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1. 发明申请

US20130084500A1 POSITIVE ELECTRODE MATERIAL 有权
标题翻译：正极电极材料
公开(公告)号：US20130084500A1
公开(公告)日：2013-04-04
申请号：US13606654
申请日：2012-09-07
申请人： Kazuki Takimoto , Hideo Yanagita , Tsutomu Kikuchi
发明人： Kazuki Takimoto , Hideo Yanagita , Tsutomu Kikuchi
IPC分类号： H01M4/485 , H01M4/505 , H01M4/525
CPC分类号： H01M4/5825 , H01M4/625 , H01M10/0525 , H01M2004/021 , Y02T10/7011
摘要： A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 μm to 2.6 μm and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.
摘要翻译：正极材料包括平均一次粒径为0.3μm至2.6μm，微晶尺寸为24nm至33nm的磷酸钒锂颗粒。相对于总的磷酸钒锂粒子，以0.5质量％〜2.4质量％的范围的导电性碳覆盖磷酸钒锂颗粒。

2. 发明申请

US20130214462A1 PROCESS FOR PRODUCING LITHIUM VANADIUM PHOSPHATE-CARBON COMPOSITE 有权
标题翻译：用于生产磷酸氢钙 - 碳复合材料的方法
公开(公告)号：US20130214462A1
公开(公告)日：2013-08-22
申请号：US13823612
申请日：2011-09-22
申请人： Tsutomu Kikuchi , Kazuki Takimoto , Hideo Yanagita
发明人： Tsutomu Kikuchi , Kazuki Takimoto , Hideo Yanagita
IPC分类号： H01M4/1397
CPC分类号： H01M4/1397 , C01B25/45 , H01M4/04 , H01M4/13 , H01M4/136 , H01M4/5825 , H01M4/625 , H01M10/0525 , Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要： A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.
摘要翻译：一种制备锂钒磷酸盐 - 碳复合材料的方法包括第一步骤，其包括在水性溶剂中将锂源，四价或五价钒化合物，磷源和通过热解产生碳的导电碳材料源混合至制备原料混合物，第二步骤包括加热原料混合物进行沉淀反应以获得包含沉淀物的反应混合物，第三步骤包括使用介质对含有沉淀物的反应混合物进行湿磨研磨研磨以获得包括研磨颗粒的浆料，第四步骤包括喷雾干燥包含研磨颗粒的浆料以获得反应前体，第五步包括在600至1300℃下煅烧反应前体，惰性气体气氛或还原气氛。通过该方法生产的锂钒磷酸铁复合物可以提供当用作阴极活性材料时具有优异的电池性能（例如，高放电容量）的锂二次电池。

3. 发明申请

US20120295163A1 ELECTRIC STORAGE DEVICE AND POSITIVE ELECTRODE 审中-公开
标题翻译：电存器件和正极电极
公开(公告)号：US20120295163A1
公开(公告)日：2012-11-22
申请号：US13475707
申请日：2012-05-18
申请人： Hideo Yanagita , Kazuki Takimoto , Takahito Sakuraba , Ken Baba , Yasuyuki Kiya , Tsutomu Kikuchi
发明人： Hideo Yanagita , Kazuki Takimoto , Takahito Sakuraba , Ken Baba , Yasuyuki Kiya , Tsutomu Kikuchi
IPC分类号： H01B1/08 , H01M4/525
CPC分类号： H01M4/5825 , H01M4/131 , H01M4/136 , H01M4/1391 , H01M4/1397 , H01M4/485 , H01M4/502 , H01M4/505 , H01M4/523 , H01M4/525 , H01M4/625 , H01M2004/028
摘要： An electric storage device is provided with a positive electrode having a positive-electrode mixture layer including a positive-electrode active material. The positive-electrode active material includes a lithium-vanadium-phosphate from 8% to 70% by mass and a lithium-nickel complex oxide from 20% to 82% by mass. A coating concentration of the positive-electrode mixture layer is from 4 mg/cm2 to 20 mg/cm2. The lithium-nickel complex oxide includes a nickel element from 0.3 mol to 0.8 mol with respect to a lithium element of 1 mol.
摘要翻译：蓄电装置设置有具有包括正极活性物质的正极混合层的正极。正极活性物质包含8〜70质量％的锂 - 磷酸钒，20〜82质量％的锂镍复合氧化物。正极混合层的涂布浓度为4mg / cm 2〜20mg / cm 2。锂镍复合氧化物包括相对于1摩尔锂元素为0.3摩尔至0.8摩尔的镍元素。

