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    • 4. 发明授权
    • Yellow toner for developing electrostatic images
    • 用于显影静电图像的黄色调色剂
    • US6022659A
    • 2000-02-08
    • US31892
    • 1998-02-27
    • Makoto KanbayashiMasaaki TayaWakashi IidaTetsuya Ida
    • Makoto KanbayashiMasaaki TayaWakashi IidaTetsuya Ida
    • G03G9/08G03G9/087G03G9/09
    • G03G9/08755G03G9/0821G03G9/09G03G9/091
    • A yellow toner for developing electrostatic images is formed of yellow toner particles containing a binder resin and a yellow colorant. The yellow toner has a storage modulus G'.sub.180 at 180.degree. C. and a minimum storage modulus G'.sub.min(120-170) in a temperature range of 120-170.degree. C. giving a ratio [G'.sub.180 /G'.sub.min(120-170) ] of 2.0-8.0. The binder resin comprises a polyester resin having a glass transition temperature of 50-65.degree. C. and an acid value of 2.0-25.0 mgKOH/g. The yellow toner is a compound represented by Formula (1) below:Formula (1): ##STR1## The primary particles of the yellow colorant exhibit a length/breadth ratio of at most 1.5. The yellow colorant is dispersed in the toner particles as independent particles (including primary particles and secondary particles) providing a number-average particle size of 0.1-0.7 .mu.m. The yellow toner is provided with improved fixability and anti-offset property as well as good color toner performances.
    • 用于显影静电图像的黄色调色剂由含有粘合剂树脂和黄色着色剂的黄色调色剂颗粒形成。 黄色调色剂在180℃的储能模量G'180和120-170℃的温度范围内具有最小储能模量G'min(120-170),得到[G'180 / G'min (120-170)]为2.0-8.0。 粘合剂树脂包括玻璃化转变温度为50-65℃,酸值为2.0-25.0mgKOH / g的聚酯树脂。 黄色调色剂是由下式(1)表示的化合物:式(1):黄色着色剂的一次颗粒的长度/宽度比至多为1.5。 作为提供数均粒径为0.1-0.7μm的独立颗粒(包括一次颗粒和二次颗粒),黄色着色剂分散在调色剂颗粒中。 黄色调色剂具有改进的定影性和抗偏移性以及良好的彩色调色剂性能。
    • 6. 发明授权
    • Color toner and image forming method
    • 彩色墨粉和成像方法
    • US06013402A
    • 2000-01-11
    • US215325
    • 1998-12-18
    • Makoto KanbayashiMasaaki TayaWakashi IidaTetsuya Ida
    • Makoto KanbayashiMasaaki TayaWakashi IidaTetsuya Ida
    • G03G9/08G03G9/097G03G13/16G03G9/09
    • G03G9/09716G03G9/0819G03G9/0821G03G9/09708
    • A color toner has (i) color toner particles containing at least a binder resin and a colorant and (ii) an external additive. The color toner has a weight-average particle diameter of 5 to 8 .mu.m and a number-average particle diameter of 4.5 to 7.5 .mu.m, and contains 5 to 40% by number of particles having a particle diameter of 4 .mu.m or less in the number distribution of the color toner and 7% by volume or less of particles having a particle diameter of 10.08 .mu.m or more in the volume distribution of the color toner. The inorganic powder selected from the group consisting of a strontium titanate powder, a cerium oxide powder and a calcium titanate powder, and a hydrophobic fine alumina powder are externally added to the color toner particles as the external additives, the inorganic powder has a longitudinal average particle diameter of 0.2 to 2 .mu.m, and the hydrophobic fine alumina powder has a longitudinal average particle diameter of 0.005 to 0.1 .mu.m. The binder resin is a polyester resin crosslinked by a crosslinking agent. The color toner particles contain 0 to 20 mg/lg of a chloroform insoluble matter. The color toner has a storage modulus (G'.sub.130) of 2.times.10.sup.3 to 2.times.10.sup.4 [dyn/cm.sup.2 ] at a temperature of 130.degree. C. and a storage modulus (G'.sub.170) of 5.times.10.sup.3 to 5.times.10.sup.4 [dyn/cm.sup.2 ] at a temperature of 170.degree. C., and a value of G'.sub.170 /G'.sub.130 is in the range of 0.25 to 10.
