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1. 发明授权

US08703684B2 Aqueous lubricant 失效
标题翻译：水性润滑剂
公开(公告)号：US08703684B2
公开(公告)日：2014-04-22
申请号：US13255663
申请日：2009-08-28
申请人： Toyoji Kakuchi , Toshifumi Satoh , Ryosuke Sakai , Fumiaki Takagi , Masami Yamanaka
发明人： Toyoji Kakuchi , Toshifumi Satoh , Ryosuke Sakai , Fumiaki Takagi , Masami Yamanaka
IPC分类号： C10M107/30 , C10M173/02 , C07C43/13
CPC分类号： C10M173/02 , C10M2209/10 , C10M2209/103 , C10N2220/021 , C10N2220/03 , C10N2230/18 , C10N2240/08 , C10N2240/401 , C10N2240/402
摘要： Provided is a water-based lubricant comprising a hyperbranch-type polyglycerol having an absolute molecular weight of from 5,000 to 500,000. The water-based lubricant has a small friction coefficient and is excellent in lubrication performance and defoamability, as compared with conventional water-based lubricants comprising an ethylene/propylene oxide copolymer, and is favorable, for example, for a water-based metal processing agent and a hydraulic pressure fluid.
摘要翻译：本发明提供一种含有绝对分子量为5000〜500000的超分支型聚甘油的水性润滑剂。与常规的包含乙烯/环氧丙烷共聚物的水性润滑剂相比，水性润滑剂具有小的摩擦系数，并且具有优异的润滑性能和消泡性，并且例如对于水性金属加工剂和液压流体。

2. 发明申请

US20120040877A1 AQUEOUS LUBRICANT 失效
标题翻译：水性润滑剂
公开(公告)号：US20120040877A1
公开(公告)日：2012-02-16
申请号：US13255663
申请日：2009-08-28
申请人： Toyoji Kakuchi , Toshifumi Satoh , Ryosuke Sakai , Fumiaki Takagi , Masami Yamanaka
发明人： Toyoji Kakuchi , Toshifumi Satoh , Ryosuke Sakai , Fumiaki Takagi , Masami Yamanaka
IPC分类号： C10M107/30 , C08G67/00
CPC分类号： C10M173/02 , C10M2209/10 , C10M2209/103 , C10N2220/021 , C10N2220/03 , C10N2230/18 , C10N2240/08 , C10N2240/401 , C10N2240/402
摘要： Provided is a water-based lubricant comprising a hyperbranch-type polyglycerol having an absolute molecular weight of from 5,000 to 500,000. The water-based lubricant has a small friction coefficient and is excellent in lubrication performance and defoamability, as compared with conventional water-based lubricants comprising an ethylene/propylene oxide copolymer, and is favorable, for example, for a water-based metal processing agent and a hydraulic pressure fluid.
摘要翻译：本发明提供一种含有绝对分子量为5000〜500000的超分支型聚甘油的水性润滑剂。与常规的包含乙烯/环氧丙烷共聚物的水性润滑剂相比，水性润滑剂具有小的摩擦系数，并且具有优异的润滑性能和消泡性，并且例如对于水性金属加工剂和液压流体。