4. 发明授权

US09437866B2 Process for producing lithium vanadium phosphate-carbon composite 有权
标题翻译：生产锂钒磷酸盐 - 碳复合材料的方法
公开(公告)号：US09437866B2
公开(公告)日：2016-09-06
申请号：US13823612
申请日：2011-09-22
申请人： Tsutomu Kikuchi , Kazuki Takimoto , Hideo Yanagita
发明人： Tsutomu Kikuchi , Kazuki Takimoto , Hideo Yanagita
IPC分类号： H01M4/1397 , H01M4/13 , H01M4/58 , C01B25/45 , H01M4/04 , H01M4/136 , H01M10/0525 , H01M4/62
CPC分类号： H01M4/1397 , C01B25/45 , H01M4/04 , H01M4/13 , H01M4/136 , H01M4/5825 , H01M4/625 , H01M10/0525 , Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要： A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.
摘要翻译：一种制备锂钒磷酸盐 - 碳复合材料的方法包括第一步骤，其包括在水性溶剂中将锂源，四价或五价钒化合物，磷源和通过热解产生碳的导电碳材料源混合至制备原料混合物，第二步骤包括加热原料混合物进行沉淀反应以获得包含沉淀物的反应混合物，第三步骤包括使用介质对含有沉淀物的反应混合物进行湿磨研磨研磨以获得包括研磨颗粒的浆料，第四步骤包括喷雾干燥包含研磨颗粒的浆料以获得反应前体，第五步包括在600至1300℃下煅烧反应前体，惰性气体气氛或还原气氛。通过该方法生产的锂钒磷酸铁复合物可以提供当用作阴极活性材料时具有优异的电池性能（例如，高放电容量）的锂二次电池。

5. 发明授权

US08802293B2 Positive electrode material 有权
标题翻译：正极材料
公开(公告)号：US08802293B2
公开(公告)日：2014-08-12
申请号：US13606654
申请日：2012-09-07
申请人： Kazuki Takimoto , Hideo Yanagita , Tsutomu Kikuchi
发明人： Kazuki Takimoto , Hideo Yanagita , Tsutomu Kikuchi
IPC分类号： H01M4/00
CPC分类号： H01M4/5825 , H01M4/625 , H01M10/0525 , H01M2004/021 , Y02T10/7011
摘要： A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 μm to 2.6 μm and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.
摘要翻译：正极材料包括平均一次粒径为0.3μm至2.6μm，微晶尺寸为24nm至33nm的磷酸钒锂颗粒。相对于总的磷酸钒锂粒子，以0.5质量％〜2.4质量％的范围的导电性碳覆盖磷酸钒锂颗粒。

6. 发明申请

US20120213920A1 POSITIVE ELECTRODE ACTIVE MATERIAL, LITHIUM ION ELECTRIC STORAGE DEVICE USING THE SAME, AND MANUFACTURING METHOD THEREOF 审中-公开
标题翻译：正电极活性材料，利用其的锂离子电储存装置及其制造方法
公开(公告)号：US20120213920A1
公开(公告)日：2012-08-23
申请号：US13371694
申请日：2012-02-13
申请人： Hideo Yanagita , Kazuki Takimoto
发明人： Hideo Yanagita , Kazuki Takimoto
IPC分类号： H01M4/131 , B05D5/12
CPC分类号： H01M4/0404 , H01G11/50 , H01M4/131 , H01M4/1391 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/621 , H01M10/0525 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： Provided are a positive electrode active material, a lithium ion electric storage device using the same, and a manufacturing method thereof. The positive electrode active material contains (1) lithium nickel cobalt manganese oxide, and at least one type of a lithium ion acceptance capacity adjustment compound selected from (2a) lithium vanadium composite oxide, vanadium oxide, lithium vanadium phosphate, and lithium vanadium fluorophosphate and (2b) Nb2O5, TiO2, Li3/4Ti5/3O4, WO2, MoO2, and Fe2O3. The lithium ion electric storage device contains this positive electrode active material.
摘要翻译：提供一种正极活性物质，使用该正极活性物质的锂离子蓄电装置及其制造方法。正极活性物质含有（1）锂镍钴锰氧化物和选自（2a）锂钒复合氧化物，氧化钒，磷酸钒锂和氟化钒锂的至少一种锂离子接受能力调整化合物，（2b）Nb2O5，TiO2，Li3 / 4Ti5 / 3O4，WO2，MoO2和Fe2O3。锂离子蓄电装置含有该正极活性物质。

7. 发明申请

US20130084499A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非水电解质二次电池
公开(公告)号：US20130084499A1
公开(公告)日：2013-04-04
申请号：US13605707
申请日：2012-09-06
申请人： Hideo Yanagita , Kazuki Takimoto
发明人： Hideo Yanagita , Kazuki Takimoto
IPC分类号： H01M4/525 , H01M4/54
CPC分类号： H01M10/0525 , H01M4/364 , H01M4/525 , H01M4/5825 , H01M2010/4292 , H01M2220/20 , Y02E60/122 , Y02T10/7011
摘要： In a non-aqueous electrolyte secondary battery, a positive electrode active material includes a carbon-coated lithium vanadium phosphate and a lithium nickel composite oxide. A negative electrode active material includes a carbon-based active material capable of intercalating and deintercalating lithium ions. When a first charge capacity of a negative electrode per unit area is “x” (mAh/cm2), and a first charge capacity of a positive electrode per unit area is “y” (mAh/cm2), a relation of “x” and “y” satisfies 0.6≦y/x≦0.92.
摘要翻译：在非水电解质二次电池中，正极活性物质包括碳涂覆的磷酸钒锂和锂镍复合氧化物。负极活性物质包括能够嵌入和脱嵌锂离子的碳系活性物质。当单位面积的负极的第一充电容量为x（mAh / cm 2），并且每单位面积的正极的第一充电容量为y（mAh / cm 2）时，x和y的关系满足0.6＆nlE; y / x＆nlE; 0.92。

