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1. 发明授权

US4460725A Polyethers containing 2,2,6,6-tetramethyl piperidinyl carboxylic acid ester groups and synthetic resin compositions 失效
标题翻译：含有2,2,6,6-四甲基哌啶基羧酸酯基团的聚醚和合成树脂组合物
公开(公告)号：US4460725A
公开(公告)日：1984-07-17
申请号：US472710
申请日：1983-03-07
申请人： William E. Leistner , Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
发明人： William E. Leistner , Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08L101/00 , C07D211/22 , C07D211/62 , C07D211/66 , C07D405/12 , C07D491/10 , C08G65/00 , C08G65/22 , C08G65/26 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L71/02 , C07D251/00 , C07D251/28 , C07D403/00
CPC分类号： C07D405/12 , C07D211/22 , C07D211/62 , C07D211/66 , C07D491/10 , C08K5/3435
摘要： Polyethers containing 2,2,6,6-tetramethyl piperidinyl carboxylic acid ester or ether groups are provided, comprising polymeric units having the structure ##STR1## wherein X is selected from the group consisting of: ##STR2## R.sub.1 is selected from the group consisting of hydrogen, --O, alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms, acyl having from one to about eighteen carbon atoms, cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms;R.sub.2 is hydrogen or hydroxy;n.sub.1 is 0 or 1;R.sub.3 is lower alkyl having from one to about six carbon atoms; andn is the average number of such units in the polymer; as well as stabilized synthetic resin compositions comprising such polyethers.
摘要翻译：提供了包含2,2,6,6-四甲基哌啶基羧酸酯或醚基团的聚醚，其包含具有以下结构的聚合物单元，其中X选自由以下组成的组： R 1选自氢，-O，烷基，羟基烷基和具有1至约18个碳原子的环氧烷基，具有1至约18个碳原子的酰基，具有3至约8个碳原子的环烷基十八个碳原子; 苯基; 具有7至约24个碳原子的苯基烷基和烷基苯基; R2是氢或羟基; n1为0或1; R3是具有1至约6个碳原子的低级烷基; n是聚合物中这些单元的平均数; 以及包含这种聚醚的稳定的合成树脂组合物。

2. 发明授权

US4525506A Polyhydric alcohol ethers of 2,2,6,6-tetramethyl-4-piperidone ketals and synthetic resin compositions 失效
标题翻译： 2,2,6,6-四甲基-4-哌啶酮缩酮的多元醇醚和合成树脂组合物
公开(公告)号：US4525506A
公开(公告)日：1985-06-25
申请号：US478610
申请日：1983-03-25
申请人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D491/056 , C07D491/113 , C07D519/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L101/00
CPC分类号： C07D519/00 , C08K5/3435 , C08K5/3477
摘要： Polyhydric alcohol ethers of 2,2,6,6-tetramethyl-4-piperidone ketals are provided, having the formula: ##STR1## wherein: R is selected from the group consisting of hydrogen, alkyl having from one to about eight carbon atoms, and alkyleneoxyalkylene, each alkylene having from two to about eight carbon atoms;R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about four carbon atoms;R.sub.2 is selected from the group consisting of hydrogen; oxyl O; alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms; acyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms; andn is a number from 3 to 6as well as synthetic resin compositions having an improved resistance to deterioration and containing such compounds.

