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    • 7. 发明授权
    • Preparation of soft and hard resins, and their use
    • 软和硬树脂的制备及其用途
    • US4220751A
    • 1980-09-02
    • US969664
    • 1978-12-15
    • Harro PetersenKurt FischerHans KlugWerner Trimborn
    • Harro PetersenKurt FischerHans KlugWerner Trimborn
    • C08G12/00C08G12/02C08G12/12C09D161/20C09D161/24
    • C08G12/12C09D161/24
    • A process for the preparation of soft and hard resins, and their use in surface-coating binders.According to the invention, soft and hard resins are prepared from a urea and a CH-acidic aldehyde by reacting a urea of the general formula (I) ##STR1## where X is oxygen or sulfur and R.sup.1 and R.sup.2 are hydrogen or identical or different alkyl, aryl or aralkyl, or may be an alkyleneurea radical, with at least 2 moles of a CH-acidic aldehyde of the general formula (II) ##STR2## where R.sup.3 is hydrogen and R.sup.4 is alkyl, aryl or aralkyl, or R.sup.3 and R.sup.4 are identical or different alkyl, aryl or aralkyl, in the presence of a strong acid, to give a condensation product, and then treating the latter with a base in an anhydrous medium.These soft and hard resins are used, in combination with other film-forming agents, as surface-coating binders.
    • 用于制备软和硬树脂的方法及其在表面涂层粘合剂中的应用。 根据本发明,通过使通式(I)的脲(I)其中X是氧或硫,R 1和R 2是氢或通式 具有至少2摩尔的通式(II)的II型的酸式醛,其中R 3是氢和R 4是烷基,芳基,芳基或芳烷基,或可以是亚烷基脲基, 或芳烷基,或者R3和R4是相同或不同的烷基,芳基或芳烷基,在强酸存在下,得到缩合产物,然后用无水介质中的碱处理后者。 这些软和硬树脂与其它成膜剂一起用作表面涂层粘合剂。
    • 8. 发明授权
    • Textile finish and processes for its preparation and use
    • 纺织品的整理及其制备和使用过程
    • US4207073A
    • 1980-06-10
    • US000815
    • 1979-01-04
    • Harro PetersenPanemangalore S. PaiManfred Reichert
    • Harro PetersenPanemangalore S. PaiManfred Reichert
    • C08L71/00C08L77/00D06M13/02D06M13/322D06M13/425D06M15/53D06M15/564D06M101/00D06M101/02D06M101/06D06M101/08D06M15/54
    • D06M15/564
    • A process for the preparation of a textile finish, the textile finish thus obtained and its use for the easy-care finishing of textiles containing, or consisting of, cellulose. The textile finish comprises an aqueous solution, of from 30 to 70 percent strength by weight, of a mixture of the conventionally formaldehyde-methylolated carbamates I and II ##STR1## where R.sup.1 is hydrogen or alkyl of 1 to 4 carbon atoms and R.sup.2 and R.sup.3 are hydrogen, or one is hydrogen and the other is methyl, in the weight ratio I:II of from 12:1 to 1:20.The textile finish is prepared by reacting a glycol or an alkylglycol of the formulae III and IV ##STR2## where R.sup.1, R.sup.2 and R.sup.3 have the above meanings, with urea at above 100.degree. C., so as to eliminate ammonia and give carbamates, and subsequent conventional methylolation with formaldehyde, wherein, in a first stage, the glycol or alkylglycol of the formula III is reacted to the extent of at least 50% with urea, in the absence of a catalyst, at from 130.degree. to 160.degree. C., to give the carbamate I, and in a second stage, carried out either in the presence of an ion exchanger, containing nickel ions, as the catalyst, at from 130.degree. to 165.degree. C., or in the absence of a catalyst at from 150.degree. to 200.degree. C., the carbamate mixture in the weight ratio I:II of from 12:1 to 1:20, is prepared by addition of the glycol or alkylglycol of the formula IV and further urea.
    • 用于制备纺织品整理剂的方法,如此获得的纺织品整理剂及其用于容易地加工含纤维素或由纤维素组成的纺织品的用途。 织物整理剂包含按重量计30%至70%的常规甲醛 - 羟甲基化氨基甲酸酯I和II II的混合物的水溶液,其中R1是氢或1-4个碳原子的烷基 原子,R2和R3是氢,或者一个是氢,另一个是甲基,重量比I:II为12:1至1:20。 通过使式III和IV的烷基二醇R 1(OCH 2 CH 2)9-100 OH III IV,其中R 1,R 2和R 3具有上述含义,与高于100℃的尿素反应制备纺织品整理剂。 ,以消除氨并产生氨基甲酸酯,以及随后与甲醛的常规羟甲基化反应,其中在第一阶段中,式III的二醇或烷基二醇与尿素的反应程度至少为50%,在不存在 催化剂,在130℃至160℃下,得到氨基甲酸酯I,在第二阶段中,在含有镍离子的离子交换剂存在下,在130-165℃下进行催化剂 或者在150℃至200℃下不存在催化剂时,重量比I:II的氨基甲酸酯混合物的重量比为12:1至1:20,通过加入二醇或烷基二醇 式IV和另外的尿素。