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1. 发明授权

US5281636A Thermosetting composition 失效
标题翻译：热固性组合物
公开(公告)号：US5281636A
公开(公告)日：1994-01-25
申请号：US751038
申请日：1991-08-28
申请人： Toshiro Nambu , Hirotoshi Kawaguchi , Masanori Kai , Hisao Furukawa
发明人： Toshiro Nambu , Hirotoshi Kawaguchi , Masanori Kai , Hisao Furukawa
IPC分类号： C09D183/06 , C08K5/05 , C08K5/10 , C08K5/541 , C08L101/08 , C08L101/10 , C09D183/04 , C09D183/07 , C09D201/02 , C09D201/08 , C09D201/10 , C08K5/06 , C08L43/04
CPC分类号： C08K5/10 , C08K5/05 , C09D201/10
摘要： A thermosetting composition comprising (A) a carboxyl group-containing polyol resin, (B) a hydrolyzable silyl group-containing polymer, and at least one member selected from the group consisting of (C) a dehydrating agent and (D) an alcohol. The composition of the present invention is excellent in the physical properties of the film as well as the storage stability of the coating composition compared to the known compositions containing the curing catalyst.
摘要翻译：一种热固性组合物，其包含（A）含羧基的多元醇树脂，（B）可水解甲硅烷基的聚合物和选自（C）脱水剂和（D）醇中的至少一种。与含有固化催化剂的已知组合物相比，本发明的组合物的膜的物理性能以及涂料组合物的储存稳定性优异。

2. 发明授权

US5344880A Thermosetting composition 失效
标题翻译：热固性组合物
公开(公告)号：US5344880A
公开(公告)日：1994-09-06
申请号：US13186
申请日：1993-01-29
申请人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
发明人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
IPC分类号： C08L33/06 , C08L43/04 , C08L83/04 , C08L83/06 , C08L83/10
CPC分类号： C08L33/066 , C08L43/04 , C08L83/04 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/26 , C08G77/28 , C08G77/70
摘要： A composition including (A) a hydroxyl group-containing acrylic resin, (B) an acrylic copolymer containing an alkoxysilyl group having the formula (I): ##STR1## (C) a polyorganosiloxane and (D) a curing catalyst. The composition can give the film with excellent weatherability, stain resistance, acid resistance, water repellency and durability and with no bad-smelling odor.
摘要翻译：包含（A）含羟基的丙烯酸树脂的组合物，（B）含有式（I）的烷氧基甲硅烷基的丙烯酸共聚物：（I）（C）聚有机硅氧烷和（D）固化催化剂。该组合物可以赋予该膜具有优异的耐候性，耐污性，耐酸性，防水性和耐久性，并且没有不良气味。

3. 发明授权

US5241000A Curable resin and composition containing the same 失效
标题翻译：可固化树脂及其组合物
公开(公告)号：US5241000A
公开(公告)日：1993-08-31
申请号：US772291
申请日：1991-10-07
申请人： Hideyuki Ohnari , Toshiro Nambu , Hirotoshi Kawaguchi , Yoshihiko Okimura , Hisao Furukawa
发明人： Hideyuki Ohnari , Toshiro Nambu , Hirotoshi Kawaguchi , Yoshihiko Okimura , Hisao Furukawa
IPC分类号： C08G18/10 , C08G18/67 , C08G18/68 , C08G18/71 , C08G18/83 , C08G63/695 , C08G63/91 , C08L67/00
CPC分类号： C08G63/91 , C08G18/10 , C08G18/6725 , C08G18/68 , C08G18/718 , C08G18/837 , C08G63/695 , C08L67/00
摘要： The curable resin having a number average molecular weight of 600 to 6000 and at least two hydrolyzable silyl groups which is prepared by reacting an aliphatic polyester resin having acryloyl group and alcoholic hydroxyl group with an isocyanate silane compound: ##STR1## reacting the obtained reaction product with an aminosilane compound: ##STR2## and reacting the obtained reaction product with a monofunctional isocyanate: OCN-R.sup.5 and/or a polyfunctional isocyanate; and the composition containing the resin. The curable resin and the composition are excellent in acid resistance such as acid resin resistance, scratch resistance, solvent resistance, flexibility, and the like.

