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1. 发明授权

US5241000A Curable resin and composition containing the same 失效
标题翻译：可固化树脂及其组合物
公开(公告)号：US5241000A
公开(公告)日：1993-08-31
申请号：US772291
申请日：1991-10-07
申请人： Hideyuki Ohnari , Toshiro Nambu , Hirotoshi Kawaguchi , Yoshihiko Okimura , Hisao Furukawa
发明人： Hideyuki Ohnari , Toshiro Nambu , Hirotoshi Kawaguchi , Yoshihiko Okimura , Hisao Furukawa
IPC分类号： C08G18/10 , C08G18/67 , C08G18/68 , C08G18/71 , C08G18/83 , C08G63/695 , C08G63/91 , C08L67/00
CPC分类号： C08G63/91 , C08G18/10 , C08G18/6725 , C08G18/68 , C08G18/718 , C08G18/837 , C08G63/695 , C08L67/00
摘要： The curable resin having a number average molecular weight of 600 to 6000 and at least two hydrolyzable silyl groups which is prepared by reacting an aliphatic polyester resin having acryloyl group and alcoholic hydroxyl group with an isocyanate silane compound: ##STR1## reacting the obtained reaction product with an aminosilane compound: ##STR2## and reacting the obtained reaction product with a monofunctional isocyanate: OCN-R.sup.5 and/or a polyfunctional isocyanate; and the composition containing the resin. The curable resin and the composition are excellent in acid resistance such as acid resin resistance, scratch resistance, solvent resistance, flexibility, and the like.

2. 发明授权

US5344879A Curable composition for paint 失效
标题翻译：油漆组合物
公开(公告)号：US5344879A
公开(公告)日：1994-09-06
申请号：US5130
申请日：1993-01-15
申请人： Masaharu Inoue , Yoshihiko Okimura , Hirotoshi Kawaguchi , Hisao Furukawa
发明人： Masaharu Inoue , Yoshihiko Okimura , Hirotoshi Kawaguchi , Hisao Furukawa
IPC分类号： C08G18/71 , C08K5/5419 , C09D143/04
CPC分类号： C08G18/44 , C08G18/4277 , C08G18/718 , C08K5/5419 , C09D143/04
摘要： A curable composition for paint including(A) 10 to 99 parts by weight of a vinyl polymer having a number average molecular weight of not less than 2,000 and at least one silicon atom to which a hydrolyzable group is bonded at an end of the main chain and/or in a side chain thereof, in one molecule, wherein the main chain is substantially a vinyl polymer chain;(B) 1 to 90 parts by weight of a compound containing a carbonyldioxy group which is at least one of(i) a compound containing a hydrolyzable silyl group, the compound having at least one carbonyldioxy group in one molecule and at least one silicon atom to which a hydrolyzable group is bonded, in one molecule, and(ii) a polycarbonate polyol compound having at least one carbonyldioxy group and at least two hydroxyl groups in one molecule; and(C) 0.001 to 10 parts by weight of a curing catalyst on the basis of 100 parts by weight of the components (A) and (B) in total.This curable composition for paint has excellent high solid content and one package storage stability as well as superior scratch resistance and acid resistance.
摘要翻译：一种涂料用固化性组合物，其含有（A）10〜99重量份数均分子量为2000以上的乙烯基聚合物和至少一个可水解基团在主链末端键合的硅原子和/或在其侧链中，在一个分子中，其中主链基本上是乙烯基聚合物链; （B）1〜90重量份含有羰基二氧基的化合物，其为（i）含有可水解甲硅烷基的化合物，在一个分子中具有至少一个羰基二氧基的化合物和至少一个硅原子在一个分子中可水解基团键合的聚碳酸酯多元醇化合物，和（ii）在一个分子中具有至少一个羰基二氧基和至少两个羟基的聚碳酸酯多元醇化合物; 和（C）基于100重量份的组分（A）和（B）的总量，0.001至10重量份的固化催化剂。这种涂料用可固化组合物具有优异的高固含量和一个包装储存稳定性以及优异的抗划伤性和耐酸性。

