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1. 发明授权

US09011309B2 Devices for thermally induced transformations controlled by irradiation of functionalized fullerenes 有权
标题翻译：通过功能化富勒烯照射控制的热诱导转化装置
公开(公告)号：US09011309B2
公开(公告)日：2015-04-21
申请号：US13106355
申请日：2011-05-12
申请人： Vijay Krishna , Karl Zawoy , Brij M. Moudgil , Benjamin L. Koopman , Nathanael Ian Stevens , Kevin William Powers
发明人： Vijay Krishna , Karl Zawoy , Brij M. Moudgil , Benjamin L. Koopman , Nathanael Ian Stevens , Kevin William Powers
IPC分类号： A61N5/00 , C08K5/10 , C08K5/17 , C08K5/3415 , A61K47/00 , A61K47/36 , A61K47/30 , A61K38/02 , A61K38/22 , A61K31/465 , A61K38/28 , A61K31/56 , A61K9/00 , A01N25/26 , C05F11/00 , F42D1/04 , C08K5/05 , B82Y30/00 , B82Y5/00 , A61B18/18 , A61N5/06 , A61N5/10
CPC分类号： A61K41/0052 , A61B18/18 , A61B18/1815 , A61N5/025 , A61N5/0601 , A61N5/062 , A61N5/10 , A61N2005/0659 , A61N2005/0661 , A61N2005/0662 , A61N2005/1098 , F42C19/08 , Y10S977/734 , Y10S977/902 , Y10S977/915 , Y10S977/931
摘要： An electromagnetic radiation activated device comprises a property changing material and at least one functionalized fullerene that upon irradiation of the functionalized fullerenes with electromagnetic radiation of one or more frequencies a thermally activated chemical or physical transformation occurs in the property changing material. The thermal activated transformation of the property changing material is triggered by the heating or combustion of the functionalized fullerenes upon their irradiation. The device can include a chemical agent that is embedded in the property changing material and is released when the material is heated by the functionalized fullerenes upon irradiation.
摘要翻译：电磁辐射激活装置包括性质改变材料和至少一种官能化富勒烯，当功能化富勒烯以一种或多种频率的电磁辐射照射时，在所述性质改变材料中发生热激活的化学或物理转变。性能改变材料的热激活转化是由于功能化的富勒烯在其照射下的加热或燃烧而触发的。该装置可以包括嵌入在性能改变材料中的化学试剂，并且当材料在照射时被官能化富勒烯加热时被释放。

2. 发明授权

US09084989B2 Enhancement of electron scavenging by water-soluble fullerenes 有权
标题翻译：通过水溶性富勒烯增强电子扫除
公开(公告)号：US09084989B2
公开(公告)日：2015-07-21
申请号：US13000765
申请日：2009-06-24
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： B60C1/00 , B01J35/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B31/02 , H01L51/00 , B01J21/06 , B01J23/06
CPC分类号： C07C39/17 , B01J21/063 , B01J23/06 , B01J35/004 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C07C2604/00 , H01L51/0047 , Y02E10/549
摘要： Polyhydroxyfullerenes (PHFs) having enhanced electron scavenging capabilities have a ratio of non-hydroxyl functional groups to hydroxyl functional groups that is less than or equal to 0.3. When combined with a semiconductor photocatalyst, such as titanium dioxide nanoparticles, the PHFs provide a photocatalyst for degradation of chemical and biological contaminates with an efficiency of at least twice that of titanium dioxide nanoparticles free of PHFs. The PRFs are included in these catalysts at a weight ratio to titanium dioxide of about 0.001 to about 0.003, whereas significantly lower and higher ratios do not achieve the highly improved photodegradation capability. PHFs outside of the desired structure are shown to be of little value for photodegradation, and can be inhibiting to the photocatalytic activity of TiO2. The enhanced electron scavenging PHFs can be employed as a component of materials for solar cells, field effect transistors, and radical scavengers.
摘要翻译：具有增强的电子清除能力的聚羟基富勒烯（PHF）具有小于或等于0.3的非羟基官能团与羟基官能团的比例。当与诸如二氧化钛纳米颗粒的半导体光催化剂组合时，PHF提供用于降解化学和生物污染物的光催化剂，其效率为不含PHF的二氧化钛纳米颗粒的至少两倍。这些催化剂中的PRF以与二氧化钛的重量比约0.001至约0.003包括在一起，而明显降低和较高的比率不能获得高度改善的光降解能力。显示出所需结构之外的PHF对于光降解没有什么价值，并且可以抑制TiO 2的光催化活性。增强的电子清除PHF可以用作太阳能电池，场效应晶体管和自由基清除剂的材料的组分。

