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1. 发明申请

US20100249466A1 THERMAL RECORDING MATERIAL CONTAINING TRIS(2-METHYL- 4-HYDROXY-5-t-BUTYLPHENYL)BUTANE 有权
标题翻译：含有TRIS（2-甲基-4-羟基-5-叔丁基苯基）丁烷的热记录材料
公开(公告)号：US20100249466A1
公开(公告)日：2010-09-30
申请号：US12745782
申请日：2008-12-25
申请人： Etsuo Tobita , Koichi Shigeno , Satoru Kanda , Ryozo Arata , Yamahiko Egami
发明人： Etsuo Tobita , Koichi Shigeno , Satoru Kanda , Ryozo Arata , Yamahiko Egami
IPC分类号： C07C39/16
CPC分类号： B41M5/3375 , B41M2205/04 , B41M2205/28
摘要： A thermal recording material of the invention contains, as a storability improver, tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane trapping and containing water and/or methanol and having a crystal structure that shows a maximum X-ray diffraction peak at a diffraction angle 2θ of 6.58° according to X-ray diffraction measurement using an X ray having a wavelength of a Cu—Kα line. The recording material has improved heat resistance in non-printing sections while maintaining the moisture-and-heat resistance in printing sections. The thermal recording material of the invention has a thermal-recording layer that contains the tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane in an amount of preferably 0.1 to 15% by mass with respect to the thermal-recording layer. The amount of the water and/or methanol trapped and contained in the tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane is preferably 0.1 to 10% by mass in total.
摘要翻译：本发明的热敏记录材料含有捕获并含有水和/或甲醇的三（2-甲基-4-羟基-5-叔丁基苯基）丁烷作为储存性改进剂，并且具有显示最大X射线衍射的晶体结构，衍射角2θ处的X射线衍射峰; 根据使用具有Cu-Kα线的波长的X射线的X射线衍射测定，为6.58°。记录材料在非印刷部分中具有改善的耐热性，同时保持印刷部分的耐湿热性。本发明的热敏记录材料具有热敏记录层，其相对于热敏记录层优选含有0.1〜15质量％的三（2-甲基-4-羟基-5-叔丁基苯基）丁烷，记录层。捕获并包含在三（2-甲基-4-羟基-5-叔丁基苯基）丁烷中的水和/或甲醇的量优选为总计0.1至10质量％。

2. 发明授权

US4698381A N,N',N"-tris((2,2,6,6-tetramethyl-4-piperidyl)triazinyl) undecane triamines as stabilizers for synthetic polymers 失效
标题翻译： N，N'，N“ - 三（（2,2,6,6-四甲基-4-哌啶基）三嗪基）十一烷三胺作为合成聚合物的稳定剂
公开(公告)号：US4698381A
公开(公告)日：1987-10-06
申请号：US778357
申请日：1985-09-19
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/34 , C07D401/14 , C07D491/10 , C07D491/113 , C08K5/00 , C08K5/3477 , C08K5/3492 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09D5/38 , C09D7/12
CPC分类号： C07D401/14 , C07D491/10 , C08K5/34926
摘要： N,N',N"-tris((2,2,6,6-tetramethyl-4-piperidyl)triazinyl) undecane triamines are provided having the formula: ##STR1## wherein: X is selected from the group consisting of ##STR2## in which: R is selected from the group consisting of hydrogen; oxyl O'; alkyl having from one to about eighteen carbon atoms; hydroxyalkyl having from two to about eight carbon atoms; epoxyalkyl having from three to about eight carbon atoms; alkaryl having from seven to about twelve carbon atoms; and acyl having from one to about eight carbon atoms;Y is O or NR.sub.2 ;R.sub.1 is alkyl having from one to about six carbon atoms; andR.sub.2 is hydrogen or alkyl having from one to about eighteen carbon atoms;as well as stabilizer compositions and stabilized synthetic polymer compositions containing the same having improved resistance to deterioration upon exposure to light.
摘要翻译：提供了具有下式的N，N'，N“ - 三（（2,2,6,6-四甲基-4-哌啶基）三嗪基）十一烷三胺，其中：X选自 IMAGE>其中：R选自氢; 氧基O' 具有1至约18个碳原子的烷基; 具有2至约8个碳原子的羟烷基; 具有3至约8个碳原子的环氧烷基; 具有7至约12个碳原子的烷芳基; 和具有1至约8个碳原子的酰基; Y为O或NR2; R1是具有1至约6个碳原子的烷基; 并且R 2是氢或具有1至约18个碳原子的烷基; 以及稳定剂组合物和包含该组合物的稳定的合成聚合物组合物具有改善的耐受暴露于光的劣化性。

