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1. 发明授权

US06627782B2 Preparation of 1-olefins 有权
公开(公告)号：US06627782B2
公开(公告)日：2003-09-30
申请号：US10067924
申请日：2002-02-08
申请人： Alfred Kaizik , Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
发明人： Alfred Kaizik , Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
IPC分类号： C07C100
CPC分类号： C07C29/145 , C07C11/02 , C07C45/74 , C07C49/203 , C07C31/125 , C07C31/10
摘要： A multi-stage synthesis is effective for preparing 1-olefins from aldehydes. The aldehyde is condensed with acetone to form an &agr;,&bgr;-unsaturated ketone. The unsaturated ketone is hydrogenated to yield a saturated alcohol. By dehydrating the saturated alcohol a 1-olefin is obtained. The olefin can be isolated in high yield and purified.

2. 发明授权

US06482992B2 Multistage process for the preparation of oxo aldehydes and/or alcohols 有权
标题翻译：用于制备羰基醛和/或醇的多步法
公开(公告)号：US06482992B2
公开(公告)日：2002-11-19
申请号：US09904893
申请日：2001-07-16
申请人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
发明人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C29/16 , C07C31/125 , C07C47/02
摘要： Olefins are hydroformylated to give alcohols and/or aldehydes in a plurality of hydroformylation stages, each of which comprises: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98%; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiler fraction in subsequent process stages comprising steps a, b and c and combining the bottoms fractions of process steps c) of all process stages.
摘要翻译：烯烃被加氢甲酰化以在多个加氢甲酰化阶段中产生醇和/或醛，其各自包括：a）在反应器中的钴或铑催化剂存在下，碳原子含量为6至24个碳原子的烯烃加氢甲酰化到烯烃反应物转化为产物的程度为20至98％; b）从从反应器排出的所得液体中除去催化剂; c）将所得液体加氢甲酰化混合物分离成包含烯烃和链烷烃的低沸点馏分，以及包含醛和/或醇的底部馏分; 和在下列工艺阶段中存在的低沸点馏分中存在的烯烃反应，包括步骤a，b和c，并组合所有工艺步骤的工艺步骤c）的底部馏分。

3. 发明授权

US06340778B1 Process for catalytic aldol condensations by means of a multiphase reaction 有权
标题翻译：通过多相反应催化醛醇缩合的方法
公开(公告)号：US06340778B1
公开(公告)日：2002-01-22
申请号：US09694350
申请日：2000-10-24
申请人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann , Juergen Koch
发明人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann , Juergen Koch
IPC分类号： C07C4572
CPC分类号： B01J8/06 , B01J2208/00265 , C07C45/74 , C07C47/21
摘要： The invention relates to a process for the catalytic aldol condensation of aldehydes by means of a multiphase reaction in a tube reactor, wherein the catalyst is present in the continuous phase and at least one aldehyde is present in a dispersed phase and the loading factor B of the tube reactor is equal to or greater than 0.8; the aldol condensation products obtained in this way can be used for preparing alcohols or carboxylic acids.
摘要翻译：本发明涉及在管式反应器中通过多相反应催化醛醛缩合的方法，其中催化剂存在于连续相中，并且至少一种醛存在于分散相中，负载因子B为管式反应器等于或大于0.8; 以这种方式获得的醛醇缩合产物可用于制备醇或羧酸。

4. 发明授权

US06433230B1 Process for conducting an aldol condensation 有权
标题翻译：醛醇缩合的方法
公开(公告)号：US06433230B1
公开(公告)日：2002-08-13
申请号：US09716941
申请日：2000-11-22
申请人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
发明人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
IPC分类号： C07C49203
CPC分类号： C07C45/75 , C07C45/74 , C07C47/21 , C07C49/203
摘要： &agr;,&bgr;-Unsaturated keto compounds are prepared by base-catalyzed aldol condensation of aldehydes and/or ketones having from 1 to 15 carbon atoms, comprising: reacting the aldehydes and/or ketones with an aqueous catalyst solution under adiabatic reaction conditions; and separating the reaction mixture obtained by rapid distillation into a top product comprising water, aldehyde and/or ketone and a bottom product comprising &agr;,&bgr;-unsaturated keto compounds and aqueous catalyst phase.
摘要翻译： α，β-不饱和酮化合物通过醛和/或具有1至15个碳原子的酮的碱催化醛醇缩合制备，包括：在绝热反应条件下使醛和/或酮与含水催化剂溶液反应; 并将通过快速蒸馏获得的反应混合物分离成包含水，醛和/或酮的顶部产物和包含α，β-不饱和酮化合物和含水催化剂相的底部产物。