8. 发明授权

US11909031B2 Film electrode, resin layer forming ink, inorganic layer forming ink, and electrode printing apparatus 有权
公开(公告)号：US11909031B2
公开(公告)日：2024-02-20
申请号：US18060045
申请日：2022-11-30
申请人： Masahiro Masuzawa , Toru Ushirogochi , Hideo Yanagita , Yuu Zama , Aya Yoshida , Shigeo Takeuchi , Anna Hirowatari , Okitoshi Kimura , Kohji Matsuoka , Keigo Takauji , Miku Ohkimoto
发明人： Masahiro Masuzawa , Toru Ushirogochi , Hideo Yanagita , Yuu Zama , Aya Yoshida , Shigeo Takeuchi , Anna Hirowatari , Okitoshi Kimura , Kohji Matsuoka , Keigo Takauji , Miku Ohkimoto
IPC分类号： H01M4/139 , H01M4/04 , H01M4/36 , H01M4/62 , H01M10/0525 , H01M10/0585
CPC分类号： H01M4/139 , H01M4/0404 , H01M4/0419 , H01M4/366 , H01M4/622 , H01M10/0525 , H01M4/0414 , H01M4/621 , H01M10/0585 , H01M2200/00 , Y02E60/10
摘要： A disclosed film electrode includes an electrode base, and an active material layer formed on the electrode base, and a resin layer adhering to at least one of a peripheral portion of the active material layer and a surface of the active material layer in a direction extending along a plane of the electrode base.

9. 发明授权

US10090554B2 Non-aqueous electrolyte storage element 有权
公开(公告)号：US10090554B2
公开(公告)日：2018-10-02
申请号：US14942379
申请日：2015-11-16
申请人： Hideo Yanagita , Satoshi Nakajima
发明人： Hideo Yanagita , Satoshi Nakajima
IPC分类号： H01M6/04 , H01M10/052 , H01M4/133 , H01M4/583 , H01M4/587 , H01M10/0525 , H01M10/0566 , H01M4/485 , H01M10/0568 , H01M4/02 , H01M10/42
摘要： Non-aqueous electrolyte storage element including; positive electrode including positive electrode material layer, which contains positive electrode active material capable of reversibly accumulating and releasing anions; negative electrode including negative electrode material layer, which contains negative electrode active material capable of reversibly accumulating and releasing cations; separator disposed between the positive electrode and the negative electrode; and non-aqueous electrolyte containing electrolyte salt, the non-aqueous electrolyte storage element satisfying formulae: 0.5≤[(V1+V2+V3)/V4]≤0.61; and 0.14≤P1/P2≤0.84, where V1 is volume of pores of the positive electrode material layer per unit area of the positive electrode, V2 is volume of pores of the negative electrode material layer per unit area of the negative electrode, V3 is volume of pores per unit area of the separator, and V4 is total volume of the non-aqueous electrolyte storage element, and P1 is porosity of the positive electrode material layer, and P2 is porosity of the separator.

10. 发明申请

US20100221587A1 WOUND-TYPE ELECTRIC STORAGE DEVICE 有权
标题翻译：绕线式电动储存装置
公开(公告)号：US20100221587A1
公开(公告)日：2010-09-02
申请号：US12708312
申请日：2010-02-18
申请人： Hideo Yanagita , Kunio Nakazato
发明人： Hideo Yanagita , Kunio Nakazato
IPC分类号： H01M6/10
CPC分类号： H01M10/0525 , H01G9/016 , H01G9/058 , H01G9/155 , H01G11/06 , H01G11/12 , H01G11/50 , H01G11/62 , H01G11/70 , H01M10/0413 , H01M10/0431 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A positive electrode sheet including a positive electrode mixture layer formed on one surface is provided at one of the outermost layers of an electrode sheet group, while a positive electrode sheet including a positive electrode mixture layer formed at one surface is provided at the other outermost layer of the electrode sheet group. A negative electrode sheet including negative electrode mixture layers formed on both surfaces is provided between the positive electrode sheets. A lithium electrode sheet including metal lithium foils formed on both surfaces is overlapped onto the electrode sheet group formed by stacking the three sheets. When a wound-type electric storage device is produced, the electrode sheet group is wound together with the lithium electrode sheet.
摘要翻译：在一个电极片组的最外层的一个上设置包括在一个表面上形成的正极合剂层的正极片，而在另一个最外层设置包括在一个表面形成的正极混合层的正极片的电极片组。在正极片之间设置包括在两面形成的负极混合层的负极片。将形成在两面的金属锂箔的锂电极片重叠在通过堆叠三片而形成的电极片组上。当制造卷绕型蓄电装置时，电极片组与锂电极片一起卷绕。

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