3. 发明申请

US20070202070A1 Moisture Retention Polymer Compound 审中-公开
标题翻译：保湿性高分子化合物
公开(公告)号：US20070202070A1
公开(公告)日：2007-08-30
申请号：US10594925
申请日：2005-03-25
申请人： Motoaki Kamachi , Toyoji Kakuchi , Toshifumi Satoh
发明人： Motoaki Kamachi , Toyoji Kakuchi , Toshifumi Satoh
IPC分类号： A61K8/73 , C08G63/91 , C08F20/00
CPC分类号： A61K8/73 , A61K2800/54 , A61Q19/00 , C08B37/00 , C08B37/0006 , C08G18/6283 , C08G18/6484 , C08G18/73 , C08G83/003 , C08L5/00
摘要： The present invention relates to (1) a moisture retention polymer compound comprising a structural unit including a multi-branched polysaccharide derivative in which the hydroxyl group (OH) may be substituted by OR wherein R represents a hydrogen atom, a hydrocarbon having 1 to 30 carbon atoms, or a hydrocarbon having 1 to 30 carbon atoms and a hetero atom, and a structural unit without a multi-branched polysaccharide derivative, (2) an external preparation for skin comprising 0.1 to 99.9% by mass of the polymer compound, which can provide moist feeling to the skin and exhibit an appropriate viscosity and solubility, and (3) a cosmetic product comprising the external preparation for skin.
摘要翻译：本发明涉及（1）一种保湿性高分子化合物，其含有包含多支链多糖衍生物的结构单元，其中羟基（OH）可以被OR取代，其中R表示氢原子，具有1〜30个碳原子或碳原子数1〜30的烃和杂原子，以及不含多支链多糖衍生物的结构单元，（2）皮肤外用剂，含有0.1〜99.9质量％的高分子化合物，其中，可以赋予皮肤湿润的感觉并显示适当的粘度和溶解性，和（3）包含外用皮肤外用剂的化妆品。

4. 发明申请

US20080234224A1 External Preparation For Skin 审中-公开
标题翻译：外用皮肤准备
公开(公告)号：US20080234224A1
公开(公告)日：2008-09-25
申请号：US10594839
申请日：2005-03-25
申请人： Motoaki Kamachi , Harumi Kamachi , Toyoji Kakuchi , Toshifumi Satoh
发明人： Motoaki Kamachi , Harumi Kamachi , Toyoji Kakuchi , Toshifumi Satoh
IPC分类号： A61K31/715 , A61Q19/00
CPC分类号： A61K8/73 , A61Q19/00 , C08B37/00 , C08B37/0006
摘要： The present invention provides an external preparation for skin, which comprises a multi-branched polysaccharide derivative with multi-branched polysaccharide skeleton consisting of saccharides as constituent units, wherein at least one of hydroxyl (OH) groups in the multi-branched polysaccharide skeleton is substituted by OR (wherein R represents a hydrogen atom, a hydrocarbon having 1 to 30 carbon groups or a hydrocarbon having 1 to 30 carbon groups which has hetero atom), which can give moisture and turgor to the skin, and cosmetics containing the external preparation.
摘要翻译：本发明提供了一种皮肤外用剂，其包含多支链多糖衍生物，多支链多糖衍生物与多糖多糖骨架中的羟基（OH）基团中的至少一个被取代，所述多支链多糖骨架由多糖构成单元构成，通过OR（其中R表示氢原子，具有1至30个碳原子的烃或具有杂原子的具有1至30个碳原子的烃），其可以给皮肤带来湿气和膨胀，以及含有外用制剂的化妆品。

5. 发明申请

US20050220744A1 Polysaccharide/functional compound complex 审中-公开
标题翻译：多糖/功能复合物
公开(公告)号：US20050220744A1
公开(公告)日：2005-10-06
申请号：US11088794
申请日：2005-03-25
申请人： Motoaki Kamachi , Harumi Kamachi , Toyoji Kakuchi , Toshifumi Satoh
发明人： Motoaki Kamachi , Harumi Kamachi , Toyoji Kakuchi , Toshifumi Satoh
IPC分类号： A61K8/67 , A61K8/73 , A61Q19/00 , A61K7/06
CPC分类号： A61Q19/00 , A61K8/676 , A61K8/73
摘要： The present invention provides a polysaccharide/functional compound complex comprising a functional compound and a multi-branched polysaccharide derivative, wherein the multi-branched polysaccharide derivative has a skeleton of a multi-branched polysaccharide composed of a saccharide as a structural unit, and at least one of the hydroxyl groups (OH) of the multi-branched polysaccharide is substituted by OR, wherein R represents a hydrogen atom, a hydrocarbon having 1 to 30 carbon atoms, or a hydrocarbon having 1 to 30 carbon atoms and hetero atom. The functional compound can be efficiently incorporated into polysaccharide derivative, and further by exposing the polysaccharide complex to an environment such as a solution, sustained release of the functional compound can be controlled. By utilizing this property, the complex can be efficiently used in external preparations for skin such as cosmetic products.
摘要翻译：本发明提供了包含功能化合物和多支链多糖衍生物的多糖/功能性复合络合物，其中，多支链多糖衍生物具有由糖类作为结构单元构成的多支链多糖的骨架，至少多支链多糖的羟基（OH）之一被OR取代，其中R表示氢原子，具有1至30个碳原子的烃或具有1至30个碳原子的烃和杂原子。功能性化合物可以有效地并入多糖衍生物中，并且通过将多糖复合物暴露于溶液等环境，可以控制功能性化合物的持续释放。通过利用该性质，可以将复合物有效地用于外用的化妆品等皮肤制剂。

