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1. 发明授权

US5179191A Polycondensation and/or addition product containing carboxyl groups and tertiary amino groups, coating agents based thereon, and the use thereof 失效
标题翻译：含有羧基和仲胺基团的聚合和/或添加产品，基于其的涂料代理及其使用
公开(公告)号：US5179191A
公开(公告)日：1993-01-12
申请号：US328583
申请日：1989-02-27
申请人： Werner A. Jung , Udo Vorbeck , Arno Schmitz , Wilhelm Heise , Lutz-Werner Gross
发明人： Werner A. Jung , Udo Vorbeck , Arno Schmitz , Wilhelm Heise , Lutz-Werner Gross
IPC分类号： C08G63/685 , C09D167/00
CPC分类号： C09D167/00 , C08G63/685
摘要： A polycondensation and/or addition product containing carboxyl groups and tertiary amino groups, coating agents based on the latter, and the use thereof.The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) and an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 300.The invention also relates to a process for the preparation of the polycondensation and/or process product, and to coating agents based on the polycondensation and/or addition product, a process for the preparation of the coating agents, and the use thereof for automobile refinishing of automobile bodies and as a topcoat, filler, varnish, primer or undercoat.
摘要翻译： PCT No.PCT / EP87 / 00429 Sec。 371日期1989年2月27日 102（e）日期1989年2月27日PCT PCT 1987年8月6日PCT公布。第WO88 / 01629号公报日期：1988年3月10日。含有羧基和叔氨基的缩聚和/或加成产物，基于后者的涂布剂及其用途。本发明涉及含有羧基和氨基的缩聚和/或加成产物。这可以通过使a）多元羧酸或其酸酐与适宜的一元羧酸反应获得，b）多元醇，如果适用，与一元醇一起，以及如果合适的话c）进一步修饰组分，如果合适，d）组分其能够与a），b）和（如果合适的话）c）的反应产物反应，条件是最终产物含有源自组分a）和/或b）和/或d）的叔氨基，，和a），b）的反应产物，如果合适的话c），如果合适的话d）和酸值为5-200，优选10-130，胺值为3- 150，优选为10-300。本发明还涉及一种制备缩聚和/或加工产品的方法，以及基于缩聚和/或加成产物的涂布剂，制备涂料的方法及其用于汽车修补的用途汽车车身和topco 在，填料，清漆，底漆或底漆。

2. 发明授权

US5336753A Polycondensation and/or addition product containing carboxyl groups and tertiary amino groups, coating agents based thereon, and the use thereof 失效
标题翻译：包含羧基和叔氨基的缩聚和/或加成产物，基于其的包衣剂及其用途
公开(公告)号：US5336753A
公开(公告)日：1994-08-09
申请号：US2291
申请日：1993-01-08
申请人： Werner A. Jung , Udo Vorbeck , Arno Schmitz , Wilhelm Heise , Lutz-Werner Gross
发明人： Werner A. Jung , Udo Vorbeck , Arno Schmitz , Wilhelm Heise , Lutz-Werner Gross
IPC分类号： C08G63/685 , C09D167/00 , C08G69/26
CPC分类号： C09D167/00 , C08G63/685
摘要： The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) has an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 100.The invention also relates to a process for the preparation of the polycondensation and/or addition product, and to coating agents based on the polycondensation and/or addition product, a process for the preparation of the coating agents, and the use thereof for automobile refinishing of automobile bodies and as a topcoat, filler, varnish, primer or undercoat.
摘要翻译：本发明涉及含有羧基和氨基的缩聚和/或加成产物。这可以通过使a）多元羧酸或其酸酐与适宜的一元羧酸反应获得，b）多元醇，如果适用，与一元醇一起，以及如果合适的话c）进一步修饰组分，如果合适，d）组分其能够与a），b）和（如果合适的话）c）的反应产物反应，条件是最终产物含有源自组分a）和/或b）和/或d）的叔氨基，，和a），b）的反应产物，如果合适c），如果合适，d）的酸值为5至200，优选10至130，胺数为3至150，优选10至100。本发明还涉及一种制备缩聚和/或加成产物的方法，以及基于缩聚和/或加成产物的涂布剂，制备涂料的方法及其用于汽车修补的用途汽车车身和顶棚燕麦，填料，清漆，底漆或底漆。

