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    • 3. 发明授权
    • Dicarboximides and their use as herbicides
    • 二酰亚胺及其作为除草剂的用途
    • US5378680A
    • 1995-01-03
    • US931951
    • 1992-08-19
    • Volker MaywaldKlaus DitrichThomas KuekenhoehnerGerhard HamprechtWolfgang FreundKarl-Otto WestphalenMatthias GerberHelmut Walter
    • Volker MaywaldKlaus DitrichThomas KuekenhoehnerGerhard HamprechtWolfgang FreundKarl-Otto WestphalenMatthias GerberHelmut Walter
    • A01N43/76A01N43/78A01N43/80A01N43/90C07D498/04C07D499/04C07D513/04
    • C07D513/04A01N43/90
    • Dicarboximides of the formulae Ia, Ib and Ic ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, halogen, cyano, alkyl, cycloalkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkoxy, haloalkylthio, alkylsulfonyl, haloalkylsulfonyl, phenyl, phenylalkyl, phenoxy or phenylthio, a 5-membered or 6-membered saturated or aromatic heterocyclic radical containing one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, where the stated organic radicals may be further substituted, andR.sup.2 is hydrogen, hydroxyl, alkoxy, alkyl, cycloalkyl, alkenyl, alkynyl, di-C.sub.1 -C.sub.4 - alkylamino, a 5-membered or 6-membered heterocyclic saturated or aromatic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, phenyl or naphthyl, where the stated organic radicals may be further substituted,and plant-tolerated salts of the dicarboximides I, except for 3-methylisoxazole-4,5-dicarboximide and thiazole-4,5-dicarboximides in which R.sup.2 is phenyl when R.sup.1 is methyl or 2-thiazolyl,and herbicides containing these compounds.
    • 其中X是氧或硫,R 1是氢,卤素,氰基,烷基,环烷基,烯基,炔基,烷氧基,烯氧基,炔氧基,烷氧基, 烷硫基,卤代烷氧基,卤代烷硫基,烷基磺酰基,卤代烷基磺酰基,苯基,苯基烷基,苯氧基或苯硫基,含有一个或两个选自氧,硫和氮的杂原子的5元或6元饱和或芳族杂环基团, 所述有机基团可以被进一步取代,并且R 2是氢,羟基,烷氧基,烷基,环烷基,链烯基,炔基,二-C 1 -C 4 - 烷基氨基,5元或6元杂环饱和或芳族基, 选自氧,硫和氮的两个杂原子,苯基或萘基,其中所述有机基团可以被进一步取代,以及二甲酰亚胺I的植物耐受盐,除了3-甲基异恶唑-4,5-二甲酰亚胺 de和噻唑-4,5-二羧酰亚胺,其中当R 1是甲基或2-噻唑基时,R 2是苯基,以及含有这些化合物的除草剂。
    • 4. 发明授权
    • Dicarboximides and their use as herbicides
    • DICARBOXIMIDES及其作为除草剂的用途
    • US5176739A
    • 1993-01-05
    • US718639
    • 1991-06-21
    • Volker MaywaldKlaus DitrichThomas KuekenhoehnerGerhard HamprechtWolfgang FreundKarl-Otto WestphalenMatthias GerberHelmut Walter
    • Volker MaywaldKlaus DitrichThomas KuekenhoehnerGerhard HamprechtWolfgang FreundKarl-Otto WestphalenMatthias GerberHelmut Walter
    • A01N43/76A01N43/78A01N43/80A01N43/90C07D498/04C07D499/04C07D513/04
    • C07D513/04A01N43/90
    • Dicarboximides of the formulae Ia, Ib and Ic ##STR1## where X is oxygen or sulfur, R.sup.1 is hydrogen, halogen, cyano, alkyl, cycloalkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkoxy, haloalkylthio, alkylsulfonyl, haloalkylsulfonyl, phenyl, phenylalkyl, phenoxy or phenylthio, a 5-membered or 6-membered saturated or aromatic heterocyclic radical containing one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, where the stated organic radicals may be further substituted, andR.sup.2 is hydrogen, hydroxyl, alkoxy, alkyl, cycloalkyl, alkenyl, alkynyl, di-C.sub.1 -C.sub.4 -alkylamino, a 5-membered or 6-membered heterocyclic saturated or aromatic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, phenyl or naphthyl, where the stated organic radicals may be further substituted,and plant-tolerated salts of the dicarboximides I, except for 3-methylisoxazole-4,5-dicarboximide and thiazole-4,5-dicarboximides in which R.sup.2 is phenyl when R.sup.1 is methyl or 2-thiazolyl,and herbicides containing these compounds.