4. 发明授权

US5063114A Coated material 失效
标题翻译：涂层材料
公开(公告)号：US5063114A
公开(公告)日：1991-11-05
申请号：US505393
申请日：1990-04-06
申请人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
发明人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
IPC分类号： C08L43/04 , C08L83/04 , C09D133/06
CPC分类号： C09D133/066 , C08L43/04 , C08L83/04 , Y10T428/2949 , Y10T428/2958 , Y10T428/31663
摘要： A coated material obtained by applying a coat containing a metallic powder and/or a coloring pigment to a substrate and further applying a topcoat clear coating thereon, wherein said topcoat clear coating is a heat-hardening coat which contains a composition comprising a hydroxyl group-containing resin, a hydrolyzable silyl group-containing polymer and a hardening catalyst as the main component. This coated material is excellent in, for example, appearance, acid resistance, staining resistance, adhesiveness and hardness.

5. 发明授权

US5891958A Curable composition suitable as top coat and coated material using the same 失效
标题翻译：适用作为外涂层和使用其的涂层材料的可固化组合物
公开(公告)号：US5891958A
公开(公告)日：1999-04-06
申请号：US765366
申请日：1997-01-08
申请人： Toshiro Nambu , Seigo Nakamura , Hirotoshi Kawaguchi , Jiro Arioka , Masaharu Inoue
发明人： Toshiro Nambu , Seigo Nakamura , Hirotoshi Kawaguchi , Jiro Arioka , Masaharu Inoue
IPC分类号： C09D143/04 , C08F8/00 , C08L83/06
CPC分类号： C09D143/04 , Y10T428/31663
摘要： A curable composition suitable as a top coat which contains a vinyl copolymer (A) having a main chain consisting of a vinyl copolymer chain, in which a reactive silyl group is combined with a carbon atom at the main chain end and/or side chain of the copolymer, the copolymer having an alcoholic hydroxyl group at its main chain end and/or side chain and having an alcoholic hydroxyl group equivalent of 400 to 2000 g/mole, a non-aqueous hydroxyl group-containing polymer dispersion (B), a silicon-containing compound and/or its partical hydrolysis condensation product (C), and a curing catalyst (D), wherein the amount of (B) is 5 to 100 parts by weight, in terms of solid matter, based on 100 parts by weight of (A), the amount of (C) is 2 to 100 parts by weight based on 100 parts by weight of (A), and the amount of (D) is 0.001 to 10 parts by weight based on 100 parts by weight of the total amount of solid matters of (A), (B) and (C), and a coated material using the same.
摘要翻译： PCT No.PCT / JP96 / 01235 Sec。 371日期1997年1月8日 102（e）日期1997年1月8日PCT提交1996年5月9日PCT公布。出版物WO96 / 35758 日期：1996年11月14日一种适用作为顶涂层的可固化组合物，其包含乙烯基共聚物（A），其具有由乙烯基共聚物链组成的主链，其中反应性甲硅烷基与主链端与碳原子结合， /或共聚物的侧链，所述共聚物在其主链端和/或侧链具有醇羟基，醇羟基当量为400至2000g / mol，非水羟基聚合物分散体（B），含硅化合物和/或其分解水解缩合产物（C）和固化催化剂（D），其中（B）的量为固体成分为5〜100重量份，基于100重量份（A），（C）的量为（A）100重量份为2〜100重量份，（D）的量为0.001〜10重量份，（A），（B）和（C）的固体成分总量的100重量份，以及使用其的涂布材料。

6. 发明授权

US5753737A Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US5753737A
公开(公告)日：1998-05-19
申请号：US761519
申请日：1996-12-09
申请人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa , Jo Kawamura , Hirotoshi Kawaguchi
发明人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa , Jo Kawamura , Hirotoshi Kawaguchi
IPC分类号： C08L63/00 , C09D143/04 , C08K5/10
CPC分类号： C09D143/04 , C08L63/00
摘要： A coating composition containing (A) a silyl group-containing vinyl polymer which has on the polymer chain ends or side chain thereof at least one silicon atom, to which a hydrolyzable group is linked, per polymer molecule, (B) a reaction product of an aminosilane compound with an epoxy compound (C) a hydrolyzable ester compound and (D) an inorganic pigment. The coating composition of the present invention has excellent film properties such as appearance, moisture resistance and grindability and is suitable for use as an undercoating and a primer coating.
摘要翻译：一种涂料组合物，其含有（A）含有甲硅烷基的乙烯基聚合物，聚合物链末端或侧链上至少有一个可水解基团连接的硅原子，每个聚合物分子，（B）反应产物具有环氧化合物的氨基硅烷化合物（C）可水解酯化合物和（D）无机颜料。本发明的涂料组合物具有优异的膜性能，如外观，耐湿性和可磨性，适合用作底涂和底漆。

