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1. 发明申请

US20120063982A1 PROCESS AND DEVICE FOR DECOMPOSING LAUGHING GAS 有权
标题翻译：用于分解气体的方法和装置
公开(公告)号：US20120063982A1
公开(公告)日：2012-03-15
申请号：US13144227
申请日：2010-01-05
申请人： Ulrike Wenning , Hans-Jörg Zander , Anton Wellenhofer , Karl-Heinz Hofmann , Wibke Korn , Franz Beran , Nicole Schödel , Wolfgang Schmehl
发明人： Ulrike Wenning , Hans-Jörg Zander , Anton Wellenhofer , Karl-Heinz Hofmann , Wibke Korn , Franz Beran , Nicole Schödel , Wolfgang Schmehl
IPC分类号： B01D53/56
CPC分类号： C01B21/22 , A61M16/009 , A61M16/0093 , A61M2202/0283 , B01D53/8631 , B01D2257/402 , B01D2259/4533 , B01J23/40 , C01B21/02 , Y02C20/10 , Y02P20/153
摘要： The laughing-gas-containing gas (1) is diluted by means of a diluting gas (2). The diluting gas (2) is virtually free from water fractions in the dryer (3). After feed of the diluting gas (2) via the feed line (13), exhaust gas (8) from the catalytic decomposition (7) is added (4) to the laughing-gas-containing feed gas (12). After addition (4) of the exhaust gas (8) from the catalytic decomposition of laughing gas (7), the laughing-gas-containing feed gas (12) is compressed (5) and passed to the heat exchanger (6). In the heat exchanger (6) the laughing-gas-containing feed gas (12) is preheated by heat exchange with the exhaust gas (8). The exhaust gas (8) is cooled in the heat exchanger (6) in this process. The preheated laughing-gas-containing feed gas (12) is passed via a further optional heater (11) as a feed to the catalytic laughing gas decomposition (7). In order to avoid a concentration build-up, some of the exhaust gas (8) is passed out (9) of the process. The exhaust gas (8) is further cooled by a further optional heat exchanger (10). The additional cooling by means of the heat exchanger (10) ensures that subsequent appliances such as the compressor are protected against overheating. By means of the heat exchanger (10), the permissible temperature of that part of the exhaust gas (8) which is released (9) to the atmosphere can also be controlled here. For optimal control of the intake temperature of the laughing-gas-containing feed gas (12) into the catalytic decomposition (7), at least some of the laughing-gas-containing feed gas (12) can bypass the heat exchanger (6) using a bypass (14).
摘要翻译：含气味气体（1）通过稀释气体（2）稀释。稀释气体（2）在干燥器（3）中几乎没有水分。在通过进料管线（13）进料稀释气体（2）之后，向含笑气的进料气体（12）中加入来自催化分解（7）的废气（8）（4）。在从气体（7）的催化分解中加入（4）废气（8）后，将含笑气的进料气体（12）压缩（5）并通入热交换器（6）。在热交换器（6）中，通过与废气（8）的热交换来预热含笑气体的进料气体（12）。在该过程中，排气（8）在热交换器（6）中被冷却。预热的含笑气体的进料气体（12）通过另外的任选的加热器（11）作为催化气体分解的进料（7）通过。为了避免浓度积聚，一部分废气（8）被排出（9）。废气（8）通过另外的任选的热交换器（10）进一步冷却。通过热交换器（10）的附加冷却确保了后续的诸如压缩机的设备被保护以免过热。通过热交换器（10），也可以控制排放到大气中的废气（8）部分的允许温度（9）。为了将含笑气的进料气体（12）的进气温度最佳控制到催化分解（7）中，至少一些含气味的进料气体（12）可绕过热交换器（6）使用旁路（14）。