3. 发明授权

US08986516B2 Optical release of hydrogen from functionalized fullerenes as storage materials 有权
标题翻译：从功能化富勒烯作为储存材料的光学释放氢
公开(公告)号：US08986516B2
公开(公告)日：2015-03-24
申请号：US12810261
申请日：2009-01-05
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： C01B3/00 , B82Y30/00 , B82Y40/00 , C01B31/00 , C01B31/02
CPC分类号： C01B3/0021 , B82Y30/00 , B82Y40/00 , C01B3/0078 , C01B32/15 , C01B32/152 , Y02E60/325
摘要： A method to release hydrogen from a material comprising hydrogen fixed fullerenes involves irradiating the hydrogen fixed fullerenes with electromagnetic radiation of sufficient intensity to release hydrogen rapidly upon irradiation. The intensity of the irradiation and/or the area of irradiation can be adjusted to control the rate and extent of hydrogen release. The hydrogen depleted material comprising hydrogen fixed fullerene can be hydrogenated to regenerate the material.
摘要翻译：从包含氢固定富勒烯的材料中释放氢的方法包括用足够强度的电磁辐射照射氢固定的富勒烯，以便在照射时快速释放氢。可以调节照射强度和/或照射面积，以控制氢的释放速度和程度。包含氢固定富勒烯的氢耗尽材料可以被氢化以再生材料。

4. 发明授权

US08883124B2 Use of fullerenes in photoacoustic imaging 有权
标题翻译：在光声成像中使用富勒烯
公开(公告)号：US08883124B2
公开(公告)日：2014-11-11
申请号：US12740884
申请日：2008-10-31
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman , Stephen Grobmyer , Iwakuma Nobutaka , Qiang Wang , Qizhi Zhang , Huabei Jiang , Parvesh Sharma , Amit Kumar Singh
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman , Stephen Grobmyer , Iwakuma Nobutaka , Qiang Wang , Qizhi Zhang , Huabei Jiang , Parvesh Sharma , Amit Kumar Singh
IPC分类号： A61B8/00 , G01S15/00 , H04B1/02 , A61K49/00 , A61B5/00 , G01N21/17
CPC分类号： A61K49/00 , A61B5/0095 , A61B8/00 , G01N21/1702 , G01N2021/1787 , Y10S977/734 , Y10S977/842 , Y10S977/927 , Y10S977/953
摘要： Fullerenes, when irradiated with electromagnetic radiation, generate acoustic waves. A photoacoustic tomography method using a material comprising fullerenes is disclosed that includes irradiating the material with a radiation beam such as a laser. The resultant photoacoustic effect produced by the material is detected by at least one detector. A photoacoustic tomography system using a material comprising fullerenes is also described.
摘要翻译：富勒烯当用电磁辐射照射时产生声波。公开了一种使用包含富勒烯的材料的光声层析成像方法，其包括用辐射束如激光照射材料。由材料产生的所得光声效应由至少一个检测器检测。还描述了使用包含富勒烯的材料的光声层析成像系统。

5. 发明申请

US20130035398A1 FUNCTIONALIZED FULLERENES AS A BIOMASS STIMULANT AND A LIFE EXTENSION AGENT 有权
标题翻译：作为生物传感器和生命延伸剂的功能丰富的富勒烯
公开(公告)号：US20130035398A1
公开(公告)日：2013-02-07
申请号：US13638054
申请日：2011-04-07
申请人： Jie Gao , Vijay Krishna , Wei Bai , Benjamin L. Koopman , Brij M. Moudgil , Paul Anthony Indeglia , Kevin Michael Folta , Angelina Tsenova Georgieva
发明人： Jie Gao , Vijay Krishna , Wei Bai , Benjamin L. Koopman , Brij M. Moudgil , Paul Anthony Indeglia , Kevin Michael Folta , Angelina Tsenova Georgieva
IPC分类号： C12N1/12 , C12N1/14 , A61K31/05
CPC分类号： C12N1/38 , B82Y5/00 , C12N1/12 , C12N1/14
摘要： Methods of stimulating an increase in biomass by stimulating the growth, lifespan and/or reproduction of organisms such as fungi, algae, plants, and other aquatic organisms are provided by applying an effective amount of functionalized fullerenes. For example, polyhydroxy fullerenes are effective at low levels of promoting the increase in biomass.
摘要翻译：通过施用有效量的官能化富勒烯来提供刺激生物体如真菌，藻类，植物和其它水生生物的生长，寿命和/或繁殖来刺激生物量增加的方法。例如，多羟基富勒烯在促进生物量增加的低水平方面是有效的。

