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    • 1. 发明授权
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US07521395B2
    • 2009-04-21
    • US10521806
    • 2003-07-22
    • William B. O'NealElmar KiblerDan E. WestbergMatthias WitschelHerve R. Vantieghem
    • William B. O'NealElmar KiblerDan E. WestbergMatthias WitschelHerve R. Vantieghem
    • A01N43/64A01N43/00A01N43/66A01N63/00A01N43/653
    • A01N43/56A01N47/36A01N61/00A01N43/70A01N43/10A01N43/88A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoly derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl, R6 is hydrogen or alkyl; or one of its environmentally compatible salts; B) nicosulfuron (II) or one of its environmentally compatible salts; and C) at least one herbicidal compound from the group triazines or one of their environmentally compatible salts, in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesirable plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯并多羟基衍生物,其中变量具有以下含义:R 1,R 3为卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R2是任选取代的杂环基团,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基,4,5-二氢异恶唑-4-基和 4,5-二氢异恶唑-5-基; R4是氢,卤素或烷基; R5是烷基,R6是氢或烷基; 或其环境相容的盐之一; B)烟嘧磺隆(II)或其与环境相容的盐之一; 和C)至少一种来自组合三嗪或其环境相容性盐之一的除草化合物,其协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 2. 发明授权
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US07632782B2
    • 2009-12-15
    • US10519978
    • 2003-07-08
    • William B. O'NealElmar KiblerMatthias WitschelHerve R. Vantieghem
    • William B. O'NealElmar KiblerMatthias WitschelHerve R. Vantieghem
    • A01N43/90A01N47/36A61K31/00
    • A01N43/80A01N47/36A01N2300/00A01N43/56A01N43/70A01N43/88
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of the compound of formula II or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; and, if desired, D) at least a safener. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3为卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R2是任选取代的杂环基团,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基,4,5-二氢异恶唑-4-基和 4,5-二氢异恶唑-5-基; R4是氢,卤素或烷基; R5是烷基; R6是氢或烷基; 或其环境相容的盐之一; 和B)协同有效量的式II化合物或其环境相容的盐之一; 并且如果需要,C)至少一种另外的除草化合物; 并且如果需要,D)至少一个安全剂。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 3. 发明申请
    • Piperazine Compounds Having Herbicidal Action
    • 具有除草作用的哌嗪化合物
    • US20100173777A1
    • 2010-07-08
    • US12663781
    • 2008-06-11
    • Eike HupeThomas SeitzMatthias WitschelDschun SongWilliam Karl MobergLiliana Parra RapadoFrank StelzerAndrea VescoviTrevor William NewtonRobert ReinhardBernd SievernichKlaus GrossmannThomas EhrhardtMichael RackElmar Kibler
    • Eike HupeThomas SeitzMatthias WitschelDschun SongWilliam Karl MobergLiliana Parra RapadoFrank StelzerAndrea VescoviTrevor William NewtonRobert ReinhardBernd SievernichKlaus GrossmannThomas EhrhardtMichael RackElmar Kibler
    • A01N43/60C07D241/04A01P13/00
    • C07D241/08A01N43/60
    • The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy; and R11 is hydrogen or C1-C4-alkyl; and the agriculturally useful salts of these compounds.
    • 本发明涉及下面定义的通式I的哌嗪化合物及其作为除草剂的用途。 此外,本发明涉及用于作物保护的组合物和用于防治不想要的植物的方法。 R 1选自卤素,氰基,硝基,Z-C(= O)-R 12,苯基和具有1,2,3或4个杂原子的5或6元杂环基,所述杂原子选自 的O,N和S作为环原子,其中苯基和杂环基是未取代的或可以具有1,2,3或4个取代基R 1a; Z是共价键或CH2基; R12是氢,C1-C6-烷基,C3-C6-环烷基,C2-C6-烯基,C5-C6-环烯基,C2-C6-炔基等; R2是氢,卤素,硝基,氰基,C1-C4-烷基,C1-C4卤代烷基,C2-C4-烯基,C1-C4-烷氧基,C1-C4-卤代烷氧基,苄基或基团S(O) 其中R 21为C 1 -C 4烷基或C 1 -C 4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4-烷基,C3-C4-烯基或C3-C4-炔基; R 5为氢,C 1 -C 4 - 烷基,C 3 -C 4 - 烯基,C 3 -C 4 - 炔基或C(= O)R 51,其中R 51为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基, C 4 - 烷氧基或C 1 -C 4 - 卤代烷氧基; R 6是C 1 -C 4烷基,C 1 -C 4羟基烷基或C 1 -C 4卤代烷基; R 7,R 8彼此独立地是氢,OH,C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4 - 烷基或C 1 -C 4卤代烷基; R 9,R 10彼此独立地选自氢,卤素,CN,NO 2,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 2 -C 4 - 烯基,C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基 和R 11是氢或C 1 -C 4 - 烷基; 和这些化合物的农业上有用的盐。
    • 4. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20060009358A1
    • 2006-01-12
    • US10522097
    • 2003-07-24
    • Elmar KiblerWilliam O'NealMatthias WitschelHerve VantiegheimDan Westberg
    • Elmar KiblerWilliam O'NealMatthias WitschelHerve VantiegheimDan Westberg
    • A01N63/00A01N57/00
    • A01N43/40A01N43/56A01N43/80A01N43/90A01N61/00A01N43/70A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) at least the compound of formula IIa or one of its environmentally compatible salts; or the compound of formula IIb or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基, 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)至少所述式IIa化合物或其环境相容的盐之一; 或式IIb的化合物或其环境相容的盐之一; 并且如果需要,C)至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 5. 发明申请
    • Piperazine Compounds Whith a Herbicidal Action
    • 哌嗪化合物具有除草作用
    • US20100152047A1
    • 2010-06-17
    • US12663784
    • 2008-06-11
    • Eike HupeThomas SeitzMatthias WitschelDschun SongWilliam Karl MobergLiliana Parra RapadoFrank StelzerAndrea VescoviTrevor William NewtonRobert ReinhardBernd SievernichKlaus GrossmannThomas EhrhardtMichael RackElmar Kibler
    • Eike HupeThomas SeitzMatthias WitschelDschun SongWilliam Karl MobergLiliana Parra RapadoFrank StelzerAndrea VescoviTrevor William NewtonRobert ReinhardBernd SievernichKlaus GrossmannThomas EhrhardtMichael RackElmar Kibler
    • A01N43/58C07D403/10C07D401/10C07D241/02C07D413/10A01N43/54A01N43/60A01P13/00
    • C07D241/08C07D403/10C07D407/10C07D409/10C07D413/10C07D417/10
    • The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. In formula I, the variables have the following meanings: R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R11, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R11 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; and R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy.