3. 发明申请

US20060293485A1 Aqueous multicomponent system, process for its preparation, and its use 审中-公开
标题翻译：水性多组分体系，其制备方法及其用途
公开(公告)号：US20060293485A1
公开(公告)日：2006-12-28
申请号：US11179193
申请日：2005-07-12
申请人： Heinz-Peter Rink , Susanne Piontek , Christine Alpert , Lutz-Werner Gross , Andreas Jansen
发明人： Heinz-Peter Rink , Susanne Piontek , Christine Alpert , Lutz-Werner Gross , Andreas Jansen
IPC分类号： C08G18/00
CPC分类号： C08G18/706 , C08F283/006 , C08G18/3206 , C08G18/3868 , C08G18/4272 , C08G18/6229 , C08L51/08 , C09D151/08 , C09D175/04
摘要： An aqueous multicomponent system comprising (I) at least one aqueous component comprising dissolved and/or dispersed therein at least one polyurethane-based graft copolymer (P) containing isocyanate-reactive functional groups and preparable by graft copolymerizing at least one polyurethane (P′) selected from the group consisting of hydrophobic or hydrophilic polyurethanes containing on average at least one functional group selected from the group consisting of thiocarbamate groups, thiol groups and sulfide groups with at least one olefinically unsaturated monomer, or alternatively (II) at least one liquid organic component comprising at least one water soluble and/or dispersible, polyurethane-based graft copolymer (P) and (III) at least one aqueous component, and (IV) at least one liquid organic component comprising or consisting of at least one polyisocyanate, processes for preparing it, and its use.
摘要翻译：一种水性多组分体系，其包含（I）至少一种水性组分，其包含溶解和/或分散有至少一种含有异氰酸酯反应性官能团的聚氨酯基接枝共聚物（P），并且可通过将至少一种聚氨酯（P'）选自包含平均至少一种选自硫代氨基甲酸酯基团，硫醇基团和硫化物基团的官能团的至少一种烯属不饱和单体的疏水或亲水性聚氨酯，或者（II）至少一种液体有机物组分，其包含至少一种水溶性和/或可分散的基于聚氨酯的接枝共聚物（P）和（III）至少一种水性组分，和（IV）至少一种包含至少一种多异氰酸酯或由至少一种多异氰酸酯组成的液体有机组分，准备它和它的使用。

4. 发明授权

US06355722B2 Aqueous binder solutions and dispersions 失效
标题翻译：水性粘合剂溶液和分散体
公开(公告)号：US06355722B2
公开(公告)日：2002-03-12
申请号：US09878552
申请日：2001-06-11
申请人： Ulrich Poth , Lutz-Werner Gross
发明人： Ulrich Poth , Lutz-Werner Gross
IPC分类号： C08L6702
CPC分类号： C09D5/02 , C09D167/00 , C08L2666/54
摘要： Aqueous solutions or dispersions of binders for preparing aqueous coating materials are produced, including as an aqueous component water of reaction which is obtained during the condensation of alcohols with carboxylic acids.
摘要翻译：制备用于制备水性涂料的粘合剂的水溶液或分散体，包括作为在醇与羧酸缩合期间获得的反应水。

5. 发明授权

US5212242A Coating composition based on a hydroxyl-containing addition polymer and an amino resin crosslinking agent, agent and containing acid catalysts having hydroxy groups 失效
标题翻译：基于含羟基的添加剂聚合物和氨基树脂交联剂的涂料组合物，具有羟基的酯和含酸催化剂
公开(公告)号：US5212242A
公开(公告)日：1993-05-18
申请号：US752651
申请日：1991-10-29
申请人： Lutz-Werner Gross , Stefan Wieditz , Werner-Alfons Jung
发明人： Lutz-Werner Gross , Stefan Wieditz , Werner-Alfons Jung
IPC分类号： C09D133/14 , C08K5/42 , C08L61/20 , C08L61/28 , C09D133/04 , C09D133/06 , C09D161/20 , C09D161/28
CPC分类号： C08K5/42 , C09D133/066 , C08L61/20 , C08L61/28
摘要： The invention relates to a coating composition containingA) 50 to 90% by weight of one or more hydroxyl-containing addition polymers, prepared by copolymerization of ethylenically unsaturated monomers which are in part hydroxyalkyl esters of .alpha.,.beta.-ethylenically unsaturated carboxylic acids andB) 10 to 50% by weight of one or more amino resin crosslinking agentsthe sum of the proportions by weight of A and B being 100% by weight, and suitable auxiliaries and additives, optionally pigments, optionally fillers, organic solvent and an acid catalyst.The coating composition is one wherein the acid catalyst used comprises1) sulfo- or sulfonio[sic]-succinic esters which each contain at least one hydroxyl group and/or2) sulfo- or sulfonio[sic]-succinic polyesters which each contain at least one hydroxyl group.The invention furthermore relates to a process for the preparation of the coating compositions according to the invention and to their use as an automobile repair finish or as a stoving paint.
摘要翻译： PCT No.PCT / EP90 / 00201 Sec。 371日期1991年10月2日 102（e）日期1991年10月2日PCT提交1990年2月8日PCT公布。 WO90 / 10039 PCT出版物 1990年9月7日。本发明涉及一种涂料组合物，其包含A）50至90重量％的一种或多种含羟基的加成聚合物，其通过烯属不饱和单体的共聚制备，烯属不饱和单体部分为α，β的羟烷基酯 - 乙烯不饱和羧酸和B）10至50重量％的一种或多种氨基树脂交联剂，A和B的重量比为100重量％的总和以及合适的助剂和添加剂，任选的颜料，任选的填料有机溶剂和酸催化剂。涂料组合物是其中使用的酸催化剂包括1）各自含有至少一个羟基的磺基或磺酰基[sic] - 琥珀酸酯和/或2）磺基或磺酰基 - 至少一个羟基。本发明还涉及制备根据本发明的涂料组合物及其用作汽车修补漆或作为烘烤油漆的方法。

