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    • 4. 发明申请
    • HABIT MODIFIED CRYSTALS OF ZINC OXIDE
    • 氧化锌的HABIT改性晶体
    • WO2018019595A1
    • 2018-02-01
    • PCT/EP2017/067579
    • 2017-07-12
    • UNILEVER N.V.UNILEVER PLCCONOPCO, INC., D/B/A UNILEVER
    • DAS, SomnathPRAMANIK, Amitava
    • C01G9/02A01N25/34A01N59/00C09K11/08
    • Disclosed is habit modified crystals of zinc oxide comprising entrapped particles of protein, wherein said crystals are shaped like a disc and are in the form of spherical assemblies of average size 0.8 μm to 1.5 μm and where the thickness of each disc is 10 nm to 30 nm and average diameter is 200 nm to 500 nm wherein said protein is water-soluble and wherein said protein is at least one of sericin, bovine serum albumin, gelatin, egg-albumin, casein, zein, whey or lysozyme. Also disclosed is process of making habit modified crystals of zinc oxide comprising the steps of: (i) mixing aqueous solution of a water-soluble protein with aqueous solution of a non- hydrolysable water-soluble zinc salt wherein said protein is water-soluble and wherein said protein is at least one of sericin, bovine serum albumin, gelatin, egg- albumin, casein, zein, whey or lysozyme; (ii) adding a weak base thereto; (iii) heating the reaction mixture of step (ii) to attain a temperature of 60 to 90 °C; and, (iv) filtering the contents of step (iii), washing the residue with water and drying it to obtain said habit modified crystals of zinc oxide as the filtrate.
    • 公开了习性改变的氧化锌晶体,其包含截留的蛋白质颗粒,其中所述晶体成形为盘状并且为平均尺寸为0.8μm至1.5μm的球形组件的形式,并且其中厚度 的平均直径为200nm至500nm,其中所述蛋白质是水溶性的,并且其中所述蛋白质是丝胶蛋白,牛血清白蛋白,明胶,蛋清蛋白,酪蛋白,玉米醇溶蛋白, 乳清或溶菌酶。 还公开了制造习性改变的氧化锌晶体的方法,其包括以下步骤:(i)将水溶性蛋白质的水溶液与不可水解的水溶性锌盐的水溶液混合,其中所述蛋白质是水溶性的并且 其中所述蛋白质是丝胶蛋白,牛血清白蛋白,明胶,蛋清蛋白,酪蛋白,玉米醇溶蛋白,乳清或溶菌酶中的至少一种; (ii)向其添加弱碱; (iii)加热步骤(ii)的反应混合物以达到60至90℃的温度; (iv)过滤步骤(iii)的内容物,用水洗涤残余物并干燥,得到所述习性改变的氧化锌晶体作为滤液。
    • 5. 发明申请
    • SURFACE TREATMENT COMPOSITION CAPABLE OF IMPARTING UNDERWATER STAIN REPELLENCY
    • 表面处理组合物可用于产生水下污渍
    • WO2018019564A1
    • 2018-02-01
    • PCT/EP2017/067343
    • 2017-07-11
    • UNILEVER N.V.UNILEVER PLCCONOPCO, INC., D/B/A UNILEVER
    • DAS, SomnathVAIDYA, Ashish, Anant
    • C09D5/00
    • The invention relates to a surface treatment composition containing a reactive polymer represented by formula (I): (R 1 O) i (R 2 ) 3-i Si-R 3 -X-pol (I) wherein: R 1 and R 2 are each independently selected from hydrogen atom and optionally substituted C 1-20 alkyl; R 3 is selected from substituted and unsubstituted C 1-12 alkylenes; X is a linker group; pol is a residue of a hydrophilic polymer selected from polyethylene glycol, polypropylene glycol, polyvinyl alcohol, poly(vinylpyrrolidone), polysaccharides and copolymers thereof; i = 1, 2 or 3. The surface treatment composition can be used to impart underwater stain repellency to surfaces by treating such surfaces with the surface treatment composition. When the surface treatment composition of the present invention is used to treat a surface, e.g. teeth enamel, the silane coupling group of the reactive polymer reacts with reactive group on said surface, thereby imparting underwater stain repellency.
