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1. 发明授权

US4600726A Preparation of ethylene glycol 失效
标题翻译：乙二醇的制备
公开(公告)号：US4600726A
公开(公告)日：1986-07-15
申请号：US758293
申请日：1985-07-24
申请人： Werner Bertleff , Franz-Josef Muller , Rudolf Kummer , Wolfgang Harder
发明人： Werner Bertleff , Franz-Josef Muller , Rudolf Kummer , Wolfgang Harder
IPC分类号： C07C27/06 , B01J23/00 , B01J23/89 , C07B61/00 , C07C27/00 , C07C29/15 , C07C29/158 , C07C31/20 , C07C67/00
CPC分类号： C07C29/158 , Y02P20/52
摘要： Ethylene glycol is prepared from carbon monoxide and hydrogen under superatmospheric pressure and at an elevated temperature in the presence of a rhodium-containing catalyst together with a cobalt catalyst, the molar ratio of rhodium to cobalt being from about 20:1 to 60:1.
摘要翻译：乙二醇由一氧化碳和氢气在超大气压和高温下在含铑催化剂和钴催化剂存在下制备，铑与钴的摩尔比为约20:1至60:1。

2. 发明授权

US4740525A Preparation of ethylene glycol 失效
标题翻译：乙二醇的制备
公开(公告)号：US4740525A
公开(公告)日：1988-04-26
申请号：US900770
申请日：1986-08-26
申请人： Robert Maerkl , Werner Bertleff , Wolfgang Harder , Rudolf Kummer
发明人： Robert Maerkl , Werner Bertleff , Wolfgang Harder , Rudolf Kummer
IPC分类号： C07B61/00 , B01J31/00 , C07C29/158 , C07C27/06 , C07C31/20
CPC分类号： C07C29/158 , Y02P20/52
摘要： Ethylene glycol is prepared from carbon monoxide and hydrogen in homogeneous liquid phase under superatmospheric pressure and at elevated temperature in the presence of a rhodium-containing catalyst and in the presence of an organic solvent, the organic solvent used being a C.sub.2 -C.sub.20 -n-alkanol and the concentration of this alkanol, based on the total amount of the mixture, constantly being maintained at not less than 50% by weight.
摘要翻译：乙二醇由均一液相中的一氧化碳和氢气在超大气压和升高的温度下在含铑催化剂存在下制备，并且在有机溶剂存在下，所用的有机溶剂是C 2 -C 20正 - 链烷醇和该烷醇的浓度，基于混合物的总量，不断保持在不小于50重量％。

3. 发明授权

US4894474A Preparation of alkyl pentenoates 失效
标题翻译：戊烯酸烷基酯的制备
公开(公告)号：US4894474A
公开(公告)日：1990-01-16
申请号：US225823
申请日：1988-07-29
申请人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
发明人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
IPC分类号： C07C67/38 , B01J31/20 , C07B61/00 , C07C69/533
CPC分类号： C07C69/533
摘要： Alkyl pentenoates are prepared by reacting butadiene with carbon monoxide and an alkanol in the presence of a cobalt carbonyl complex and a tertiary, aromatic heterocyclic nitrogen base at from 80.degree. to 160.degree. C. under from 100 to 1,000 bar in the presence of from 0.1 to 10% by volume of hydrogen, based on the amount of carbon monoxide used.
摘要翻译：烷基戊烯酸酯是通过使丁二烯与一氧化碳和链烷醇在羰基钴配合物和叔芳族杂环氮碱存在下，在80-160℃，100-1,000巴下，存在0.1当量至10体积％的氢气，基于所用一氧化碳的量。