7. 发明授权

US5639825A Thermosetting silicon-containing composition 失效
标题翻译：热固性含硅组合物
公开(公告)号：US5639825A
公开(公告)日：1997-06-17
申请号：US317777
申请日：1994-10-04
申请人： Toshiro Nanbu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
发明人： Toshiro Nanbu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
IPC分类号： C08L43/04 , C08L101/06 , C08L101/10 , C09D133/06 , C09D201/10 , C08F230/08
CPC分类号： C08L101/10 , C08L101/06 , C08L43/04 , C09D133/066 , C09D201/10
摘要： When a thermosetting composition comprising(A) a resin having hydroxyl group,(B) a hydrolyzable silyl group-containing polymer,(C) a hydrolyzable silicon compound and(D) a curing catalyst is used, coating materials having no problem as to bad-smelling can be obtained and the coating films formed therefrom are improved in physical properties such as adhesion, solvent resistance and hardness.
摘要翻译：当使用包含（A）具有羟基的树脂（B）可水解的含甲硅烷基的聚合物，（C）可水解的硅化合物和（D）固化催化剂）的热固性组合物时，没有问题的涂料可以获得耐磨性，并且由其形成的涂膜改善了诸如粘合性，耐溶剂性和硬度的物理性能。

8. 发明授权

US5416165A Curable composition for paint 失效
标题翻译：油漆组合物
公开(公告)号：US5416165A
公开(公告)日：1995-05-16
申请号：US138444
申请日：1993-10-20
申请人： Yoshihiko Okimura , Masaharu Inoue , Hirotoshi Kawaguchi , Hisao Furukawa
发明人： Yoshihiko Okimura , Masaharu Inoue , Hirotoshi Kawaguchi , Hisao Furukawa
IPC分类号： C09D133/14 , C08L43/04 , C09D133/04 , C09D137/00 , C09D143/04 , C09D183/04 , C09D201/00 , C09D201/10
CPC分类号： C09D143/04 , C08L2205/02 , C08L43/04
摘要： A curable composition for paint containing:(A) 95 to 5 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group and at least one specific alcoholic hydroxyl group existing at an end of the main chain and/or in a side chain thereof in one molecule, in which the main chain contains substantially a vinyl copolymer chain and the alcoholic hydroxyl equivalent is from 180 to 2000 g/mol;(B) 5 to 95 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group at an end of the main chain and/or in a side chain thereof in one molecule and having no alcoholic hydroxyl group in the same molecule, in which the main chain contains substantially a vinyl copolymer chain; and(C) 0.001 to 10 parts by weight of a curing catalyst per 100 parts by weight of the total resin solids content.This curable composition for paint has well-balanced properties of good acid resistance, water resistance, scratch resistance, weathering resistance, and so forth.
摘要翻译：一种用于涂料的可固化组合物，其包含：（A）95至5重量份的具有至少一个特定的可水解甲硅烷基和至少一个特定的醇羟基的乙烯基共聚物，其存在于主链的末端和/或侧面其中主链含有基本上乙烯基共聚物链，醇羟基当量为180-2000g / mol; （B）5〜95重量份在一分子中在主链末端和/或侧链具有至少一个特定的可水解甲硅烷基并且在同一分子中不含醇羟基的乙烯基共聚物，其中主链含有基本上乙烯基共聚物链; 和（C）每100重量份总树脂固体含量为0.001〜10重量份的固化催化剂。这种涂料用固化性组合物具有良好的耐酸性，耐水性，耐擦伤性，耐候性等特性。

