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    • 2. 发明专利
    • Compound oxide and method for producing the same, and exhaust gas purifying catalyst
    • 化合物及其制造方法,以及排气净化催化剂
    • JP2013215651A
    • 2013-10-24
    • JP2012086825
    • 2012-04-05
    • Toyota Motor Corpトヨタ自動車株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • KUMAGAI NAOKIMIURA MASAHIDEHONMA YUJIROTANABE TOSHITAKAMORIKAWA AKIRAYAMAMURA YOSHIE
    • B01J23/63B01D53/94B01J37/04F01N3/10
    • PROBLEM TO BE SOLVED: To provide a compound oxide in which a pyrochlore phase is stabilized by arranging a diffusion barrier around the pyrochlore phase and which is excellent in an oxygen storage capacity and is used for an exhaust gas purifying catalyst, and to provide an exhaust gas purifying catalyst including the compound oxide, and further, a method for producing the compound oxide.SOLUTION: A compound oxide is composed of an MgAlO-CeO-ZrOternary system compound oxide, and has a pyrochlore phase in which Ce and Zr are regularly arrayed. A method for producing the compound oxide includes: a step of adding a precipitant to a solution containing a cerium compound and a zirconium compound to form a first coprecipitate, firing it, and obtaining a first fired material; a step of adding a precipitant to a solution containing a magnesium compound and an aluminum compound to form a second coprecipitate, firing it, and obtaining a second fired material; and a step of producing the compound oxide which is composed of the MgAlO-CeO-ZrOternary system compound oxide, and has the pyrochlore phase in which Ce and Zr are regularly arrayed, by mixing, heating and reducing the first and second fired materials.
    • 要解决的问题:为了提供通过在烧绿石相周围设置扩散阻挡层来稳定烧绿石相的复合氧化物,其具有优异的储氧能力并且用于排气净化催化剂,并且提供排气 包括复合氧化物的气体净化催化剂,以及复合氧化物的制造方法。复合氧化物由MgAlO-CeO-Zr系复合氧化物构成,具有烧绿石相,其中Ce和Zr规则排列 。 复合氧化物的制造方法包括:将沉淀剂添加到含有铈化合物和锆化合物的溶液中,形成第一共沉淀物,烧成,得到第一烧成物的工序; 向含有镁化合物和铝化合物的溶液中添加沉淀剂以形成第二共沉淀物,烧制,得到第二烧成物的工序; 以及通过混合,加热和还原第一和第二烧制材料,制备由MgAlO-CeO-Zr复合氧化物组成的复合氧化物并具有规则排列Ce和Zr的烧绿石相的步骤。
    • 4. 发明专利
    • Method for producing exhaust cleaning catalyst
    • 生产排气清洁催化剂的方法
    • JP2011143339A
    • 2011-07-28
    • JP2010005635
    • 2010-01-14
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • SATO KIMITOSHIYAMAMURA YOSHIEMORIKAWA AKIRASUDA AKIHIKONAGAO SATOSHIHIRATA HIROTO
    • B01J37/02B01D53/94B01J23/63F01N3/10
    • PROBLEM TO BE SOLVED: To provide a method for producing an exhaust cleaning catalyst wherein fine particles of noble metal are disposed in a state of being extensively dispersed throughout a support made from a metallic compound or in a state of being extensively dispersed in controlled sites present in the support made from a metallic compound. SOLUTION: The method for producing an exhaust cleaning catalyst is characterized by including a mixing process of mixing either one of a colloidal solution of a metallic compound selected from a colloidal solution (M1) comprising fine particles of a metallic compound and a polyalkyleneimine of a specific molecular weight with the fine particles of the metallic compound dispersed in the colloidal solution having specific particle diameters and a specific particle size distribution, and a colloidal solution (M2) comprising fine