4. 发明授权

US5434291A Preparation of aminopropionitriles 失效
标题翻译：氨基丙腈的制备
公开(公告)号：US5434291A
公开(公告)日：1995-07-18
申请号：US251334
申请日：1994-06-01
申请人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
发明人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
IPC分类号： C07C253/18 , C07C253/30 , C07C255/24
CPC分类号： C07C253/30 , C07C255/24
摘要： A process for the preparation of aminopropionitriles of the general formula I ##STR1## in which R denotes hydrogen or methyl, wherein ammonia is caused to react with an acrylonitrile of the general formula II ##STR2## In which the substituent has the aforementioned meanings, in a molar ratio of from 1:1 to 500:1 over a heterogenic catalyst at temperatures ranging from 40.degree. to 180.degree. C. and pressures ranging from 10 to 350 bar.
摘要翻译：（I）的氨基丙腈的制备方法，其中R表示氢或甲基，其中使氨与通式II的丙烯腈反应（II）其中取代基具有上述含义，摩尔比为1：1至500：1，相对于异质催化剂，温度范围为40至180℃，压力范围为10至350巴。

5. 发明授权

US5142087A Process for the preparation of dialkyl carbonates 失效
标题翻译：制备碳酸二甲酯的方法
公开(公告)号：US5142087A
公开(公告)日：1992-08-25
申请号：US564324
申请日：1990-08-08
申请人： Klaus Joerg , Franz-Josef Mueller , Wolfgang Harder , Rudolf Kummer
发明人： Klaus Joerg , Franz-Josef Mueller , Wolfgang Harder , Rudolf Kummer
IPC分类号： B01J27/122 , B01J31/02 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： C07C68/005
摘要： A process for the continuous synthesis of dialkyl carbonates of the general formula I ##STR1## in which R denotes C.sub.1 -C.sub.4 -alkyl, by reaction of C.sub.1 -C.sub.4 -alkanols with carbon monoxide and oxygen at elevated temperature and pressure and in the presence of a copper-containing catalyst dissolved or suspended in the reaction medium, whereina) a gas stream containing carbon monoxide and oxygen is bubbled through the alkanol/catalyst mixture present in the reactor at a rate of from 1 to 100 liters per hours per gram of copper present in the reactor, part of which gas stream reacts with the alkanol to form dialkyl carbonate and water, which components are continuously entrained, together with alkanol, as a gaseous mixture, from the reaction mixture by means of the remaining, unreacted portion of the carbon monoxide/oxygen gas stream, whereuponb) the resulting gaseous mixture is separated, in a separator, into gaseous and liquid phases, the gaseous phase being recycled to the reactor if desired, andc) the liquid phase, which essentially consists of dialkyl carbonate, water and alkanol, is separated into its components, the dialkyl carbonate being isolated and the alkanol, if desired, recycled to the reactor, andd) the liquid in the reactor is replenished by adding fresh or recycled alkanol at the rate at which the alkanol is consumed and discharged.
摘要翻译：通过在升高的温度和压力下将C1-C4-链烷醇与一氧化碳和氧气反应，连续合成通式I的二烷基碳酸酯的方法，其中R表示C 1 -C 4 - 烷基，溶解或悬浮在反应介质中的含铜催化剂的存在，其中a）含有一氧化碳和氧气的气流以1至100升/小时的速率通过反应器中存在的链烷醇/催化剂混合物存在于反应器中的每克铜，其中一部分气流与链烷醇反应以形成碳酸二烷基酯和水，该组分与来自反应混合物的烷醇作为气态混合物一起通过剩余的，一氧化碳/氧气流的未反应部分，然后b）将所得气体混合物在分离器中分离成气相和液相，如果需要，将气相再循环至反应器，和c）基本上由碳酸二烷基酯，水和链烷醇组成的液相被分离成其组分，分离出碳酸二烷基酯，如果需要，链烷醇再循环到反应器中，和d）反应器中的液体通过以消耗和排出链烷醇的速率加入新鲜或回收的链烷醇来补充。

