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1. 发明申请

US20070125702A1 MEMBRANE STRUCTURE AND METHOD OF MAKING 失效
标题翻译：膜结构和制备方法
公开(公告)号：US20070125702A1
公开(公告)日：2007-06-07
申请号：US11555506
申请日：2006-11-01
申请人： Vidya Ramaswamy , James Ruud , Anthony Ku , William Huber
发明人： Vidya Ramaswamy , James Ruud , Anthony Ku , William Huber
IPC分类号： B01D71/06
CPC分类号： B01D67/0062 , B01D69/12 , B01D71/022 , B01J2219/00835 , B01J2219/00907 , Y10T428/249981
摘要： A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process.
摘要翻译：提供膜结构。膜结构包括具有多个孔的聚合物层; 以及设置在聚合物层上的陶瓷层。陶瓷层具有多个基本上未连接的孔。每个基本上未连接的孔与聚合物层的至少一个孔流体连通。提供一种制造膜结构的方法。该方法包括提供具有多个孔的聚合物层的步骤; 并在聚合物层上设置陶瓷层。布置陶瓷层包括在聚合物层上沉积金属层; 并阳极氧化金属层以将金属层转化为多孔层。沉积步骤和阳极氧化步骤中的至少一个作为连续工艺进行。或者，沉积和阳极化步骤中的至少一个作为分批处理进行。

2. 发明申请

US20070068382A1 Functionalized inorganic membranes for gas separation 有权
标题翻译：用于气体分离的官能化无机膜
公开(公告)号：US20070068382A1
公开(公告)日：2007-03-29
申请号：US11263165
申请日：2005-10-31
申请人： Anthony Ku , James Ruud , Jennifer Molaison , Louis Schick , Vidya Ramaswamy
发明人： Anthony Ku , James Ruud , Jennifer Molaison , Louis Schick , Vidya Ramaswamy
IPC分类号： B01D53/22
CPC分类号： B01D71/024 , B01D53/228 , B01D69/12 , B01D2323/08 , Y02C10/10
摘要： A porous membrane for separation of carbon dioxide from a fluid stream at a temperature higher than about 200° C. with selectivity higher than Knudsen diffusion selectivity. The porous membrane comprises a porous support layer comprising alumina, silica, zirconia or stabilized zirconia; a porous separation layer comprising alumina, silica, zirconia or stabilized zirconia, and a functional layer comprising a ceramic oxide contactable with the fluid stream to preferentially transport carbon dioxide. In particular, the functional layer may be MgO, CaO, SrO, BaO, La2O3, CeO2, ATiO3, AZrO3, AAl2O4, A1FeO3, A1MnO3, A1CoO3, A1NiO3, A2HfO3, A3CeO3, Li2ZrO3, Li2SiO3, Li2TiO3 or a mixture thereof; wherein A is Mg, Ca, Sr or Ba; A1 is La, Ca, Sr or Ba; A2 is Ca, Sr or Ba; and A3 is Sr or Ba.
摘要翻译：一种用于在高于约200℃的温度下将二氧化碳与流体物流分离的多孔膜，选择性高于克努森扩散选择性。多孔膜包括多孔支撑层，包括氧化铝，二氧化硅，氧化锆或稳定的氧化锆; 包括氧化铝，二氧化硅，氧化锆或稳定的氧化锆的多孔分离层和包含可与流体流接触以优先输送二氧化碳的陶瓷氧化物的功能层。特别地，功能层可以是MgO，CaO，SrO，BaO，La 2 O 3，CeO 2，ATiO 3 AZrO 3，AA 1，2 O 4，A 1，Fe 3，3， A 1，...，N 2，A 1，...，...，...，...，... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... NiO 3，3O 3，3O 3，3％，3％，3％，3％，3％ SUB 2 2 ZrO 3 3，Li 2 SiO 3 3，Li 2 TiO 3 或其混合物; 其中A是Mg，Ca，Sr或Ba; A 1是La，Ca，Sr或Ba; A 是Ca，Sr或Ba; 和A 3是Sr或Ba。

