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1. 发明授权

US4320067A Process for the preparation of modified polyisocyanates 失效
标题翻译：制备改性多异氰酸酯的方法
公开(公告)号：US4320067A
公开(公告)日：1982-03-16
申请号：US228513
申请日：1981-01-26
申请人： Wulf von Bonin , Helmut Kleimann , Hans-Albrecht Freitag
发明人： Wulf von Bonin , Helmut Kleimann , Hans-Albrecht Freitag
IPC分类号： C07D251/34 , C07C67/00 , C07C239/00 , C07C273/18 , C07C275/00 , C07D295/13 , C08G18/00 , C08G18/32 , C08G18/78 , C08G18/80 , C07C119/042 , C07C119/045 , C07C119/048
CPC分类号： C07D295/13 , C07C273/1827 , C08G18/3228 , C08G18/8038
摘要： A process for preparing modified polyisocyanates in which an organic polyisocyanate is reacted with a polyamine present in less than stoichiometric amount. Polyamines suitable to this process include (a) polyamines having more than three nonaromatically bound, basic nitrogen atoms of which at least two are primary and/or secondary amino nitrogen atoms, and (b) polyamine mixtures having an average of more than three nonaromatically bound, basic nitrogen atoms of which at least two are primary and/or secondary amino nitrogen atoms. These modified polyisocyanates are particularly useful starting materials for production of polyurethane plastics by the isocyanate-polyaddition process.
摘要翻译：制备改性多异氰酸酯的方法，其中有机多异氰酸酯与少于化学计量的多胺反应。适用于该方法的多胺包括（a）具有多于三个非结合的碱性氮原子的多胺，其中至少两个是伯和/或仲氨基氮原子，和（b）平均多于三个非结合的多胺混合物，其中至少两个为碱性氮原子和/或仲氨基氮原子的碱性氮原子。这些改性的多异氰酸酯是通过异氰酸酯加聚方法生产聚氨酯塑料的特别有用的起始原料。

2. 发明授权

US4644017A Process for the production of polyisocyanate addition products and composite polyisocyanate addition products 失效
标题翻译：制备多异氰酸酯加成产物和复合多异氰酸酯加成产物的方法
公开(公告)号：US4644017A
公开(公告)日：1987-02-17
申请号：US775274
申请日：1985-09-12
申请人： Peter Haas , Hans-Albrecht Freitag , Geza Avar , Claus-Dieter Sommerfeld , Hans-Walter Illger
发明人： Peter Haas , Hans-Albrecht Freitag , Geza Avar , Claus-Dieter Sommerfeld , Hans-Walter Illger
IPC分类号： C08G18/00 , B29C39/10 , B29K75/00 , B29K105/04 , C08G18/08 , C08G18/16 , C08G18/18 , C08G101/00 , C08J9/02 , C08G18/14
CPC分类号： C08G18/1841 , Y10T428/31551 , Y10T428/31554 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31576 , Y10T428/3158 , Y10T428/31583 , Y10T428/31587 , Y10T428/31591
摘要： Composite polyisocyanate addition products are formed from (1) the reaction product of a compound having at least two isocyanate-reactive hydrogen atoms and a molecular weight of from 400 to 10,000, a polyisocyanate and a catalyst which is a diffusion stable amino alkyl urea having tertiary amino groups and corresponds to the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and n each represent specified groups or values and (2) another different material such as polyvinyl chloride, ABS, lacquers and textiles. Known additives such as blowing agents, chain extenders and foam stabilizers may optionally be used in the production of reaction product (1). The composite materials of the present invention which are particularly useful in the production of bedding and seating furniture, seats used in transport means, dashboard panels, arm-rests and for other similar applications are characterized by their lack of discoloration due to the diffusion of the catalyst employed in producing reaction product (1).
摘要翻译：复合多异氰酸酯加成产物由（1）具有至少两个异氰酸酯反应性氢原子和分子量为400至10,000的化合物的反应产物形成，多异氰酸酯和作为扩散稳定的氨基烷基脲的催化剂具有叔氨基，并且对应于其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和n各自表示指定的基团或数值的式（IMAGE）和（2）另一种不同的材料，如聚氯乙烯，ABS，漆和纺织品。已知的添加剂如发泡剂，增链剂和泡沫稳定剂可以任选地用于制备反应产物（1）。特别可用于生产床上用品和座椅家具的本发明的复合材料，用于运输工具的座椅，仪表盘，扶手和用于其它类似应用的复合材料的特征在于它们由于用于制备反应产物（1）的催化剂。