    • 本发明涉及下面定义的通式I的哌嗪化合物及其作为除草剂的用途。 此外,本发明涉及用于作物保护的组合物和用于防治不想要的植物的方法。 在式I中,变量具有以下含义:R 1选自卤素,氰基,硝基,Z-C(= O)-R 11,苯基和具有1, 2,3或4个选自O,N和S作为环原子的杂原子,其中苯基和杂环基是未取代的或可以具有1,2,3或4个取代基R 1a; Z是共价键或CH2基; R11是氢,C1-C6-烷基,C3-C6-环烷基,C2-C6-烯基,C5-C6-环烯基,C2-C6-炔基等; R2是氢,卤素,硝基,氰基,C1-C4-烷基,C1-C4卤代烷基,C2-C4-烯基,C1-C4-烷氧基,C1-C4-卤代烷氧基,苄基或基团S(O) 其中R 21为C 1 -C 4烷基或C 1 -C 4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4-烷基,C3-C4-烯基或C3-C4-炔基; R 5为氢,C 1 -C 4 - 烷基,C 3 -C 4 - 烯基,C 3 -C 4 - 炔基或C(= O)R 51,其中R 51为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基, C 4 - 烷氧基或C 1 -C 4 - 卤代烷氧基; R 6是C 1 -C 4烷基,C 1 -C 4羟基烷基或C 1 -C 4卤代烷基; R 7,R 8彼此独立地是氢,OH,C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4 - 烷基或C 1 -C 4卤代烷基; R 9,R 10彼此独立地选自氢,卤素,CN,NO 2,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 2 -C 4 - 烯基,C 1 -C 4 - 烷氧基和C 1 -C 4 卤代烷氧基。
    • 6. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20050256002A1
    • 2005-11-17
    • US10521806
    • 2003-07-22
    • William O'NealElmar KiblerDan WestbergMatthias WitschelHerve Vantiegheim
    • William O'NealElmar KiblerDan WestbergMatthias WitschelHerve Vantiegheim
    • A01N43/80A01N43/10A01N43/56A01N43/647A01N43/70A01N43/713A01N43/88A01N47/36
    • A01N43/56A01N47/36A01N61/00A01N43/70A01N43/10A01N43/88A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydro-isoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) the compound of formula II or one of its environmentally compatible salts; and C) at least one further herbicidal compound from the group of the acetolactate synthase inhibitors (ALS), lipid biosynthesis inhibitors and photosynthesis inhibitors; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基, 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)式II化合物或其环境相容的盐之一; 和C)来自乙酰乳酸合酶抑制剂(ALS),脂质生物合成抑制剂和光合作用抑制剂的至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 8. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20050239654A1
    • 2005-10-27
    • US10522157
    • 2003-07-22
    • Elmar KiblerWilliam O'NealMatthias WitschelHerve Vantieghem
    • Elmar KiblerWilliam O'NealMatthias WitschelHerve Vantieghem
    • A01N43/50A01N43/647A01N43/70A01N43/713A01N43/72A01N43/80
    • A01N43/80A01N2300/00
    • A synergistic herbicidal mixture comprising: A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) two herbicides selected from the group including imazapyr, imazaquin, imazamethabenz-methyl, imazarnox, imazapic and imazethapyr; or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants
    • 一种协同除草混合物,其包含:A)至少一种式(I)的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基, 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)选自以下的两种除草剂:咪草烟,咪草喹,咪草地嗪 - 甲基,咪草铵,咪唑并咪唑和咪草烟; 或其环境相容的盐之一; 并且如果需要,C)至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途
    • 9. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20060166828A1
    • 2006-07-27
    • US10519978
    • 2003-07-08
    • William O'NealElmar KiblerMatthias WitschelHerve Vantieghem
    • William O'NealElmar KiblerMatthias WitschelHerve Vantieghem
    • A01N43/60
    • A01N43/80A01N47/36A01N2300/00A01N43/56A01N43/70A01N43/88
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of the compound of formula II or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; and, if desired, D) at least a safener. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基, 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)协同有效量的式II化合物或其环境相容的盐之一; 并且如果需要,C)至少一种另外的除草化合物; 并且如果需要,D)至少一个安全剂。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。