3. 发明授权

US4525506A Polyhydric alcohol ethers of 2,2,6,6-tetramethyl-4-piperidone ketals and synthetic resin compositions 失效
标题翻译： 2,2,6,6-四甲基-4-哌啶酮缩酮的多元醇醚和合成树脂组合物
公开(公告)号：US4525506A
公开(公告)日：1985-06-25
申请号：US478610
申请日：1983-03-25
申请人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D491/056 , C07D491/113 , C07D519/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L101/00
CPC分类号： C07D519/00 , C08K5/3435 , C08K5/3477
摘要： Polyhydric alcohol ethers of 2,2,6,6-tetramethyl-4-piperidone ketals are provided, having the formula: ##STR1## wherein: R is selected from the group consisting of hydrogen, alkyl having from one to about eight carbon atoms, and alkyleneoxyalkylene, each alkylene having from two to about eight carbon atoms;R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about four carbon atoms;R.sub.2 is selected from the group consisting of hydrogen; oxyl O; alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms; acyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms; andn is a number from 3 to 6as well as synthetic resin compositions having an improved resistance to deterioration and containing such compounds.

4. 发明授权

US4500663A Light stabilizing N,N,N-tris(2,2,6,6-tetramethyl-4-piperidone ketal)-1,3,5-triazine derivatives and light stabilized synthetic resin compositions 失效
标题翻译：光稳定N，N，N-三（2,2,6,6-四甲基-4-哌啶酮缩酮）-1,3,5-三嗪衍生物和光稳定的合成树脂组合物
公开(公告)号：US4500663A
公开(公告)日：1985-02-19
申请号：US478609
申请日：1983-03-25
申请人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D491/056 , C07D491/113 , C07D519/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L101/00 , C07D405/14
CPC分类号： C07D519/00 , C08K5/3435 , C08K5/3477
摘要： N,N,N-tris(2,2,6,6-tetramethyl-4-piperidone ketal)-1,3,5-triazines are provided, having the formula: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about four carbon atoms; andR.sub.2 is selected from the group consisting of hydrogen; oxyl O; alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms; alkanoyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms; as well as synthetic resin compositions having an improved resistance to deterioration and containing such compounds.
摘要翻译：提供N，N，N-三（2,2,6,6-四甲基-4-哌啶酮缩酮）-1,3,5-三嗪，具有下式：其中：R 1选自的氢和具有1至约4个碳原子的烷基; 并且R 2选自氢; 氧基O; 烷基，羟基烷基和具有1至约18个碳原子的环氧烷基; 具有1至约18个碳原子的烷酰基; 具有3至约18个碳原子的环烷基; 苯基; 具有7至约24个碳原子的苯基烷基和烷基苯基; 以及具有改善的耐劣化性和含有这些化合物的合成树脂组合物。

5. 发明授权

US4888371A Bis(2,6-dis-tert-butyl-4-branched propyl or butyl phenyl)-pentaerythritol spiro phosphites and synthetic resin compositions containing such phosphites 失效
标题翻译：双（2,6-二叔丁基-4-支链丙基或丁基苯基） - 季戊四醇螺亚磷酸酯和含有这种亚磷酸酯的合成树脂组合物
公开(公告)号：US4888371A
公开(公告)日：1989-12-19
申请号：US120564
申请日：1987-11-13
申请人： Kenji Tajima , Tetsuo Tsuboi , Ryozo Arata
发明人： Kenji Tajima , Tetsuo Tsuboi , Ryozo Arata
IPC分类号： C08K5/52 , C07F9/6574 , C08K5/527 , C08L101/00
CPC分类号： C08K5/527 , C07F9/65746
摘要： Bis(2,6-di tert butyl-4-branched propyl or butyl phenyl)-pentaerythritol spiro phosphites are provided having the formula: ##STR1## wherein R is a branched propyl or butyl group, such as isopropyl, iso-butyl, or sec-butyl, as well as synthetic resin compositions having enhanced resistance to deterioration upon exposure to the heat and light comprising such as bis(2,6-di-t-butyl-4-branched propyl or butyl phenyl)pentaerythritol spiro phosphites.
摘要翻译：提供了具有下式的双（2,6-二叔丁基-4-支链丙基或丁基苯基） - 季戊四醇螺亚磷酸酯：其中R是支链丙基或丁基，例如异丙基，异丁基或仲丁基，以及具有增强的耐受暴露于热和光的劣化的合成树脂组合物，包括例如双（2,6-二叔丁基-4-支链丙基或丁基苯基）季戊四醇螺亚磷酸酯。

