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1. 发明授权

US4870129A Adhesive and use of the adhesive for the formation of bonds 失效
标题翻译：粘合剂和粘合剂的使用形成结合
公开(公告)号：US4870129A
公开(公告)日：1989-09-26
申请号：US87542
申请日：1987-08-19
申请人： Wolfgang Henning , Rudolf Hombach , Walter Meckel , Manfred Dollhausen
发明人： Wolfgang Henning , Rudolf Hombach , Walter Meckel , Manfred Dollhausen
IPC分类号： C08G18/65 , C08G18/08 , C08G18/12 , C08G18/42 , C08G18/72 , C09J175/00 , C09J175/06
CPC分类号： C09J175/06 , C08G18/0819 , C08G18/12 , C08G18/4238 , C08G18/722 , C08G18/724 , C08G2170/80
摘要： An adhesive consisting substantially of an aqueous solution or dispersion of a polyurethane containing chemically incorporated carboxylate and/or sulphonate groups is prepared from a mixture of at least two (cyclo)-aliphatic diisocyanate and selected polyester diols based on (i) adipic acid and (ii) tetramethylenediol, hexamethylenediol or mixtures of these diols. The use of such aqueous solutions for the formation of bonds on any substrates, in particular on leather, plastics, rubber materials and/or polyvinyl chloride containing plasticizer, with the same material or with other materials is disclosed.
摘要翻译：基于（i）己二酸和（i）己二酸的（i）脂族二异氰酸酯和选择的聚酯二醇的混合物，制备基本上由含有化学结合的羧酸盐和/或磺酸盐基团的聚氨酯的水溶液或分散体组成的粘合剂， ii）四亚甲基二醇，六亚甲基二醇或这些二醇的混合物。公开了这种水溶液用于在任何基底上形成粘结剂，特别是在具有相同材料或其它材料的皮革，塑料，橡胶材料和/或含聚氯乙烯的增塑剂上形成粘合剂。

2. 发明授权

US5432228A Aqueous solutions and dispersions of polyisocyanate polyaddition products, a process for the production of the aqueous solutions and dispersions and their use as adhesives 失效
标题翻译：多异氰酸酯加成产物的水溶液和分散体，用于生产水溶液和分散体的方法及其作为粘合剂的用途
公开(公告)号：US5432228A
公开(公告)日：1995-07-11
申请号：US483167
申请日：1990-02-21
申请人： Genter Hilken , Wolfgang Henning , Walter Meckel , Rudolf Hombach
发明人： Genter Hilken , Wolfgang Henning , Walter Meckel , Rudolf Hombach
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/83 , C08J3/02 , C09J175/04 , C08J3/00 , C08K3/20 , C08L75/00 , C09J4/00
CPC分类号： C08G18/2865 , C08G18/0819 , C08G18/10 , C08G18/283 , C08G2170/80 , Y10T428/31551
摘要： Aqueous solutions and dispersions of polyisocyanate polyaddition products containing 2 to 200 milliequivalents chemically incorporated carboxylate and/or sulfonate groups per 100 g solids and 0 to 25% by weight, based on solids, of incorporated ethylene oxide units arranged within terminal and/or lateral polyether chains, in the production of which primary and/or secondary monoamino compounds are usd, a process for their production and their use as adhesives.
摘要翻译：含有2至200毫当量的多异氰酸酯加成产物的水溶液和分散体每100克固体化学掺入羧酸盐和/或磺酸盐基团，基于固体，0-25重量％，结合的环氧乙烷单元排列在末端和/或侧向聚醚链，其生产的主要和/或次要单氨基化合物是其生产方法，以及它们作为粘合剂的用途。