3. 发明申请

US20070125701A1 Membrane structure and method of making 失效
标题翻译：膜结构及制作方法
公开(公告)号：US20070125701A1
公开(公告)日：2007-06-07
申请号：US11296746
申请日：2005-12-07
申请人： Vidya Ramaswamy , James Ruud , Melissa Sander , Anthony Ku , Mohan Manoharan , Milivoj Brun , Seth Taylor
发明人： Vidya Ramaswamy , James Ruud , Melissa Sander , Anthony Ku , Mohan Manoharan , Milivoj Brun , Seth Taylor
IPC分类号： B01D29/00
CPC分类号： B01D67/0062 , B01D67/0069 , B01D69/12 , B01D71/022 , B01D2325/021 , B01D2325/04 , Y10T428/31504
摘要： A membrane structure is provided. The membrane structure includes a first layer having a plurality of interconnected pores; and a second layer disposed on the first layer. The second layer has a plurality of unconnected pores. Each of the unconnected pores is in fluid communication with at least one of the interconnected pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; and disposing a second layer on the first layer. Disposing a second layer includes depositing a conducting layer on the first layer; and anodizing the conducting layer to convert the conducting layer into a porous layer.
摘要翻译：提供膜结构。膜结构包括具有多个互连孔的第一层; 以及设置在第一层上的第二层。第二层具有多个未连接的孔。每个未连接的孔与第一层的至少一个相互连通的孔流体连通。提供了制造膜结构的方法。该方法包括提供具有多个互连孔的第一层的步骤; 以及在所述第一层上设置第二层。布置第二层包括在第一层上沉积导电层; 并将导电层阳极氧化以将导电层转化为多孔层。

4. 发明申请

US20070131609A1 Membrane structure and method of making 审中-公开
标题翻译：膜结构及制作方法
公开(公告)号：US20070131609A1
公开(公告)日：2007-06-14
申请号：US11297776
申请日：2005-12-08
申请人： Vidya Ramaswamy , Milivoj Brun , Sergio Loureiro , Anthony Ku , Mohan Manoharan
发明人： Vidya Ramaswamy , Milivoj Brun , Sergio Loureiro , Anthony Ku , Mohan Manoharan
IPC分类号： B01D29/00
CPC分类号： B01D71/02 , B01D53/228 , B01D61/145 , B01D61/147 , B01D67/0046 , B01D67/0088 , B01D69/12 , B01D69/145 , B01D2325/023 , B01D2325/14 , B01D2325/16 , B01D2325/18 , B32B18/00 , C01B3/503 , C01B3/505 , C01B13/0255 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2210/0046 , C04B35/111 , C04B35/645 , C04B38/00 , C04B2111/00405 , C04B2111/00413 , C04B2111/00612 , C04B2111/00801 , C04B2111/0081 , C04B2111/94 , C04B2235/5436 , C04B2235/5445 , C04B2235/6025 , C04B2235/604 , C04B2237/343 , C04B2237/586 , C04B2237/588 , C04B2237/704 , Y10T156/10 , C04B35/00 , C04B38/0054 , C04B38/0096
摘要： A membrane structure is provided. A membrane structure has a top surface and a bottom surface. The membrane structure includes a plurality of sintered layers including an inner layer disposed between two outer layers. The membrane structure further includes a nonmonotonic gradient in pore size extending between the top surface and the bottom surface. A method of making a membrane structure is provided. The method includes the steps of providing at least one inner layer; providing a plurality of outer layers; and laminating the inner layer and the outer layers to obtain a membrane structure.
摘要翻译：提供膜结构。膜结构具有顶表面和底表面。膜结构包括多个烧结层，其包括设置在两个外层之间的内层。膜结构还包括在顶表面和底表面之间延伸的孔径的非单调梯度。提供了制造膜结构的方法。该方法包括提供至少一个内层的步骤; 提供多个外层; 并层压内层和外层以获得膜结构。

