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1. 发明申请

WO2009043023A2 ELECTRONIC SWITCHING, MEMORY, AND SENSOR DEVICES FROM CARBON SHEETS ON DIELECTRIC MATERIALS 审中-公开
标题翻译：电子材料上的碳片的电子开关，存储器和传感器装置
公开(公告)号：WO2009043023A2
公开(公告)日：2009-04-02
申请号：PCT/US2008/078152
申请日：2008-09-29
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , LI, Yubao , SINITSKIY, Alexander
发明人： TOUR, James, M. , LI, Yubao , SINITSKIY, Alexander
IPC分类号： H01L45/00 , H01L29/786 , G01N27/12
CPC分类号： H01L45/04 , H01L45/1206 , H01L45/1226 , H01L45/149 , H01L45/1608
摘要： Electronic devices comprising a dielectric material, at least one carbon sheet, and two electrode terminals are described herein. The devices exhibit non-linear current-versus-voltage response over a voltage sweep range in various embodiments. Uses of the electronic devices as two- terminal memory devices, logic units, and sensors are disclosed. Processes for making the electronic devices are disclosed. Methods for using the electronic devices in analytical methods are disclosed.
摘要翻译：本文描述了包括电介质材料，至少一个碳片和两个电极端子的电子器件。在各种实施例中，器件在电压扫描范围内表现出非线性电流对电压响应。公开了将电子设备用作双终端存储设备，逻辑单元和传感器的用途。公开了制造电子设备的过程。公开了在分析方法中使用电子装置的方法。

2. 发明申请

WO2009064842A1 VERTICALLY-STACKED ELECTRONIC DEVICES HAVING CONDUCTIVE CARBON FILMS 审中-公开
标题翻译：具有导电碳膜的垂直电子装置
公开(公告)号：WO2009064842A1
公开(公告)日：2009-05-22
申请号：PCT/US2008/083337
申请日：2008-11-13
申请人： WILLIAM MARSH RICE UNVIRSITY , TOUR, James, M. , LI, Yubao , SINITSKIY, Alexander , ZHONG, Lin , DONG, Mian , YAO, Jun
发明人： TOUR, James, M. , LI, Yubao , SINITSKIY, Alexander , ZHONG, Lin , DONG, Mian , YAO, Jun
IPC分类号： H01L27/24 , H01L45/00
CPC分类号： H01L45/04 , H01L27/2481 , H01L45/1233 , H01L45/124 , H01L45/149 , H01L45/1616
摘要： Vertically-stacked electronic devices having conductive carbon films are disclosed. The vertically-stacked devices exhibit non-linear current-versus-voltage response over a voltage sweep range in various embodiments. The vertically-stacked devices may be assembled into arrays where the vertically-stacked devices may be electrically addressed independently of one another. Uses of the vertically-stacked electronic devices and arrays as two-terminal memory devices, logic units, and sensors are disclosed. Crossbar arrays of vertically-stacked electronic devices having conductive carbon films and nanowire electrodes are disclosed.
摘要翻译：公开了具有导电碳膜的垂直堆叠的电子器件。在各种实施例中，垂直堆叠的器件在电压扫描范围内表现出非线性电流对电压响应。垂直堆叠的器件可以组装成阵列，其中垂直堆叠的器件可以彼此独立地电寻址。公开了垂直堆叠的电子设备和阵列作为双端存储器件，逻辑单元和传感器的用途。公开了具有导电碳膜和纳米线电极的垂直堆叠的电子器件的横杆阵列。