6. 发明申请

US20050252761A1 Distillative preparation of ipda having a high cis-trans isomer ratio 有权
标题翻译：具有高顺反异构体比例的ipda的蒸馏制备
公开(公告)号：US20050252761A1
公开(公告)日：2005-11-17
申请号：US10524084
申请日：2003-08-08
申请人： Frank Funke , Thomas Hill , Jobst Watzdorf , Wolfgang Mattmann , Wolfgang Harder , Erhard Henkes , Gerd Littmann , Manfred Julius
发明人： Frank Funke , Thomas Hill , Jobst Watzdorf , Wolfgang Mattmann , Wolfgang Harder , Erhard Henkes , Gerd Littmann , Manfred Julius
IPC分类号： C07C209/86 , B01D3/14 , C07C209/84 , C07C211/36 , B01D3/00
CPC分类号： B01D3/141 , B01D3/146 , C07C209/84 , Y10S203/20 , C07C211/36
摘要： The invention relates to a process for recovering 3-aminomethyl-3,5,5-trimethylcyclohexylamine(isophoronediamine, IPDA) having a cis/trans isomer ratio of at least 73/27 by fractional distillation, which comprises the following steps: a) providing IPDA in a cis/trans isomer ratio of
摘要翻译：本发明涉及通过分馏回收顺式/反式异构体比为73/27的3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺，IPDA）的方法，其包括以下步骤：a）提供 IPDA以顺式/反式异构体比为<73/27; b）将IPDA进料到具有内部的蒸馏塔的中间区域，并在该蒸馏塔中在5-300℃的温度和10-2000mbar的压力下蒸馏该IPDA; c）任选地通过在至少一个另外的塔中蒸馏来进一步纯化通过步骤b）获得的IPDA; 其中步骤b）和c）将步骤a）中使用的IPDA分离成至少五个分数ia）至iv）：ia）沸点低于tans-IPDA的一部分杂质的有机比例，ib）水分比的沸点低于反式 - IPDA的杂质的一部分，ii）沸点高于顺式-IPDA的一部分杂质，iii）顺式/反式异构体比为> 73/27的IPDA馏分和iv）顺式/反式异构体比例<66/34的IPDA级分。

7. 发明申请

US20050245767A1 Method for the production of isophorondiamine (ipda, 3-aminomethyl-3,5,5-trimethyl- cyclohexylamine) having a high cis/tran-isomer ratio 有权
标题翻译：用于制备具有高顺/异构体比例的异佛尔酮二胺（ipda，3-氨基甲基-3,5,5-三甲基 - 环己胺）的方法
公开(公告)号：US20050245767A1
公开(公告)日：2005-11-03
申请号：US10522994
申请日：2003-08-06
申请人： Frank Funke , Thomas Hill , Jobst Von Watzdorf , Wolfgang Mattmann , Wolfgang Harder , Erhard Henkes , Gerd Littman , Manfred Jukius
发明人： Frank Funke , Thomas Hill , Jobst Von Watzdorf , Wolfgang Mattmann , Wolfgang Harder , Erhard Henkes , Gerd Littman , Manfred Jukius
IPC分类号： C07C209/54 , C07B61/00 , C07C29/68 , C07C209/82 , C07C209/84 , C07C209/86 , C07C211/36
CPC分类号： C07C209/84 , C07C209/86 , C07C2601/14 , C07C211/36
摘要： The invention relates to processes for preparing 3-aminomethyl-3,5,5-trimethylcyclo-hexylamine (isophoronediamine, IPDA) having a high cis/trans isomer ratio. IPDA having a cis/trans isomer ratio in the range from 63/37 to 66/34 can be obtained in any desired cis/trans isomer ratio, irrespective of temperature, by reacting IPDA with H2 and NH3 in the presence of a hydrogenation catalyst. IPDA having a cis/trans isomer ratio of at least 73/27 which is an important starting material for the synthesis of polyurethanes and polyamides can be obtained by combining this isomerization process with distillative processes.
摘要翻译：本发明涉及具有高顺/反异构体比的3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺，IPDA）的方法。具有63/37至66/34范围内的顺式/反式异构体比例的IPDA可通过使IPDA与H 2 N和NH反应，以任何所需顺式/反式异构体比例与温度无关地获得在氢化催化剂的存在下进行。具有至少73/27的顺/反异构体比例的IPDA可以通过将该异构化方法与蒸馏过程组合来获得，其是用于合成聚氨酯和聚酰胺的重要原料。

