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1. 发明授权

US4549898A N-Heterocyclosulfonyl-N'-pyrimidinylureas and N-heterocyclosulfonyl-N'-triazinylureas 失效
公开(公告)号：US4549898A
公开(公告)日：1985-10-29
申请号：US501459
申请日：1983-06-06
申请人： Beat Bohner , Werner Fory , Karl Gass , Willy Meyer
发明人： Beat Bohner , Werner Fory , Karl Gass , Willy Meyer
IPC分类号： A01N47/36 , C07D401/12 , C07D403/12 , C07D407/12 , C07D409/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： N-heterocyclosulfonyl-N'-pyrimidinylureas and N-heterocyclosulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein X is oxygen, sulfur, ##STR2## Y is oxygen or sulfur, Z is oxygen or sulfur,E is nitrogen or --CH.dbd.,R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 alkylthio, --NR.sub.6 R.sub.7 or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.2 is hydrogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, halogen, nitro, C.sub.1 -C.sub.3 alkoxy, ##STR3## --SO.sub.2 --NR.sub.6 R.sub.7, --SO.sub.n --C.sub.1 -C.sub.3 alkyl or --CO--R.sub.9,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, methoxy, nitro or trifluoromethyl,R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 cyanoalkyl, C.sub.3 14 C.sub.6 cycloalkyl, benzyl, --CO--C.sub.1 -C.sub.4 alkoxy, --CO--NR.sub.6 R.sub.7 or --CO--C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.5 is hydrogen, nitro, fluorine, chlorine, bromine, methyl, trifluoromethyl, --SO.sub.n --C.sub.1 -C.sub.3 alkyl, --CO--C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.3 alkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 cyanoalkyl, methoxy or ethoxy,R.sub.7 is hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 alkenyl, orR.sub.6 and R.sub.7, together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated heterocyclic ring which may contain an oxygen or a sulfur atom as ring member,R.sub.8 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.4 -Chd 7cycloalkylalkyl or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.9 is C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.2 -C.sub.6 haloalkoxy, C.sub.1 -C.sub.4 cyanoalkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynylthio, C.sub.5 -C.sub.6 cycloalkoxy, C.sub.4 -C.sub.7 cycloalkylalkoxy, --NR.sub.6 R.sub.7 or alkoxyalkoxy containing not more than 6 carbon atoms,W is oxygen or .dbd.N--O--R.sub.10, wherein R.sub.10 is hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 alkenyl, andn is a value from 0 to 2and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.

2. 发明授权

US5114462A 1,5-Diphenylpyrazole-3-carboxylic acid derivatives for the protection of cultivated plants 失效
公开(公告)号：US5114462A
公开(公告)日：1992-05-19
申请号：US325834
申请日：1989-03-20
申请人： Hans Moser , Beat Bohner , Werner Fory
发明人： Hans Moser , Beat Bohner , Werner Fory
IPC分类号： C07F7/18 , A01N25/04 , A01N25/32 , A01N43/40 , A01N43/56 , A01P13/00 , C07D231/14 , C07D401/12 , C07D405/12 , C07D409/12 , C07D417/12 , C07D487/04 , C07D521/00
CPC分类号： C07D231/12 , A01N25/32 , C07D231/14 , C07D233/56 , C07D249/08 , C07D401/12 , C07D405/12 , C07D409/12 , C07D417/12 , C07D487/04
摘要： 1,5-diphenylpyrazole-3-carboxylic acid derivatives of the formula ##STR1## in which each of R.sub.a and R.sub.b, independently of the other, represents halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl or cyano, n represents zero or an integer from 1 to 3, and OR.sub.1 represents hydroxy, a plant-physiologically tolerable salt radical or any desired ester radical, are capable of antagonizing specifically the phytotoxic action of phenoxypropionic acid ester herbicides of the formula II ##STR2## in which G represents ##STR3## in which Hal.sub.1 represents fluorine, chlorine, bromine, iodine or trifluoromethyl, Hal.sub.2 represents hydrogen, fluorine, chlorine, bromine or trifluoromethyl, Z represents nitrogen or methine (--CH.dbd.), X represents an oxygen or sulphur atom, R.sub.1 ' represents halogen, trifluoromethyl, nitro, cyano, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and n represents, 0, 1, 2 or 3 and T represents an ester, amide, cyanamide or oxime radical.Compositions, containing those components, as selective herbicides and the use of those two active ingredients for controlling weeds in crops of useful plants are described, as are also novel 1,5-diphenyl-pyrazole-3-carboxylic acid derivatives corresponding to the formula I and the preparation thereof.