5. 发明申请

US20060105141A1 Mesoporous nano-crystalline titania structures for hydrogen sensing 审中-公开
标题翻译：用于氢气感测的介孔纳米结晶二氧化钛结构
公开(公告)号：US20060105141A1
公开(公告)日：2006-05-18
申请号：US10993569
申请日：2004-11-18
申请人： Anthony Ku , Sergio Loureiro , James Ruud
发明人： Anthony Ku , Sergio Loureiro , James Ruud
IPC分类号： B32B3/10
CPC分类号： G01N33/005 , B82Y15/00 , B82Y30/00 , C04B35/46 , C04B38/0045 , C04B2111/00827 , Y10S977/953 , Y10S977/957 , Y10T428/24273 , C04B38/0003 , C04B38/0054
摘要： A structure includes a substantially non-conductive frame having an exterior surface. The structure defines a plurality of passages that open to the exterior surface. Mesoporous material is disposed in the plurality of passages and is supported therein by the frame. In a method for making a mesoporous nanocrystalline titania hybrid material, a templating agent, an acid, and a titania precursor is mixed into a template liquid. A frame that defines a plurality of passages is placed into the template liquid. A solvent is evaporated from the template liquid, thereby forming a titania gel encapsulating the templating agent. The gel is heated to remove substantially the templating agent from the non-conductive frame and the titania, thereby leaving a mesoporous titania material.
摘要翻译：一种结构包括具有外表面的基本不导电的框架。该结构限定了多个通向外表面的通道。介孔材料设置在多个通道中并被框架支撑在其中。在制备介孔纳米晶二氧化钛混合材料的方法中，将模板剂，酸和二氧化钛前体混合到模板液中。将限定多个通道的框架放置在模板液体中。从模板液中蒸发溶剂，从而形成包封模板剂的二氧化钛凝胶。将凝胶加热以从非导电性框架和二氧化钛基本上除去模板剂，从而留下介孔二氧化钛材料。

6. 发明申请

US20070149399A1 Multifunctional catalyst and methods of manufacture thereof 审中-公开
标题翻译：多功能催化剂及其制造方法
公开(公告)号：US20070149399A1
公开(公告)日：2007-06-28
申请号：US11317470
申请日：2005-12-22
申请人： Anthony Ku , Lawrence Kool , Sergio Martins-Loureiro , Mohan Manoharan , Seth Taylor , James Ruud
发明人： Anthony Ku , Lawrence Kool , Sergio Martins-Loureiro , Mohan Manoharan , Seth Taylor , James Ruud
IPC分类号： B01J21/04
CPC分类号： B01J35/0006 , B01J23/10 , B01J23/75 , B01J35/065 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/345 , B01J2219/00432 , B01J2219/00639 , B01J2219/00747
摘要： Disclosed herein is a multifunctional catalyst system comprising a substrate; and a catalyst pair disposed upon the substrate; wherein the catalyst pair comprises a first catalyst and a second catalyst; and wherein an average particle or domain spacing between particles or domains comprising the first catalyst or the second catalyst is about 10 to about 1,000 nanometers. Disclosed herein too is a process comprising selectively functionalizing a substrate to form a functionalized substrate; reacting a first catalyst to a first region of the functionalized substrate; and reacting a second catalyst to a second region of the functionalized substrate; wherein an average particle or domain spacing between particles or domains comprising the first catalyst or the second catalyst is about 10 to about 1,000 nanometers.
摘要翻译：本文公开了一种包括基材的多功能催化剂体系; 以及设置在所述基板上的催化剂对; 其中所述催化剂对包含第一催化剂和第二催化剂; 并且其中包含第一催化剂或第二催化剂的颗粒或域之间的平均颗粒或畴间隔为约10至约1000纳米。本文还公开了包括选择性地官能化基底以形成官能化基底的方法; 使第一催化剂与官能化基材的第一区域反应; 并使第二催化剂与官能化基材的第二区域反应; 其中包含第一催化剂或第二催化剂的颗粒或结构域之间的平均颗粒或畴间隔为约10至约1000纳米。