3. 发明授权

US4500663A Light stabilizing N,N,N-tris(2,2,6,6-tetramethyl-4-piperidone ketal)-1,3,5-triazine derivatives and light stabilized synthetic resin compositions 失效
标题翻译：光稳定N，N，N-三（2,2,6,6-四甲基-4-哌啶酮缩酮）-1,3,5-三嗪衍生物和光稳定的合成树脂组合物
公开(公告)号：US4500663A
公开(公告)日：1985-02-19
申请号：US478609
申请日：1983-03-25
申请人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D491/056 , C07D491/113 , C07D519/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L101/00 , C07D405/14
CPC分类号： C07D519/00 , C08K5/3435 , C08K5/3477
摘要： N,N,N-tris(2,2,6,6-tetramethyl-4-piperidone ketal)-1,3,5-triazines are provided, having the formula: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about four carbon atoms; andR.sub.2 is selected from the group consisting of hydrogen; oxyl O; alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms; alkanoyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms; as well as synthetic resin compositions having an improved resistance to deterioration and containing such compounds.
摘要翻译：提供N，N，N-三（2,2,6,6-四甲基-4-哌啶酮缩酮）-1,3,5-三嗪，具有下式：其中：R 1选自的氢和具有1至约4个碳原子的烷基; 并且R 2选自氢; 氧基O; 烷基，羟基烷基和具有1至约18个碳原子的环氧烷基; 具有1至约18个碳原子的烷酰基; 具有3至约18个碳原子的环烷基; 苯基; 具有7至约24个碳原子的苯基烷基和烷基苯基; 以及具有改善的耐劣化性和含有这些化合物的合成树脂组合物。

4. 发明授权

US4698381A N,N',N"-tris((2,2,6,6-tetramethyl-4-piperidyl)triazinyl) undecane triamines as stabilizers for synthetic polymers 失效
标题翻译： N，N'，N“ - 三（（2,2,6,6-四甲基-4-哌啶基）三嗪基）十一烷三胺作为合成聚合物的稳定剂
公开(公告)号：US4698381A
公开(公告)日：1987-10-06
申请号：US778357
申请日：1985-09-19
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/34 , C07D401/14 , C07D491/10 , C07D491/113 , C08K5/00 , C08K5/3477 , C08K5/3492 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09D5/38 , C09D7/12
CPC分类号： C07D401/14 , C07D491/10 , C08K5/34926
摘要： N,N',N"-tris((2,2,6,6-tetramethyl-4-piperidyl)triazinyl) undecane triamines are provided having the formula: ##STR1## wherein: X is selected from the group consisting of ##STR2## in which: R is selected from the group consisting of hydrogen; oxyl O'; alkyl having from one to about eighteen carbon atoms; hydroxyalkyl having from two to about eight carbon atoms; epoxyalkyl having from three to about eight carbon atoms; alkaryl having from seven to about twelve carbon atoms; and acyl having from one to about eight carbon atoms;Y is O or NR.sub.2 ;R.sub.1 is alkyl having from one to about six carbon atoms; andR.sub.2 is hydrogen or alkyl having from one to about eighteen carbon atoms;as well as stabilizer compositions and stabilized synthetic polymer compositions containing the same having improved resistance to deterioration upon exposure to light.
摘要翻译：提供了具有下式的N，N'，N“ - 三（（2,2,6,6-四甲基-4-哌啶基）三嗪基）十一烷三胺，其中：X选自 IMAGE>其中：R选自氢; 氧基O' 具有1至约18个碳原子的烷基; 具有2至约8个碳原子的羟烷基; 具有3至约8个碳原子的环氧烷基; 具有7至约12个碳原子的烷芳基; 和具有1至约8个碳原子的酰基; Y为O或NR2; R1是具有1至约6个碳原子的烷基; 并且R 2是氢或具有1至约18个碳原子的烷基; 以及稳定剂组合物和包含该组合物的稳定的合成聚合物组合物具有改善的耐受暴露于光的劣化性。

5. 发明授权

US4468488A Poly(piperidylamine) alkanes and synthetic resin compositions stabilized thereby 失效
标题翻译：聚（哌啶胺）烷烃和由此稳定的合成树脂组合物
公开(公告)号：US4468488A
公开(公告)日：1984-08-28
申请号：US470103
申请日：1983-02-28
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D211/58 , C07D401/12 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L101/00 , C07D401/14 , C08L25/06
CPC分类号： C07D401/12 , C07D211/58 , C08K5/3435
摘要： Poly(piperidylamine) alkanes represented by the Formula (I) or (II): ##STR1## and synthetic resin compositions having improved resistance to deterioration by light containing such compounds.
摘要翻译：由式（I）或（II）表示的聚（哌啶胺）烷烃：具有改善的抗含劣化性的光的耐劣化性的合成树脂组合物。

