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    • 1. 发明专利
    • Exhaust gas purifying method
    • 排气净化方法
    • JP2010249093A
    • 2010-11-04
    • JP2009101978
    • 2009-04-20
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • NOMURA KAZUHIROTANAKA HISAYUKINOBUKAWA KEN
    • F01N3/10B01D53/94B01J23/58F01N3/28
    • PROBLEM TO BE SOLVED: To provide an exhaust gas purifying method capable of sufficiently removing a nitrogen oxide in exhaust gas at a high standard.
      SOLUTION: An exhaust gas purifying catalyst is used including a first catalyst particle having a first porous carrier carrying at least one kind of a first noble metal selected from platinum and palladium, rhodium, and a nitrogen oxide occlusion material with a carrying rate of the first noble metal at 0.3-2.0 part by mass with respect to 1 part by mass rhodium, and a second catalyst particle having a second porous carrier carrying at least one kind of a second noble metal selected from platinum and palladium, and a nitrogen oxide occlusion material where rhodium is substantially not carried by the second porous carrier. The nitrogen oxide in the exhaust gas is removed by bringing the exhaust gas in contact with the exhaust gas purifying catalyst while alternately repeating steps of making the air-fuel ratio of the exhaust gas brought in contact with the exhaust gas purifying catalyst into a fuel lean state, and making the air-fuel ratio into a fuel rich state.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供能够以高标准充分除去废气中的氮氧化物的废气净化方法。 解决方案:使用排气净化催化剂,其包括具有第一催化剂颗粒的第一催化剂颗粒,所述第一催化剂颗粒具有携带至少一种选自铂和钯,铑和氮氧化物封闭材料中的至少一种第一贵金属,载体率 相对于1质量份铑为0.3〜2.0质量份的第一贵金属,第二催化剂粒子,其具有携带至少一种选自铂和钯的第二贵金属的第二多孔载体,以及氮 氧化物封闭材料,其中铑基本上不被第二多孔载体承载。 通过使废气与排气净化催化剂接触而排出废气中的氮氧化物,同时交替重复使与废气净化催化剂接触的废气的空燃比成为稀燃的步骤 状态,并且使空燃比成为富燃料状态。 版权所有(C)2011,JPO&INPIT
    • 2. 发明专利
    • Exhaust emission control method and exhaust emission control device
    • 排气排放控制方法和排气控制装置
    • JP2009299521A
    • 2009-12-24
    • JP2008152761
    • 2008-06-11
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAZAKI KIYOSHIKAYAMA TOMOYUKISAKAKIBARA YUJINOMURA KAZUHIROMORI KENJITAKAGI NOBUYUKI
    • F01N3/02B01D53/94B01J23/66F01N3/10F01N3/24
    • PROBLEM TO BE SOLVED: To sufficiently oxidize and remove particulate matter in exhaust gas in a temperature range of a comparatively low temperature. SOLUTION: This exhaust emission control method is for oxidizing and removing the particulate matter in exhaust gas using the exhaust emission control device equipped with an oxidation catalyst disposed in an exhaust gas flow passage in which exhaust gas from an internal combustion engine flows. The oxidation catalyst is provided with an aggregate comprising: a metal particle carrier containing at least one kind of a first metal selected from a group of Ag, Pt, Rh, Pd, Ru, Ir, Os, Au, and Cu, and becoming a core; and metal oxide particulates having an average primary particle diameter of 1-100 nm comprising an oxide of a second valence variable metal covering the periphery of the metal particle carrier. The steps of: contacting exhaust gas to the oxidation catalyst so that the air-fuel ratio becomes a lean atmosphere; and contacting the exhaust gas to the oxidation catalyst so that the air-fuel ratio becomes a rich atmosphere (steps 5, 6), are performed in order, to oxidize the particulate matter. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:在相对较低温度的温度范围内对废气中的颗粒物进行充分氧化和除去。 解决方案:该废气排放控制方法是使用配备有排气流路的排气排放控制装置,其排气排出控制方法,其中排气排放控制装置设置在内燃机的废气流动的排气流路中。 氧化催化剂具有聚集体,其包括:含有选自Ag,Pt,Rh,Pd,Ru,Ir,Os,Au和Cu中的至少一种第一金属的金属颗粒载体,并成为 核心; 和平均一次粒径为1-100nm的金属氧化物微粒包含覆盖金属粒子载体周围的第二价数可变金属的氧化物。 以下步骤:使废气与氧化催化剂接触,使空燃比变成稀薄气氛; 并且使排气与氧化催化剂接触以使空燃比成为富气氛(步骤5,6),以使颗粒物质氧化。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Nitrogen dioxide eliminating method and nitrogen dioxide eliminating device