9. 发明授权

US5399607A One component composition containing a catalyst and having increased storability 失效
标题翻译：含有催化剂并具有增加的储存性的单组分组合物
公开(公告)号：US5399607A
公开(公告)日：1995-03-21
申请号：US189710
申请日：1994-02-01
申请人： Toshiro Nanbu , Hirotoshi Kawaguchi , Yasushi Kato , Hisao Furukawa
发明人： Toshiro Nanbu , Hirotoshi Kawaguchi , Yasushi Kato , Hisao Furukawa
IPC分类号： C08L33/06 , C08L43/04 , C08L83/04 , C08L101/06 , C08L101/10 , C09D133/06 , C09D143/04 , C09D201/10 , C08K5/05 , C08F230/08
CPC分类号： C09D143/04 , C08L101/06 , C08L101/10 , C08L33/066 , C08L43/04 , C08L83/04 , C09D133/066 , C09D201/10 , C08G77/42 , C08L33/06
摘要： A one component composition suitable for use as coatings which are excellent in storage stability and coating workability, which comprises:(A) an acrylic resin having hydroxyl group,(B) an alkoxysilyl group-containing acrylic copolymer having a group represented by the formula: ##STR1## wherein R.sup.1 is an alkyl group having 1 to 10 carbon atoms, R.sup.2 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms selected from the group consisting of an alkyl group, an aryl group and an aralkyl group, and a is 0, 1 or 2,(C) a curing catalyst, andat least one member selected from the group consisting of (D) a dehydrating agent and (E) an alkyl alcohol.
摘要翻译：一种适合用作保存稳定性和涂布加工性优异的涂料的单组分组合物，其包括：（A）具有羟基的丙烯酸树脂，（B）具有下式表示的基团的含烷氧基甲硅烷基丙烯酸共聚物：其中，R 1为碳原子数1〜10的烷基，R 2为氢原子或碳原子数1〜10的选自烷基，芳基和芳烷基的一价烃基，和（A）为0,1或2，（C）固化催化剂和选自（D）脱水剂和（E）烷基醇中的至少一种。

10. 发明授权

US5344879A Curable composition for paint 失效
标题翻译：油漆组合物
公开(公告)号：US5344879A
公开(公告)日：1994-09-06
申请号：US5130
申请日：1993-01-15
申请人： Masaharu Inoue , Yoshihiko Okimura , Hirotoshi Kawaguchi , Hisao Furukawa
发明人： Masaharu Inoue , Yoshihiko Okimura , Hirotoshi Kawaguchi , Hisao Furukawa
IPC分类号： C08G18/71 , C08K5/5419 , C09D143/04
CPC分类号： C08G18/44 , C08G18/4277 , C08G18/718 , C08K5/5419 , C09D143/04
摘要： A curable composition for paint including(A) 10 to 99 parts by weight of a vinyl polymer having a number average molecular weight of not less than 2,000 and at least one silicon atom to which a hydrolyzable group is bonded at an end of the main chain and/or in a side chain thereof, in one molecule, wherein the main chain is substantially a vinyl polymer chain;(B) 1 to 90 parts by weight of a compound containing a carbonyldioxy group which is at least one of(i) a compound containing a hydrolyzable silyl group, the compound having at least one carbonyldioxy group in one molecule and at least one silicon atom to which a hydrolyzable group is bonded, in one molecule, and(ii) a polycarbonate polyol compound having at least one carbonyldioxy group and at least two hydroxyl groups in one molecule; and(C) 0.001 to 10 parts by weight of a curing catalyst on the basis of 100 parts by weight of the components (A) and (B) in total.This curable composition for paint has excellent high solid content and one package storage stability as well as superior scratch resistance and acid resistance.
摘要翻译：一种涂料用固化性组合物，其含有（A）10〜99重量份数均分子量为2000以上的乙烯基聚合物和至少一个可水解基团在主链末端键合的硅原子和/或在其侧链中，在一个分子中，其中主链基本上是乙烯基聚合物链; （B）1〜90重量份含有羰基二氧基的化合物，其为（i）含有可水解甲硅烷基的化合物，在一个分子中具有至少一个羰基二氧基的化合物和至少一个硅原子在一个分子中可水解基团键合的聚碳酸酯多元醇化合物，和（ii）在一个分子中具有至少一个羰基二氧基和至少两个羟基的聚碳酸酯多元醇化合物; 和（C）基于100重量份的组分（A）和（B）的总量，0.001至10重量份的固化催化剂。这种涂料用可固化组合物具有优异的高固含量和一个包装储存稳定性以及优异的抗划伤性和耐酸性。

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