3. 发明授权

US4707551A Pyrazinyl sulfonamides useful as intermediates for herbicides 失效
标题翻译：吡嗪基磺酰胺，可用作除草剂的中间体
公开(公告)号：US4707551A
公开(公告)日：1987-11-17
申请号：US842618
申请日：1986-03-21
申请人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
发明人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D237/00 , C07D237/18 , C07D239/00 , C07D239/38 , C07D239/42 , C07D241/00 , C07D241/18 , C07D251/00 , C07D403/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36 , C07D237/18 , C07D241/18
摘要： Novel pyrazinyl sulfonamides of the formulaQ--SO.sub.2 --NH.sub.2wherein Q is a substituted pyrazine group are intermediates for the production of sulfonylureas and suflonylthioureas which are useful in controlling weeds or selectively influencing plant growth.
摘要翻译：式Q-SO 2 -NH 2的新型吡嗪基磺酰胺，其中Q是取代的吡嗪基团是用于生产可用于控制杂草或选择性影响植物生长的磺酰脲和磺酰硫脲的中间体。

4. 发明授权

US4681620A Sulfonylureas and sulfonylthioureas, and method of use thereof as herbicides and/or growth regulators 失效
标题翻译：磺酰脲和磺酰硫脲，以及其用作除草剂和/或生长调节剂的方法
公开(公告)号：US4681620A
公开(公告)日：1987-07-21
申请号：US842696
申请日：1986-03-21
申请人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
发明人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D237/00 , C07D237/18 , C07D239/00 , C07D239/38 , C07D239/42 , C07D241/00 , C07D241/18 , C07D251/00 , C07D403/12 , C07D521/00 , A01N43/66 , A01N43/70
CPC分类号： C07D521/00 , A01N47/36 , C07D237/18 , C07D241/18
摘要： The invention relates to novel sulfonylureas of the formula I ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.2 and R.sub.3, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 alkylthio, C.sub.1 -C.sub.5 haloalkyl, halogen, C.sub.1 -C.sub.5 haloalkylthio, C.sub.1 -C.sub.4 alkylamino, C.sub.1 -C.sub.4 dialkylamino, an alkoxyalkyl group or alkoxyalkoxy group, each containing not more than 6 carbon atoms,Z is oxygen or sulfur,E is --CH.dbd. or --N.dbd., andQ is an unsubstituted or substituted 6-membered heterocyclic radical containing 2 to 3 nitrogen atoms and bound through a carbon atom,and the salts thereof.A process for the preparation of the novel compounds and the use thereof are also described. The compounds of formula I can be used in the form of agriculturally useful compositions for controlling weeds and/or for selectively influencing plant growth.
摘要翻译：本发明涉及式I（I）的新型磺酰脲，其中R 1是氢或C 1 -C 5烷基，R 2和R 3各自独立地是氢，C 1 -C 5烷基，C 1 -C 5烷氧基，C 1 -C 5烷硫基，各自含有不超过6个碳原子，Z为氧或硫的C 1 -C 5卤代烷基，卤素，C 1 -C 5卤代烷硫基，C 1 -C 4烷基氨基，C 1 -C 4二烷基氨基，烷氧基烷基或烷氧基烷氧基，E为-CH =或-N = 并且Q是含有2至3个氮原子并通过碳原子结合的未取代或取代的6元杂环基及其盐。还描述了制备新化合物的方法及其用途。式I化合物可以用于控制杂草和/或选择性地影响植物生长的农业上有用的组合物的形式。