6. 发明授权

US07338989B2 Aqueous coating material, method of producing the same and use thereof 有权
标题翻译：水性涂料，其制造方法及其用途
公开(公告)号：US07338989B2
公开(公告)日：2008-03-04
申请号：US10415202
申请日：2001-11-27
申请人： Lutz-Werner Gross , Ludwig Moorkamp , Heinz-Ulrich Grumpe
发明人： Lutz-Werner Gross , Ludwig Moorkamp , Heinz-Ulrich Grumpe
IPC分类号： C08L63/00 , B32B27/38
CPC分类号： C08J3/05 , C08G59/50 , C08J2363/00 , C09D163/00 , Y10T428/31515 , Y10T428/31522
摘要： An aqueous coating material comprising at least one epoxy resin as binder and at least one polyamine as curing agent, wherein said epoxy resin or at least one of the epoxy resins (i) is solid per se at room temperature and/or is present in a powder coating material, and (ii) the solid epoxy resin and/or the epoxy resin powder coating material is or are present in fine dispersion in an aqueous dispersion comprising the polyamine or polyamines; and the use of the aqueous coating material to produce antistonechip primers.
摘要翻译：一种水性涂料，其包含至少一种作为粘合剂的环氧树脂和至少一种多胺作为固化剂，其中所述环氧树脂或至少一种环氧树脂（i）在室温下为固体本身，和/或存在于粉末涂料，和（ii）固体环氧树脂和/或环氧树脂粉末涂料在微分散体中存在于包含多胺或多胺的水分散体中; 以及使用水性涂料生产抗丝氨酸底漆。

7. 发明授权

US06822038B1 Aqueous coating substance, method for its production and its use 有权
标题翻译：水性涂料，其制备方法及其用途
公开(公告)号：US06822038B1
公开(公告)日：2004-11-23
申请号：US10030307
申请日：2002-02-26
申请人： Lutz-Werner Gross , Ludwig Moorkamp , Heinz-Ulrich Grumpe , Ulrich Poth
发明人： Lutz-Werner Gross , Ludwig Moorkamp , Heinz-Ulrich Grumpe , Ulrich Poth
IPC分类号： C08J300
CPC分类号： C09D167/00 , C08G18/10 , C08G18/68 , C08L61/20 , C08L75/16 , C09D161/28 , C09D175/04 , C08G18/3206 , C08L2666/14 , C08L67/00 , C08L2666/18
摘要： An aqueous coating material comprising A) at least one polyester that is water-soluble or water-dispersible, B) at least one polyurethane acrylate that is water-soluble or water-dispersible, C) at least one amino resin that is itself water-soluble or water-dispersible or is water-soluble or water-dispersible in the presence of the polyester and the polyurethane acrylate, D) at least one of a color pigment, an effect pigment, a color and effect pigment, and a filler, and E) optionally at least one polyisocyanate. Also, processes for preparing and using the aqueous coating material.
摘要翻译：一种水性涂料，包括A）至少一种水溶性或水分散性的聚酯，B）至少一种水溶性或水分散性的聚氨酯丙烯酸酯，C）至少一种本身是水溶性的氨基树脂或水分散性或在聚酯和聚氨酯丙烯酸酯存在下是水溶性或水分散性的，D）彩色颜料，效果颜料，着色颜料和效果颜料和填料中的至少一种，和E）任选地至少一种多异氰酸酯。另外，制备和使用水性涂料的方法。