3. 发明授权

US4390640A Process for the production of optionally-foamed polyurethanes 失效
标题翻译：用于生产任选发泡聚氨酯的方法
公开(公告)号：US4390640A
公开(公告)日：1983-06-28
申请号：US342303
申请日：1982-01-25
申请人： Werner Rasshofer , Geza Avar , Hans-Albrecht Freitag , Gerhard Grogler , Richard Kopp
发明人： Werner Rasshofer , Geza Avar , Hans-Albrecht Freitag , Gerhard Grogler , Richard Kopp
IPC分类号： C08G18/00 , C08G18/22 , C08G18/24 , C08J9/02 , C08G18/14
CPC分类号： C08G18/246
摘要： This invention relates to a process for the production of polyurethanes, particularly polyurethane foam moldings having a compact skin and a cellular core, using special tin activators.
摘要翻译：本发明涉及使用特殊的锡活化剂来生产聚氨酯的方法，特别是具有紧密表皮和细胞芯的聚氨酯泡沫塑料模制品。

4. 发明授权

US4618532A Upholstered seat having an air-permeable covering and a cold foam core 失效
标题翻译：软垫座具有透气性覆盖物和冷泡芯
公开(公告)号：US4618532A
公开(公告)日：1986-10-21
申请号：US641118
申请日：1984-08-15
申请人： Robert Volland , Hans-Albrecht Freitag , Johannes Seesing , Herbert Bergmann
发明人： Robert Volland , Hans-Albrecht Freitag , Johannes Seesing , Herbert Bergmann
IPC分类号： B32B5/18 , A47C7/18 , A47C27/00 , B29C39/10 , B29C44/12 , B29C44/16 , B29K105/04 , B29L31/58 , B32B5/24 , B68G7/06 , B68G11/04 , B32B3/26
CPC分类号： B29C44/16 , A47C7/18 , B29C44/1261 , B29L2031/58 , B29L2031/751 , Y10T428/233 , Y10T428/239 , Y10T428/249953 , Y10T428/24996 , Y10T428/249976
摘要： The present invention is directed to an upholstered seat consisting of an in situ foam core based on a cold foam formulation and an air-permeable covering and to a process for integrally producing an upholstered seat with improved standards of comfort by back foaming a covering material in a mold, characterized in that, in a split mold of which the dividing plane preferably extends in the vicinity of the actual seat surface, a sealed foam-impermeable covering material is applied to the internal contour of the mold and that part of the covering material which forms the actual seat surface is clamped in the dividing plane of the mold, the entire mold cavity is filled with foam by metering the foam in correspondingly large quantities, after which the sealing layer around the fully reacted foam core, where it consists of an air-impermeable material, is destroyed by a mechanical treatment, such as needle punching, flexing, compression, knocking, or by solvents to at least such an extent that it becomes permeable to air.
摘要翻译：本发明涉及一种软垫座椅，其由基于冷泡沫配方的原位泡沫芯和透气性覆盖物组成，并且涉及一种通过使覆盖材料反向发泡来改善舒适度的整体制造软垫座椅的方法模具，其特征在于，在分割平面优选在实际座面附近延伸的分割模具中，将密封的不透泡覆盖材料施加到模具的内部轮廓，并且该部分覆盖材料形成实际的座面的模具被夹紧在模具的分割平面中，整个模腔通过相当大量地计量泡沫填充泡沫，此后，完全反应的泡沫芯周围的密封层由不透气材料通过机械处理如针刺，弯曲，压缩，敲击或通过溶剂破坏至少至少这样的程度它变得透气。