3. 发明授权

US4623416A Aqueous solutions or dispersions of polyisocyanate polyaddition products, a process for their production and their use as, or in the production of, adhesives 失效
标题翻译：多异氰酸酯加成产物的水溶液或分散体，其生产方法及其在胶粘剂生产中的用途
公开(公告)号：US4623416A
公开(公告)日：1986-11-18
申请号：US675042
申请日：1984-11-26
申请人： Wolfgang Henning , Rudolf Hombach , Walter Meckel , Helmut Reiff
发明人： Wolfgang Henning , Rudolf Hombach , Walter Meckel , Helmut Reiff
IPC分类号： C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/42 , C09J175/00 , C09J175/06 , C09J3/14 , C08G18/44
CPC分类号： C09J175/06 , C08G18/0814 , C08G18/12 , C08G18/283 , C08G18/42 , C08G18/4269 , C08G2170/80 , Y10T428/31587
摘要： The present invention relates to aqueous solutions or dispersions of polyisocyanate polyaddition products containing from about 2 to 200 milliequivalents per 100 g of solids of chemically incorporated, ternary or quaternary ammonium groups and up to about 25%, based on solids, of incorporated ethylene oxide units present within terminally and/or laterally arranged polyether chains, characterized in that the polyisocyanate polyaddition products contain from about 20 to 95% by weight of polyester segments Q incorporated through urethane groups, whereinQ represents a radical of the type obtained by removing the hydroxyl groups from(i) dicarboxylic acid polyester polyols having a molecular weight in the range from about 700 to 1400and/or(ii) hydroxyl-terminated lactone homopolymers or copolymers having a molecular weight in the range from about 700 to 2500.The present invention also relates to the preparation of these polyisocyanate polyaddition products and their use for bonding substrates, in particular rubber.
摘要翻译：本发明涉及多异氰酸酯加成产物的水溶液或分散体，其含有约2- 200毫当量/ 100g化学掺入的三元或季铵基固体，至多约25％，基于固体，结合的环氧乙烷单元存在于末端和/或横向排列的聚醚链中，其特征在于多异氰酸酯加聚产物含有约20至95重量％的通过氨基甲酸酯基团引入的聚酯链段Q，其中Q表示通过除去羟基获得的类型的基团从（i）分子量在约700至1400范围内的二羧酸聚酯多元醇和/或（ii）分子量在约700至2500范围内的羟基封端的内酯均聚物或共聚物。本发明还涉及这些多异氰酸酯加成产物的制备及其用于粘合的用途特别是橡胶。

4. 发明授权

US4240861A Process for the preparation of dihydroxypolyurethanes and the use thereof as adhesives or as raw materials for adhesives 失效
标题翻译：制备二羟基聚氨酯的方法及其作为粘合剂或粘合剂的原料的用途
公开(公告)号：US4240861A
公开(公告)日：1980-12-23
申请号：US39702
申请日：1979-05-17
申请人： Walter Meckel , Horst Muller-Albrecht , Manfred Dollhausen , Eugen Velker
发明人： Walter Meckel , Horst Muller-Albrecht , Manfred Dollhausen , Eugen Velker
IPC分类号： C08G18/00 , C08G18/08 , C08G18/65 , C08G18/66 , C09J175/00 , C09J175/06 , C08G18/34
CPC分类号： C09J175/06 , C08G18/0804 , C08G18/0833 , C08G18/6659 , C08G2170/20 , C08G2170/90 , Y10S528/905
摘要： The instant invention is directed to a process for the preparation of dihydroxypolyurethanes containing carboxyl groups and chemically fixed ionic groups, comprising reacting(A) dihydroxypolyesters having molecular weights of from 600 to 8,000;(B) organic diisocyanates;(C) compounds containing carboxyl groups and groups having a higher isocyanate-reactivity than said carboxyl groups; and(D) compounds containing ionic groups and isocyanate-reactive groupswherein the products of said process contain from 0.01 to 1.0%, by weight of carboxyl groups and from 0.1 to 10 milliequivalents of ionic groups per 100 g of polyurethane.
摘要翻译：本发明涉及一种制备含有羧基和化学固定的离子基团的二羟基聚氨酯的方法，包括使（A）分子量为600-8,000的二羟基聚酯与（B）有机二异氰酸酯; （C）含有羧基的化合物和具有比所述羧基更高的异氰酸酯反应性的基团; 和（D）含有离子基团和异氰酸酯反应性基团的化合物，其中所述方法的产物含有0.01至1.0重量％的羧基和0.1至10毫当量的每100g聚氨酯的离子基团。

5. 发明授权

US4946535A Polyester polyurethanes containing hydroxyl end groups and their use as adhesives 失效
标题翻译：含有羟基端基的聚酯聚氨酯及其作为粘合剂的用途
公开(公告)号：US4946535A
公开(公告)日：1990-08-07
申请号：US275253
申请日：1988-11-23
申请人： Walter Meckel , Horst Muller-Albrecht , Manfred Dollhausen
发明人： Walter Meckel , Horst Muller-Albrecht , Manfred Dollhausen
IPC分类号： C08G18/00 , C08G18/08 , C08G18/12 , C08G18/42 , C08G18/66 , C09J175/00 , C09J175/06
CPC分类号： C09J175/06 , C08G18/0804 , C08G18/12 , C08G18/4238 , C08G18/664 , Y10S36/01 , Y10T428/31558
摘要： This invention relates to new, substantially linear polyester polyurethanes containing hydroxyl end groups, based on selected starting materials, and their use as adhesives or for the production of adhesives.
摘要翻译：本发明涉及基于所选原料的含有羟基端基的新的基本上线性的聚酯聚氨酯，以及它们作为粘合剂或粘合剂生产的用途。