2. 发明授权

US08480985B2 Process and device for decomposing laughing gas 有权
标题翻译：分解笑气的工艺和装置
公开(公告)号：US08480985B2
公开(公告)日：2013-07-09
申请号：US13144227
申请日：2010-01-05
申请人： Ulrike Wenning , Hans-Jörg Zander , Anton Wellenhofer , Karl-Heinz Hofmann , Wibke Korn , Franz Beran , Nicole Schödel , Wolfgang Schmehl
发明人： Ulrike Wenning , Hans-Jörg Zander , Anton Wellenhofer , Karl-Heinz Hofmann , Wibke Korn , Franz Beran , Nicole Schödel , Wolfgang Schmehl
IPC分类号： B01D53/56 , B01D53/74 , B01D53/86
CPC分类号： C01B21/22 , A61M16/009 , A61M16/0093 , A61M2202/0283 , B01D53/8631 , B01D2257/402 , B01D2259/4533 , B01J23/40 , C01B21/02 , Y02C20/10 , Y02P20/153
摘要： A method and device for the catalytic decomposition of laughing gas in a laughing-gas-bearing gas. The method includes diluting the laughing-gas-bearing gas with a diluting gas, while forming a laughing-gas-bearing charge gas. The laughing-gas bearing charge gas is passed through a heat-exchange step where heat exchange occurs with an exhaust. A heating step occurs for occasional heating of the laughing-gas-bearing charge gas in a fixed-bed reactor for catalytic decomposition of the laughing gas. In some embodiments the diluting gas is dried, and at least a part of the exhaust from the catalytic decomposition of the laughing gas is mixed with the laughing-gas-bearing charge gas upstream of the catalytic decomposition of the laughing gas.
摘要翻译：用于在含气气体的气体中催化分解笑气的方法和装置。该方法包括用稀释气体稀释含气体的气体，同时形成含气体的充气气体。带有气体的充气气体通过与废气进行热交换的热交换步骤。在用于催化分解笑气的固定床反应器中偶尔加热含气气的充气气体，发生加热步骤。在一些实施方案中，稀释气体被干燥，并且来自笑气体的催化分解的排气的至少一部分与笑气的催化分解上游的含气气的加料气体混合。

3. 发明授权

US08460627B2 Apparatus and process for decomposing dinitrogen monoxide in an adiabatic fixed bed reactor 有权
标题翻译：在绝热固定床反应器中分解一氧化二氮的装置和方法
公开(公告)号：US08460627B2
公开(公告)日：2013-06-11
申请号：US13144224
申请日：2010-01-05
申请人： Franz Beran , Karl-Heinz Hofmann , Nicole Schödel , Wolfgang Schmehl , Ulrike Wenning , Hans-Jörg Zander
发明人： Franz Beran , Karl-Heinz Hofmann , Nicole Schödel , Wolfgang Schmehl , Ulrike Wenning , Hans-Jörg Zander
IPC分类号： B01D53/56 , B01D53/86
CPC分类号： C01B21/22 , A61M16/009 , A61M16/0093 , A61M2202/0283 , B01D53/8631 , B01D2257/402 , B01D2259/4533 , B01J23/40 , C01B21/02 , Y02C20/10 , Y02P20/153
摘要： A device and method for the decomposition of laughing gas including a gas inlet for supplying a laughing-gas-bearing gas; a first heat-exchanger for the exchange of heat between an exhaust and the laughing-gas-bearing gas; a heating device for occasional heating of the laughing-gas-bearing gas and a fixed-bed reactor in which a catalyst is included in order to decompose the laughing gas. The device also includes a gas outlet, through which exhaust leaving the fixed-bed reactor can be taken away through the heat exchanger. The device may be used to implement a method where the catalyst for decomposition of laughing gas is maintained at temperatures below 800° C. and in which the fixed-bed reactor is arranged as an adiabatic reactor.
摘要翻译：一种用于分解笑气的装置和方法，包括用于提供含气气体的气体的气体入口; 用于在排气和含气体气体之间交换热量的第一热交换器; 用于偶尔加热含气气体的加热装置和其中包含催化剂以便分解笑气的固定床反应器。该装置还包括气体出口，离开固定床反应器的排气通过该出口可以通过热交换器被带走。该装置可用于实现其中将笑气分解催化剂保持在低于800℃的温度并且其中固定床反应器被设置为绝热反应器的方法。

4. 发明申请

US20120014855A1 APPARATUS AND PROCESS FOR DECOMPOSING DINITROGEN MONOXIDE IN AN ADIABATIC FIXED BED REACTOR 有权
标题翻译：在固定床反应器中分解一氧化氮的装置和方法
公开(公告)号：US20120014855A1
公开(公告)日：2012-01-19
申请号：US13144224
申请日：2010-01-05
申请人： Franz Beran , Karl-Heinz Hofmann , Nicole Schödel , Wolfgang Schmehl , Ulrike Wenning , Hans-Jörg Zander
发明人： Franz Beran , Karl-Heinz Hofmann , Nicole Schödel , Wolfgang Schmehl , Ulrike Wenning , Hans-Jörg Zander
IPC分类号： B01D53/56 , B01J19/00
CPC分类号： C01B21/22 , A61M16/009 , A61M16/0093 , A61M2202/0283 , B01D53/8631 , B01D2257/402 , B01D2259/4533 , B01J23/40 , C01B21/02 , Y02C20/10 , Y02P20/153
摘要： The invention relates to an apparatus and to a process for decomposing dinitrogen monoxide. The apparatus comprises a gas inlet 1 for supplying a nitrogen monoxide-containing gas, a first heat exchange medium 3 for exchanging heat between an offgas and the nitrogen monoxide-containing gas, a heating apparatus 4 for occasional heating of the nitrogen monoxide-containing gas, a fixed bed reactor 5 in which a catalyst is accommodated, in order to decompose the dinitrogen monoxide in the dinitrogen monoxide-containing gas, a gas outlet through which the offgas leaving the fixed bed reactor can be conducted out via the heat exchange medium 3. According to the invention, the catalyst is suitable for decomposing dinitrogen monoxide at temperatures below 800° C., especially preferably below 450° C., more preferably below 400° C. The fixed bed reactor 5 is configured for operation in an adiabatic state.
摘要翻译：本发明涉及一种用于分解一氧化二氮的装置和方法。该装置包括用于供给一氧化二氮气体的气体入口1，用于在废气和含一氧化碳气体之间交换热的第一热交换介质3，用于偶尔加热含一氧化碳的气体的加热装置4 ，其中容纳有催化剂的固定床反应器5，以便分解一氧化二氮气体中的一氧化二氮，可以通过热交换介质3将出口离开固定床反应器的废气通过出口排出气体出口根据本发明，催化剂适用于在低于800℃，特别优选低于450℃，更优选低于400℃的温度下分解一氧化二氮。固定床反应器5构造成在绝热状态下操作。

