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    • 4. 发明公开
    • Aqueous detergent compositions and methods of forming them
    • WässrigeReinigungsmittel und Verfahren zu deren Herstellung。
    • EP0328176A2
    • 1989-08-16
    • EP89200162.9
    • 1989-01-26
    • UNILEVER N.V.UNILEVER PLC
    • Machin, DavidNaik, Appaya RaghunathBuytenhek, Cornelis Johannesvan de Pas, Johannes Cornelis
    • C11D17/00
    • C11D3/14C11D17/0026
    • A structured aqueous detergent composition containing detergent-active material in the form of at least one detergent-active component and at least one electrolyte and having the following phases:

      (a) an isotropic aqueous solution forming a continuous phase;
      (b) distributed and suspended in said solution (a) discrete units of one or more non-network-­forming phases, each selected from the following:

      (i) solid particles containing detergent-active material,
      (ii) lyotropic liquid crystals containing detergent-active material; and
      (iii) non-encapsulated liquid droplets containing detergent-active material,

      (c) one or more suspending phases which cause the composition to be structured so as to suspend the non-network-forming phase (b);
      said non-network-forming phase (b) having a higher concentration by weight of detergent-­active material than said aqueous solution (a).
    • 一种结构化的含水洗涤剂组合物,其含有至少一种洗涤剂 - 活性组分和至少一种电解质形式的洗涤剂 - 活性材料,并具有以下相:(a)形成连续相的各向同性水溶液; (b)分布和悬浮在所述溶液(a)中的一个或多个非网络形成相的离散单元,每个离子单元选自以下:(i)含有洗涤剂活性物质的固体颗粒,(ii)含有洗涤剂的溶致液晶 活性物质 和(iii)含有洗涤剂活性物质的未包封液滴,(c)一种或多种使所述组合物构成以悬浮非网络形成相(b)的悬浮相; 所述非网络形成相(b)具有比所述水溶液(a)更高的洗涤剂 - 活性物质的浓度。
    • 6. 发明公开
    • Liquid detergents
    • FlüssigeWaschmittel。
    • EP0359308A2
    • 1990-03-21
    • EP89202220.3
    • 1989-09-01
    • UNILEVER N.V.UNILEVER PLC
    • Machin, Davidvan de Pas, Johannes Cornelis
    • C11D17/00
    • C11D17/0026
    • A concentrated structured aqueous liquid detergent composition comprising detergent active material and an aqueous medium Containing dissolved electrolyte material, characterised by at least any two of the following features:-

      (i) the electrolyte material comprises a relatively insoluble electrolyte and a co-electrolyte which promotes the solubility of said relatively insoluble electrolyte;
      (ii) the surfactant material comprises a stabilising surfactant which has a salting-out resistance (as hereinbefore defined) of at least 4.0; and
      (iii) the viscosity of the composition is no greater than 2.5 Pas at a shear rate of 21s⁻¹ by virtue of

      a) the composition being internally structured and a portion of the surfactant material being contained in an non-network-forming phase; and/or the composition comprising a viscosity-­reducing polymer; or
      b) the composition is externally structured and contains sufficient hydrotrope to inhibit the surfactant material from forming sufficient of an internal structure to be capable of suspending solid particles in the absence of the external structure;

      provided that when the composition is formulated with feature (ii) and feature (iii) a) and contains a non-network-forming phase, then the composition also comprises a viscosity reducing polymer and/or is characterised by feature (i).
    • 包含洗涤剂活性物质和含水介质的浓缩结构化水性液体洗涤剂组合物,其包含溶解的电解质材料,其特征在于至少两个以下特征: - (i)所述电解质材料包含相对不溶解的电解质和促进 所述相对不溶性电解质的溶解度; (ii)表面活性剂材料包含具有至少4.0的耐盐析性(如上所述)的稳定表面活性剂; 和(iii)组合物的粘度在21s -1的剪切速率下不大于2.5Pa·s,这是由于a)组合物是内部结构的,并且表面活性剂材料的一部分包含在非水溶液中, 网络形成阶段; 和/或包含降粘聚合物的组合物; 或b)组合物是外部结构的并且含有足够的水溶助长剂以抑制表面活性剂材料形成足够的内部结构,以便在没有外部结构的情况下能够悬浮固体颗粒; 条件是当组合物用特征(ii)和特征(iii)a)配制并且包含非网状形成相时,组合物还包含降粘聚合物和/或以特征(i)为特征。
    • 10. 发明公开
    • Detergent compositions
    • 洗涤剂组合物
    • EP0153857A2
    • 1985-09-04
    • EP85301297.9
    • 1985-02-26
    • UNILEVER N.V.
    • Leng, Francis JohnMachin, DavidReed, David AlanErkey, Özalp
    • C11D17/00
    • C11D17/0026C11D17/003
    • Detergent compositions comprising stable transparent, translucent or opaque hexagonal phase gels contain an anionic or cationic surfactant which is "secondary", i.e. its polar head group is either positioned non-terminally on a hydrophobic chain or carries two or more hydrophobic chains; optionally a further surfactant which is nonionic or non-"secondary"; a material (the "additive") capable of forcing the surfactant system into hexagonal phase; optionally builder, perfume, colouring or other adjuncts; and water. A solid such as abrasive or insoluble builder may be suspended in the gel. Preferred gels of the invention contain alkylbenzene sulphonate or dialkyl sulphosuccinate as the "secondary" surfactant and urea as the "additive". The compositions may be used inter alia for manual dishwashing.
    • 包含稳定的透明,半透明或不透明六方相凝胶的洗涤剂组合物含有“二级”的阴离子或阳离子表面活性剂,即其极性头部基团或者非末端地位于疏水链上或者携带两个或更多个疏水链; 任选的非离子或非“次要”的另外的表面活性剂; 能够使表面活性剂体系变为六方相的材料(“添加剂”); 任选的助洗剂,香料,着色剂或其他助剂; 和水。 固体如研磨剂或不溶性助洗剂可以悬浮在凝胶中。 本发明优选的凝胶包含烷基苯磺酸盐或二烷基磺基琥珀酸盐作为“次要”表面活性剂和尿素作为“添加剂”。 该组合物尤其可用于手动洗碗。