8. 发明授权

US5272187A Carboxyl polyol-derived polyester and epoxide resin aqueous coating 失效
标题翻译：羧基多元醇衍生的聚酯和环氧树脂水性涂料
公开(公告)号：US5272187A
公开(公告)日：1993-12-21
申请号：US964169
申请日：1992-10-21
申请人： Lutz-Werner Gross , Ulrich Poth , Dieter Hille , Klaus Weidemeier
发明人： Lutz-Werner Gross , Ulrich Poth , Dieter Hille , Klaus Weidemeier
IPC分类号： C09D163/00 , C09D167/00 , C08K3/20 , C08L63/02 , C08L63/10 , C08L67/02
CPC分类号： C09D167/00 , C09D163/00 , Y10T428/31522 , Y10T428/31529
摘要： A water-dilutable coating comprising a binder obtained from an epoxide resin-modified polyester possessing free carboxyl groups prepared from the reaction of:A) a polyester polymerized from:a.sub.1) a polycarboxylic acid containing at least three carboxyl groups and/ora.sub.2) a polyol containing at least one carboxyl group anda.sub.3) a polycarboxylic acid containing two carboxyl groups anda.sub.4) a polyol, wherein the polyester contains (cyclo)aliphatic elements having at least six carbon atoms;B) from 0.3-1.5 equivalents per polyester molecule of a bisphenol epoxide resin or a reaction product thereof containing at least one epoxide group per molecule with a carboxylic acid; andC) a crosslinking agent.
摘要翻译：一种水可稀释涂层，其包含由具有由以下反应制备的具有游离羧基的环氧树脂改性聚酯获得的粘合剂：A）聚合的聚酯：a1）含有至少三个羧基的多元羧酸和/或a2）含有至少一个羧基的多元醇和a3）含有两个羧基的多元羧酸和a4）多元醇，其中所述聚酯含有具有至少6个碳原子的（环）脂族元素; B）每个聚酯分子的双酚环氧树脂0.3-1.5当量或其每分子含有至少一个环氧基的反应产物与羧酸; 和C）交联剂。

9. 发明授权

US06221949B1 Coating formulation for use in aqueous multicoat paint systems 失效
标题翻译：涂料配方用于水性多色漆系统
公开(公告)号：US06221949B1
公开(公告)日：2001-04-24
申请号：US08848684
申请日：1997-06-20
申请人： Lutz-Werner Gross , Ralf Stein , Egon Wegner , Gudrun Wiemann
发明人： Lutz-Werner Gross , Ralf Stein , Egon Wegner , Gudrun Wiemann
IPC分类号： C08G1865
CPC分类号： B05D7/577 , C08G18/0819 , C09D175/04 , C08L2666/54
摘要： The present invention relates to a coating formulation for use in multicoat paint systems, which a) comprises as binder a water-dilutable polyurethane resin which has an acid number of from 10 to 60 and a number-average molecular weight of from 4000 to 25,000 and can be prepared by reacting with one another aa) a polyester—and/or polyether-polyol having a number-average molecular weight of from 400 to 5000 or a mixture of such polyester—and/or polyether-polyols, bb) a polyisocyanate or mixture of polyisocyanates, cc) a compound which has in the molecule at least one group which in reactive toward isocyanate groups and at least one group which is capable of forming anions, or a mixture of such compounds, and optionally dd) a hydroxyl—and/or amino-containing organic compound having a molecular weight of from 40 to 400, or a mixture of such compounds and at least partially neutralizing the resulting reaction product, and b) comprises pigments and/or fillers, the ratio of binder to pigment being between 0.5:1 and 1.5:1.
摘要翻译：本发明涉及用于多涂漆系统的涂料配方，其包括作为粘合剂的水可稀释的聚氨酯树脂，其具有10至60的酸值和数均分子量为4000至25,000，并且可以通过使数均分子量为400-5000的聚酯和/或聚醚多元醇或这种聚酯和/或聚醚多元醇的混合物，bb）多异氰酸酯或多异氰酸酯，cc）在分子中具有至少一个对异氰酸酯基团具有反应性的基团和至少一个能够形成阴离子的基团的化合物，或这些化合物的混合物，以及任选地奇数化羟基和/或氨基分子量为40〜400的有机化合物，或这些化合物的混合物，并且至少部分中和得到的反应产物，和b）包含颜料和/或填料，粘合剂与颜料的比例为在0.5：1和1.5：1之间。

10. 发明授权

US5589228A Process for coating vehicle bodies and aqueous coating 失效
标题翻译：涂料车身和水性涂料的工艺
公开(公告)号：US5589228A
公开(公告)日：1996-12-31
申请号：US321082
申请日：1994-10-11
申请人： Egon Wegner , Ulrich Poth , Lutz-Werner Gross , Klaus Weidemeier
发明人： Egon Wegner , Ulrich Poth , Lutz-Werner Gross , Klaus Weidemeier
IPC分类号： B05D7/00 , C09D175/04 , B05D3/02 , B05D1/36
CPC分类号： B05D7/576 , B05D7/577 , C09D175/04
摘要： The invention relates to a process for coating vehicle bodies in which an aqueous coating containing as the binder a combination of a water-dilutable polyurethane resin, a water-dilutable polyester resin and an aminoplast resin is employed as the stone-chip intermediate primer and/or filler.
摘要翻译：本发明涉及一种涂布车体的方法，其中使用含有水可稀释的聚氨酯树脂，水可稀释的聚酯树脂和氨基塑料树脂的组合作为粘合剂的水性涂料作为石芯片中间体底漆和/ 或填料。

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