6. 发明申请

US20050010023A1 Hyperbranched polymers derived from anhydrosugar-related compounds and process for the preparation thereof 失效
标题翻译：衍生自脱氢糖相关化合物的超支化聚合物及其制备方法
公开(公告)号：US20050010023A1
公开(公告)日：2005-01-13
申请号：US10768174
申请日：2004-02-02
申请人： Harumi Kaga , Toyoji Kakuchi , Toshifumi Satoh , Tomoko Imai
发明人： Harumi Kaga , Toyoji Kakuchi , Toshifumi Satoh , Tomoko Imai
IPC分类号： C08G59/22 , C08G59/62 , C08G59/02
CPC分类号： C08G59/22 , C08G59/62 , C08G83/005
摘要： The hyperbranched polymers are at least one anhydrosugar-related compound selected from the dianhydrosugar alcohol [1]: (wherein R is hydrogen atom or a hydrocarbon group having from 1 to 30 carbon atoms, provided that nR's are equal to or different from one another and at least one R of nR's is hydrogen atom, and symbol n is an integer from 1 to 10) and the anhydrosugar alcohol [2]: (wherein each of R1, R2, R3 and R4 is hydrogen atom or a hydrocarbon group having from 1 to 30 carbon atoms; provided that R1, mR2's, pR3's and R4 are equal to or different from one another and at least one R2 or R3 of said mR2's and pR3's is hydrogen atom, respectively; and symbol m is zero (0) or an integer from 1 to 20 and symbol p is an integer from 1 to 20, provided that symbol m+p is an integer from 1 to 20) or at least one anhydrosugar-related compound selected from the dianhydrosugar alcohol [1] and/or the anhydrosugar alcohol [2] with at least one sugar compound selected from the anhydrosugar as represented by the general formula [3], [4], [5], [6] or [7]. The hyperbranched polymers are readily prepared by polymerizing the dianhydrosugar alcohol or the anhydrosugar [1] or [2] or the dianhydrosugar alcohol or the anhydrosugar [1] or [2] together with the anhydrosugar in the presence of a cationic or anionic initiator.
摘要翻译：超支化聚合物是选自二脱水葡萄糖醇[1]中的至少一种脱水糖相关化合物：其中R是氢原子或具有1至30个碳原子的烃基，条件是nR彼此相同或不同; nR的至少一个为氢原子，符号n为1〜10的整数）和脱水葡萄糖醇[2] :(式中，R 1，R 2，R 3，R 4分别为氢原子或1个至30个碳原子;条件是R1，mR2，pR3和R4彼此相同或不同，并且所述mR2和pR3的至少一个R2或R3分别为氢原子;符号m为零（0）或 1〜20的整数，符号p为1〜20的整数，条件是符号m + p为1〜20的整数）或至少一种选自二脱水糖醇[1]和/或具有至少一种选自脱水葡萄糖的糖化合物的脱水葡萄糖醇[2]作为r 由通式[3]，[4]，[5]，[6]或[7]表示。通过在阳离子或阴离子引发剂的存在下，将二脱水糖醇或脱水葡萄糖[1]或[2]或二脱水糖醇或脱水葡萄糖[1]或[2]与脱水葡萄糖聚合，可以容易地制备超支化聚合物。

