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    • 2. 发明授权
    • Process for producing amorphous alloy material
    • 生产非晶合金材料的方法
    • US5296059A
    • 1994-03-22
    • US943703
    • 1992-09-11
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • C22C45/00B22F3/00C22C1/00C22C45/08C22F1/00C22F1/04C22F1/06C22F1/18
    • C22F1/186B22F3/006C22C1/00C22F1/00C22F1/04C22F1/06C22F1/18C21D2201/03
    • A process for producing an amorphous alloy material characterized by imparting ductility to an amorphous alloy having a supercooled liquid region by giving a prescribed amount of strain at a prescribed strain rate to the alloy in the glass transition temperature region of the alloy. The amorphous alloy may be in the form of spherical or irregular-shaped powders or thin ribbons or in the form of primary consolidated shapes thereof or an amorphous alloy casting. The amount of strain and strain rate are preferably 50% or greater and 2.times.10.sup.-2 /sec or higher, respectively, and the worked amorphous alloy material is preferably allowed to cool in a furnace or spontaneously. Suitable examples of the amorphous alloy to be employed include Al-TM-Ln, Mg-TM-Ln, Zr-TM-Al and Hf-TM-Al alloys, wherein TM is a transition metal element and Ln is a rare earth metal element. The thus obtained amorphous alloy is greatly improved in the prevention of embrittlement in hot working peculiar to the alloy.
    • 一种非晶态合金材料的制造方法,其特征在于,在合金的玻璃化转变温度区域中,通过以规定的应变速率向合金赋予规定量的应变率,赋予具有过冷液体区域的非晶质合金的延展性。 非晶合金可以是球形或不规则形状的粉末或薄带的形式,或者是其主要固结形状或非晶态合金铸件的形式。 应变量和应变速率分别优选为50%以上且2×10 -2 /秒以上,加工后的非晶态合金材料优选在炉内自发冷却。 所使用的非晶合金的合适实例包括Al-TM-Ln,Mg-TM-Ln,Zr-TM-Al和Hf-TM-Al合金,其中TM是过渡金属元素,Ln是稀土金属元素 。 由此获得的非晶态合金在防止合金特有的热加工中脆化方面大大提高。
    • 4. 发明授权
    • Thin aluminum-based alloy foil and wire and a process for producing same
    • 薄铝基合金箔和线及其制造方法
    • US5306363A
    • 1994-04-26
    • US574654
    • 1990-08-20
    • Tsuyoshi MasumotoAkihisa InoueHitoshi YamaguchiNoriaki MatsumotoKazuhiko Kita
    • Tsuyoshi MasumotoAkihisa InoueHitoshi YamaguchiNoriaki MatsumotoKazuhiko Kita
    • B21C1/00C21D8/02C21D8/06C22C45/08C22F1/00
    • C22C45/08
    • An aluminum-based alloy foil or thin aluminum-based alloy wire is produced from an amorphous material made by a quenching and solidifying process and having a composition represented by the general formula:Al.sub.a M.sub.b X.sub.cwherein M is one or more elements selected from a group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si; X is one or more elements selected from a group consisting of Y, Nb, Hf, Ta, La, Ce, Sm, Nd and Mm (misch metal); and a, b, and c are atomic percentages falling within the following range:50.ltoreq.a.ltoreq.950.5.ltoreq.b.ltoreq.35 and0.5.ltoreq.c.ltoreq.25Such foil or wire has a smooth surface and a very small and uniform foil thickness or wire diameter, contains at least 50% by volume of an amorphous phase, and has excellent strength and resistance to corrosion. The foil thickness and wire diameter are reduced in a rolling or drawing process at an elevated temperature over a short time period.