6. 发明授权

US4623685A Thermosetting synthetic resin lacquer compositions of improved light stability 失效
标题翻译：改善光稳定性的热固性合成树脂漆组合物
公开(公告)号：US4623685A
公开(公告)日：1986-11-18
申请号：US714236
申请日：1985-03-21
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C09D7/00 , C08K5/3435 , C08L61/20 , C09D5/00 , C09D5/32 , C09D7/12 , C09D133/06 , C09D167/00 , C08K5/34
CPC分类号： C09D133/06 , C08K5/3435 , C09D167/00 , C09D7/1241 , C08L61/20
摘要： Thermosetting synthetic resin lacquer compositions are provided having improved resistance to deterioration when exposed to ultraviolet light, comprising a 1-phenoxycarbonyl-2,2,6,6-tetramethylpiperidyl compound.
摘要翻译：提供热固化合成树脂漆组合物，其在暴露于紫外线时具有改善的耐劣化性，其包含1-苯氧羰基-2,2,6,6-四甲基哌啶化合物。

7. 发明授权

US4415688A Poly(piperidylamine) alkanes and synthetic resin compositions stabilized thereby 失效
标题翻译：聚（哌啶胺）烷烃和由此稳定的合成树脂组合物
公开(公告)号：US4415688A
公开(公告)日：1983-11-15
申请号：US443274
申请日：1982-11-22
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D211/58 , C07D211/72 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08L7/00 , C08L21/00 , C08L23/00 , C08L101/00 , C08L25/06
CPC分类号： C08K5/3435 , C07D211/58 , C07D211/72
摘要： Poly(piperidylamine) alkanes represented by the Formula (I) or (II): ##STR1## R is selected from the group consisting of: --NH.sub.2 ; ##STR2## and synthetic resin compositions having improved resistance to deterioration by light containing such compounds.
摘要翻译：由式（I）或（II）表示的聚（哌啶基胺）烷烃：其中R 1选自：-NH 2; 以及具有改善的耐含有这种化合物的光的劣化性能的合成树脂组合物。

8. 发明授权

US4673701A Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups and synthetic resin composition 失效
标题翻译：亚烷基双酚亚磷酸酯和具有2,2,6,6-四甲基哌啶基的磷酸酯和合成树脂组合物
公开(公告)号：US4673701A
公开(公告)日：1987-06-16
申请号：US687090
申请日：1984-12-28
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07F9/6574 , C08K5/52 , C08K5/523 , C08K5/526 , C08K5/529 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C08K5/34
CPC分类号： C07F9/65744 , C08K5/529
摘要： Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula: ##STR1## wherein: R.sub.1 is alkyl having from one to about twelve carbon atoms;R.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;m is 0 or 1;n is 0 or 1;X is selected from the group consisting of ##STR2## wherein: R.sub.5 is selected from the group consisting of hydrogen, oxyl O.sup.2, alkyl having from one to about twelve carbon atoms; arylalkyl having from seven to about eighteen carbon atoms; 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and ##STR3## in which R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y.sub.1 is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and ##STR4## Z.sub.1 is selected from the group consisting of ##STR5## wherein R.sub.7 is alkyl from one to about twelve carbon atoms; and ##STR6## wherein: R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl; andZ.sub.2 is selected from the group consisting of ##STR7## in which R.sub.7 is alkyl having from one to about twelve carbon atoms; R.sub.6 is alkylene having from one to about eight carbon atoms andY.sub.2 is selected from the group consisting of hydrogen and acyl having from one to about eight carbon atoms.
摘要翻译：提供具有2,2,6,6-四甲基哌啶基的亚烷基双酚亚磷酸酯和磷酸酯，其具有下式：其中：R1是具有1至约12个碳原子的烷基; R2，R3和R4各自选自氢和具有1至约12个碳原子的烷基; m为0或1; n为0或1; X选自（1）其中：R 5选自氢，氧基O 2，具有1至约12个碳原子的烷基; 具有7至约18个碳原子的芳基烷基; 2,3-环氧丙基，具有1至约8个碳原子的酰基和，其中R 6选自氢，具有1至约12个碳原子的烷基和苯基，Y 1选自由氢组成具有1至约12个碳原子的酰基; 并且＆lt; IMAGE＆gt; Z1选自，其中R 7为1至约12个碳原子的烷基; （2）其中：R6选自氢，具有1至约12个碳原子的烷基和苯基; Z2选自由下列组成的组：其中R 7为具有1至约12个碳原子的烷基; R 6是具有1至约8个碳原子的亚烷基，Y 2选自氢和具有1至约8个碳原子的酰基。