6. 发明授权

US4868266A Heat curable adhesive system 失效
标题翻译：热固化胶粘剂系统
公开(公告)号：US4868266A
公开(公告)日：1989-09-19
申请号：US253210
申请日：1988-10-04
申请人： Walter Meckel , Rudolf Hombach
发明人： Walter Meckel , Rudolf Hombach
IPC分类号： C09J175/04 , C08G18/10 , C08G18/22 , C08G18/48 , C09J175/00 , C09J175/08
CPC分类号： C09J175/08 , C08G18/10 , C08G18/22
摘要： The present invention relates to a heat curable adhesive system comprising a prepolymer (P) based on isocyanate groups and polyether segments, and at least one polyhydroxyl compound (C), and a catalyst (D) characterized in that(a) the prepolymer (P) is formed on the basis of one or more polyols (A) containing polyether segments and having an average hydroxyl number of from 50 to 160 and an average functionality of from 2.05 to 2.6 and o at least one diphenylmethane diisocyanate (B) and(b) the polyhydroxyl compound (c) contains at least three hydroxyl groups per molecule and is dispersed in prepolymer (P) in a quantity of from 1 to 10 hydroxyl groups for each isocyanate group still available in the prepolymer (P) and melts at a temperature above 110.degree. C. and(c) the catalyst (D) consists of at least one carboxylic acid salt of bismuth, cadminum, lead or zinc containing more than 12, in particular 14 carbon atoms, used in a solid form melting at a temperature above 100.degree. C.
摘要翻译：本发明涉及一种包含基于异氰酸酯基团和聚醚部分的预聚物（P）和至少一种多羟基化合物（C）和催化剂（D）的热固性粘合剂体系，其特征在于（a）预聚物（P ）基于一种或多种含有聚醚链段并且平均羟基数为50至160且平均官能度为2.05至2.6的多元醇（A）和至少一种二苯基甲烷二异氰酸酯（B）和（b ）多羟基化合物（c）每分子含有至少三个羟基，并且在预聚物（P）中仍然可得到的每个异氰酸酯基团分散在预聚物（P）中的量为1至10个羟基，并在温度高于110℃，和（c）催化剂（D）由至少一种含有超过12个，特别是14个碳原子的铋，镉，铅或锌的羧酸盐组成，其以在温度下熔融的固体形式使用高于100℃

7. 发明授权

US4769436A Polyester polyalcohols containing amino and amide groups and poly (urea) urethane produced therefrom 失效
标题翻译：含有氨基和酰胺基团的聚酯多元醇和由其制备的聚（脲）氨基甲酸酯
公开(公告)号：US4769436A
公开(公告)日：1988-09-06
申请号：US133518
申请日：1987-12-16
申请人： Manfred Beck , Rudolf Hombach , Walter Meckel
发明人： Manfred Beck , Rudolf Hombach , Walter Meckel
IPC分类号： C08F299/06 , C08F290/00 , C08G18/42 , C08G18/46 , C09J175/00 , C09J175/12 , C08G18/32
CPC分类号： C09J175/12 , C08G18/4615 , C08G18/4669
摘要： A process for the manufacture of polyester polyalcohols with amino and amide groups by the reaction of polyester polyalcohols with polyamines is characterized in that unsaturated polyester polyalcohols if necessary in admixture with saturated polyester polyalcohols are used as polyester polyalcohols, and low molecular weight, aliphatic polyamines with two primary amino groups are used as polyamines.
摘要翻译：通过聚酯多元醇与多胺的反应制备具有氨基和酰胺基团的聚酯多元醇的方法的特征在于，如果必要，不饱和聚酯多元醇与饱和聚酯多元醇的混合物用作聚酯多元醇，并且使用低分子量脂族多胺，两个伯氨基用作多胺。

8. 发明授权

US5210170A Process for stabilizing plastics containing ester groups 失效
标题翻译：用于稳定含有酯类的塑料的方法
公开(公告)号：US5210170A
公开(公告)日：1993-05-11
申请号：US708590
申请日：1991-05-31
申请人： Bernd Quiring , Thomas Munzmay , Wolfgang Henning , Eduard Mayer , Walter Meckel , Wilhelm Goyert
发明人： Bernd Quiring , Thomas Munzmay , Wolfgang Henning , Eduard Mayer , Walter Meckel , Wilhelm Goyert
IPC分类号： C08G63/91 , C08G18/10 , C08G18/42 , C08G18/60 , C08G18/76 , C08G18/79 , C08G18/83 , C08K5/29 , C08L67/00 , C09J175/06
CPC分类号： C09J175/06 , C08G18/10 , C08G18/42 , C08G18/60 , C08G18/7678 , C08G18/797 , C08K5/29 , C08G2101/00 , C08G2150/20
摘要： The invention relates to a process for stabilizing ester-containing plastics against degradation by heat and/or hydrolysis by the incorporation of sterically hindered isocyanate-terminated carbodiimides. The incorporable carbodiimides produce an excellent anti-aging effect and do not give rise to volatile products, even at very high temperatures.
摘要翻译：本发明涉及稳定含酯塑料的方法，以防止加入和/或水解通过加入空间位阻异氰酸酯封端的碳二亚胺的降解。可加入的碳二亚胺产生优异的抗老化作用，即使在非常高的温度下也不会产生挥发性产物。