5. 发明授权

US4612037A Novel sulfonylureas and sulfonylthioureas, and method of use thereof as herbicides and/or growth regulators 失效
标题翻译：新型磺酰脲类和磺酰硫脲，以及作为除草剂和/或生长调节剂的方法
公开(公告)号：US4612037A
公开(公告)日：1986-09-16
申请号：US496325
申请日：1983-05-19
申请人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
发明人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D237/00 , C07D237/18 , C07D239/00 , C07D239/38 , C07D239/42 , C07D241/00 , C07D241/18 , C07D251/00 , C07D403/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36 , C07D237/18 , C07D241/18
摘要： The invention relates to novel sulfonylureas of the formula I ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.2 and R.sub.3, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 alkylthio, C.sub.1 -C.sub.5 haloalkyl, halogen, C.sub.1 -C.sub.5 haloalkylthio, C.sub.1 -C.sub.4 alkylamino, C.sub.1 -C.sub.4 dialkylamino, an alkoxyalkyl group or alkoxyalkoxy group, each containing not more than 6 carbon atoms,Z is oxygen or sulfur,E is --CH.dbd. or --N.dbd., andQ is an unsubstituted or substituted 6-membered heterocyclic radical containing 2 to 3 nitrogen atoms and bound through a carbon atom,and the salts thereof.A process for the preparation of the novel compounds and the use thereof are also described. The compounds of formula I can be used in the form of agriculturally useful compositions for controlling weeds and/or for selectively influencing plant growth.
摘要翻译：本发明涉及式I（I）的新型磺酰脲，其中R 1是氢或C 1 -C 5烷基，R 2和R 3各自独立地是氢，C 1 -C 5烷基，C 1 -C 5烷氧基，C 1 -C 5烷硫基，C 1 -C 5卤代烷基，卤素，C 1 -C 5卤代烷硫基，C 1 -C 4烷基氨基，C 1 -C 4二烷基氨基，烷氧基烷基或烷氧基烷氧基，各自含有不超过6个碳原子，Z为氧或硫，E为 -CH =或-N =，Q为含有2至3个氮原子并通过碳原子结合的未取代或取代的6元杂环基及其盐。还描述了制备新化合物的方法及其用途。式I化合物可以用于控制杂草和/或选择性地影响植物生长的农业上有用的组合物的形式。

6. 发明授权

US4227914A Herbicidal phenoxyalkyloxazolines 失效
标题翻译：除草苯氧基烷基恶唑啉
公开(公告)号：US4227914A
公开(公告)日：1980-10-14
申请号：US4961
申请日：1979-01-19
申请人： Werner Fory , Beat Bohner , Dieter Durr , Georg Pissiotas , Otto Rohr , Henry Szczepanski
发明人： Werner Fory , Beat Bohner , Dieter Durr , Georg Pissiotas , Otto Rohr , Henry Szczepanski
IPC分类号： A01N43/76 , C07D263/08 , C07D263/10 , C07D263/14 , A01N9/22
CPC分类号： C07D263/10 , A01N43/76 , C07D263/14
摘要： Novel herbicidally active phenoxy-alkyloxazolines, of the formula ##STR1## are disclosed, wherein A is hydrogen, halogen, cyano, nitro and amido or thiamido radical,B is hydrogen, C.sub.1 -C.sub.4 alkyl,C is halogen, cyano, nitro or trifluoromethyl, amido or thiamido,D is halogen, cyano or nitro,n is 0, 1 or 2,R.sub.1, R.sub.2 and R.sub.3, independently are hydrogen or C.sub.1 -C.sub.4 alkyl andX is oxygen, sulfur, sulfinyl or sulfonyl.
摘要翻译：公开了具有式“IMAGE”的新型除草活性苯氧基 - 烷基恶唑啉，其中A是氢，卤素，氰基，硝基和酰氨基或噻二烷基，B是氢，C 1 -C 4烷基，C是卤素，氰基，硝基或三氟甲基，酰氨基或噻二氨基，D是卤素，氰基或硝基，n是0,1或2，R 1，R 2和R 3独立地是氢或C 1 -C 4烷基，X是氧，硫，亚磺酰基或磺酰基。