6. 发明授权

US4468488A Poly(piperidylamine) alkanes and synthetic resin compositions stabilized thereby 失效
标题翻译：聚（哌啶胺）烷烃和由此稳定的合成树脂组合物
公开(公告)号：US4468488A
公开(公告)日：1984-08-28
申请号：US470103
申请日：1983-02-28
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07D211/58 , C07D401/12 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L101/00 , C07D401/14 , C08L25/06
CPC分类号： C07D401/12 , C07D211/58 , C08K5/3435
摘要： Poly(piperidylamine) alkanes represented by the Formula (I) or (II): ##STR1## and synthetic resin compositions having improved resistance to deterioration by light containing such compounds.
摘要翻译：由式（I）或（II）表示的聚（哌啶胺）烷烃：具有改善的抗含劣化性的光的耐劣化性的合成树脂组合物。

7. 发明授权

US08154571B2 Thermal recording material containing tris(2-Methyl-4-hydroxy-5-t-butylphenyl)butane 有权
标题翻译：含有三（2-甲基-4-羟基-5-叔丁基苯基）丁烷的热敏记录材料
公开(公告)号：US08154571B2
公开(公告)日：2012-04-10
申请号：US12745782
申请日：2008-12-25
申请人： Etsuo Tobita , Koichi Shigeno , Satoru Kanda , Ryozo Arata , Yamahiko Egami
发明人： Etsuo Tobita , Koichi Shigeno , Satoru Kanda , Ryozo Arata , Yamahiko Egami
IPC分类号： G01D9/00 , C07C39/16 , B41M5/337
CPC分类号： B41M5/3375 , B41M2205/04 , B41M2205/28
摘要： A thermal recording material of the invention contains, as a storability improver, tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane trapping and containing water and/or methanol and having a crystal structure that shows a maximum X-ray diffraction peak at a diffraction angle 2θ of 6.58° according to X-ray diffraction measurement using an X ray having a wavelength of a Cu—Kα line. The recording material has improved heat resistance in non-printing sections while maintaining the moisture-and-heat resistance in printing sections. The thermal recording material of the invention has a thermal-recording layer that contains the tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane in an amount of preferably 0.1 to 15% by mass with respect to the thermal-recording layer. The amount of the water and/or methanol trapped and contained in the tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane is preferably 0.1 to 10% by mass in total.
摘要翻译：本发明的热敏记录材料含有捕获并含有水和/或甲醇的三（2-甲基-4-羟基-5-叔丁基苯基）丁烷作为储存性改进剂，并且具有显示最大X射线衍射的晶体结构，衍射角2θ处的X射线衍射峰; 根据使用具有Cu-Kα线的波长的X射线的X射线衍射测定，为6.58°。记录材料在非印刷部分中具有改善的耐热性，同时保持印刷部分的耐湿热性。本发明的热敏记录材料具有热敏记录层，其相对于热敏记录层优选含有0.1〜15质量％的三（2-甲基-4-羟基-5-叔丁基苯基）丁烷，记录层。捕获并包含在三（2-甲基-4-羟基-5-叔丁基苯基）丁烷中的水和/或甲醇的量优选为总计0.1至10质量％。

8. 发明授权

US4673701A Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups and synthetic resin composition 失效
标题翻译：亚烷基双酚亚磷酸酯和具有2,2,6,6-四甲基哌啶基的磷酸酯和合成树脂组合物
公开(公告)号：US4673701A
公开(公告)日：1987-06-16
申请号：US687090
申请日：1984-12-28
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08K5/00 , C07F9/6574 , C08K5/52 , C08K5/523 , C08K5/526 , C08K5/529 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C08K5/34
CPC分类号： C07F9/65744 , C08K5/529
摘要： Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula: ##STR1## wherein: R.sub.1 is alkyl having from one to about twelve carbon atoms;R.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;m is 0 or 1;n is 0 or 1;X is selected from the group consisting of ##STR2## wherein: R.sub.5 is selected from the group consisting of hydrogen, oxyl O.sup.2, alkyl having from one to about twelve carbon atoms; arylalkyl having from seven to about eighteen carbon atoms; 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and ##STR3## in which R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y.sub.1 is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and ##STR4## Z.sub.1 is selected from the group consisting of ##STR5## wherein R.sub.7 is alkyl from one to about twelve carbon atoms; and ##STR6## wherein: R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl; andZ.sub.2 is selected from the group consisting of ##STR7## in which R.sub.7 is alkyl having from one to about twelve carbon atoms; R.sub.6 is alkylene having from one to about eight carbon atoms andY.sub.2 is selected from the group consisting of hydrogen and acyl having from one to about eight carbon atoms.
摘要翻译：提供具有2,2,6,6-四甲基哌啶基的亚烷基双酚亚磷酸酯和磷酸酯，其具有下式：其中：R1是具有1至约12个碳原子的烷基; R2，R3和R4各自选自氢和具有1至约12个碳原子的烷基; m为0或1; n为0或1; X选自（1）其中：R 5选自氢，氧基O 2，具有1至约12个碳原子的烷基; 具有7至约18个碳原子的芳基烷基; 2,3-环氧丙基，具有1至约8个碳原子的酰基和，其中R 6选自氢，具有1至约12个碳原子的烷基和苯基，Y 1选自由氢组成具有1至约12个碳原子的酰基; 并且＆lt; IMAGE＆gt; Z1选自，其中R 7为1至约12个碳原子的烷基; （2）其中：R6选自氢，具有1至约12个碳原子的烷基和苯基; Z2选自由下列组成的组：其中R 7为具有1至约12个碳原子的烷基; R 6是具有1至约8个碳原子的亚烷基，Y 2选自氢和具有1至约8个碳原子的酰基。