    • 彩色调色剂具有(i)着色至少含有粘合剂树脂和着色剂的调色剂颗粒和(ii)外部添加剂。 彩色调色剂的重均粒径为5〜8μm,数均粒径为4.5〜7.5μm,并且含有5〜40个数量的粒径为4μm以下的粒子 在彩色调色剂的体积分布中,彩色调色剂的数量分布和7体积%以下的粒径为10.08μm以上的粒子。 从作为外部添加剂的彩色调色剂颗粒外部添加选自钛酸锶粉末,氧化铈粉末和钛酸钙粉末和疏水性微细氧化铝粉末的无机粉末,无机粉末具有纵向平均值 粒径为0.2〜2μm,疏水性细氧化铝粉末的纵向平均粒径为0.005〜0.1μm。 粘合剂树脂是通过交联剂交联的聚酯树脂。 彩色调色剂颗粒含有0至20mg / l氯仿不溶物质。 彩色调色剂在130℃的温度下具有2x103至2×104 [dyn / cm 2]的储能模量(G'130),在温度下的储能模量(G'170)为5×10 3至5×10 4 [dyn / cm 2] 为170℃,G'170 / G'130的值在0.25〜10的范围内。
    • 8. 发明授权
    • Electrophotographic developer carrier, two-component type developer and
image forming method
    • 电子照相显影剂载体,双组分型显影剂和成像方法
    • US06001525A
    • 1999-12-14
    • US974728
    • 1997-11-19
    • Tetsuya IdaMasaaki TayaMakoto Kanbayashi
    • Tetsuya IdaMasaaki TayaMakoto Kanbayashi
    • G03G9/113
    • G03G9/1136
    • An electrophotographic two-component type developer includes a toner and a magnetic carrier showing stable charge-imparting performances for a long period of continuous image formation and wherein various environmental conditions. The magnetic carrier comprises: magnetic carrier core particles and a silicone resin coating the magnetic carrier core particles; wherein the silicone resin is characterized by having (i) both (a) a --COO-- group and (b) a phenyl group or nitrogen-containing group, (ii) a carbon content attributable to the --COO-- group of 10-70 atomic % of silicon constituting the silicone resin, based on ESCA, and (iii) a carbon content attributable to the phenyl group of 0.1-300 atomic % or a nitrogen content attributable to the nitrogen-containing group of 0.01-10 atomic %, respectively, of the carbon content attributable to the --COO-- group, based on ESCA.
    • 电子照相双组分型显影剂包括调色剂和磁性载体,其对于长时间的连续图像形成表现出稳定的电荷赋予性能,并且其中各种环境条件。 磁性载体包括:磁性载体芯颗粒和涂覆磁性载体芯颗粒的硅树脂; 其特征在于:(i)-COO-基团和(b)苯基或含氮基团,(ii)可归因于10-70的-COO-基团的碳含量 基于ESCA的构成有机硅树脂的硅的原子%,(iii)归属于苯基的碳含量为0.1-300原子%或含氮基团的氮含量分别为0.01-10原子% ,归因于-COO-基团的碳含量,基于ESCA。
    • 10. 发明授权
    • Toner with organically treated alumina for developing electrostatic image
    • 具有有机处理氧化铝的调色剂用于显影静电图像
    • US5607806A
    • 1997-03-04
    • US579729
    • 1995-12-28
    • Makoto KanbayashiWakashi Iida
    • Makoto KanbayashiWakashi Iida
    • G03G9/08G03G9/097
    • G03G9/09716G03G9/0819
    • A toner for developing electrostatic images includes: toner particles and organically treated alumina powder. The organically treated alumina powder has an X-ray diffraction characteristic showing a maximum X-ray intensity level I.sub.a-max and a minimum X-ray intensity level I.sub.a-min in a 2.theta. range of 20 to 70 degrees providing a ratio I.sub.a-max /I.sub.a-min of below 6. The alumina powder is amorphous or has a low-crystallinity of .gamma.-form, thereby showing a low agglomeratability to function as an effective flowability-improving agent for a toner. The structural water contained in the alumina powder contained favors hydrophobization treatment thereof and functions to suppress a charge-up phenomenon in a low humidity environment after the hydrophobization.
    • 用于显影静电图像的调色剂包括:调色剂颗粒和有机处理的氧化铝粉末。 有机处理的氧化铝粉末具有X射线衍射特征,其显示在20度至70度的2θ范围内的最大X射线强度水平Ia-max和最小X射线强度水平Ia-min,提供比率Ia-max / Ia-min。氧化铝粉末是无定形的或具有γ型的低结晶度,因此显示出低的附聚性,作为调色剂的有效流动性改进剂。 包含在氧化铝粉末中的结构水含有疏水化处理,其功能是在疏水化之后在低湿度环境中抑制电荷现象。