7. 发明授权

US5078780A 1,5-diphenylpyrazole-3-carboxylic acid derivatives for the protection of cultivated plants 失效
标题翻译：用于保护植物的1,5-二硝基吡唑-3-羧酸衍生物
公开(公告)号：US5078780A
公开(公告)日：1992-01-07
申请号：US109667
申请日：1987-10-16
申请人： Hans Moser , Beat Bohner , Werner Fory
发明人： Hans Moser , Beat Bohner , Werner Fory
IPC分类号： C07F7/18 , A01N25/04 , A01N25/32 , A01N43/40 , A01N43/56 , A01P13/00 , C07D231/14 , C07D401/12 , C07D405/12 , C07D409/12 , C07D417/12 , C07D487/04 , C07D521/00
CPC分类号： C07D231/12 , A01N25/32 , C07D231/14 , C07D233/56 , C07D249/08 , C07D401/12 , C07D405/12 , C07D409/12 , C07D417/12 , C07D487/04
摘要： 1,5-diphenylpyrazole-3-carboxylic acid derivatives of the formula ##STR1## are capable of antagonising specifically the phytotoxic action of phenoxypropionic acid ester herbicides of the formula II ##STR2## in which G represents ##STR3## Compositions, containing those compositions, as selective herbicides and the use of those two active ingredients for controlling weeds in crops of useful plants are described, as are also novel 1,5-diphenylpyrazole-3-carboxylic acid derivatives corresponding to the formula I and the preparation thereof.

8. 发明授权

US4944790A 1,5-diphenylpyrazole-3-carboxylic acid derivatives for the protection of cultivated plants 失效
标题翻译： 1,5-二苯基吡唑-3-羧酸衍生物，用于保护栽培植物
公开(公告)号：US4944790A
公开(公告)日：1990-07-31
申请号：US325833
申请日：1989-03-20
申请人： Hans Moser , Beat Bohner , Werner Fory
发明人： Hans Moser , Beat Bohner , Werner Fory
IPC分类号： C07F7/18 , A01N25/04 , A01N25/32 , A01N43/40 , A01N43/56 , A01P13/00 , C07D231/14 , C07D401/12 , C07D405/12 , C07D409/12 , C07D417/12 , C07D487/04 , C07D521/00
CPC分类号： C07D231/12 , A01N25/32 , C07D231/14 , C07D233/56 , C07D249/08 , C07D401/12 , C07D405/12 , C07D409/12 , C07D417/12 , C07D487/04
摘要： 1,5-diphenylpyrazole-3-carboxylic acid derivatives of the formula ##STR1## in which each of R.sub.a and R.sub.b, independently of the other represents halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl or cyano, n represents zero or an integer from 1 to 3, and OR.sub.1 represents hydroxy, a plant-physiologically tolerable salt radical or any desired ester radical, are capable of antagonizing specifically the phytotoxic action of phenoxypropionic acid ester herbicides of the formula II ##STR2## in which G represents ##STR3## in which Hal.sub.1 represents fluorine, chlorine, bromine, iodine or trifluoromethyl, Hal.sub.2 represents hydrogen, fluorine, chlorine, bromine or trifluoromethyl, Z represents nitrogen or methine (--CH.dbd.), X represents an oxygen or sulphur atom, R.sub.1 ' represents halogen, trifluoromethyl, nitro, cyano, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and n represents 0, 1, 2 or 3 and T represents an ester, amide, cyanamide or oxime radical.Compositions, containing those components, as selective herbicides and the use of those two active ingredients for controlling weeds in crops of useful plants are described, as are also novel 1,5-diphenylpyrazole-3-carboxylic acid derivatives corresponding to the formula I and the preparation thereof.
摘要翻译：其中R a和R b各自独立地表示卤素，C 1 -C 5 - 烷基，C 1 -C 5 - 卤代烷基，C 2 -C 5 - 烯基的1,5-二苯基吡唑-3-羧酸衍生物，C 2 -C 5炔基或氰基，n表示0或1至3的整数，OR 1表示羟基，植物 - 生理上可耐受的盐基或任何所需的酯基，能够特异性地拮抗苯氧基丙酸酯的植物毒性作用其中G代表其中Hal1代表氟，氯，溴，碘或三氟甲基的式Ⅱ的除草剂，其中G代表氢，氯，溴，碘或三氟甲基，Hal2代表氢，氟，氯，溴或三氟甲基，Z 表示氮或次甲基（-CH =），X表示氧或硫原子，R1'表示卤素，三氟甲基，硝基，氰基，C1-C4-烷基或C1-C4-烷氧基，n表示0,1,2或3 T代表酯，酰胺，氰胺或肟基。描述了含有这些成分的作为选择性除草剂的组合物以及这两种活性成分用于控制有用植物作物中的杂草的用途，以及对应于式I的新的1,5-二苯基吡唑-3-羧酸衍生物和的制备。

