu
IPC分类号： C01F11/20
CPC分类号： C07F15/045 , C01F7/004 , C01G9/006 , C01G45/00 , C01G49/009 , C01G53/006 , C01P2002/22 , C01P2002/72 , C01P2002/74 , C01P2002/82 , C01P2004/04 , C01P2004/20
摘要： Disclosed is a clean method for preparing layered double hydroxides (LDHs), in which hydroxides of different metals are used as starting materials for production of LDHs by atom-economical reactions. The atom efficiency of the reaction is 100% in each case because all the atoms of the reactants are converted into the target product since only M2+(OH)2, M3+(OH)3, and CO2 or HnAn− are used, without any NaOH or other materials. Since there is no by-product, filtration or washing process is unnecessary. The consequent reduction in water consumption is also beneficial to the environment.
摘要翻译：公开了一种用于制备层状双氢氧化物（LDH）的清洁方法，其中使用不同金属的氢氧化物作为通过原子 - 经济反应生产LDH的起始原料。在每种情况下，反应的原子效率为100％，因为所有的反应物原子转化成目标产物，因为只使用M2 +（OH）2，M3 +（OH）3和CO 2或HnAn-，而不使用任何NaOH 或其他材料。由于没有副产品，过滤或洗涤过程是不必要的。随之而来的用水量减少也有利于环境。

6. 发明申请

US20080170978A1 CLEAN METHOD FOR PREPARING LAYERED DOUBLE HYDROXIDES 有权
标题翻译：用于制备层状双羟基的清洁方法
公开(公告)号：US20080170978A1
公开(公告)日：2008-07-17
申请号：US11853788
申请日：2007-09-11
申请人： Xue Duan , Dianqing Li , Zhi Lv , Yanjun Lin , Xiangyu Xu
发明人： Xue Duan , Dianqing Li , Zhi Lv , Yanjun Lin , Xiangyu Xu
IPC分类号： C01B31/00 , C01B25/12 , C07F15/02
CPC分类号： C07F15/045 , C01F7/004 , C01G9/006 , C01G45/00 , C01G49/009 , C01G53/006 , C01P2002/22 , C01P2002/72 , C01P2002/74 , C01P2002/82 , C01P2004/04 , C01P2004/20
摘要： Disclosed is a clean method for preparing layered double hydroxides (LDHs), in which hydroxides of different metals are used as starting materials for production of LDHs by atom-economical reactions. The atom efficiency of the reaction is 100% in each case because all the atoms of the reactants are converted into the target product since only M2+(OH)2, M3+(OH)3, and CO2 or HnAn− are used, without any NaOH or other materials. Since there is no by-product, filtration or washing process is unnecessary. The consequent reduction in water consumption is also beneficial to the environment.
摘要翻译：公开了一种用于制备层状双氢氧化物（LDH）的清洁方法，其中使用不同金属的氢氧化物作为通过原子 - 经济反应生产LDH的起始原料。在每种情况下，反应的原子效率为100％，因为反应物的所有原子都转化为目标产物，因为只有M 2 +（OH）2，M 3 +（OH）3 3，和CO 2或H N >，不使用任何NaOH或其他材料。由于没有副产品，过滤或洗涤过程是不必要的。随之而来的用水量减少也有利于环境。

