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    • 10. 发明申请
    • Mesoporous Metal-Organic Framework
    • 介孔金属有机框架
    • US20080188677A1
    • 2008-08-07
    • US11996976
    • 2006-08-16
    • Markus SchubertUlrich MullerHendrick MattenheimerMarkus Tonigold
    • Markus SchubertUlrich MullerHendrick MattenheimerMarkus Tonigold
    • C07F5/06
    • C07F5/069C01B3/001C01B3/0015C01B3/0026C07C51/418Y02E60/327Y02E60/328C07C63/307
    • The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.
    • 本发明涉及包含III-III族和至少一种至少二齿化合物的多孔金属 - 有机骨架,其中至少一种至少二齿的有机化合物是六元芳烃环A 其中一个或多个环碳可以被氮替代并且具有三个取代基X和任选的一个或多个选自R,NRR',OR,SR,F,Cl和Br的取代基,其中R,R'是 各自独立地为氢,可以任选被一个或多个氟原子取代的甲基或可任选被一个或多个氟原子取代的乙基,并且每个X独立地为C(-O)O C( - )O - , - (C(O)S) - , - (C(O) / SUP>或其质子化形式。 本发明还提供了一种制备该方法并提供了新的多孔金属 - 有机骨架的用途。