5. 发明授权

US07785550B2 Process and device for separating hydrogen from gas flows by a pressure swing adsorption process 有权
标题翻译：通过变压吸附法从氢气中分离氢的工艺和装置
公开(公告)号：US07785550B2
公开(公告)日：2010-08-31
申请号：US12139168
申请日：2008-06-13
申请人： Karl-Heinz Hofmann , Paul Leitgeb , Ulrike Wenning , Hans-joerg Zander , Werner Leitmayr
发明人： Karl-Heinz Hofmann , Paul Leitgeb , Ulrike Wenning , Hans-joerg Zander , Werner Leitmayr
IPC分类号： C01B3/00 , C01B3/02 , C01B13/00
CPC分类号： B01D53/047 , B01D53/005 , B01D2256/16 , B01D2257/104 , C01B3/50 , C01B3/56 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , Y02E60/324 , Y02P20/129
摘要： A process for separating hydrogen from a gas flow having an oxygen constituent and including predominantly hydrogen, nitrogen, oxygen, carbon dioxide, carbon monoxide, methane and/or other hydrocarbons, as well as a device for conducting the process, is disclosed. The gas flow undergoes a process to thermally convert oxygen prior to the pressure swing adsorption process.
摘要翻译：公开了一种从具有氧成分并主要包含氢，氮，氧，二氧化碳，一氧化碳，甲烷和/或其它烃的气流中分离氢的方法，以及用于进行该方法的装置。气体流经过在变压吸附过程之前热氧转化的过程。

6. 发明授权

US5955045A Removal of nitrogen oxides from gases 失效
标题翻译：从气体中去除氮氧化物
公开(公告)号：US5955045A
公开(公告)日：1999-09-21
申请号：US874662
申请日：1997-06-13
申请人： Karl Baur , Hans-Peter Langebach , Hartmut Neumann , Ulrike Wenning
发明人： Karl Baur , Hans-Peter Langebach , Hartmut Neumann , Ulrike Wenning
IPC分类号： B01D53/56 , C07C7/148 , C10G70/04 , B01D53/02
CPC分类号： C07C7/1485 , B01D53/565 , C10G70/046
摘要： For selectively removing nitrogen oxides from a carrier gas that contains hydrocarbons, the nitrogen oxides are removed by chemisorption on metal oxides, without the occurrence of undesirable secondary reactions. The metal oxides are preferably formed from metals of the 6th to 8th subgroups, whereby manganese dioxide (MnO.sub.2,) is especially preferred as a metal oxide. The process can be conducted with one or more reactor beds, which preferably operate at 10 to 40.degree. C. and are regenerated with nitrogen at a temperature of 130 to 170.degree. C.By removing nitrogen oxides from an olefin-rich gas, for example from the waste gas of an FCC unit, the resultant gas can then be fed to a cryogenic olefin extraction stage without danger of explosion.Such a waste gas contains unsaturated hydrocarbons, hydrogen, carbon monoxide, and oxygen, the oxygen having a concentration preferably between 100 and 5000 mol ppm.
摘要翻译：为了从含有烃的载气中选择性地除去氮氧化物，通过金属氧化物上的化学吸附除去氮氧化物，而不会发生不希望的二次反应。金属氧化物优选由第6〜8族的金属形成，特别优选二氧化锰（MnO 2）作为金属氧化物。该方法可以用一个或多个反应器床进行，优选在10至40℃下操作，并在130-170℃的温度下用氮气再生。通过从富含烯烃的气体中除去氮氧化物，例如从FCC装置的废气中获得的气体可以被送入低温烯烃提取阶段而不会有爆炸的危险。这样的废气含有不饱和烃，氢，一氧化碳和氧，氧浓度优选为100-5000mol ppm。

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