9. 发明授权

US4396735A Synergistic light stabilizer compositions for synthetic resins and resin compositions containing the same 失效
公开(公告)号：US4396735A
公开(公告)日：1983-08-02
申请号：US193551
申请日：1980-10-03
申请人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata
发明人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata
IPC分类号： C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08K5/3462 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09K15/18
CPC分类号： C08K5/3462 , C08K5/3435
摘要： Light stabilizers for synthetic resin compositions and synthetic resin compositions containing such stabilizers are provided, comprising(1) at least one hindered heterocyclic amine having the formula: ##STR1## wherein: X is a bivalent linking radical forming with the ring structure ##STR2## a nitrogen-containing heterocyclic ring having from five to seven ring atoms, preferably piperidine;R.sub.1 and R.sub.2 are each selected from the group consisting of lower alkyl, preferably methyl, and R.sub.1 and R.sub.2 taken together as pentylene (CH.sub.2).sub.5 ;R.sub.3 and R.sub.4 are each selected from the group consisting of lower alkyl, and R.sub.3 and R.sub.4 taken together as one of butylene--(CH.sub.2).sub.4, pentylene--(CH.sub.2).sub.5, and CH.sub.2 --C(CH.sub.3).sub.2 --NH--C(CH.sub.3).sub.2 --CH.sub.2 --;n is 1 or 2; andwhen n is 1, Y.sub.1 is selected from the group consisting of hydrogen, O.sup..cndot., OH, alkyl, alkenyl, alkynyl, aralkyl and acyl having from one to about thirty carbon atoms; andwhen n is 2, Y.sub.1 is selected from the group consisting of alkylene, alkenylene, alkynylene, cycloalkylene and aralkylene having from one to about thirty carbon atoms; together with(2) at least one heterocyclic acid hydrazide having the formula: ##STR3## wherein: R is selected from the group consisting of hydrogen, alkyl, aryl and such groups having hydroxyl, carboxylic acid ester, oxyether and carbonyl groups having from one to about thirty carbon atoms; ##STR4## is the residue of a dicarboxylic or tetracarboxylic acid, wherein Z is selected from the group consisting of alkylene, alkenylene, cycloalkylene, alkylcycloalkylene, arylene and alkylarylene having from one to about thirty carbon atoms, and such radicals bearing free carboxylic acid or carboxylic acid ester groups; andm is 1 or 2.In such combinations, the heterocyclic acid hydrazide, which alone is not a light-stabilizer, synergizes the stabilizing effectiveness of the hindered heterocyclic amine.

10. 再颁专利

USRE31261E 2,2,6,6-Tetrasubstituted-4-piperidyl carboxy heterocyclic compounds as stabilizers for synthetic polymers 失效
标题翻译： 2,2,6,6-四取代-4-哌啶基羧基杂环化合物作为合成聚合物的稳定剂
公开(公告)号：USRE31261E
公开(公告)日：1983-05-31
申请号：US325392
申请日：1981-11-27
申请人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata
发明人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata
IPC分类号： C08K5/34 , C08K5/3477
CPC分类号： C08K5/34 , C08K5/3477
摘要： 2,2,6,6-Tetrasubstituted-4-piperidyl carboxy heterocyclic compounds are provided which are useful as stabilizers for organic polymeric materials.

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