7. 发明申请

US20050129609A1 Method for preparation of magnetic spinel ferrites from layered double hydroxide precursors 失效
标题翻译：从层状双氢氧化物前体制备磁性尖晶石铁氧体的方法
公开(公告)号：US20050129609A1
公开(公告)日：2005-06-16
申请号：US11040533
申请日：2005-01-21
申请人： Xue Duan , Feng Li , Junjie Liu
发明人： Xue Duan , Feng Li , Junjie Liu
IPC分类号： C01G49/02 , C04B35/26 , H01F10/20 , H01F41/02 , H01F41/24
CPC分类号： C04B35/2625 , C04B35/265 , C04B35/2658 , C04B35/2666 , C04B35/2683 , C04B35/6265 , C04B2235/3205 , C04B2235/3206 , C04B2235/3222 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , H01F10/20 , H01F41/0253 , H01F41/24
摘要： The invention describes a method of preparing magnetic ferrites from layered precursors in which Fe2+ is first introduced into the layers of layered double hydroxides (LDHs) in order to prepare Me-Fe2+—Fe3+ LDHs, and then by utilizing the easily oxidized nature of Fe2+, binary or multi-component ferrite materials containing Fe3+ in a single crystalline phase can be prepared. Values of the saturation magnetization of ferrites prepared by the method are significantly increased compared with ferrites prepared by traditional methods. Because the metal elements in the layered precursor have the characteristics of a high degree of dispersion, high activity and small particle size (average particle size 40-200 nm), no milling is required before calcination, thus simplifying the production process, shortening the production period, reducing capital investment in equipment and economizing on energy costs. In addition, the method does not corrode production equipment and does not pollute the environment.
摘要翻译：本发明描述了一种从层状前体制备磁性铁氧体的方法，其中Fe 2+ 2首先被引入层状双氢氧化物（LDH）层中以制备Me-Fe 2+， / Fe 3+ LDH，然后通过利用Fe 2+的易氧化性质，含Fe 3+的二元或多组分铁素体材料，可以制备单晶相中的。通过该方法制备的铁氧体的饱和磁化强度与通过传统方法制备的铁氧体相比显着增加。由于层状前体中的金属元素具有高分散性，高活性，小粒径（平均粒径40〜200nm）的特征，因此在煅烧前不需要研磨，因此简化了制造工序，缩短了生产减少设备资金投入，节约能源成本。此外，该方法不会腐蚀生产设备，也不会污染环境。

8. 发明授权

US07247598B2 Nano-scale magnetic solid base catalyst and its preparation method 失效
标题翻译：纳米磁性固体碱催化剂及其制备方法
公开(公告)号：US07247598B2
公开(公告)日：2007-07-24
申请号：US11040408
申请日：2005-01-21
申请人： Xue Duan , Hui Zhang , Rong Qi
发明人： Xue Duan , Hui Zhang , Rong Qi
IPC分类号： B01J23/00
CPC分类号： B01J37/03 , B01J23/002 , B01J23/74 , B01J35/0013 , B01J35/0033 , B01J37/0036 , B01J2523/00 , Y10S502/524 , Y10T428/2993 , B01J2523/22 , B01J2523/31 , B01J2523/842 , B01J2523/847 , B01J2523/27
摘要： This invention describes a nano-scale magnetic solid base catalyst and its preparation method. The catalyst involves a magnetic core coated with a solid base active layer. The synthesis of the nano-scale magnetic cores was first carried out using a rapid nucleation method in a colloid mill reactor using a liquid-liquid reaction. The nano-scale magnetic cores were mixed with a mixed salt solution. The LDH-containing magnetic cores were prepared in a colloid mill reactor by a rapid nucleation method, and subsequently calcined to give a solid base mixed oxides coated on magnetic cores. The characteristics of this catalyst are: nano-scale, high surface area and high activity and selectivity in base-catalyzed reactions. The highly dispersed catalyst can be easily reclaimed using an external magnetic field because of its magnetism. The catalyst can be utilized in base catalysis in organic reactions such as glycol ether synthesis, ester exchange, aldol condensation, etc.
摘要翻译：本发明描述了一种纳米级磁性固体碱催化剂及其制备方法。催化剂包括涂覆有固体碱性活性层的磁芯。首先使用液 - 液反应在胶体磨反应器中使用快速成核法进行纳米级磁芯的合成。将纳米级磁芯与混合盐溶液混合。通过快速成核法在胶体磨反应器中制备含LDH的磁芯，随后煅烧，得到涂覆在磁芯上的固体基础混合氧化物。该催化剂的特征是：纳米级，高表面积，碱催化反应中的高活性和选择性。高度分散的催化剂由于其磁性而可以使用外部磁场容易地回收。催化剂可用于有机反应的碱催化，如二醇醚合成，酯交换，醛醇缩合等。