3. 发明申请

WO2013032983A1 ADDRESSABLE SIOX MEMORY ARRAY WITH INCORPORATED DIODES 审中-公开
标题翻译：可寻址的存储器阵列与入射二极管
公开(公告)号：WO2013032983A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/052450
申请日：2012-08-27
申请人： WILLIAM MARSH RICE UNIVERSITY , NANYANG TECHNOLOGICAL UNIVERSITY , TOUR, James, M. , YAO, Jun , LIN, Jian , WANG, Gunuk , PALEM, Krishna
发明人： TOUR, James, M. , YAO, Jun , LIN, Jian , WANG, Gunuk , PALEM, Krishna
IPC分类号： H01L47/00
CPC分类号： H01L27/2463 , H01L27/2409 , H01L29/66136 , H01L29/66143 , H01L29/8611 , H01L29/8613 , H01L29/872 , H01L45/04 , H01L45/1233 , H01L45/1253 , H01L45/145 , H01L45/1608 , H01L45/1616 , H01L45/1625 , H01L45/1675
摘要： Various embodiments of the resistive memory cells and arrays discussed herein comprise: (1) a first electrode; (2) a second electrode; (3) resistive memory material; and (4) a diode. The resistive memory material is selected from the group consisting of SiO x , SiO x H, SiO x N y , SiO x N y H, SiO x Cz, SiO x C z H, and combinations thereof, wherein each of x, y and z are equal or greater than 1 or equal or less than 2. The diode may be any suitable diode, such as n-p diodes, p-n diodes, and Schottky diodes.
摘要翻译：本文讨论的电阻式存储器单元和阵列的各种实施例包括：（1）第一电极; （2）第二电极; （3）电阻记忆材料; 和（4）二极管。电阻性存储材料选自SiOx，SiOxH，SiOxNy，SiOxNyH，SiOxCz，SiOxCzH及其组合，其中x，y和z各自等于或大于1或等于或小于2.二极管可以是任何合适的二极管，例如np二极管，pn二极管和肖特基二极管。

4. 发明申请

WO2012158194A1 COMPOSITE MATERIALS FOR REVERSIBLE CO2 CAPTURE 审中-公开
标题翻译：用于可逆二氧化碳捕获的复合材料
公开(公告)号：WO2012158194A1
公开(公告)日：2012-11-22
申请号：PCT/US2011/057695
申请日：2011-10-25
申请人： WILLIAM MARSH RICE UNIVERSITY , NALCO COMPANY , TOUR, James, M. , HWANG, Garry, Chih-chau , LOMEDA, Jay, R.
发明人： TOUR, James, M. , HWANG, Garry, Chih-chau , LOMEDA, Jay, R.
IPC分类号： B01D53/02 , C01B31/08
CPC分类号： B01D53/04 , B01D53/02 , B01D2253/102 , B01D2253/202 , B01D2253/25 , B01D2257/504 , B01J20/20 , B01J20/261 , B01J20/262 , B01J20/28069 , B01J20/2808 , B01J20/28083 , B01J20/28085 , B01J20/28097 , B01J20/327 , B01J20/3272 , B01J2220/46 , Y02C10/08
摘要： Composite materials for carbon dioxide (C02) capture that include: (1) a mesoporous carbon source; and (2) an in situ polymerized polymer that is associated with the mesoporous carbon source, where the in situ polymerized polymer is selected from the group consisting of thiol-based polymers, amine-based polymers, and combinations thereof. Methods of making the composite materials for C02 capture include: (1) associating a mesoporous carbon source with monomers, where the monomers are selected from the group consisting of thiol-based monomers, amine-based monomers, and combinations thereof; and (2) polymerizing the monomers in situ to form said composite materials. Further embodiments of the present invention pertain to methods of capturing C02 from an environment by associating the environment with one or more of the aforementioned composite materials.
摘要翻译：用于二氧化碳（CO 2）捕获的复合材料包括：（1）介孔碳源; 和（2）与介孔碳源相关联的原位聚合的聚合物，其中原位聚合的聚合物选自硫醇基聚合物，胺基聚合物及其组合。制备用于CO 2捕获的复合材料的方法包括：（1）将介孔碳源与单体缔合，其中单体选自硫醇基单体，胺基单体及其组合; 和（2）原位聚合单体以形成所述复合材料。本发明的其它实施方案涉及通过将环境与一种或多种上述复合材料相关联来从环境捕获CO 2的方法。