7. 发明申请

US20080011050A1 MESOPOROUS NANO-CRYSTALLINE TITANIA STRUCTURES FOR HYDROGEN SENSING 失效
标题翻译：用于氢感测的多孔纳米晶体TITANIA结构
公开(公告)号：US20080011050A1
公开(公告)日：2008-01-17
申请号：US11777305
申请日：2007-07-13
申请人： Anthony Ku , Sergio Loureiro , James Ruud
发明人： Anthony Ku , Sergio Loureiro , James Ruud
IPC分类号： G01N37/00
CPC分类号： G01N33/005 , B82Y15/00 , B82Y30/00 , C04B35/46 , C04B38/0045 , C04B2111/00827 , Y10S977/953 , Y10S977/957 , Y10T428/24273 , C04B38/0003 , C04B38/0054
摘要： A structure includes a substantially non-conductive frame having an exterior surface. The structure defines a plurality of passages that open to the exterior surface. Mesoporous material is disposed in the plurality of passages and is supported therein by the frame. In a method for making a mesoporous nanocrystalline titania hybrid material, a templating agent, an acid, and a titania precursor is mixed into a template liquid. A frame that defines a plurality of passages is placed into the template liquid. A solvent is evaporated from the template liquid, thereby forming a titania gel encapsulating the templating agent. The gel is heated to remove substantially the templating agent from the non-conductive frame and the titania, thereby leaving a mesoporous titania material.
摘要翻译：一种结构包括具有外表面的基本不导电的框架。该结构限定了多个通向外表面的通道。介孔材料设置在多个通道中并被框架支撑在其中。在制备介孔纳米晶二氧化钛混合材料的方法中，将模板剂，酸和二氧化钛前体混合到模板液中。将限定多个通道的框架放置在模板液体中。从模板液中蒸发溶剂，从而形成包封模板剂的二氧化钛凝胶。将凝胶加热以从非导电性框架和二氧化钛基本上除去模板剂，从而留下介孔二氧化钛材料。

8. 发明申请

US20070149392A1 Reactor for carbon dioxide capture and conversion 审中-公开
标题翻译：二氧化碳捕集和转化反应堆
公开(公告)号：US20070149392A1
公开(公告)日：2007-06-28
申请号：US11317138
申请日：2005-12-22
申请人： Anthony Ku , James Ruud , Mohan Manoharan , Lawrence Kool , Sergio Martins-Loureiro , Margaret Blohm , Bruce Norman
发明人： Anthony Ku , James Ruud , Mohan Manoharan , Lawrence Kool , Sergio Martins-Loureiro , Margaret Blohm , Bruce Norman
IPC分类号： B01J23/00 , B01D53/94
CPC分类号： B01D53/864 , B01D53/944 , B01D53/9477 , B01D2257/504 , B01J23/80 , B01J23/83 , B01J23/835 , B01J23/8933 , B01J35/0006 , C07C1/044 , C07C11/04 , C07C29/1518 , C07C2521/08 , C07C2523/74 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C10G2/332 , Y02A50/2341 , Y02P20/152 , Y02P20/51 , Y02P20/52 , C07C31/04
摘要： Disclosed herein is a multifunctional catalyst system comprising a substrate; and a catalyst pair disposed upon the substrate; wherein the catalyst pair comprises a first catalyst and a second catalyst; and wherein the first catalyst initiates or facilitates the reduction of carbon dioxide to carbon monoxide while the second catalyst initiates or facilitates the conversion of carbon monoxide to an organic compound. Disclosed herein is a method comprising reducing carbon dioxide to carbon monoxide in a first reaction catalyzed by a first catalyst; and reacting carbon monoxide with hydrogen in a second reaction catalyzed by second catalyst; wherein the first catalyst and the second catalyst are disposed upon a single substrate.
摘要翻译：本文公开了一种包括基材的多功能催化剂体系; 以及设置在所述基板上的催化剂对; 其中所述催化剂对包含第一催化剂和第二催化剂; 并且其中所述第一催化剂起始或促进二氧化碳还原成一氧化碳，而第二催化剂起始或促进一氧化碳转化为有机化合物。本文公开了一种方法，包括在由第一催化剂催化的第一反应中将二氧化碳还原成一氧化碳; 并在第二反应催化下由一氧化碳与氢反应; 其中所述第一催化剂和所述第二催化剂设置在单个基板上。

