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    • 5. 发明授权
    • Pulverulent rubber powders comprising modified fillers, processes for their preparation and their use
    • 包含改性填料的粉末状橡胶粉末,其制备方法及其用途
    • US06329449B1
    • 2001-12-11
    • US09401850
    • 1999-09-22
    • Udo GorlReinhard StoberHartmut LauerUwe Ernst
    • Udo GorlReinhard StoberHartmut LauerUwe Ernst
    • C08J307
    • A61K31/18A61K31/64C07C311/58C07C335/42C08K5/5406C08L21/00
    • The invention relates to a process for the preparation of finely divided rubbers (rubber powders) by precipitation from aqueous mixtures, which comprise filler in the form of suspensions, water-soluble salts of a metal of groups IIa, IIb, IIIa and VIII of the periodic table of the elements arid a rubber latex (polymer latex), aqueous emulsions of a rubber or rubber solution, in which one or more organosilicon compound(s) containing at least one alkoxy group is or are dissolved or emulsified, optionally in the presence of a surface-active substance, in water, or the compounds mentioned are mixed directly, optionally with a surface-active substance, with an aqueous suspension of an oxidic or silicatic finely divided filler or a mixture of these fillers at a temperature of 10 to 60° C., preferably at room temperature, while stirring, the amount of this mixture envisaged for incoporation in the rubber, based on the filler content, in general being divided into two batches.
    • 本发明涉及一种通过从含水混合物中沉淀制备细碎橡胶(橡胶粉末)的方法,该方法包括悬浮液形式的填料,IIa,IIb,IIIa和VIII族金属的水溶性盐 元素周期表和橡胶胶乳(聚合物胶乳),橡胶或橡胶溶液的水性乳液,其中一种或多种含有至少一个烷氧基的有机硅化合物被溶解或乳化,任选地存在 表面活性物质在水中或所提及的化合物任选地与表面活性物质混合,与氧化或硅化细分散填料或这些填料的混合物的水悬浮液在10〜 60℃,优选在室温下,同时搅拌,基于填料含量,设想用于在橡胶中进行开孔的该混合物的量通常被分成两批。