    • 铝基合金箔或薄铝基合金线由淬火和固化方法制成的无定形材料制成,具有由以下通式表示的组成:AlaMbXc,其中M是选自以下的一种或多种元素: V,Cr,Mn,Fe,Co,Ni,Cu,Zr,Ti,Mo,W,Ca,Li,Mg和Si; X是选自Y,Nb,Hf,Ta,La,Ce,Sm,Nd和Mm(混合稀土金属)中的一种或多种元素; 和a,b和c是原子百分比在以下范围内:50 <= a <= 95 0.5 <= b <= 35和0.5 <= c <= 25这种箔或线具有光滑的表面和非常小的 箔厚度均匀,线径均匀,含有至少50体积%的非晶相,具有优异的强度和耐腐蚀性。 箔片厚度和线径在轧制或拉伸过程中在较短的时间内在升高的温度下降低。
    • 6. 发明授权
    • Aluminum alloy powders for coating materials, and coating materials
containing the alloy powders
    • 用于涂料的铝合金粉末和含有合金粉末的涂料
    • US5198042A
    • 1993-03-30
    • US791572
    • 1991-11-12
    • Tsuyoshi MasumotoAkihisa InoueKazuhiko KitaYoshio HarakawaMasahiro Oguchi
    • Tsuyoshi MasumotoAkihisa InoueKazuhiko KitaYoshio HarakawaMasahiro Oguchi
    • B22F1/00B22F9/00B22F9/10C09C1/62C09C1/64C22C1/04C22C45/08C23C4/04C23C4/12
    • C22C1/0416B22F9/008B22F9/10C09C1/62C09C1/622C23C4/04C23C4/123B22F2009/084C01P2002/02C01P2002/70C01P2004/03C01P2004/54C01P2004/61C01P2004/62C01P2006/11C01P2006/22C01P2006/60C01P2006/90Y10T428/256
    • An aluminum alloy powder for coating materials and a coating material containing the aluminum alloy powder. The aluminum alloy powder comprises an amorphous aluminum alloy consisting essentially of from 83 to 91% of Al, from 0.5 to 5% of Ca and from 8 to 12% of Ni, all in atom %, and comprising a leaf-shaped particle having a thickness of 0.3 to 3 .mu.m, a minor axis of from 10 to 150 .mu.m, a ratio of the minor axis to a major axis of from 1 to 3, and an aspect ratio which is the ratio of the minor axis to the thickness of from 3 to 100, wherein the aluminum alloy powder is contained in an amount of from 5 to 25 parts by weight based on 100 parts by weight of the total weight of (i) the coating material resin component and (ii) aluminum alloy powder, and the coating material resin component is selected from the group consisting of a water-based synthetic latex and a water-soluble resin. The aluminum alloy powder has a superior dispersibility in a resin in a coating material. When added to a coating material and then coated, the aluminum alloy powder can bring about leafing in a desirable state, so that the coating surface can be effectively covered with the powder. The aluminum alloy powder can impart better hiding power and reflecting properties, even when added in a smaller quantity than conventional powders. Since the aluminum alloy powder is comprised of an amorphous alloy, it does not cause deterioration of reflecting properties, even when used in coating materials containing water-soluble solvents.
    • 用于涂料的铝合金粉末和含有铝合金粉末的涂料。 所述铝合金粉末包含非晶态铝合金,其基本上由Al:83〜91%,0.5〜5%的Ca和8〜12%的Ni组成,全部为原子%,并且包含具有 厚度为0.3〜3μm,短轴为10〜150μm,短轴与长轴的比例为1〜3,纵轴比与纵轴的长径比 为3〜100,其中,相对于(i)涂料树脂成分和(ii)铝合金粉末的总重量的100重量份,铝合金粉末的含量为5〜25重量份 涂料树脂成分选自水性合成胶乳和水溶性树脂。 铝合金粉末在涂料中的树脂中具有优异的分散性。 当添加到涂料中然后涂覆时,铝合金粉末可以在期望的状态下带来漂浮,从而可以用粉末有效地覆盖涂层表面。 铝合金粉末即使加入比常规粉末更少的量,也能赋予更好的遮盖力和反射性能。 由于铝合金粉末是由非晶合金组成的,所以即使在含有水溶性溶剂的涂料中使用也不会引起反射性能的劣化。