3. 发明授权

US5416165A Curable composition for paint 失效
标题翻译：油漆组合物
公开(公告)号：US5416165A
公开(公告)日：1995-05-16
申请号：US138444
申请日：1993-10-20
申请人： Yoshihiko Okimura , Masaharu Inoue , Hirotoshi Kawaguchi , Hisao Furukawa
发明人： Yoshihiko Okimura , Masaharu Inoue , Hirotoshi Kawaguchi , Hisao Furukawa
IPC分类号： C09D133/14 , C08L43/04 , C09D133/04 , C09D137/00 , C09D143/04 , C09D183/04 , C09D201/00 , C09D201/10
CPC分类号： C09D143/04 , C08L2205/02 , C08L43/04
摘要： A curable composition for paint containing:(A) 95 to 5 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group and at least one specific alcoholic hydroxyl group existing at an end of the main chain and/or in a side chain thereof in one molecule, in which the main chain contains substantially a vinyl copolymer chain and the alcoholic hydroxyl equivalent is from 180 to 2000 g/mol;(B) 5 to 95 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group at an end of the main chain and/or in a side chain thereof in one molecule and having no alcoholic hydroxyl group in the same molecule, in which the main chain contains substantially a vinyl copolymer chain; and(C) 0.001 to 10 parts by weight of a curing catalyst per 100 parts by weight of the total resin solids content.This curable composition for paint has well-balanced properties of good acid resistance, water resistance, scratch resistance, weathering resistance, and so forth.
摘要翻译：一种用于涂料的可固化组合物，其包含：（A）95至5重量份的具有至少一个特定的可水解甲硅烷基和至少一个特定的醇羟基的乙烯基共聚物，其存在于主链的末端和/或侧面其中主链含有基本上乙烯基共聚物链，醇羟基当量为180-2000g / mol; （B）5〜95重量份在一分子中在主链末端和/或侧链具有至少一个特定的可水解甲硅烷基并且在同一分子中不含醇羟基的乙烯基共聚物，其中主链含有基本上乙烯基共聚物链; 和（C）每100重量份总树脂固体含量为0.001〜10重量份的固化催化剂。这种涂料用固化性组合物具有良好的耐酸性，耐水性，耐擦伤性，耐候性等特性。

4. 发明授权

US5344880A Thermosetting composition 失效
标题翻译：热固性组合物
公开(公告)号：US5344880A
公开(公告)日：1994-09-06
申请号：US13186
申请日：1993-01-29
申请人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
发明人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
IPC分类号： C08L33/06 , C08L43/04 , C08L83/04 , C08L83/06 , C08L83/10
CPC分类号： C08L33/066 , C08L43/04 , C08L83/04 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/26 , C08G77/28 , C08G77/70
摘要： A composition including (A) a hydroxyl group-containing acrylic resin, (B) an acrylic copolymer containing an alkoxysilyl group having the formula (I): ##STR1## (C) a polyorganosiloxane and (D) a curing catalyst. The composition can give the film with excellent weatherability, stain resistance, acid resistance, water repellency and durability and with no bad-smelling odor.
摘要翻译：包含（A）含羟基的丙烯酸树脂的组合物，（B）含有式（I）的烷氧基甲硅烷基的丙烯酸共聚物：（I）（C）聚有机硅氧烷和（D）固化催化剂。该组合物可以赋予该膜具有优异的耐候性，耐污性，耐酸性，防水性和耐久性，并且没有不良气味。

5. 发明授权

US5281636A Thermosetting composition 失效
标题翻译：热固性组合物
公开(公告)号：US5281636A
公开(公告)日：1994-01-25
申请号：US751038
申请日：1991-08-28
申请人： Toshiro Nambu , Hirotoshi Kawaguchi , Masanori Kai , Hisao Furukawa
发明人： Toshiro Nambu , Hirotoshi Kawaguchi , Masanori Kai , Hisao Furukawa
IPC分类号： C09D183/06 , C08K5/05 , C08K5/10 , C08K5/541 , C08L101/08 , C08L101/10 , C09D183/04 , C09D183/07 , C09D201/02 , C09D201/08 , C09D201/10 , C08K5/06 , C08L43/04
CPC分类号： C08K5/10 , C08K5/05 , C09D201/10
摘要： A thermosetting composition comprising (A) a carboxyl group-containing polyol resin, (B) a hydrolyzable silyl group-containing polymer, and at least one member selected from the group consisting of (C) a dehydrating agent and (D) an alcohol. The composition of the present invention is excellent in the physical properties of the film as well as the storage stability of the coating composition compared to the known compositions containing the curing catalyst.
摘要翻译：一种热固性组合物，其包含（A）含羧基的多元醇树脂，（B）可水解甲硅烷基的聚合物和选自（C）脱水剂和（D）醇中的至少一种。与含有固化催化剂的已知组合物相比，本发明的组合物的膜的物理性能以及涂料组合物的储存稳定性优异。

6. 发明授权

US5063114A Coated material 失效
标题翻译：涂层材料
公开(公告)号：US5063114A
公开(公告)日：1991-11-05
申请号：US505393
申请日：1990-04-06
申请人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
发明人： Toshiro Nambu , Hirotoshi Kawaguchi , Hisao Furukawa , Yasushi Kato
IPC分类号： C08L43/04 , C08L83/04 , C09D133/06
CPC分类号： C09D133/066 , C08L43/04 , C08L83/04 , Y10T428/2949 , Y10T428/2958 , Y10T428/31663
摘要： A coated material obtained by applying a coat containing a metallic powder and/or a coloring pigment to a substrate and further applying a topcoat clear coating thereon, wherein said topcoat clear coating is a heat-hardening coat which contains a composition comprising a hydroxyl group-containing resin, a hydrolyzable silyl group-containing polymer and a hardening catalyst as the main component. This coated material is excellent in, for example, appearance, acid resistance, staining resistance, adhesiveness and hardness.