    • 其中X是氧或硫,R 1是氢,卤素,氰基,烷基,环烷基,烯基,炔基,烷氧基,烯氧基,炔氧基,烷氧基, 烷硫基,卤代烷氧基,卤代烷硫基,烷基磺酰基,卤代烷基磺酰基,苯基,苯基烷基,苯氧基或苯硫基,含有一个或两个选自氧,硫和氮的杂原子的5元或6元饱和或芳族杂环基团, 所述有机基团可以被进一步取代,并且R 2是氢,羟基,烷氧基,烷基,环烷基,烯基,炔基,二-C 1 -C 4 - 烷基氨基,具有一个或多个的五元或六元杂环饱和或芳族基团 选自氧,硫和氮的两个杂原子,苯基或萘基,其中所述有机基团可以被进一步取代,以及二甲酰亚胺I的植物耐受盐,除了3-甲基异恶唑-4,5-二甲酰亚胺 e和噻唑-4,5-二羧酰亚胺,当R 1为甲基或2-噻唑基时,R 2为苯基,以及含有这些化合物的除草剂。
    • 6. 发明授权
    • Substituted 2-phenylpyridines
    • 取代的2-苯基吡啶
    • US5783522A
    • 1998-07-21
    • US592355
    • 1996-01-11
    • Peter SchaeferGerhard HamprechtElisabeth HeistracherHartmann KoenigRalf KlintzPeter MuensterHarald RangKarl-Otto WestphalenMatthias GerberHelmut Walter
    • Peter SchaeferGerhard HamprechtElisabeth HeistracherHartmann KoenigRalf KlintzPeter MuensterHarald RangKarl-Otto WestphalenMatthias GerberHelmut Walter
    • A01N43/40A01N43/42A01N43/60A01N43/647A01N43/76A01N43/78A01N43/84A01N47/22C07D213/30C07D213/61C07D213/65C07D213/70C07D213/89C07D265/36C07D401/04C07D405/04C07D405/14C07D409/04C07D409/12C07D413/04C07D417/04
    • C07D213/30C07D213/61C07D265/36C07D409/12
    • Substituted 2-phenylpyridines I ##STR1## R.sup.1,R.sup.3 =H, halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO.sub.2 H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, CONH.sub.2, alkyl-aminocarbonyl, dialkylaminocarbonyl, pyrrolidinyl-carbonyl piperidylcarbonyl, morpholinylcarbonyl, NO.sub.2, NH.sub.2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R.sup.2 =halogen, CN, NO.sub.2, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R.sup.1 +R.sup.2 or R.sup.2 +R.sup.3 =trimethylene or tetramethylene chain;R.sup.4 =halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO.sub.2 H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO.sub.2, NH.sub.2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R.sup.5 =hydrogen or halogen; R.sup.6 =halogen, CN, NO.sub.2, OH, CF.sub.3, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy; R.sup.7 =various radicals; and the N-oxides of I and the agriculturally utilizable salts of I where these exist, excepting those compounds I where R.sup.2 is C.sub.1 -C.sub.4 -alkoxy and R.sup.1 and/or R.sup.3 is carboxyl or the salt, ester or amide thereof.