9. 发明授权

US4857565A Process for the continuous production of aqueous polyurethane dispersions and their use as a coating composition or as an adhesive 失效
标题翻译：用于连续生产水性聚氨酯分散体的方法及其作为涂料组合物或粘合剂的用途
公开(公告)号：US4857565A
公开(公告)日：1989-08-15
申请号：US242015
申请日：1988-09-08
申请人： Wolfgang Henning , Walter Meckel , Peter Fuhrmann
发明人： Wolfgang Henning , Walter Meckel , Peter Fuhrmann
IPC分类号： C08G18/00 , C08G18/08 , C08G18/50 , C08J3/07 , C09D175/00 , C09J175/00
CPC分类号： C08J3/07 , C08G18/0804 , C08G18/0842 , C08G18/0866 , C08G18/5042 , C08G2170/80 , C08J2375/04
摘要： The present invention is directed to a continuous process for the production of aqueous polyurethane dispersions by continuously mixing solutions of polyurethanes or isocyanate prepolymers dissolved in an organic solvent with water and subsequently continuously removing at least a portion of the solvent using a circulation-type evaporator. The present invention is also directed to the production of coatings or adhesives by applying the aqueous polyurethane dispersions to a substrate.
摘要翻译：本发明涉及通过将溶解在有机溶剂中的聚氨酯或异氰酸酯预聚物的溶液与水连续混合并随后使用循环型蒸发器连续地除去至少一部分溶剂来生产水性聚氨酯分散体的连续方法。本发明还涉及通过将水性聚氨酯分散体施用于基材来生产涂料或粘合剂。

10. 发明授权

US4670100A Aqueous solutions or dispersions of polyisocyanate addition products, a process for their preparation, and their use as coating compounds or as sizing agents for paper 失效
标题翻译：多异氰酸酯加成产物的水溶液或分散体，它们的制备方法以及它们作为涂料化合物或作为纸张施胶剂的用途
公开(公告)号：US4670100A
公开(公告)日：1987-06-02
申请号：US876526
申请日：1986-06-19
申请人： Wolfgang Henning , Walter Meckel , Ulrich Beck , Heinz Baumgen , Joachim Konig
发明人： Wolfgang Henning , Walter Meckel , Ulrich Beck , Heinz Baumgen , Joachim Konig
IPC分类号： C08G18/00 , C08G18/08 , C08G18/38 , C08G18/50 , C08G18/78 , C09D175/08 , D06M15/564 , D21H17/46 , D21H17/57 , C08L75/00 , D21H3/48
CPC分类号： C08G18/7818 , C08G18/0814 , C08G18/3823 , C08G18/5042 , D21H17/57
摘要： The present invention relates to aqueous solutions or dispersions of polyisocyanate addition products which contain about 2 to 300 milliequivalents per 100 g of solids of chemically incorporated ternary or quaternary ammonium groups and up to about 25% by weight, based on solids, of chemically incorporated ethylene oxide units, --CH.sub.2 --CH.sub.2 --O--, present within a polyether chain, the ternary or quaternary ammonium groups and the ethylene oxide units being present in an amount sufficient to guarantee the solubility or dispersibility of the polyisocyanate addition products in water, characterized in that the polyisocyanate addition products have segments incorporated in the polymer chain which correspond to the following general formula ##STR1## in an amount of about 0.1 to 20% by weight based on the above formula, but excluding the weight of R.The present invention also relates to a process for the production of polyisocyanate addition products and to their use as coating agents for flexible or inflexible substrates and as sizing agents for paper or for the production sizing agents for paper.
摘要翻译：本发明涉及多异氰酸酯加成产物的水溶液或分散体，其含有约2至300毫当量/ 100g化学掺入的三元或季铵基团的固体，至多约25重量％，基于固体，化学结合的乙烯存在于聚醚链内的氧化单元，-CH 2 -CH 2 -O-，三元或季铵基团和环氧乙烷单元的存在量足以保证多异氰酸酯加成产物在水中的溶解度或分散性，其特征在于多异氰酸酯加成产物具有引入聚合物链中的链段，其对应于下列通式（IMAGE），其量为约0.1至20重量％，基于上式，但不包括R的重量。本发明还涉及用于制备多异氰酸酯加成产物的方法及其作为柔性涂料的用途或不灵活的基材和作为纸张的上浆剂或用于纸的生产施胶剂。

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