7. 发明授权

US5142012A Curable resin and process for preparing the same 失效
标题翻译：可固化树脂及其制备方法
公开(公告)号：US5142012A
公开(公告)日：1992-08-25
申请号：US379834
申请日：1989-07-14
申请人： Hisao Furukawa , Hideyuki Ohnari , Yasushi Kato
发明人： Hisao Furukawa , Hideyuki Ohnari , Yasushi Kato
IPC分类号： C08F230/08 , C08F30/08 , C08F290/00 , C08F290/06 , C08F299/02 , C08G18/10 , C08G18/68 , C08G18/81 , C08G18/83 , C08L55/00 , C09D155/00 , C09D183/00 , C09D201/02
CPC分类号： C08L55/005 , C08F290/06 , C08G18/10 , C08G18/68 , C08G18/8175 , C08G18/837
摘要： A curable resin having a number average molecular weight of 1,000 to 100,000 and having the formula (I): ##STR1## and a process for preparing the curable resin (I). The curable resin (I) of the invention is excellent in flexibility, solvent resistance, adhesion to organic materials as well as inorganic materials, storage stability, curability at ordinary temperature and weatherability.

8. 发明授权

US4975488A Curable composition at room temperature 失效
标题翻译：固化组合物在室温下
公开(公告)号：US4975488A
公开(公告)日：1990-12-04
申请号：US246110
申请日：1988-09-19
申请人： Hisao Furukawa , Jo Kawamura , Naotami Ando , Hideyuki Ohnari
发明人： Hisao Furukawa , Jo Kawamura , Naotami Ando , Hideyuki Ohnari
IPC分类号： C08K5/54 , C08L101/00 , C08L101/10 , C09D143/04
CPC分类号： C08K5/54 , C09D143/04 , Y10S528/901
摘要： A curable composition at room temperature comprising (A) 100 parts by weight of a hydrolyzable silyl group-containing vinyl polymer, (B) 0.1 to 100 parts by weight of a specific silane compound and (C) 0 to 20 parts by weight of a curing catalyst, the silane compound (B) being a silane compound selected from ##STR1## The composition is excellent in not only adhesion to melamine alkyd or malamine acrylic resin coatings but also hardness, solvent resistance and staining resistance.

9. 发明授权

US5498666A Curable composition suitable as top coat 失效
标题翻译：适合作为面漆的可固化组合物
公开(公告)号：US5498666A
公开(公告)日：1996-03-12
申请号：US278340
申请日：1994-07-21
申请人： Toshiro Nambu , Masaharu Inoue , Seigo Nakamura , Hisao Furukawa
发明人： Toshiro Nambu , Masaharu Inoue , Seigo Nakamura , Hisao Furukawa
IPC分类号： C08L43/04 , C08L83/04 , C09D143/04 , C09D183/04 , C04L83/06
CPC分类号： C09D143/04 , C08L43/04 , C08L83/04
摘要： A curable composition suitable as top coats having an improved excellent acid resistance as well as excellent properties such as thermosetting property, appearance, water resistance, scratch resistance and weatherability, which comprises (A) a vinyl copolymer having a main chain substantially composed of a vinyl copolymer and having in its molecule both at least one hydrolyzable silyl group and at least one alcoholic hydroxyl group, (B) a silanol group-containing organopolysiloxne having at least one silanol group, and (C) a curing catalyst.
摘要翻译：适合作为顶涂层的可固化组合物具有改进的优异耐酸性以及优异的性能如热固性，外观，耐水性，耐擦伤性和耐候性，其包括（A）乙烯基共聚物，其主链基本上由乙烯基共聚物，并且在其分子中具有至少一个可水解甲硅烷基和至少一个醇羟基，（B）具有至少一个硅烷醇基的含硅烷醇基的有机聚硅氧烷，和（C）固化催化剂。

10. 发明授权

US5753737A Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US5753737A
公开(公告)日：1998-05-19
申请号：US761519
申请日：1996-12-09
申请人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa , Jo Kawamura , Hirotoshi Kawaguchi
发明人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa , Jo Kawamura , Hirotoshi Kawaguchi
IPC分类号： C08L63/00 , C09D143/04 , C08K5/10
CPC分类号： C09D143/04 , C08L63/00
摘要： A coating composition containing (A) a silyl group-containing vinyl polymer which has on the polymer chain ends or side chain thereof at least one silicon atom, to which a hydrolyzable group is linked, per polymer molecule, (B) a reaction product of an aminosilane compound with an epoxy compound (C) a hydrolyzable ester compound and (D) an inorganic pigment. The coating composition of the present invention has excellent film properties such as appearance, moisture resistance and grindability and is suitable for use as an undercoating and a primer coating.
摘要翻译：一种涂料组合物，其含有（A）含有甲硅烷基的乙烯基聚合物，聚合物链末端或侧链上至少有一个可水解基团连接的硅原子，每个聚合物分子，（B）反应产物具有环氧化合物的氨基硅烷化合物（C）可水解酯化合物和（D）无机颜料。本发明的涂料组合物具有优异的膜性能，如外观，耐湿性和可磨性，适合用作底涂和底漆。

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