5. 发明申请

WO2012112435A1 GRAPHENE NANORIBBON COMPOSITES AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：石墨纳米星复合材料及其制备方法
公开(公告)号：WO2012112435A1
公开(公告)日：2012-08-23
申请号：PCT/US2012/024846
申请日：2012-02-13
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , ZHU, Yu , RAJI, Abdul-Rahman, O.
发明人： TOUR, James, M. , ZHU, Yu , RAJI, Abdul-Rahman, O.
IPC分类号： C01B31/04
CPC分类号： C09J9/02 , B82Y30/00 , B82Y40/00 , C01B32/184 , C01B2204/06
摘要： In some embodiments, the present invention provides graphene nanoribbon composites that include a polymer matrix and graphene nanoribbons that are dispersed in the polymer matrix. In more specific embodiments, the polymer matrix of the composite is an epoxy matrix, and the graphene nanoribbons of the composite include functionalized graphene nanoribbons. In further embodiments, the composites of the present invention further comprise metals, such as tin, copper, gold, silver, aluminum and combinations thereof. Additional embodiments of the present invention pertain to methods of making the graphene nanoribbon composites of the present invention. In some embodiments, such methods include mixing graphene nanoribbons with polymer precursors to form a mixture, and then curing the mixture to form the composite.
摘要翻译：在一些实施方案中，本发明提供石墨烯纳米纤维复合材料，其包括分散在聚合物基质中的聚合物基质和石墨烯纳米带。在更具体的实施方案中，复合材料的聚合物基质是环氧基质，并且复合材料的石墨烯纳米带包括官能化的石墨烯纳米带。在另外的实施方案中，本发明的复合材料还包括金属，例如锡，铜，金，银，铝及其组合。本发明的另外的实施方案涉及制备本发明的石墨烯纳米纤维复合材料的方法。在一些实施方案中，这样的方法包括将石墨烯纳米带与聚合物前体混合以形成混合物，然后固化混合物以形成复合材料。

6. 发明申请

WO2010022164A1 PREPARATION OF GRAPHENE NANORIBBONS FROM CARBON NANOTUBES 审中-公开
标题翻译：碳纳米管从碳纳米管的制备
公开(公告)号：WO2010022164A1
公开(公告)日：2010-02-25
申请号：PCT/US2009/054334
申请日：2009-08-19
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , KOSYNKIN, Dmitry, W. , HIGGINBOTHAM, Amanda , PRICE, Katherine B.
发明人： TOUR, James, M. , KOSYNKIN, Dmitry, W. , HIGGINBOTHAM, Amanda , PRICE, Katherine B.
IPC分类号： H01J9/02 , D01F11/00 , B82B3/00
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/184 , C01B32/194 , C01B32/23 , C01B2204/06 , H01J9/025 , Y10S977/734 , Y10S977/842
摘要： Methods for producing macroscopic quantities of oxidized graphene nanoribbons are disclosed herein. The methods include providing a plurality of carbon nanotubes and reacting the plurality of carbon nanotubes with at least one oxidant to form oxidized graphene nanoribbons. The at least one oxidant is operable to longitudinally open the carbon nanotubes. In some embodiments, the reacting step takes place in the presence of at least one acid. In some embodiments, the reacting step takes place in the presence of at least one protective agent. Various embodiments of the present disclosure also include methods for producing reduced graphene nanoribbons by reacting oxidized graphene nanoribbons with at least one reducing agent. Oxidized graphene nanoribbons, reduced graphene nanoribbons and compositions and articles derived therefrom are also disclosed herein.
摘要翻译：本文公开了生产宏观量的氧化石墨烯纳米带的方法。所述方法包括提供多个碳纳米管并使多个碳纳米管与至少一种氧化剂反应以形成氧化石墨烯纳米带。至少一种氧化剂可操作以纵向打开碳纳米管。在一些实施方案中，反应步骤在至少一种酸的存在下进行。在一些实施方案中，反应步骤在至少一种保护剂的存在下进行。本公开的各种实施方案还包括通过使氧化石墨烯纳米带与至少一种还原剂反应来生产还原的石墨烯纳米带的方法。氧化石墨烯纳米带，还原石墨烯纳米带以及由其衍生的组合物和制品也在本文中公开。