7. 发明授权

US07473757B2 Hyperbranched polymers derived from anhydrosugar-related compounds and process for the preparation thereof 失效
标题翻译：衍生自脱氢糖相关化合物的超支化聚合物及其制备方法
公开(公告)号：US07473757B2
公开(公告)日：2009-01-06
申请号：US10768174
申请日：2004-02-02
申请人： Harumi Kaga , Toyoji Kakuchi , Toshifumi Satoh , Tomoko Imai
发明人： Harumi Kaga , Toyoji Kakuchi , Toshifumi Satoh , Tomoko Imai
IPC分类号： C08G59/00 , C08G65/00
CPC分类号： C08G59/22 , C08G59/62 , C08G83/005
摘要： The hyperbranched polymers are at least one anhydrosugar-related compound selected from the dianhydrosugar alcohol [1]: (wherein R is hydrogen atom or a hydrocarbon group having from 1 to 30 carbon atoms, provided that nR's are equal to or different from one another and at least one R of nR's is hydrogen atom, and symbol n is an integer from 1 to 10) and the anhydrosugar alcohol [2]: (wherein each of R1, R2, R3 and R4 is hydrogen atom or a hydrocarbon group having from 1 to 30 carbon atoms; provided that R1, mR2's, pR3's and R4 are equal to or different from one another and at least one R2 or R3 of said mR2's and pR3's is hydrogen atom, respectively; and symbol m is zero (0) or an integer from 1 to 20 and symbol p is an integer from 1 to 20, provided that symbol m+p is an integer from 1 to 20)or at least one anhydrosugar-related compound selected from the dianhydrosugar alcohol [1] and/or the anhydrosugar alcohol [2] with at least one sugar compound selected from the anhydrosugar as represented by the general formula [3], [4], [5], [6] or [7].The hyperbranched polymers are readily prepared by polymerizing the dianhydrosugar alcohol or the anhydrosugar [1] or [2] or the dianhydrosugar alcohol or the anhydrosugar [1] or [2] together with the anhydrosugar in the presence of a cationic or anionic initiator.
摘要翻译：超支化聚合物是选自二脱水葡萄糖醇[1]中的至少一种脱水糖相关化合物：其中R是氢原子或具有1至30个碳原子的烃基，条件是nR彼此相同或不同; nR的至少一个为氢原子，符号n为1〜10的整数）和脱水葡萄糖醇[2] :(式中，R 1，R 2，R 3，R 4分别为氢原子或1个至30个碳原子;条件是R1，mR2，pR3和R4彼此相同或不同，并且所述mR2和pR3的至少一个R2或R3分别为氢原子;符号m为零（0）或 1〜20的整数，符号p为1〜20的整数，条件是符号m + p为1〜20的整数）或至少一种选自二脱水糖醇[1]和/或具有至少一种选自脱水葡萄糖的糖化合物的脱水葡萄糖醇[2]作为r 由通式[3]，[4]，[5]，[6]或[7]表示。通过在阳离子或阴离子引发剂的存在下，将二脱水糖醇或脱水葡萄糖[1]或[2]或二脱水糖醇或脱水葡萄糖[1]或[2]与脱水葡萄糖一起聚合，可以容易地制备超支化聚合物。