5. 发明授权

US08226829B2 Method for separating organic transition metal complex catalysts 有权
标题翻译：分离有机过渡金属络合物催化剂的方法
公开(公告)号：US08226829B2
公开(公告)日：2012-07-24
申请号：US12088041
申请日：2006-09-08
申请人： Klaus-Diether Wiese , Goetz Baumgarten , Franz-Felix Kuppinger , Oliver Moeller , Dagmara Ortmann , Cornelia Borgmann , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Goetz Baumgarten , Franz-Felix Kuppinger , Oliver Moeller , Dagmara Ortmann , Cornelia Borgmann , Wilfried Bueschken
IPC分类号： B01D63/00 , C07C47/00
CPC分类号： B01D61/027 , B01D53/22 , B01D2311/2653 , B01D2313/143 , B01D2325/30 , B01D2325/38 , B01J31/1845 , B01J2231/321 , B01J2531/822 , Y02P20/582
摘要： Process for separating a dissolved complex catalyst of a metal of group 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements and/or any free organophosphorus ligand present from a nonaqueous hydroformylation reaction mixture which contains an aldehyde product and an organic solvent at least one membrane which is more permeable to the hydroformylation product than to the organophosphorus ligand, the separation being carried out under a carbon monoxide partial vapor pressure of more than 200 kPa.
摘要翻译：分离元素周期表第4,5,6,7,8,9或10族金属的溶解络合物催化剂的方法和/或从含有醛的非水加氢甲酰化反应混合物中存在的任何游离有机磷配体产物和有机溶剂至少一种对加氢甲酰化产物比对有机磷配体更可渗透的膜，该分离是在大于200kPa的一氧化碳部分蒸气压下进行的。

6. 发明授权

US06603047B2 Condensation of aldehydes with ketones by multiphase reaction 失效
公开(公告)号：US06603047B2
公开(公告)日：2003-08-05
申请号：US10068955
申请日：2002-02-11
申请人： Klaus-Diether Wiese , Wilfried Buschken , Guido Protzmann
发明人： Klaus-Diether Wiese , Wilfried Buschken , Guido Protzmann
IPC分类号： C07C4573
CPC分类号： C07C45/74 , C07C29/172 , C07C45/62 , C07C49/203 , C07C31/20
摘要： A process for conducting multiphase reactions, especially the preparation of &agr;,&bgr;-unsaturated ketones by condensation of aldehydes with ketones.

7. 发明授权

US08461394B2 Process for preparing C5 aldehyde mixtures with a high n-pentanal content 有权
标题翻译：制备具有高正戊醛含量的C5醛混合物的方法
公开(公告)号：US08461394B2
公开(公告)日：2013-06-11
申请号：US12995800
申请日：2009-04-28
申请人： Hans-Gerd Lueken , Dirk Fridag , Udo Lenz , Hermann-Josef Schulte-Althoff , Klaus-Diether Wiese , Alfred Kaizik , Patrick Muhlack , Wilfried Bueschken , Frank Hoeper
发明人： Hans-Gerd Lueken , Dirk Fridag , Udo Lenz , Hermann-Josef Schulte-Althoff , Klaus-Diether Wiese , Alfred Kaizik , Patrick Muhlack , Wilfried Bueschken , Frank Hoeper
IPC分类号： C07C45/50
CPC分类号： B01J31/0237 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/582 , C07C47/02
摘要： A process for preparing a C5 aldehyde mixture from a hydrocarbon mixture comprising at least one linear butene by terminal hydroformylation under isomerizing conditions, using a catalyst system comprising rhodium, a bisphosphite ligand, and an amine.
摘要翻译：一种通过使用包含铑，二亚磷酸酯配位体和胺的催化剂体系在异构化条件下通过末端加氢甲酰基化从包含至少一个直链丁烯的烃混合物制备C5醛混合物的方法。

8. 发明授权

US08143468B2 Process for preparing 3-methylbut-1-ene 有权
标题翻译： 3-甲基丁-1-烯的制备方法
公开(公告)号：US08143468B2
公开(公告)日：2012-03-27
申请号：US12300224
申请日：2007-05-11
申请人： Alfred Kaizik , Klaus-Diether Wiese , Dietrich Maschmeyer , Dieter Hess , Wilfried Bueschken , Franz Nierlich
发明人： Alfred Kaizik , Klaus-Diether Wiese , Dietrich Maschmeyer , Dieter Hess , Wilfried Bueschken , Franz Nierlich
IPC分类号： C08F110/08 , C07C5/27
CPC分类号： C07C1/24 , Y02P20/127 , C07C11/10
摘要： The present invention relates to the preparation of 3-methylbut-1-ene from a hydrocarbon stream I comprising isobutene by feeding a hydrocarbon stream II which comprises at least 70% by mass of isobutene in relation to the olefins present in the hydrocarbon stream and which has been obtained from hydrocarbon stream I or is identical to it to a process step for hydroformylation in which isobutene is hydroformylated in the presence of a rhodium catalyst, hydrogenating the aldehyde obtained from the hydroformylation of isobutene to the corresponding alcohol and preparing 3-methylbut-1-ene by water elimination from the alcohol.
摘要翻译：本发明涉及从包含异丁烯的烃流I中制备3-甲基丁-1-烯，该烃流包含相对于存在于烃流中的烯烃至少70质量％的异丁烯的烃流II，其中已经从烃流I获得或者与加氢甲酰化的方法步骤相同，其中异丁烯在铑催化剂的存在下被加氢甲酰化，氢化从异丁烯的加氢甲酰化得到的醛到相应的醇，并制备3-甲基丁酸， 1-ene由酒精消除水分。