8. 发明申请

US20050038253A1 Method for production of alkali metal dialkylamides 审中-公开
标题翻译：碱金属二烷基酰胺的生产方法
公开(公告)号：US20050038253A1
公开(公告)日：2005-02-17
申请号：US10495356
申请日：2002-11-08
申请人： Ulrich Steinbrenner , Ralf Bohling , Frank Funke , Wolfgang Harder
发明人： Ulrich Steinbrenner , Ralf Bohling , Frank Funke , Wolfgang Harder
IPC分类号： B01J31/26 , B01J31/02 , C07B61/00 , C07C209/00 , C07C209/60 , C07C211/03 , C07C211/35 , C07C211/65 , C07F1/00 , C07F1/02 , C07F1/04 , C07F1/06
CPC分类号： C07C209/00 , C07C211/65
摘要： A process for preparing dialkylamides of the alkali metals by reacting the corresponding dialkylamine with the corresponding alkali metal in the presence of an electron-donating substance selected from the group consisting of 1,3-butadiene, isoprene, naphthalene and styrene with formation of small amounts of butenyldialkylamine comprises suspending the corresponding alkali metal in a solvent and subsequently adding dialkylamine and electron-donating substance in such a way that the dialkylamine is present in an amount of up to 45% by weight, preferably up to 25% by, weight, in particular up to 15% by weight, and the butadiene is present in an amount of up to 5% by weight, preferably up to 3% by weight, in particular up to 1.5% by weight.
摘要翻译：一种通过使相应的二烷基胺与相应的碱金属在选自1,3-丁二烯，异戊二烯，萘和苯乙烯的给电子物质存在下，形成少量的碱金属制备二烷基酰胺的方法的丁烯基二烷基胺包括将相应的碱金属悬浮在溶剂中，随后加入二烷基胺和给电子物质，使得二烷基胺以高达45重量％，优选至多25重量％的量存在特别地高达15重量％，丁二烯的存在量为至多5重量％，优选至多3重量％，特别是至多1.5重量％。

9. 发明授权

US06380119B1 Method for regenerating a zeolitic catalyst 有权
标题翻译：再生沸石催化剂的方法
公开(公告)号：US06380119B1
公开(公告)日：2002-04-30
申请号：US09424854
申请日：2000-01-13
申请人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Wolfgang Harder
发明人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Wolfgang Harder
IPC分类号： B01J2990
CPC分类号： B01J29/90 , B01J38/20 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof.
摘要翻译：再生沸石催化剂的方法包括以下步骤：（I）在含有少于2体积％氧气的气氛中将部分或完全失活的催化剂加热至250-600℃，（II）将催化剂处理 250至800℃，优选350至600℃，含有0.1至4体积％的供氧物质或氧气或其两种或多种的混合物的气流和（III）在250至800℃，优选350至600℃下处理催化剂，其中气流含有超过4至100体积％的供氧物质或氧气或其两种或更多种的混合物。

10. 发明授权

US5916838A Catalysts for the amination of alkylene oxides, alcohols, aldehydes and ketones 失效
公开(公告)号：US5916838A
公开(公告)日：1999-06-29
申请号：US955264
申请日：1997-10-21
申请人： Joachim Wulff-Doring , Johann-Peter Melder , Gerhard Schulz , Guido Voit , Gutshoven Frank , Wolfgang Harder
发明人： Joachim Wulff-Doring , Johann-Peter Melder , Gerhard Schulz , Guido Voit , Gutshoven Frank , Wolfgang Harder
IPC分类号： B01J23/89 , C07B61/00 , C07C209/02 , C07C209/14 , C07C209/16 , C07C209/26 , C07C211/10 , C07C211/13 , C07C213/02 , C07C215/14 , B01J23/40 , B01J23/46
CPC分类号： C07C209/16 , B01J23/8926 , B01J23/8933
摘要： A catalyst comprises, based on the total weight of the catalyst,0.1-6% by weight of cobalt, nickel or a mixture thereof,0.001-25% by weight of ruthenium,0-10% by weight of copper and0-5% by weight of promoterson a porous metal oxide carrier.It preferably comprises 0.1-3% by weight of cobalt and 0.1-3% by weight of nickel. It can be used in hydrogenation reactions, dehydrogenation reactions or hydrogenation/dehydrogenation reactions, in particular in the amination of alkylene oxides, alcohols, aldehydes or ketones with ammonia or primary or secondary amines.

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