    • 硝酸二氧化物消除方法和氮氧化物消除装置
    • JP2010242614A
    • 2010-10-28
    • JP2009091984
    • 2009-04-06
    • Aisin Seiki Co LtdToyota Central R&D Labs Incアイシン精機株式会社株式会社豊田中央研究所
    • NOMURA KAZUHIROTANAKA HISAYUKIOHASHI YASUHITO
    • F01N3/08B01D53/94B01J23/42F01N3/10
    • Y02A50/2345
    • PROBLEM TO BE SOLVED: To provide a nitrogen dioxide eliminating method capable of sufficiently eliminating nitrogen dioxide in exhaust gas from an internal combustion engine which does not substantially include a reducing component, under a low temperature condition. SOLUTION: The nitrogen dioxide eliminating method eliminates nitrogen dioxide in the exhaust gas from the internal combustion engine 10 which does not substantially include a reducing component, by decomposing with catalyst at low temperature. As the catalyst 12, catalyst equipped with a metal oxide porous carrier and noble metal supported by the metal oxide porous carrier is used. Exhaust gas wherein a content ratio of carbon monoxide is adjusted not less than 5 equivalent amount and less than 10 in regard to nitrogen dioxide 1 equivalent amount is contacted with the catalyst 12, thereby decomposing and eliminating the nitrogen dioxide in the exhaust gas at low temperature. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决的问题:提供一种能够在低温条件下能够充分地除去基本上不含有还原成分的内燃机的排气中的二氧化氮的二氧化氮除去方法。 解决方案:二氧化氮去除方法通过在低温下用催化剂分解来消除来自内燃机10的基本上不包括还原组分的废气中的二氧化氮。 作为催化剂12,使用配备有金属氧化物多孔载体的催化剂和由金属氧化物多孔载体担载的贵金属。 将一氧化碳的含量比例调整为相当于二氧化氮的1当量的5当量以上且小于10的废气与催化剂12接触,从而在低温下分解除去废气中的二氧化氮 。 版权所有(C)2011,JPO&INPIT
    • 10. 发明专利
    • Filter type exhaust gas-cleaning catalyst
    • 过滤型排气净化催化剂
    • JP2007252997A
    • 2007-10-04
    • JP2006077887
    • 2006-03-21
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • NOMURA KAZUHIROSAKANO KOJI
    • B01J35/10B01D39/14B01D53/94B01J23/10F01N3/02F01N3/08F01N3/10F01N3/28
    • PROBLEM TO BE SOLVED: To provide a filter type exhaust gas-cleaning catalyst capturing a particulate (grain-like substance) contained in an exhaust gas from an internal combustion engine such as a diesel engine and suitable for cleaning a harmful component in the exhaust gas. SOLUTION: The filter type exhaust gas-cleaning catalyst is provided with fine pores having a pore inner wall of a diesel particulate filter covered with a covering layer containing a porous oxide particle and having a porous diameter of 10-100 μm and an extremely fine pore constituted by a void between the porous oxide particles in the covering layer and having a porous diameter of 5-50 nm. The whole volume of the fine pore is a volume in which a volume ratio relative to the whole volume of the pore of the diesel particulate filter (whole volume of fine pore/whole volume of pore) becoming a predetermined range, and the whole volume is made to a volume in which a volume ratio relative to the whole volume of the pore of the diesel particulate filter (whole volume of fine pore/whole volume of pore) becoming a predetermined range. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种过滤器型排气净化催化剂,其捕获来自诸如柴油发动机的内燃机的废气中包含的颗粒(颗粒状物质),并且适合于清洁有害成分 废气。 解决方案:过滤式排气净化催化剂具有细孔,其具有覆盖有包含多孔氧化物颗粒并且具有10-100μm的多孔直径的覆盖层的柴油颗粒过滤器的孔内壁和 由覆盖层中的多孔氧化物颗粒之间的空隙构成的具有5-50nm多孔直径的极细孔。 细孔的整体体积是相对于柴油机微粒过滤器(细孔的全部体积/孔体积的总体积)的孔体积的体积比成为规定范围的体积比,整体积为 制成体积比,其相对于柴油机微粒过滤器(细孔的全部体积/孔体积的全部体积)的孔体积的体积比成为预定范围。 版权所有(C)2008,JPO&INPIT