5. 发明授权

US4379861A Process for the production of polyurethanes using morpholine compounds as catalysts 失效
标题翻译：使用吗啉化合物作为催化剂生产聚氨酯的方法
公开(公告)号：US4379861A
公开(公告)日：1983-04-12
申请号：US325539
申请日：1981-11-27
申请人： Peter Haas , Hans-Albrecht Freitag
发明人： Peter Haas , Hans-Albrecht Freitag
IPC分类号： C08G18/00 , C07D295/12 , C08G18/18 , C08G18/20 , C08J9/02 , C08G18/14
CPC分类号： C08G18/2081 , C08G18/2018
摘要： The invention relates to a process for the preparation of foamed or unfoamed polyurethanes by the reaction of compounds with molecular weights of 400 to 10,000 having at least two isocyanate-reactive hydrogen atoms with polyisocyanates in the presence of catalysts containing tertiary amino groups and optionally in the presence of chain-lengthening agents of molecular weight 32 to 400, foam stabilizers, water and/or organic blowing agents and optionally other auxiliary agents and additives, characterized in that the catalysts are morpholine derivatives of the general formula ##STR1## wherein X is an integer from 3 to 6 andR.sup.1 and R.sup.2 are identical or different and(a) represent a C.sub.1 -C.sub.6 -alkyl or C.sub.6 -C.sub.10 -cycloalkyl group or(b) form a heterocyclic ring containing 4-7 C-atoms, which heterocyclic ring may contain hetero groups in addition to the N-atom and wherein the additional hetero groups may be substituted by a C.sub.1 -C.sub.3 alkyl, or(c) together denote a group of the formula ##STR2## in which n and m are identical or different numbers from 2 to 4, preferably 2, or(d) represent ##STR3##
摘要翻译：本发明涉及一种制备泡沫或未发泡的聚氨酯的方法，其通过在含有叔氨基的催化剂存在下，通过使分子量为400至10,000的化合物与多异氰酸酯反应而具有至少两个异氰酸酯反应性氢原子与任选在存在分子量为32至400的链延长剂，泡沫稳定剂，水和/或有机发泡剂和任选的其它助剂和添加剂，其特征在于催化剂是通式为“IMAGE”的吗啉衍生物，其中X为 3至6的整数，R 1和R 2相同或不同，（a）表示C 1 -C 6烷基或C 6 -C 10 - 环烷基或（b）形成含有4-7个C原子的杂环，该杂环可以含有除了N-原子以外的杂基，其中另外的杂基可以被C 1 -C 3烷基取代，或者（c）一起表示式“IMAGE”的基团，其中n 和m是相同或不同的数2至4，优选2，或（d）表示

6. 发明授权

US5342855A Stable dispersions of polyhydrazodicarbonamides useful in the preparation of polyurethane products having improved load-bearing capacity 失效
标题翻译：用于制备具有改善的承载能力的聚氨酯产品的聚二酰二酰胺的稳定分散体
公开(公告)号：US5342855A
公开(公告)日：1994-08-30
申请号：US468535
申请日：1990-01-23
申请人： Michael A. Lucarelli , Richard E. Keegan , Mark A. Koshute , Hans-Albrecht Freitag , Geza Avar
发明人： Michael A. Lucarelli , Richard E. Keegan , Mark A. Koshute , Hans-Albrecht Freitag , Geza Avar
IPC分类号： C08G18/08 , C08G18/32 , C08G18/38 , C08G18/40 , C08G18/65 , C08J9/00
CPC分类号： C08G18/409 , C08G18/0876 , C08G18/3231 , C08G18/3834 , C08G18/6529 , C08G2101/0008
摘要： This invention relates to a process for the preparation of stable dispersions of hydroxyl-containing polyhydrazodicarbonamides in a hydroxyl-containing compound. The dispersions are prepared by the reaction of organic isocyanates, isocyanate-reactive compounds having a molecular weight in the range from 400 to 10,000, relatively low molecular weight isocyanate-reactive compounds, and hydrazines or hydrazides. This invention further relates to the dispersions prepared by said process, the use of the dispersions to prepare polyurethane foams having exceptional hardness, and the foams prepared thereby.
摘要翻译：本发明涉及一种在含羟基的化合物中制备含羟基的聚二酰二酰胺的稳定分散体的方法。分散体通过有机异氰酸酯，分子量在400至10,000的异氰酸酯反应性化合物，相对低分子量的异氰酸酯反应性化合物和肼或酰肼的反应来制备。本发明还涉及通过所述方法制备的分散体，使用分散体制备具有优异硬度的聚氨酯泡沫以及由此制备的泡沫。