9. 发明申请

US20050130838A1 Nano-scale magnetic solid base catalyst and its preparatiion method 失效
标题翻译：纳米级磁性固体碱催化剂及其制备方法
公开(公告)号：US20050130838A1
公开(公告)日：2005-06-16
申请号：US11040408
申请日：2005-01-21
申请人： Xue Duan , Hui Zhang , Rong Qi
发明人： Xue Duan , Hui Zhang , Rong Qi
IPC分类号： B01J23/00 , B01J23/74 , B01J35/00 , B01J37/00 , B01J37/03 , B01J23/78
CPC分类号： B01J37/03 , B01J23/002 , B01J23/74 , B01J35/0013 , B01J35/0033 , B01J37/0036 , B01J2523/00 , Y10S502/524 , Y10T428/2993 , B01J2523/22 , B01J2523/31 , B01J2523/842 , B01J2523/847 , B01J2523/27
摘要： This invention describes a nano-scale magnetic solid base catalyst and its preparation method. The catalyst involves a magnetic core coated with a solid base active layer. The synthesis of the nano-scale magnetic cores was first carried out using a rapid nucleation method in a colloid mill reactor using a liquid-liquid reaction. The nano-scale magnetic cores were mixed with a mixed salt solution. The LDH-containing magnetic cores were prepared in a colloid mill reactor by a rapid nucleation method, and subsequently calcined to give a solid base mixed oxides coated on magnetic cores. The characteristics of this catalyst are: nano-scale, high surface area and high activity and selectivity in base-catalyzed reactions. The highly dispersed catalyst can be easily reclaimed using an external magnetic field because of its magnetism. The catalyst can be utilized in base catalysis in organic reactions such as glycol ether synthesis, ester exchange, aldol condensation, etc.
摘要翻译：本发明描述了一种纳米级磁性固体碱催化剂及其制备方法。催化剂包括涂覆有固体碱性活性层的磁芯。首先使用液 - 液反应在胶体磨反应器中使用快速成核法进行纳米级磁芯的合成。将纳米级磁芯与混合盐溶液混合。通过快速成核法在胶体磨反应器中制备含LDH的磁芯，随后煅烧，得到涂覆在磁芯上的固体基础混合氧化物。该催化剂的特征是：纳米级，高表面积，碱催化反应中的高活性和选择性。高度分散的催化剂由于其磁性而可以使用外部磁场容易地回收。催化剂可用于有机反应的碱催化，如二醇醚合成，酯交换，醛醇缩合等。

10. 发明授权

US07232557B2 Method for preparation of magnetic spinel ferrites from layered double hydroxide precursors 失效
标题翻译：从层状双氢氧化物前体制备磁性尖晶石铁氧体的方法
公开(公告)号：US07232557B2
公开(公告)日：2007-06-19
申请号：US11040533
申请日：2005-01-21
申请人： Xue Duan , Feng Li , Junjie Liu
发明人： Xue Duan , Feng Li , Junjie Liu
IPC分类号： C01G1/00 , C01G49/00
CPC分类号： C04B35/2625 , C04B35/265 , C04B35/2658 , C04B35/2666 , C04B35/2683 , C04B35/6265 , C04B2235/3205 , C04B2235/3206 , C04B2235/3222 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , H01F10/20 , H01F41/0253 , H01F41/24
摘要： The invention describes a method of preparing magnetic ferrites from layered precursors in which Fe2+ is first introduced into the layers of layered double hydroxides (LDHs) in order to prepare Me-Fe2+—Fe3+ LDHs, and then by utilizing the easily oxidized nature of Fe2+, binary or multi-component ferrite materials containing Fe3+ in a single crystalline phase can be prepared. Values of the saturation magnetization of ferrites prepared by the method are significantly increased compared with ferrites prepared by traditional methods. Because the metal elements in the layered precursor have the characteristics of a high degree of dispersion, high activity and small particle size (average particle size 40-200 nm), no milling is required before calcination, thus simplifying the production process, shortening the production period, reducing capital investment in equipment and economizing on energy costs. In addition, the method does not corrode production equipment and does not pollute the environment.
摘要翻译：本发明描述了一种从层状前体制备磁性铁氧体的方法，其中Fe 2+ 2首先被引入层状双氢氧化物（LDH）层中以制备Me-Fe 2+， / Fe 3+ LDH，然后通过利用Fe 2+的易氧化性质，含Fe 3+的二元或多组分铁素体材料，可以制备单晶相中的。通过该方法制备的铁氧体的饱和磁化强度与通过传统方法制备的铁氧体相比显着增加。由于层状前体中的金属元素具有高分散性，高活性，小粒径（平均粒径40〜200nm）的特征，因此在煅烧前不需要研磨，因此简化了制造工序，缩短了生产减少设备资金投入，节约能源成本。此外，该方法不会腐蚀生产设备，也不会污染环境。

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