6. 发明授权

US08709217B2 Production of carbon nanostructures from functionalized fullerenes 有权
标题翻译：从功能化富勒烯生产碳纳米结构
公开(公告)号：US08709217B2
公开(公告)日：2014-04-29
申请号：US13128585
申请日：2009-11-09
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： C01B31/00 , B01J19/12 , B82Y99/00 , B82Y40/00 , B82Y30/00
CPC分类号： C01B31/0226 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/16 , C01B32/18 , C01B32/25 , C01B2202/06 , C01B2202/34 , C01B2202/36 , Y10S977/752 , Y10S977/842 , Y10S977/902
摘要： Electromagnetic irradiation of functionalized fullerenes in an oxygen-free environment induces conversion of the functionalized fullerenes to carbon nanotubes, carbon nanohorns, carbon onions, diamonds and/or carbon schwarzites. The carbon nanotubes can be multi-wall carbon nanotubes. Advantageously, the subject invention can be used for in-situ synthesis of carbon nanostructures within a matrix to form a carbon nanostructure composite, where positioning of the carbon nanostructures is controlled by the manner of dispersion of the functionalized fullerenes in the matrix. Carbon nanotube comprising features, such as electrical connects, can be formed on a surface by irradiating a portion of a functionalized fullerene coating with a laser beam.
摘要翻译：在无氧环境中的功能化富勒烯的电磁辐射诱导官能化的富勒烯转化为碳纳米管，碳纳米角，碳鎓，金刚石和/或碳施瓦镁石。碳纳米管可以是多壁碳纳米管。有利地，本发明可用于在基质内原位合成碳纳米结构以形成碳纳米结构复合材料，其中通过官能化富勒烯在基质中分散的方式控制碳纳米结构的定位。通过用激光束照射功能化的富勒烯涂层的一部分，可以在表面上形成包括诸如电连接的特征的碳纳米管。

7. 发明申请

US20120015045A1 FUNCTIONALIZED FULLERENES AS ANTIFUNGAL AGENTS 有权
标题翻译：作为反兴奋剂的功能齐全的富勒烯
公开(公告)号：US20120015045A1
公开(公告)日：2012-01-19
申请号：US13258649
申请日：2010-04-01
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： A01N31/16 , A01P3/00 , C07C39/17 , A61P31/10 , A01N59/16 , A61K31/05
CPC分类号： A01N45/00 , C01B32/152 , A01N25/00 , A01N59/00 , A01N59/16 , A01N2300/00
摘要： Functionalized fullerenes are used in a method of combating fungal growth on surfaces and treating fungal diseases of patients. Surfaces that can be treated by the materials comprising an effective amount of functionalized fullerenes include those of fruits, vegetables, harvested grains, plants, or plant seeds. The method of combating fungal growth on a surface can be augmented but is not dependent on irradiation of the surface by light. Functional fullerenes are employed in various dosage forms such as topical, ingestible or administration.
摘要翻译：功能性富勒烯用于对抗表面真菌生长并治疗患者真菌病的方法。可以由包含有效量的官能化富勒烯的材料处理的表面包括水果，蔬菜，收获的谷物，植物或植物种子的表面。可以增强在表面上对抗真菌生长的方法，但不依赖于光的照射。功能性富勒烯以各种剂型使用，例如局部，可食用或给药。

