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    • 3. 发明授权
    • Pressure swing adsorption process
    • 变压吸附过程
    • US5051115A
    • 1991-09-24
    • US51563
    • 1987-05-20
    • Paul LeitgebJohann Leis
    • Paul LeitgebJohann Leis
    • B01D53/047C01B21/04C01B32/40
    • B01D53/0476C01B21/045C01B31/18B01D2256/10B01D2256/12B01D2257/502B01D2259/40052B01D2259/404C01B2210/005
    • In a pressure swing adsorption process, after the adsorption phase, the residual less adsorbable components are purged by the introduction of a gas consisting essentially of the more adsorbable component. The more adsorbable component is subsequently recovered by drawing a vacuum on the adsorber. When separating a gaseous mixture containing 40-75 mol % of the more adsorbable component, after a vacuum recovery step to 0.03-0.3 bar, a first pressure buildup phase is performed with a gas consisting essentially of less adsorbable components. Preferably, the gas is an unadsorbed gas exiting during the adsorption phase from another adsorber. The gas employed in the first pressure build up is introduced into the adsorber countercurrently to the adsorption direction until an intermediate pressure of 0.1-1 bar is reached. A further pressure buildup is then conducted, preferably with expansion gas from another adsorber and/or with the gaseous mixture to be separated.
    • 在变压吸附方法中,在吸附阶段之后,通过引入基本上由较易吸附组分组成的气体来清除残留的较少吸附组分。 随后通过在吸附器上抽真空来回收更易吸附的组分。 当分离含有40-75mol%的较吸附组分的气体混合物时,在真空回收步骤至0.03-0.3巴之后,用基本上由较不吸附组分组成的气体进行第一压力积聚阶段。 优选地,气体是在吸附阶段期间从另一吸附器排出的未被吸收的气体。 在第一压力累积中使用的气体与吸附方向逆流引入吸附器,直到达到0.1-1巴的中间压力。 然后进一步的压力累积,优选地使用来自另一吸附器的膨胀气体和/或待分离的气体混合物。
    • 4. 发明授权
    • Adsorption process producing varying amounts of product gas of a
constant purity
    • 吸附过程产生不同量的具有恒定纯度的产物气体
    • US4323370A
    • 1982-04-06
    • US156946
    • 1980-06-06
    • Paul Leitgeb
    • Paul Leitgeb
    • B01D53/04
    • B01D53/04B01D2253/102B01D2256/10B01D2256/12B01D2257/102B01D2257/104
    • A cyclic adsorption process for the fractionation of a gaseous mixture, over an adsorbent exhibiting differential rates of adsorption for the components of the gaseous mixture. The process delivers a product gas of a constant concentration by varying the length of time of the adsorption phase and the rate of flow of the product gas from the adsorber, in response to a varying demand for the product gas. The rate of flow of a feed gas is varied in relationship to the rate of flow of the product gas. The rates of flow of the feed gas and of the product gas and the length of time of the adsorption cycle are determined from a correlation of the rate of flow of the product gas as a function of the product gas purity. The correlation is established experimentally for each feed/product gas combination.
    • 用于气态混合物分级的循环吸附方法,对于气体混合物的组分,吸附剂表现出不同的吸附速率。 响应于对产品气体的不同需求,该方法通过改变吸附阶段的时间长度和产物气体从吸附器的流速来提供恒定浓度的产物气体。 进料气体的流速与产物气体的流速相关地变化。 进料气体和产物气体的流速和吸附循环的时间长度是根据产物气体的流速与产物气体纯度的关系来确定的。 对于每个进料/产物气体组合,实验建立了相关性。
    • 8. 发明授权
    • Method of operating a cyclical pressure-swing adsorption installation
    • 操作循环变压吸附装置的方法
    • US4299595A
    • 1981-11-10
    • US98508
    • 1979-11-29
    • Christian BenkmannPaul LeitgebStefan Asztalos
    • Christian BenkmannPaul LeitgebStefan Asztalos
    • B01D53/04B01D53/047
    • B01D53/047B01D2259/40009B01D2259/4003B01D2259/40032B01D2259/40037B01D2259/40041B01D2259/40045B01D2259/40067B01D2259/40075B01D2259/404B01D2259/4066
    • A method of operating a multi-adsorber pressure-swing adsorber installation in which each adsorber is, in a given cycle, operated for a plurality of time slots in an adsorption stage, subjected to a plurality of pressure-relief phases over corresponding time slots by pressure equalization with other adsorbers, the pressure-relief phases are followed by purging phases and ultimately pressure buildup phases likewise by pressure equalization with other adsorbers. According to the invention, upon the detection of a pressure condition, either by direct measurement of pressure or by measurement of another parameter, deviating from a setpoint value indicating a defect in one adsorber or its valve or duct systems, this adsorber is cut out of the system and the remaining adsorbers are continued to be cycled or are temporarily retained in a previous phase with readjustment of the sequencing so that the feed and output remain continuous, the remaining adsorber sequences corresponding to the number of adsorbers which remain operative.
    • 一种操作多吸附器变压吸附器装置的方法,其中每个吸附器在给定的循环中在吸附阶段中对多个时间槽进行操作,在相应的时间段经过多个压力释放阶段 与其他吸附器进行压力均衡,压力释放阶段之后是清洗阶段,最后通过与其他吸附器的压力平衡来形成压力累积阶段。 根据本发明,通过直接测量压力或通过测量另一个参数来检测压力条件,偏离指示一个吸附器或其阀或管道系统中的缺陷的设定点值,该吸附器被从 系统和剩余的吸附剂继续循环,或者在先前阶段中被暂时保留,重新调整测序,使得进料和输出保持连续,剩余的吸附器序列对应于保持有效的吸附器的数量。