8. 发明授权

US07157432B2 Tetraphenylbacteriochlorin derivatives and compositions containing the same 失效
标题翻译：四苯基细菌二氢卟吩衍生物和含有它们的组合物
公开(公告)号：US07157432B2
公开(公告)日：2007-01-02
申请号：US11219853
申请日：2005-09-07
申请人： Shigenobu Yano , Toyoji Kakuchi , Yuji Mikata
发明人： Shigenobu Yano , Toyoji Kakuchi , Yuji Mikata
IPC分类号： A61K31/70 , C07H1/00 , C07H17/00
CPC分类号： C07H15/203 , C07H15/26 , Y02P20/55
摘要： Provided is a tetraphenylbacteriochlorin derivative represented by the formula (I): [wherein R1, R2, R3 and R4, independently from each other, are a residue of a monosaccharide represented by the formulae: (wherein, R is a hydrogen or a protecting group)], or its salt. The tetraphenylbacteriochlorin derivative or its salt has a large molar extinction coefficient at long wavelengths which are expected to have a high tissue-penetrating property, and exhibits high selectivity to tumor cells and hydrophilicity.
摘要翻译：本发明提供由式（I）表示的四苯基细菌二氢卟酚衍生物：其中R 1，R 2，R 3和R 4 彼此独立地是由下式表示的单糖的残基：（其中，R是氢或保护基）]或其盐。四苯基细菌二氢卟酚衍生物或其盐在长波长处具有大的摩尔消光系数，其预期具有高的组织穿透性，并且对肿瘤细胞和亲水性显示出高选择性。

9. 发明申请

US20060003946A1 Tetraphenylbacteriochlorin derivatives and compositions containing the same 失效
标题翻译：四苯基细菌二氢卟吩衍生物和含有它们的组合物
公开(公告)号：US20060003946A1
公开(公告)日：2006-01-05
申请号：US11219853
申请日：2005-09-07
申请人： Shigenobu Yano , Toyoji Kakuchi , Yuji Mikata
发明人： Shigenobu Yano , Toyoji Kakuchi , Yuji Mikata
IPC分类号： A61K31/7052 , C07H17/02
CPC分类号： C07H15/203 , C07H15/26 , Y02P20/55
摘要： Provided is a tetraphenylbacteriochlorin derivative represented by the formula (I): [wherein R1, R2, R3 and R4, independently from each other, are a residue of a monosaccharide represented by the formulae: (wherein, R is a hydrogen or a protecting group)], or its salt. The tetraphenylbacteriochlorin derivative or its salt has a large molar extinction coefficient at long wavelengths which are expected to have a high tissue-penetrating property, and exhibits high selectivity to tumor cells and hydrophilicity.
摘要翻译：本发明提供由式（I）表示的四苯基细菌二氢卟酚衍生物：其中R 1，R 2，R 3和R 4 彼此独立地是由下式表示的单糖的残基：（其中，R是氢或保护基）]或其盐。四苯基细菌二氢卟酚衍生物或其盐在长波长处具有大的摩尔消光系数，其预期具有高的组织穿透性，并且对肿瘤细胞和亲水性显示出高选择性。

10. 发明授权

US06844429B2 Fullerene derivative and composition comprising the same 失效
标题翻译：富勒烯衍生物及其组合物
公开(公告)号：US06844429B2
公开(公告)日：2005-01-18
申请号：US10466870
申请日：2002-07-18
申请人： Yuji Mikata , Toyoji Kakuchi , Shigenobu Yano
发明人： Yuji Mikata , Toyoji Kakuchi , Shigenobu Yano
IPC分类号： C07H15/26 , A61K31/70 , A61K41/00 , A61P35/00 , A61P43/00 , C07H15/18 , C07H17/02 , C09K3/00 , C07H15/00
CPC分类号： C07H15/18 , A61K31/70 , C07H17/02 , Y10S977/734
摘要： A fullerene derivative represented by the formula (I): [wherein, A is a residue of monosaccharides or disaccharides, and Alk is a lower alkylene group, the group represented by the formula (X): is a fullerene residual skeleton, and n is an integral number of 1 or 2] or its salt produces a formulation usable for PDT which has more hydrophilicity and lipophilicity, is expected to have selectivity to tumor cells by cell recognition, shows no toxicity to the cells in a dark place and has a cytocidal effect by light irradiation.
摘要翻译：由式（I）表示的富勒烯衍生物：[其中，A是单糖或二糖的残基，Alk是低级亚烷基，由式（X）表示的基团是富勒烯残基骨架，n为整数为1或2]或其盐产生可用于具有更高亲水性和亲油性的PDT的制剂，预期通过细胞识别对肿瘤细胞具有选择性，对黑暗中的细胞没有毒性并具有杀细胞活性光照射效果。

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