9. 发明授权

US07381838B2 Preparation of tertiary carboxylic acids 失效
标题翻译：叔羧酸的制备
公开(公告)号：US07381838B2
公开(公告)日：2008-06-03
申请号：US11071166
申请日：2005-03-04
申请人： Klaus-Diether Wiese , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Wilfried Bueschken
IPC分类号： C07C51/14 , C07C51/10
CPC分类号： B01J19/243 , B01J19/2415 , B01J2219/00033 , B01J2219/00103 , B01J2219/00108 , B01J2219/00243 , C07C51/14 , C07C53/126
摘要： Process for carrying out catalytic multiphase reactions in a tubular reactor, in which at least three reactants are present in three different phases, wherein the process is carried out in at least one tubular reactor, and the catalyst is present in a continuous phase, at least one reactant is present in this continuous phase, and at least two reactants are present dispersed in the continuous phase and the loading factor B of the tubular reactor is equal to or greater than 0.2. In particular, the multiphase reaction is a hydrocarboxylation of at least one olefin to a carboxylic acid.
摘要翻译：在管式反应器中进行催化多相反应的方法，其中至少三种反应物存在于三个不同的相中，其中该方法在至少一个管式反应器中进行，并且催化剂至少存在于连续相中在该连续相中存在一种反应物，并且至少两种反应物分散在连续相中，并且管式反应器的负载因子B等于或大于0.2。特别地，多相反应是至少一种烯烃与羧酸的加氢羧化反应。

10. 发明授权

US07323586B2 Phthalic acid alkyl ester mixtures with controlled viscosity 失效
标题翻译：邻苯二甲酸烷基酯混合物具有可控的粘度
公开(公告)号：US07323586B2
公开(公告)日：2008-01-29
申请号：US10487061
申请日：2002-09-20
申请人： Klaus-Diether Wiese , Michael Grass , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Michael Grass , Wilfried Bueschken
IPC分类号： C07C67/08 , C07C67/10 , C07C69/76 , C09K3/00
CPC分类号： C07C69/80 , C08K5/12 , C10M105/36 , C10M129/72 , C10M2207/285 , C10M2207/2855 , C10N2240/08 , C10N2270/00
摘要： Mixtures of isomeric dialkyl phthalates that have a desired viscosity are prepared by esterifying phthalic acid or phthalic anhydride with a mixture of isomeric alkyl alcohols having a certain carbon number of carbon atoms, where the molar fraction of each alkyl alcohol isomer of the isomeric alcohol mixture is determined, and where the viscosity parameter of each alkyl alcohol isomer of the alcohol mixture, which, upon reacting with phthalic acid or phthalic anhydride, results in a mixed isomer dialkyl phalate ester product having a specific desired viscosity, is determined in accordance with formula (I): ln(η)=Σχi*ln(ηi) (I) where η=the calculated viscosity of a dialkyl phthalate mixture, χi=the molar fraction of an isomerically pure alcohol (i), and ηi=the viscosity parameter of isomerically pure alcohol (i).
摘要翻译：具有所需粘度的异构二烷基邻苯二甲酸酯的混合物通过用具有一定碳原子数的异构烷基醇的混合物酯化邻苯二甲酸或邻苯二甲酸酐来制备，其中异构醇混合物的各烷基醇异构体的摩尔分数为并且其中与邻苯二甲酸或邻苯二甲酸酐反应产生具有特定所需粘度的混合异构体癸酸二烷基酯产物的醇混合物的每种烷基醇异构体的粘度参数根据式（ I）：<？in-line-formula description =“In-line Formulas”end =“lead”？> ln（eta）= Sigmachi >）（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中eta =邻苯二甲酸二烷基酯混合物的计算粘度，异构纯的醇（i）的摩尔分数，和异构纯的醇钠的粘度参数（i）。

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