7. 发明授权

US4644016A Process for the production of polyurethanes 失效
标题翻译：聚氨酯生产工艺
公开(公告)号：US4644016A
公开(公告)日：1987-02-17
申请号：US761278
申请日：1985-08-01
申请人： Werner Rasshofer , Hans-Albrecht Freitag
发明人： Werner Rasshofer , Hans-Albrecht Freitag
IPC分类号： C08G18/18 , C08G18/14 , C08G18/20
CPC分类号： C08G18/1866
摘要： Polyurethanes are made by reacting a polyisocyanate with a compound containing at least two isocyanate-reactive hydrogen atoms having a molecular weight of from 400 to 10,000 in the presence of a catalyst containing tertiary amino groups. The required catalyst corresponds to the formula ##STR1## in which R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 represent a specified group or radical. A blowing agent and/or stabilizer and/or chain extending agent and/or other additives commonly used in the production of polyurethanes may optionally be included in the reaction mixture. The catalyst employed in the process is particularly advantageous in that it does not have a noticeable amine odor.
摘要翻译：聚氨酯通过使多异氰酸酯与含有至少两个分子量为400至10,000的异氰酸酯反应性氢原子的化合物在含有叔氨基的催化剂存在下反应而制备。所需的催化剂对应于其中R，R 1，R 2，R 3，R 4，R 5，R 6和R 7表示指定基团或基团的式“IMAGE”。在制备聚氨酯中通常使用的发泡剂和/或稳定剂和/或增链剂和/或其它添加剂可任选地包括在反应混合物中。在该方法中使用的催化剂特别有利的是它不具有明显的胺气味。

8. 发明授权

US4510269A Process for the production of optionally cellular polyurethanes 失效
标题翻译：用于生产任选的细胞聚氨酯的方法
公开(公告)号：US4510269A
公开(公告)日：1985-04-09
申请号：US638160
申请日：1984-08-06
申请人： Richard Kopp , Hans-Albrecht Freitag
发明人： Richard Kopp , Hans-Albrecht Freitag
IPC分类号： C08G18/00 , C08G18/16 , C08G18/18 , C08G18/14
CPC分类号： C08G18/1833 , C08G18/1825
摘要： A process for the production of an optionally cellular polyurethane by reacting at least one compound having at least two hydrogen atoms which are reactive with isocyanate groups and have a molecular weight of from about 400 to 10,000 with polyisocyanates in the presence of a poly(dialkylaminoalkyl)ether catalyst corresponding to the formula ##STR1## wherein A represents a straight-chain or branched-chain (x+1)-valent, optionally substituted C.sub.2 -C.sub.6 alkyl radical,x represents an integer of 1 to 4 andR.sup.1 -R.sup.4 represent the same or different C.sub.1 -C.sub.4 alkyl radicals, which optionally form a heterocyclic radical with N.
摘要翻译：通过使至少两种具有至少两个与异氰酸酯基团反应的氢原子和具有约400至10,000的分子量的化合物与聚异氰酸酯在聚（二烷基氨基烷基）基团的存在下反应生产任选的细胞聚氨酯的方法，其中A代表直链或支链（x + 1）价任选取代的C 2 -C 6烷基，x代表1至4的整数，并且R 1 -R 4代表相同或不同的C1-C4烷基，其任选地与N.形成杂环基。