    • 本发明涉及含有由式(I)表示的反应性聚合物的表面处理组合物:(R 1 O)i(R 1) (I)其中:R 1和R 2独立地选自氢,C 1 -C 4烷基,C 1 -C 4烷基, 其各自独立地选自氢原子和任选取代的C 1-20 - 烷基; R 3选自取代和未取代的C 1-12亚烷基; X是连接基团; pol是选自聚乙二醇,聚丙二醇,聚乙烯醇,聚(乙烯吡咯烷酮),多糖及其共聚物的亲水性聚合物的残基; i = 1,2或3.通过用表面处理组合物处理这些表面,表面处理组合物可以用于赋予表面以水下抗污性。 当本发明的表面处理组合物用于处理表面时, 牙齿珐琅质,反应性聚合物的硅烷偶联基团与所述表面上的反应性基团反应,从而赋予水下抗污性。
    • 9. 发明申请
    • ADSORBENT COMPRISING LAYERED DOUBLE HYDROXIDE AND ACTIVATED CARBON
    • 包含分层的双氢氧化物和活性炭的吸附剂
    • WO2018046286A1
    • 2018-03-15
    • PCT/EP2017/071010
    • 2017-08-21
    • UNILEVER N.V.UNILEVER PLCCONOPCO, INC., D/B/A UNILEVER
    • PRAMANIK, AmitavaDAS, SomnathSARKAR, PriyankaAPPAVOO, Shanthi
    • B01J20/06B01J20/08B01J20/04B01J20/20B01J20/28B01J20/32B01J20/30
    • B01J20/06B01D2253/25B01D2257/306B01J20/041B01J20/08B01J20/20B01J20/28004B01J20/28064B01J20/3071B01J20/3204B01J20/3236
    • The present invention relates to a material that absorbs volatile compounds, in particular sulphurous compounds. It is found that an absorbent of high surface area suitable for highly volatile compounds can be obtained by growing nanoparticles of a layered double hydroxide (LDH) on the surface of powder activated carbon (PAC). Disclosed is a composite adsorbent comprising nanoparticles of a layered double hydroxide (LDH) and a powder activated carbon (PAC) of the general formula [M 2+ 1-x M 3+ x (OH) 2 ] q+ (X n- ) q/n .yH 2 O, in which, M 2+ = Ca 2+ , Mg 2+ , Mn 2+ , Fe 2+ , CO 2+ , Ni 2+ , Cu 2+ or Zn 2+ ; M 3+ = Al 3+ or Fe 3+ ; x = [M 3+ ]/ [M 3+ + M 2+ ]; q = x n = 1 to 4; and, y = number of water molecules present on the LDH; X = anions selected from halides, sulphates, nitrates, carbonates or anionic moiety from organic sources wherein said composite is obtainable by a hydrothermal process comprising, in sequence, the steps of: (a) contacting, and mixing, powder activated carbon with a water soluble salt of M 2+ and a water soluble salt of M 3+ ; (b) adding an alkali to the dispersion of step (a); (c) aging the dispersion of step (b) by heating it to 80 to 100 °C; (d) separating, by any means, the aqueous phase of the dispersion from the dispersed phase; and (e) washing said dispersed phase with water to remove excess alkali, to get the composite adsorbent, wherein amount of nanoparticles of said layered double hydroxide (LDH) is 10 to 30% by weight and wherein particle size of said powder activated carbon is 50 μm to 500 μm.
    • 本发明涉及吸收挥发性化合物,特别是含硫化合物的材料。 发现通过在粉末活性炭(PAC)的表面上生长层状双氢氧化物(LDH)的纳米颗粒可以获得适用于高挥发性化合物的高表面积吸收剂。 本发明公开了一种复合吸附剂,其包含层状双氢氧化物(LDH)和粉末活性炭(PAC)的通式为[M + 2 + 1-x M] (OH)2] q +(X n - 其中,M 2 + 2 = Ca 2 + 2,Mg 2→2, Mn + 2 +,Fe +2 +,CO + 2 +,Ni + 2 +, Cu 2 +或Zn + 2 +; M + 3 + = Al 3 +或Fe 3+ +; x = [M + 3 +] / [M + 3 + M + 2 +]; q = x n = 1至4; y = LDH上存在的水分子的数量; X =选自来自有机来源的卤化物,硫酸盐,硝酸盐,碳酸盐或阴离子部分的阴离子,其中所述组合物可通过水热法获得,所述水热法依次包括以下步骤:(a)使粉末活性炭与水接触并混合 M 2 +的水溶性盐和M 3 +的水溶性盐; (b)向步骤(a)的分散体中加入碱; (c)通过将步骤(b)的分散体加热至80至100℃使其老化; (d)通过任何方式将分散体的水相从分散相中分离出来; (e)用水洗涤所述分散相以除去多余的碱,得到所述复合吸附剂,其中所述层状双氢氧化物(LDH)的纳米颗粒的量为10-30重量%,并且其中所述粉末状活性炭的粒径为 50微米至500微米。
    • 10. 发明申请
    • SURFACE TREATMENT COMPOSITION CAPABLE OF IMPARTING UNDERWATER SUPEROLEOPHOBICITY
    • 表面处理组合物能够引起水下过度血小板减少
    • WO2018019519A1
    • 2018-02-01
    • PCT/EP2017/066478
    • 2017-07-03
    • UNILEVER N.V.UNILEVER PLCCONOPCO, INC., D/B/A UNILEVER
    • DAS, SomnathMAHENDRAN, DivyaVAIDYA, Ashish,Anant
    • C09D5/16
    • The invention relates to a surface treatment composition containing functionalized micro/nanoparticles, said functionalized micro/nanoparticles comprising a core particle having a diameter in the range of 50-5,000 nm, said core particle carrying a plurality of covalently bound silane polymer residues on the surfacewherein the hydrophilic polymer residue is residue of a polymer selected from polyethylene glycol, polypropylene glycol, polyvinyl alcohol, polyacrylamide, polyoxazoline, polyethyleneimine, acrylic polymers, poly(vinylpyrrolidone), polysaccharides, chitosan and copolymers thereof. This surface treatment composition can be used to impart underwater superoleophobicity to surfaces by treating such surfaces with the surface treatment composition. The invention also relates to the use of the aforementioned surface treatment composition for imparting underwater superoleophobicity to a surface, for imparting stain repellency to a surface and/or for imparting antimicrobial properties to a surface, said use comprising treating the surface with the treatment composition.
    • 本发明涉及含有官能化微米/纳米颗粒的表面处理组合物,所述官能化微米/纳米颗粒包含直径在50-5,000nm范围内的核心颗粒,所述核心颗粒携带多个 其中亲水性聚合物残基是选自聚乙二醇,聚丙二醇,聚乙烯醇,聚丙烯酰胺,聚恶唑啉,聚乙烯亚胺,丙烯酸聚合物,聚(乙烯吡咯烷酮),多糖,壳聚糖及其共聚物的聚合物的残基。 该表面处理组合物可用于通过用表面处理组合物处理这些表面而将水下超疏油性赋予表面。 本发明还涉及上述表面处理组合物用于赋予表面水下超疏油性,赋予表面抗污性和/或赋予表面抗微生物性能的用途,所述用途包括用处理组合物处理表面。