9. 发明授权

US4460725A Polyethers containing 2,2,6,6-tetramethyl piperidinyl carboxylic acid ester groups and synthetic resin compositions 失效
标题翻译：含有2,2,6,6-四甲基哌啶基羧酸酯基团的聚醚和合成树脂组合物
公开(公告)号：US4460725A
公开(公告)日：1984-07-17
申请号：US472710
申请日：1983-03-07
申请人： William E. Leistner , Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
发明人： William E. Leistner , Motonobu Minagawa , Naohiro Kubota , Toshihiro Shibata , Ryozo Arata
IPC分类号： C08L101/00 , C07D211/22 , C07D211/62 , C07D211/66 , C07D405/12 , C07D491/10 , C08G65/00 , C08G65/22 , C08G65/26 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L71/02 , C07D251/00 , C07D251/28 , C07D403/00
CPC分类号： C07D405/12 , C07D211/22 , C07D211/62 , C07D211/66 , C07D491/10 , C08K5/3435
摘要： Polyethers containing 2,2,6,6-tetramethyl piperidinyl carboxylic acid ester or ether groups are provided, comprising polymeric units having the structure ##STR1## wherein X is selected from the group consisting of: ##STR2## R.sub.1 is selected from the group consisting of hydrogen, --O, alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms, acyl having from one to about eighteen carbon atoms, cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms;R.sub.2 is hydrogen or hydroxy;n.sub.1 is 0 or 1;R.sub.3 is lower alkyl having from one to about six carbon atoms; andn is the average number of such units in the polymer; as well as stabilized synthetic resin compositions comprising such polyethers.
摘要翻译：提供了包含2,2,6,6-四甲基哌啶基羧酸酯或醚基团的聚醚，其包含具有以下结构的聚合物单元，其中X选自由以下组成的组： R 1选自氢，-O，烷基，羟基烷基和具有1至约18个碳原子的环氧烷基，具有1至约18个碳原子的酰基，具有3至约8个碳原子的环烷基十八个碳原子; 苯基; 具有7至约24个碳原子的苯基烷基和烷基苯基; R2是氢或羟基; n1为0或1; R3是具有1至约6个碳原子的低级烷基; n是聚合物中这些单元的平均数; 以及包含这种聚醚的稳定的合成树脂组合物。

10. 发明授权

US4623685A Thermosetting synthetic resin lacquer compositions of improved light stability 失效
标题翻译：改善光稳定性的热固性合成树脂漆组合物
公开(公告)号：US4623685A
公开(公告)日：1986-11-18
申请号：US714236
申请日：1985-03-21
申请人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
发明人： Motonobu Minagawa , Yutaka Nakahara , Toshihiro Shibata , Ryozo Arata
IPC分类号： C09D7/00 , C08K5/3435 , C08L61/20 , C09D5/00 , C09D5/32 , C09D7/12 , C09D133/06 , C09D167/00 , C08K5/34
CPC分类号： C09D133/06 , C08K5/3435 , C09D167/00 , C09D7/1241 , C08L61/20
摘要： Thermosetting synthetic resin lacquer compositions are provided having improved resistance to deterioration when exposed to ultraviolet light, comprising a 1-phenoxycarbonyl-2,2,6,6-tetramethylpiperidyl compound.
摘要翻译：提供热固化合成树脂漆组合物，其在暴露于紫外线时具有改善的耐劣化性，其包含1-苯氧羰基-2,2,6,6-四甲基哌啶化合物。

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