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    • 3. 发明申请
    • Semiconductor nanocrystal quantum dots and metallic nanocrystals as UV blockers and colorants for suncreens and/or sunless tanning compositions
    • 半导体纳米晶体量子点和金属纳米晶体作为UV阻挡剂和防晒剂和/或无阳光鞣制组合物的着色剂
    • US20050265935A1
    • 2005-12-01
    • US10857583
    • 2004-05-28
    • Jennifer HollingsworthVictor KlimovPolina Anikeeva
    • Jennifer HollingsworthVictor KlimovPolina Anikeeva
    • A61K8/02A61K8/23A61K8/25A61Q17/04A61K7/42
    • B82Y5/00A61K8/02A61K8/23A61K8/25A61K2800/413A61K2800/52A61Q17/04
    • The present invention is directed to photostable sunscreen and/or artificial tanning compositions including quantum dot nanocrystals of a material selected from semiconductor nanocrystals, modified semiconductor nanocrystals, multicomponent semiconductor/semiconductor nanocrystals, and hybrid semiconductor/metal nanocrystals, the quantum dot nanocrystals having an absorption band gap occurring at wavelengths higher than 400 nm whereby the quantum dot nanocrystals have substantial broadband absorption properties of ultraviolet light at wavelengths across the range of both UV-A (320-400 nm) and UV-B (280-320 nm), and a dermatologically acceptable carrier for the quantum dot nanocrystals. The present invention is further directed to photostable sunscreen and/or artificial tanning compositions including a material selected from metallic nanocrystals, multicomponent metal/metal nanocrystals, and alloyed metal nanocrystals, the metallic material having a surface plasmon resonance occurring sufficiently into the visible or infrared spectral region whereby broad absorption features due to electronic transitions, the broad absorption features located at higher energies, provide substantial broadband absorption properties of ultraviolet light at wavelengths across the range of both UV-A (320-400 nm) and UV-B (280-320 nm), and a dermatologically acceptable carrier for the metallic material.
    • 本发明涉及包含选自半导体纳米晶体,改性半导体纳米晶体,多组分半导体/半导体纳米晶体和混合半导体/金属纳米晶体的材料的量子点纳米晶体的光稳定防晒剂和/或人造鞣制组合物,所述量子点纳米晶体具有吸收 发生在高于400nm的波长处的带隙,由此量子点纳米晶体在UV-A(320-400nm)和UV-B(280-320nm)的范围内的波长处具有相当大的紫外光的宽带吸收特性,以及 用于量子点纳米晶体的皮肤病学可接受的载体。 本发明还涉及包含选自金属纳米晶体,多组分金属/金属纳米晶体和合金化金属纳米晶体的材料的光稳定性防晒剂和/或人造鞣制组合物,所述金属材料具有充分进入可见光或红外光谱的表面等离子体共振 区域,由于电子跃迁的广泛吸收特征,位于较高能量的宽吸收特征,在UV-A(320-400nm)和UV-B(280- 400nm)范围内的波长处提供紫外光的实质宽带吸收特性, 320nm),以及用于金属材料的皮肤病学可接受的载体。
    • 7. 发明申请
    • Nanocrystal/sol-gel nanocomposites
    • 纳米晶体/溶胶 - 凝胶纳米复合材料
    • US20050107478A1
    • 2005-05-19
    • US10715733
    • 2003-11-17
    • Victor KlimovMelissa Petruska
    • Victor KlimovMelissa Petruska
    • C08J3/02C08K3/08
    • B82Y30/00C08K3/08C08K2201/011Y10S977/773
    • The present invention is directed to a process for preparing a solid composite having colloidal nanocrystals dispersed within a sol-gel matrix, the process including admixing colloidal nanocrystals with an amphiphilic polymer including hydrophilic groups selected from the group consisting of —COOH, —OH, —SO3H, —NH2, and —PO3H2 within a solvent to form an alcohol-soluble colloidal nanocrystal-polymer complex, admixing the alcohol-soluble colloidal nanocrystal-polymer complex and a sol-gel precursor material, and, forming the solid composite from the admixture. The present invention is also directed to the resultant solid composites and to the alcohol-soluble colloidal nanocrystal-polymer complexes.
    • 本发明涉及一种制备具有分散在溶胶 - 凝胶基体内的胶态纳米晶体的固体复合物的方法,该方法包括将胶态纳米晶体与包括亲水基团的两亲性聚合物混合,所述亲水基团选自-COOH,-OH, - SO 3 H 2,-NH 2 H 2和-SO 3 H 2 H 2,以形成醇 - 可溶性胶体纳米晶体 - 聚合物复合物,混合醇溶性胶体纳米晶体 - 聚合物复合物和溶胶 - 凝胶前体材料,并从混合物形成固体复合物。 本发明还涉及所得固体复合物和醇可溶性胶体纳米晶体 - 聚合物复合物。