9. 发明申请

US20070148415A1 Mesoporous membranes with complex functional architectures and methods for making 审中-公开
标题翻译：具有复杂功能结构和制造方法的介孔膜
公开(公告)号：US20070148415A1
公开(公告)日：2007-06-28
申请号：US11315209
申请日：2005-12-23
申请人： Anthony Ku , Seth Taylor , Mohan Manoharan , Sergio Paulo Loureiro , James Ruud
发明人： Anthony Ku , Seth Taylor , Mohan Manoharan , Sergio Paulo Loureiro , James Ruud
IPC分类号： B01J21/04
CPC分类号： B01D71/024 , B01D67/0069 , B01D67/0093 , B01D2323/24 , B01D2325/08 , C04B38/0064 , Y10S977/893 , Y10T428/24802 , C04B35/00 , C04B38/0054
摘要： In some embodiments, the present invention is directed to methods of making structures with complex functional architectures, where such structures generally comprise at least two mesoporous regions comprising different chemical activity, and where such methods afford spatial control over the placement of such regions of differing chemical activity. In some embodiments, the present invention is also directed to the structures formed by such methods, where such structures are themselves novel.
摘要翻译：在一些实施方案中，本发明涉及制备具有复杂功能结构的结构的方法，其中这样的结构通常包含至少两个包含不同化学活性的介孔区，并且其中这些方法提供对不同化学物质的这些区域的放置的空间控制活动。在一些实施方案中，本发明还涉及通过这些方法形成的结构，其中这些结构本身是新颖的。

10. 发明申请

US20060266700A1 Porous structures with engineered wettability properties and methods of making them 审中-公开
标题翻译：具有工程润湿性的多孔结构及其制备方法
公开(公告)号：US20060266700A1
公开(公告)日：2006-11-30
申请号：US11141576
申请日：2005-05-31
申请人： Anthony Ku , Sergio Loureiro , James Ruud , Mohan Manoharan , Lawrence Kool , Seth Taylor
发明人： Anthony Ku , Sergio Loureiro , James Ruud , Mohan Manoharan , Lawrence Kool , Seth Taylor
IPC分类号： B01D71/00
CPC分类号： B01D69/02 , B01D39/1676 , B01D39/2051 , B01D39/2093 , B01D67/0088 , B01D69/00 , B01D69/12 , B01D69/141 , B01D71/02 , B01D71/027 , B01D2239/0478 , B01D2239/065 , B01D2239/1216 , C04B38/0096 , C04B2111/00801 , C04B35/00
摘要： A porous structure and method of making the porous structure is disclosed. The porous structure includes a substrate comprising at least one pore having an internal surface. At least a first portion of the internal surface of the at least one pore has a first fluid contact angle and at least second portion of the internal surface of the at least one pore has a second fluid contact angle. The difference between the first fluid contact angle and the second fluid contact angle has an absolute value of at least about 5 degrees and the second fluid contact angle is greater than about 40 degrees.
摘要翻译：公开了一种制造多孔结构的多孔结构和方法。多孔结构包括包含至少一个具有内表面的孔的基底。至少一个孔的内表面的至少第一部分具有第一流体接触角，并且至少一个孔的内表面的至少第二部分具有第二流体接触角。第一流体接触角和第二流体接触角之间的差异具有至少约5度的绝对值，并且第二流体接触角大于约40度。

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