7. 发明申请

WO2004007364A1 PROCESS FOR FUNCTIONALIZING CARBON NANOTUBES UNDER SOLVENT-FREE CONDITIONS 审中-公开
标题翻译：在无溶剂条件下功能化碳纳米管的方法
公开(公告)号：WO2004007364A1
公开(公告)日：2004-01-22
申请号：PCT/US2003/022072
申请日：2003-07-15
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , DYKE, Christopher, A.
发明人： TOUR, James, M. , DYKE, Christopher, A.
IPC分类号： C01B31/02
CPC分类号： B82Y30/00 , B82Y10/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/36 , D01F9/12 , D01F11/14 , Y10S977/84 , Y10S977/842 , Y10S977/847 , Y10S977/895 , Y10S977/896
摘要： The present invention provides methods by which carbon nanotubes can be functionalized under solvent-free conditions. As extremely large quantities are typically required to dissolve or disperse carbon nanotubes, solvent elimination renders the processes more favorable for scale-up. Such processes are also amenable to a wide variety of chemical reactions and organic functionalizing agents.
摘要翻译：本发明提供了可在无溶剂条件下使碳纳米管功能化的方法。通常需要非常大的量来溶解或分散碳纳米管，消除溶剂使得该方法对于放大比较有利。这些方法也适用于各种各样的化学反应和有机官能化剂。

8. 发明申请

WO2013040356A1 SOLVENT-BASED METHODS FOR PRODUCTION OF GRAPHENE NANORIBBONS 审中-公开
标题翻译：用于生产石墨纳米粒子的溶剂型方法
公开(公告)号：WO2013040356A1
公开(公告)日：2013-03-21
申请号：PCT/US2012/055414
申请日：2012-09-14
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , LU, Wei , GENORIO, Bostjan
发明人： TOUR, James, M. , LU, Wei , GENORIO, Bostjan
IPC分类号： B05D5/12
CPC分类号： C08F112/08 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/178 , C01B32/18 , C01B32/184 , C01B32/194 , C01B2202/06 , C01B2204/06 , C07C2/76 , C07C15/56 , C07C29/32 , C07C67/035 , C07C69/76 , D01F9/12 , Y10S977/734 , Y10S977/846 , Y10S977/961
摘要： The present invention provides methods of preparing functionalized graphene nanoribbons. Such methods include: (1) exposing a plurality of carbon nanotubes (CNTs) to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to an electrophile to form functionalized graphene nanoribbons (GNRs). The methods may also include a step of exposing the opened CNTs to a protic solvent to quench any reactive species on them. Additional methods include preparing unfunctionalized GNRs by: (1) exposing a plurality of CNTs to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to a protic solvent to form unfunctionalized GNRs.
摘要翻译：本发明提供了制备官能化石墨烯纳米带的方法。这些方法包括：（1）在非质子溶剂的存在下将多个碳纳米管（CNT）暴露于碱金属源以将其打开; 和（2）将开放的CNT暴露于亲电子试剂以形成官能化的石墨烯纳米带（GNR）。所述方法还可以包括将开放的CNT暴露于质子溶剂以淬灭其上的任何反应性物质的步骤。另外的方法包括：通过以下步骤制备未官能化的GNR：（1）在非质子溶剂存在下将多个CNT暴露于碱金属源以打开它们; 和（2）将开放的CNT暴露于质子溶剂以形成未官能化的GNR。