8. 发明申请

US20110112232A1 ENHANCEMENT OF ELECTRON SCAVENGING BY WATER-SOLUBLE FULLERENES 有权
标题翻译：通过水溶性电解液增强电子扫描
公开(公告)号：US20110112232A1
公开(公告)日：2011-05-12
申请号：US13000765
申请日：2009-06-24
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： C08K3/18 , C07C39/14 , B01J31/38 , B01J31/26 , A61L2/08 , A61L2/10 , B82Y30/00
CPC分类号： C07C39/17 , B01J21/063 , B01J23/06 , B01J35/004 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C07C2604/00 , H01L51/0047 , Y02E10/549
摘要： Polyhydroxyfullerenes (PHFs) having enhanced electron scavenging capabilities have a ratio of non-hydroxyl functional groups to hydroxyl functional groups that is less than or equal to 0.3. When combined with a semiconductor photocatalyst, such as titanium dioxide nanoparticles, the PHFs provide a photocatalyst for degradation of chemical and biological contaminates with an efficiency of at least twice that of titanium dioxide nanoparticles free of PHFs. The PRFs are included in these catalysts at a weight ratio to titanium dioxide of about 0.001 to about 0.003, whereas significantly lower and higher ratios do not achieve the highly improved photodegradation capability. PHFs outside of the desired structure are shown to be of little value for photodegradation, and can be inhibiting to the photocatalytic activity of TiO2. The enhanced electron scavenging PHFs can be employed as a component of materials for solar cells, field effect transistors, and radical scavengers.
摘要翻译：具有增强的电子清除能力的聚羟基富勒烯（PHF）具有小于或等于0.3的非羟基官能团与羟基官能团的比例。当与诸如二氧化钛纳米颗粒的半导体光催化剂组合时，PHF提供用于降解化学和生物污染物的光催化剂，其效率为不含PHF的二氧化钛纳米颗粒的至少两倍。这些催化剂中的PRF以与二氧化钛的重量比约0.001至约0.003包括在一起，而明显降低和较高的比率不能获得高度改善的光降解能力。显示出所需结构之外的PHF对于光降解没有什么价值，并且可以抑制TiO 2的光催化活性。增强的电子清除PHF可以用作太阳能电池，场效应晶体管和自由基清除剂的材料的组分。

9. 发明授权

US09314027B2 Functionalized fullerenes as antifungal agents 有权
标题翻译：功能性富勒烯作为抗真菌剂
公开(公告)号：US09314027B2
公开(公告)日：2016-04-19
申请号：US13258649
申请日：2010-04-01
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： A01N45/00 , A01N59/16 , C01B31/02
CPC分类号： A01N45/00 , C01B32/152 , A01N25/00 , A01N59/00 , A01N59/16 , A01N2300/00
摘要： Functionalized fullerenes are used in a method of combating fungal growth on surfaces and treating fungal diseases of patients. Surfaces that can be treated by the materials comprising an effective amount of functionalized fullerenes include those of fruits, vegetables, harvested grains, plants, or plant seeds. The method of combating fungal growth on a surface can be augmented but is not dependent on irradiation of the surface by light. Functional fullerenes are employed in various dosage forms such as topical, ingestible or administration.
摘要翻译：功能性富勒烯用于对抗表面真菌生长并治疗患者真菌病的方法。可以由包含有效量的官能化富勒烯的材料处理的表面包括水果，蔬菜，收获的谷物，植物或植物种子的表面。可以增强在表面上对抗真菌生长的方法，但不依赖于光的照射。功能性富勒烯以各种剂型使用，例如局部，可食用或给药。

10. 发明授权

US08373139B2 Optical luminescence of functionalized fullerenes in an oxygen free environment 有权
标题翻译：功能化富勒烯在无氧环境中的光学发光
公开(公告)号：US08373139B2
公开(公告)日：2013-02-12
申请号：US12810248
申请日：2009-01-05
申请人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
发明人： Vijay Krishna , Brij M. Moudgil , Benjamin L. Koopman
IPC分类号： G01N21/64
CPC分类号： C09K11/06 , C09K2211/1011 , C09K2211/1416 , G01N2021/6432
摘要： Functionalized fullerenes, when excited at any of a broad range of wavelengths in an oxygen free environment, undergo luminescence. The oxygen sensitive luminescence of functionalized fullerenes is used for numerous applications including oxygen detection; irradiation induced healing of polymeric materials; and phosphors for optical location and display applications. The degradation of the functionalized fullerenes allows for the detection of oxygen by diminished luminescence when the fullerenes are exposed to an irradiation source, such as a laser beam, in the presence of oxygen. The luminescence from a portion of a surface of a material with functionalized fullerenes allows for the location of the surface containing a functionalized fullerene target in the absence of oxygen or to heat the object in the area irradiated that is exposed to oxygen. The localized heating can be used to repair defects to a material containing the functionalized fullerenes. Materials containing functionalized fullerenes can be used as phosphors in display applications.
摘要翻译：当无氧环境中的任何波长激发时，官能化的富勒烯经受发光。官能化富勒烯的氧敏感发光用于许多应用，包括氧气检测; 辐射诱导的聚合材料愈合; 和用于光学位置和显示应用的荧光体。官能化富勒烯的降解允许当富氧存在下，当富勒烯暴露于照射源（例如激光束）时，通过减少的发光来检测氧。具有官能化富勒烯的材料的表面的一部分的发光允许在不存在氧的情况下包含官能化的富勒烯靶的表面的位置或者在暴露于氧的被照射区域中加热物体。局部加热可用于将缺陷修复到含有官能化富勒烯的材料上。含有官能化富勒烯的材料可用作显示应用中的荧光体。

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