9. 发明授权

US4225336A Phenoxyalkyloxazolines, as selective herbicides in cereals 失效
标题翻译：苯氧基恶唑啉，作为谷物中的选择性除草剂
公开(公告)号：US4225336A
公开(公告)日：1980-09-30
申请号：US62191
申请日：1979-07-30
申请人： Werner Fory , Hermann Rempfler , Georg Pissiotas , Otto Rohr , Beat Bohner
发明人： Werner Fory , Hermann Rempfler , Georg Pissiotas , Otto Rohr , Beat Bohner
IPC分类号： A01N43/76 , C07D263/14 , A01N9/28
CPC分类号： C07D263/14 , A01N43/76
摘要： Phenoxyalkyloxyzolines corresponding to the formula ##STR1## wherein R is hydrogen or methylZ is a Phenyl-or Pyridyl-radical ##STR2## R.sub.1 is halogen, trifluoromethyl, cyano or nitro R.sub.2 is hydrogen, halogen or cyanoR.sub.3 is halogen trifluoromethyl or cyano andn is 1 or 2.are effective herbicides which are tolerant towards cereal.
摘要翻译：对应于式“IMAGE”的苯氧基烷氧基唑，其中R为氢或甲基Z为苯基或吡啶基，R1为卤素，三氟甲基，氰基或硝基，R2为氢，卤素或氰基R3为卤素三氟甲基或氰基，n为是1或2.是对谷物耐受的有效除草剂。

10. 发明授权

US4804757A Pyrimidinylsulfonyl carbamates and thiocarbamates 失效
标题翻译：嘧啶基磺酰氨基甲酸酯和硫代氨基甲酸酯
公开(公告)号：US4804757A
公开(公告)日：1989-02-14
申请号：US50656
申请日：1987-05-18
申请人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
发明人： Beat Bohner , Werner Fory , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D237/00 , C07D237/18 , C07D239/00 , C07D239/38 , C07D239/42 , C07D241/00 , C07D241/18 , C07D251/00 , C07D403/12 , C07D521/00 , C07D239/30 , C07D239/34
CPC分类号： C07D521/00 , A01N47/36 , C07D237/18 , C07D241/18
摘要： The invention relates to novel suylfonylureas of the formula I ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.2 and R.sub.3, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 alkylthio, C.sub.1 -C.sub.5 haloalkyl, halogen, C.sub.1 -C.sub.5 haloalkylthio, C.sub.1 -C.sub.4 alkylamino, C.sub.1 -C.sub.4 dialkylamino, an alkoxyalkyl group or alkoxyalkoxy group, each containing not more than 6 carbon atoms,Z is oxygen or sulfur,E is --CH.dbd. or --N.dbd., andQ is an unsubstituted or substituted 6-membered heterocyclic radical containing 2 to 3 nitrogen atoms and bound through a carbon atom,and the salts thereof.A process for the preparation of the novel compounds and the use thereof are also described. The compounds of formula I can be used in the form of agriculturally useful compositions for controlling weeds and/or for selectively influencing plant growth.
摘要翻译：本发明涉及式I（I）的新型磺酰基脲，其中R 1是氢或C 1 -C 5烷基，R 2和R 3各自独立地是氢，C 1 -C 5烷基，C 1 -C 5烷氧基，C 1 -C 5烷硫基，各自含有不超过6个碳原子，Z为氧或硫的C 1 -C 5卤代烷基，卤素，C 1 -C 5卤代烷硫基，C 1 -C 4烷基氨基，C 1 -C 4二烷基氨基，烷氧基烷基或烷氧基烷氧基，E为-CH =或-N = 并且Q是含有2至3个氮原子并通过碳原子结合的未取代或取代的6元杂环基及其盐。还描述了制备新化合物的方法及其用途。式I化合物可以用于控制杂草和/或选择性地影响植物生长的农业上有用的组合物的形式。

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