particles of the metallic compound and a polymeric dispersant other than polyalkyleneimines with the fine particles of the metallic compound dispersed therein having specific diameters and a specific particle size distribution, or a suspension of the metallic compound prepared by adjusting pH of the colloidal solution (M1) or (M2) of the metallic compound to desorb the polyalkyleneimine or the polymeric dispersant adsorbed by the fine particles of the metallic compound present in the colloidal solution (M1) or (M2), homogeneously with a colloidal solution of noble metal comprising fine particles of noble metal dispersed therein having specific particle diameters; and a heating process of subjecting the mixture prepared by the mixing process to a heat treatment. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决问题的方法:提供一种排气净化催化剂的制造方法,其中贵金属的细颗粒被布置在广泛分散在由金属化合物制成的载体上的状态下,或者以广泛分散的状态 存在于由金属化合物制成的载体中的受控部位。 解决方案:废气净化催化剂的制造方法的特征在于,包括将从金属化合物的微粒的胶体溶液(M1)中选择的金属化合物的胶体溶液和聚亚烷基亚胺 具有分散在具有特定粒径和比粒径分布的胶体溶液中的金属化合物的细颗粒的特定分子量,以及包含金属化合物的微粒和聚亚烷基亚胺以外的聚合物分散体的胶体溶液(M2) 其中分散有特定直径和比粒度分布的金属化合物的细颗粒或通过调节金属化合物的胶体溶液(M1)或(M2)的pH来制备的金属化合物的悬浮液,以将聚亚烷基亚胺 或被金属微粒吸附的聚合物分散剂 胶体溶液(M1)或(M2)中存在的化合物与包含分散在其中的具有特定粒径的贵金属微粒的贵金属胶体溶液均匀地混合; 以及对通过混合过程制备的混合物进行热处理的加热方法。 版权所有(C)2011,JPO&INPIT
    • 6. 发明专利
    • Colloidal solution of metallic compound, and method for producing the same
    • 金属化合物的胶体溶液及其制造方法
    • JP2011143340A
    • 2011-07-28
    • JP2010005642
    • 2010-01-14
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • SATO KIMITOSHIYAMAMURA YOSHIEMORIKAWA AKIRASUDA AKIHIKONAGAO SATOSHIHIRATA HIROTO
    • B01J13/00B01F17/52C01G25/00
    • PROBLEM TO BE SOLVED: To provide a colloidal solution of a metallic compound having excellent preservability, wherein crystallites of a metallic compound of a small and uniform diameter are dispersed as they are or in a state of an aggregate of a metallic compound of a uniform and even smaller diameter.
      SOLUTION: The colloidal solution of a metallic compound comprising crystallites of a metallic compound having a crystallite diameter d
      50 of not smaller than 0.8 nm and not greater than 3 nm whereat the cumulative number of the crystallite particles in the particle size distribution reaches 50% and having a crystallite diameter d
      90 of not greater than 1.5 times the crystallite diameter d
      50 whereat the cumulative number thereof reaches 90%, and a polymeric dispersant, is characterized in that the fine particles dispersed therein are the crystallites of the metallic compound and/or the aggregates of the compound having a particle diameter D
      50 of not smaller than 0.8 nm and smaller than 4 nm whereat the cumulative mass in the particle size distribution reaches 50% and a particle diameter D
      90 of not greater than 2.5 times the particle diameter D
      50 whereat the cumulative mass reaches 90%.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供具有优异保存性的金属化合物的胶体溶液,其中直径小且均匀分布的金属化合物的微晶原样分散或以金属化合物的集合体的状态分散 均匀甚至更小的直径。 解决方案:包含微晶直径d 50 的金属化合物的微晶的金属化合物的胶体溶液不小于0.8nm且不大于3nm,其中微晶的累积数 颗粒尺寸分布达到50%,晶粒直径d 90 不大于微晶直径d 50 的1.5倍,其累积数达到90% 和聚合物分散剂,其特征在于分散在其中的细颗粒是金属化合物和/或粒径D 50 的化合物的聚集体的晶体不小于0.8nm和更小 超过4nm,其中粒度分布中的累积质量达到50%,粒径D 90 不大于粒径D 50 的2.5倍,其中累积质量 达到90%。 版权所有(C)2011,JPO&INPIT