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    • 2. 发明专利
    • Exhaust emission control method and exhaust emission control device
    • 排气排放控制方法和排气控制装置
    • JP2009299521A
    • 2009-12-24
    • JP2008152761
    • 2008-06-11
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAZAKI KIYOSHIKAYAMA TOMOYUKISAKAKIBARA YUJINOMURA KAZUHIROMORI KENJITAKAGI NOBUYUKI
    • F01N3/02B01D53/94B01J23/66F01N3/10F01N3/24
    • PROBLEM TO BE SOLVED: To sufficiently oxidize and remove particulate matter in exhaust gas in a temperature range of a comparatively low temperature. SOLUTION: This exhaust emission control method is for oxidizing and removing the particulate matter in exhaust gas using the exhaust emission control device equipped with an oxidation catalyst disposed in an exhaust gas flow passage in which exhaust gas from an internal combustion engine flows. The oxidation catalyst is provided with an aggregate comprising: a metal particle carrier containing at least one kind of a first metal selected from a group of Ag, Pt, Rh, Pd, Ru, Ir, Os, Au, and Cu, and becoming a core; and metal oxide particulates having an average primary particle diameter of 1-100 nm comprising an oxide of a second valence variable metal covering the periphery of the metal particle carrier. The steps of: contacting exhaust gas to the oxidation catalyst so that the air-fuel ratio becomes a lean atmosphere; and contacting the exhaust gas to the oxidation catalyst so that the air-fuel ratio becomes a rich atmosphere (steps 5, 6), are performed in order, to oxidize the particulate matter. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:在相对较低温度的温度范围内对废气中的颗粒物进行充分氧化和除去。 解决方案:该废气排放控制方法是使用配备有排气流路的排气排放控制装置,其排气排出控制方法,其中排气排放控制装置设置在内燃机的废气流动的排气流路中。 氧化催化剂具有聚集体,其包括:含有选自Ag,Pt,Rh,Pd,Ru,Ir,Os,Au和Cu中的至少一种第一金属的金属颗粒载体,并成为 核心; 和平均一次粒径为1-100nm的金属氧化物微粒包含覆盖金属粒子载体周围的第二价数可变金属的氧化物。 以下步骤:使废气与氧化催化剂接触,使空燃比变成稀薄气氛; 并且使排气与氧化催化剂接触以使空燃比成为富气氛(步骤5,6),以使颗粒物质氧化。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Exhaust gas cleaning apparatus
    • 排气清洁装置
    • JP2009178673A
    • 2009-08-13
    • JP2008020747
    • 2008-01-31
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAZAKI KIYOSHIKAYAMA TOMOYUKISAKAKIBARA YUJITAKAGI NOBUYUKI
    • B01J23/63B01D46/42B01D53/94B01J35/04B01J35/10F01N3/02F01N3/10F01N3/20F01N3/24
    • PROBLEM TO BE SOLVED: To provide an exhaust gas cleaning apparatus capable of efficiently oxidizing a granular substance in an exhaust gas discharged from an internal combustion engine at a temperature area of low temperature and sufficiently regenerating an oxidation activity by applying regeneration treatment utilizing carbon monoxide (CO) contained in the exhaust gas even after poisoned with sulfur. SOLUTION: The exhaust gas cleaning apparatus for oxidizing/eliminating the granular substance contained in the exhaust gas is provided with a catalyst carrier containing at least one selected from the group consisting of ceria, titania and zirconia, a catalyst for a CO shift reaction having a noble metal carried on the catalyst carrier and a catalyst containing silver for removing the granular substance. The catalyst for the CO shift reaction is arranged in an upstream side of a gas flow passage circulated with the exhaust gas, and the catalyst for removing the granular substance is arranged in a downstream side of the gas flow passage. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供一种废气净化装置,其能够在低温的温度区域内有效地氧化从内燃机排出的废气中的粒状物质,并通过利用再生处理充分再生氧化活性 即使在用硫中毒后,废气中也含有一氧化碳(CO)。 解决方案:用于氧化/除去废气中所含的颗粒状物质的排气净化装置设置有含有选自二氧化铈,二氧化钛和氧化锆中的至少一种的催化剂载体,CO转移用催化剂 具有负载在催化剂载体上的贵金属的反应物和含有银的催化剂以除去粒状物质。 CO转化反应用催化剂配置在与废气循环的气体流路的上游侧,除去粒状物质用催化剂配置在气体流路的下游侧。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Particle of metal oxide catalyst-support for use in cleaning exhaust, and exhaust cleaning catalyst
    • 用于清洁废气的金属氧化物催化剂支持颗粒和排气清洁催化剂
    • JP2011125862A
    • 2011-06-30
    • JP2011020875
    • 2011-02-02
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • MIURA MASAHIDETAKAGI NOBUYUKIMATSUMOTO SHINICHITANABE TOSHITAKANAGAI YASUTAKADOMAE KAZUHIKOIKEDA YASUO
    • B01J23/63B01D53/94B01J23/96B01J35/10B01J38/10B01J38/12F01N3/10F01N3/28
    • Y02A50/2324
    • PROBLEM TO BE SOLVED: To provide an exhaust cleaning catalyst that allows suitable redistribution of platinum present therein, a method of redistributing platinum present in the exhaust cleaning catalyst, particles of a metal oxide catalyst-support for producing the exhaust cleaning catalyst, and a method of producing the particles of a metal oxide catalyst-support. SOLUTION: The particle of a metal oxide catalyst-support includes a first and a second metal oxides and is constituted of a core and a shell each having a mutually different composition. The molar fraction of the metal constituting the first metal oxide present in the core is greater than that of the metal constituting the first metal oxide present in the shell, and the molar fraction of the metal constituting the second metal oxide present in the shell is greater than that of the metal constituting the second metal oxide present in the core. The second metal oxide is selected from the group consisting of oxides of rare earth excluding ceria and oxides of alkali earth metal. The exhaust cleaning catalyst includes the particles of the metal oxide catalyst-support, and platinum supported thereby. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供允许铂的存在的适当的再分配的排气净化催化剂,重新分配排气净化催化剂中存在的铂的方法,用于制造废气净化催化剂的金属氧化物催化剂载体的颗粒, 以及制造金属氧化物催化剂载体的颗粒的方法。 解决方案:金属氧化物催化剂载体的颗粒包括第一和第二金属氧化物,并且由具有相互不同组成的芯和壳构成。 存在于芯中的构成第一金属氧化物的金属的摩尔分数大于构成外壳中存在的第一金属氧化物的金属的摩尔分数,构成壳中的第二金属氧化物的金属的摩尔分数更大 比构成芯中存在的第二金属氧化物的金属更高。 第二金属氧化物选自不含二氧化铈的稀土氧化物和碱土金属的氧化物。 废气净化催化剂包括金属氧化物催化剂载体的颗粒和由其负载的铂。 版权所有(C)2011,JPO&INPIT