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    • 7. 发明授权
    • Flue gas denitration catalyst and preparation process thereof
    • 烟气脱硝催化剂及其制备方法
    • US07256155B2
    • 2007-08-14
    • US10705365
    • 2003-11-10
    • Shigeru NojimaKozo IidaYoshiaki ObayashiKatsumi NochiMasashi Kiyosawa
    • Shigeru NojimaKozo IidaYoshiaki ObayashiKatsumi NochiMasashi Kiyosawa
    • B01J23/00B01J21/00
    • B01D53/8631B01D53/8628B01J23/002B01J23/30B01J35/04B01J37/0238
    • Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
    • 提供了具有高脱硝活性并能够抑制副反应,即SO 2氧化的烟道气脱硝催化剂。 和催化剂的制备方法。 烟道气脱硝催化剂包括TiO 2,WO 3和V 2 O 5。 在催化剂的表面200μm以内的表面层中,V 2 O 2 O 5负载在含有TiO 2和WO 2的载体上 3 。 V 2 O 5的支持量为0.4-5重量%。 %,基于表层的重量,为0.1-0.9wt。 %,基于催化剂的总重量。 如此支撑的V 2 O 5 5具有通过X射线衍射测量的小于10nm的微晶尺寸。 催化剂可以通过制备含有TiO 2和WO 3的混合物并具有V 2 O 5 O 5 在制备的混合物的挤出产物的表面上通过气相法。 催化剂也可以通过使V 2 O 2 O 5通过气相法负载在所制备的混合物的粉末上,并将所得粉末负载在表面上 成型产品。