    • PCT No.PCT / EP94 / 02263 371日期1996年1月11日 102(e)日期1996年1月11日PCT提交1994年7月11日PCT公布。 公开号WO95 / 02580 日期1995年1月26日取代的2-苯基吡啶I R1,R3 = H,卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,烷氧基烷氧基,OH,卤代烷氧基,烷基羰基氧基,卤代烷基羰氧基,SH,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷硫基, 卤代烷基亚磺酰基,卤代烷基磺酰基,CHO,CN,CO 2 H,烷氧基羰基,烷氧基烷氧基羰基,卤代烷氧基羰基,烷基羰基,卤代烷基羰基,烷氧基烷基羰基,CONH 2,烷基氨基羰基,二烷基氨基羰基,吡咯烷基 - 羰基哌啶基羰基,吗啉基羰基,NO 2,NH 2,烷基氨基,二烷基氨基,吡咯烷基,哌啶基,吗啉基 ,烷基羰基氨基,卤代烷基羰基氨基,烷基磺酰基氨基; R 2 =卤素,CN,NO 2,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基; 或R1 + R2或R2 + R3 =三亚甲基或四亚甲基链; R 4 =卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,烷氧基烷氧基,OH,卤代烷氧基,烷基羰基氧基,卤代烷基羰氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷硫基,卤代烷基亚磺酰基,卤代烷基磺酰基,CHO,CN,CO 2 H,烷氧基羰基,烷氧基烷氧基羰基,卤代烷氧基羰基,烷基羰基, 卤代烷基羰基,烷氧基烷基羰基,NO 2,NH 2,烷基氨基,二烷基氨基,吡咯烷基,哌啶基,吗啉基,烷基羰基氨基,卤代烷基羰基氨基,烷基磺酰基氨基。 R5 =氢或卤素; R6 =卤素,CN,NO2,OH,CF3,C1-C6-烷基,C1-C4-烷氧基; R7 =各种基团; 和I的N-氧化物和其中存在的I的农业上可利用的盐,除了其中R 2是C 1 -C 4 - 烷氧基且R 1和/或R 3是羧基的化合物I或其盐,酯或酰胺。
    • 8. 发明授权
    • Carboxamides
    • US5201932A
    • 1993-04-13
    • US877365
    • 1992-05-04
    • Volker MaywaldWolfgang FreundGerhard HamprechtThomas KuekenhoehnerPeter PlathBruno WuerzerKarl-Otto Westphalen
    • Volker MaywaldWolfgang FreundGerhard HamprechtThomas KuekenhoehnerPeter PlathBruno WuerzerKarl-Otto Westphalen
    • A01N43/80C07D261/18C07D275/02C07D275/03
    • C07D275/03A01N43/80C07D261/18
    • Carboxamides Ia, Ib, Ic and Id ##STR1## (X=O, S; R.sup.1 =H, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, substituted or unsubstituted phenyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; R.sup.1 '=cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted cycloalkenyl; R.sup.2 =CHO, 4,5-dihydrooxazol-2-yl, COYR.sup.5, CONR.sup.6 R.sup.7 ; Y=O, S; R.sup.5 =H, substituted or unsubstituted alkyl, cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted cycloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted phenyl, a 5- or 6-membered heterocyclic radical containing up to 3 heteroatoms, benzotriazole, N-phthalimido, tetrahydrophthalimido, succinimido, maleiimido, 2,2-dimethyl-1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, and when Y.dbd.O: one equivalent of a cation from the group of the alkali or alkaline earth metals, Mn, Cu, Fe ammonium and substituted ammonium, a radical --N.dbd.CR.sup.8 R.sup.9 or --W--Z; R.sup.8, R.sup.9 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, cycloalkyl, alkoxy, furanyl, substituted or unsubstituted phenyl; R.sup.8 +R.sup.9 =4-7-membered methylene chain; W=alkylene chain, ethoxyethylene chain, butylene, butynylene chain; Z=a molecular moiety bonded to W in the .omega.-position and is the same as that linked to W in the .alpha.-position of W; R.sup.6 .dbd.H, alkyl, cycloalkyl; R.sup.7 .dbd.H; alkyl; --C(O-alkyl).dbd.N--H or --(O--alkyl).dbd.N--alkyl; R.sup.6 +R.sup.7 =4-5-membered methylene chain; R.sup.3 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl; R.sup.4 .dbd.H, OH, alkoxy, subsituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, di-(C.sub.1 -C.sub.4)-alkylamino, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl; R.sub.3 +R.sub.4 =4-7-membered methylene chain which may be interrupted by O, S or N--CH.sub.3, or --(CH.sub.2).sub.3 --CO--)and their environmentally tolerated salts.The compounds Ia to Id are suitable as herbicides.