9. 发明申请

WO2012100178A1 GRAPHENE-BASED THIN FILMS IN HEAT CIRCUITS AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：加热电路中基于石墨的薄膜及其制造方法
公开(公告)号：WO2012100178A1
公开(公告)日：2012-07-26
申请号：PCT/US2012/022052
申请日：2012-01-20
申请人： WILLIAM MARSH RICE UNIVERSITY , LOCKHEED MARTIN CORPORATION , TOUR, James, M. , VOLMAN, Vladimir , ZHU, Yu
发明人： TOUR, James, M. , VOLMAN, Vladimir , ZHU, Yu
IPC分类号： B05D5/12 , B32B9/04
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B32/18 , C01B32/194 , H01B1/04 , Y10T428/265 , Y10T428/31511 , Y10T428/31551 , Y10T428/31721 , Y10T428/31855
摘要： In various embodiments, the present invention provides electrically conductive and radio frequency (RF) transparent films that include a graphene layer and a substrate associated with the graphene layer. In some embodiments, the graphene layer has a thickness of less than about 100 nm. In some embodiments, the graphene layer of the film is adhesively associated with the substrate. In more specific embodiments, the graphene layer includes graphene nanoribbons that are in a disordered network. Further embodiments of the present invention pertain to methods of making the aforementioned electrically conductive and RF transparent films. Such methods generally include associating a graphene composition with a substrate to form a graphene layer on a surface of the substrate.
摘要翻译：在各种实施例中，本发明提供了包括石墨烯层和与石墨烯层相关联的衬底的导电和射频（RF）透明膜。在一些实施例中，石墨烯层具有小于约100nm的厚度。在一些实施例中，膜的石墨烯层与衬底粘合地相关联。在更具体的实施方案中，石墨烯层包括位于无序网络中的石墨烯纳米带。本发明的其它实施方案涉及制备上述导电和RF透明膜的方法。这样的方法通常包括将石墨烯组合物与基材缔合以在基材的表面上形成石墨烯层。

10. 发明申请

WO2009070380A2 WATER-SOLUBLE CARBON NANOTUBE COMPOSITIONS FOR DRUG DELIVERY AND MEDICAL APPLICATIONS 审中-公开
标题翻译：用于药物输送和医疗应用的可溶性碳纳米管组合物
公开(公告)号：WO2009070380A2
公开(公告)日：2009-06-04
申请号：PCT/US2008/078776
申请日：2008-10-03
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , LUCENTE-SCHULTZ, Rebecca , LEONARD, Ashley , KOSYNKIN, Dmitry, V. , PRICE, Brandi, Katherine , HUDSON, Jared, L. , CONYERS, Jodie, L. , MOORE, Valerie, C. , CASSCELLS, S., Ward , MYERS, Jeffrey, N. , MILAS, Zvonimir, L. , MASON, Kathy, A. , MILAS, Luka
发明人： TOUR, James, M. , LUCENTE-SCHULTZ, Rebecca , LEONARD, Ashley , KOSYNKIN, Dmitry, V. , PRICE, Brandi, Katherine , HUDSON, Jared, L. , CONYERS, Jodie, L. , MOORE, Valerie, C. , CASSCELLS, S., Ward , MYERS, Jeffrey, N. , MILAS, Zvonimir, L. , MASON, Kathy, A. , MILAS, Luka
IPC分类号： A61K47/48
CPC分类号： B82Y5/00 , A61K47/60 , A61K47/6925 , A61K47/6929
摘要： Compositions comprising a plurality of functionalized carbon nanotubes and at least one type of payload molecule are provided herein. The compositions are soluble in water and PBS in some embodiments. In certain embodiments, the payload molecules are insoluble in water. Methods are described for making the compositions and administering the compositions. An extended release formulation for paclitaxel utilizing functionalized carbon nanotubes is also described.
摘要翻译：本文提供了包含多个官能化碳纳米管和至少一种有效载荷分子的组合物。在一些实施方案中，组合物可溶于水和PBS。在某些实施方案中，有效载荷分子不溶于水。描述了制备组合物和施用组合物的方法。还描述了利用官能化碳纳米管的紫杉醇的延长释放制剂。

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