9. 发明授权

US5109035A Process for the production of moldings or films of cross-linked polyisocyanate polyadducts and the moldings thus obtained 失效
标题翻译：制造交联聚异氰酸酯多糖的胶片或胶片的方法及其获得的胶片
公开(公告)号：US5109035A
公开(公告)日：1992-04-28
申请号：US628766
申请日：1990-12-17
申请人： Joachim Wagner , Werner Rasshofer , Thomas Elsner , Hans-Albrecht Freitag
发明人： Joachim Wagner , Werner Rasshofer , Thomas Elsner , Hans-Albrecht Freitag
IPC分类号： C08G18/28 , C08G18/30 , C08G18/32 , C08G18/48 , C08G18/65 , C08G18/66 , C08J9/02 , C08J9/36 , C08K7/00 , C08L75/00 , C08L75/04
CPC分类号： C08J9/36 , C08G18/4804 , C08G18/6674 , C08G2101/0008 , C08G2101/0066 , C08G2120/00 , C08J2375/04 , Y10T428/249953 , Y10T428/249986 , Y10T428/31551
摘要： The present invention is directed to a process of thermoplastically molding a specific foam composition. The composition is formed by reacting an isocyanate and a relatively low molecular weight tri or higher polyol in the presence of a blowing agent.
摘要翻译：本发明涉及对特定泡沫组合物进行热塑性模塑的方法。通过使异氰酸酯和相对低分子量的三元醇或更高级的多元醇在发泡剂存在下反应形成组合物。

10. 发明授权

US4824595A Polyisocyanate compositions containing reversibly blocked catalysts and addition products of sulfonyl isocyanates with catalysts having a tin(II)- or tin(IV)-carboxylate structure 失效
标题翻译：含有可逆封闭的催化剂的多异氰酸酯组合物和具有锡（II） - 或锡（IV） - 羧酸盐结构的催化剂的磺酰基异氰酸酯的加成产物
公开(公告)号：US4824595A
公开(公告)日：1989-04-25
申请号：US633732
申请日：1984-07-23
申请人： Roland Richter , Hanns P. Muller , Rudolf Hombach , Manfred Dollhausen , Geza Avar , Hans-Albrecht Freitag
发明人： Roland Richter , Hanns P. Muller , Rudolf Hombach , Manfred Dollhausen , Geza Avar , Hans-Albrecht Freitag
IPC分类号： C08G18/00 , C08G18/16 , C08G18/24 , C08G18/72 , C09K3/00
CPC分类号： C08G18/72 , C08G18/16 , C08G18/24
摘要： The present invention relates to polyisocyanate compositions containing reversibly blocked catalysts for the isocyanate addition reaction, characterized in that they contain(a) at least one organic polyisocyanate,(b) at least one addition product dissolved or dispersed in the polyisocyanate compositions, of a sulfonyl isocyanate with a tertiary amine and/or with a catalyst having a tin(II)- or tin(IV)-carboxylate structure as the reversibly blocked catalyst.The present invention also relates to a process for producing these polyisocyanate compositions and to the use of new polyisocyanate compositions as reactants for compounds containing isocyanate-reactive groups for the production of isocyanate addition products such as polyurethane plastics using a one-component or two-component principle. The present invention finally relates to the latent polyurethane catalysts prepared from a sulfonyl isocyanate and a tin(II)- or tin(IV)-carboxylate.
摘要翻译：本发明涉及含有用于异氰酸酯加成反应的可逆封闭的催化剂的多异氰酸酯组合物，其特征在于它们含有（a）至少一种有机多异氰酸酯，（b）至少一种溶解或分散在多异氰酸酯组合物中的加成产物，异氰酸酯与叔胺和/或具有锡（II） - 或锡（IV） - 羧酸盐结构的催化剂作为可逆阻挡的催化剂。本发明还涉及一种制备这些多异氰酸酯组合物的方法，以及使用新的多异氰酸酯组合物作为含有异氰酸酯反应性基团的化合物的反应物，用于生产异氰酸酯加成产物如聚氨酯塑料，其使用单组分或双组分原理。本发明最终涉及由磺酰基异氰酸酯和锡（II） - 或锡（IV） - 羧酸酯制备的潜在聚氨酯催化剂。

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