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    • 2. 发明授权
    • Oxygen sensor with heater
    • 带加热器的氧气传感器
    • US4512871A
    • 1985-04-23
    • US604473
    • 1984-04-27
    • Nobuhide KatoTakao Murase
    • Nobuhide KatoTakao Murase
    • G01N27/406G01N27/58
    • G01N27/4067
    • An oxygen sensor having a bar-shaped heater inserted in an elongate bore formed in a tubular solid electrolyte body which has porous platinum electrodes on its inner and outer surfaces and which is supported by a housing such that its closed end portion is exposed to exhaust gas and such that the elongate bore is gas-tight with respect to the exhaust gas. The bar-shaped heater comprises a heating resistor having a positive temperature coefficient, a ceramic body carrying the heating resistor so as to embed the latter, and a pair of lead wires. The ceramic body has on its periphery a pair of terminal pads connected to the heating resistor. The ends of the lead wires are brazed to the pads with a mass of brazing material containing silver. An exposed surface of the brazing mass is coated with a metal layer made of metal which is different from silver or its alloy. The metal layer may be further coated with a heat-resistant layer.
    • 一种氧传感器,其具有插入形成在管状固体电解质体中的细长孔中的棒状加热器,其在其内表面和外表面上具有多孔铂电极,并且由壳体支撑,使得其封闭端部暴露于废气 并且使得细长孔相对于废气气密。 棒状加热器包括具有正温度系数的加热电阻器,承载加热电阻器以便嵌入加热电阻器的陶瓷体和一对引线。 陶瓷体在其周边上具有连接到加热电阻器的一对端子焊盘。 引线的端部用大量含银的钎焊材料钎焊到焊盘。 钎焊块的暴露表面涂覆有不同于银或其合金的金属制成的金属层。 金属层可以进一步涂覆耐热层。
    • 3. 发明授权
    • Electric connection terminal for a sensor element utilizing ceramics
    • 一种利用陶瓷的传感器元件的电气连接端子
    • US4668375A
    • 1987-05-26
    • US791538
    • 1985-10-25
    • Nobuhide KatoTakao Murase
    • Nobuhide KatoTakao Murase
    • G01N27/04G01N27/00G01N27/12G01N27/403G01N27/407G01N27/409H05K1/11G01N27/46
    • G01N27/4071
    • An electric connection terminal arranged at a rear end of a sensor element and capable of affording quick and easy connection of the sensor element with a contacting element connected to a lead wire extending into a connector socket or connector insulator accommodating the contacting element for transmitting a signal detected at the front end of the sensor element, is composed of at least two conductive layers, and at least the lowermost layer of the conductive layers is composed of a mixture of a conductive metal and ceramics and/or glass, so that the layers bond firmly with each other and the lowermost layer bonds most firmly to the sensor element, whereby peeling-off of the connection terminal from the sensor element due to friction thereof against the contacting element and repetition of heating and cooling of the sensor element is eliminated.
    • 电连接端子布置在传感器元件的后端,并且能够快速且容易地连接传感器元件与连接到延伸到连接器插座的引线的接触元件或容纳接触元件的连接器绝缘体,用于传输信号 在传感器元件的前端检测到,由至少两个导电层构成,并且导电层的至少最下层由导电金属和陶瓷和/或玻璃的混合物组成,使得层结合 彼此牢固并且最底层最牢固地结合到传感器元件,从而消除了由于其与接触元件的摩擦而导致的连接端子与传感器元件的剥离以及传感器元件的加热和冷却的重复。
    • 4. 发明授权
    • Oxygen sensor with heater
    • 带加热器的氧气传感器
    • US4528086A
    • 1985-07-09
    • US604474
    • 1984-04-27
    • Nobuhide KatoTakao Murase
    • Nobuhide KatoTakao Murase
    • F02D41/14G01N27/406G01N27/409G01N27/46
    • G01N27/4067
    • An oxygen sensor having a bar-shaped heater inserted in an elongate bore formed in a tubular body of solid electrolyte which has porous platinum electrodes on its inner and outer surfaces and which is supported by a housing such that its closed end portion is exposed to exhaust gas and such that the elongate bore is gas-tight with respect to the exhaust gas. The bar-shaped heater comprises a heating resistor having a positive temperature coefficient, a ceramic body carrying the heating resistor so as to embed the latter, and a pair of lead wires. The ceramic body has on its periphery a pair of terminal pads connected to the heating resistor. The ends of the lead wires are brazed to the terminal pads with a brazing material containing silver. The ceramic body further has a pair of equipotential members disposed outwardly of the pair of terminal pads to enclose at least portions of the peripheries of the pads which are opposite to each other.
    • 一种氧传感器,其具有插入在形成于固体电解质的管状体中的细长孔中的棒状加热器,其在其内表面和外表面上具有多孔铂电极,并且由壳体支撑,使得其封闭端部暴露于排气 气体并且使得细长孔相对于废气气密。 棒状加热器包括具有正温度系数的加热电阻器,承载加热电阻器以便嵌入加热电阻器的陶瓷体和一对引线。 陶瓷体在其周边上具有连接到加热电阻器的一对端子焊盘。 引线的端部用含有银的钎焊材料钎焊到端子焊盘。 陶瓷体还具有一对等电位构件,该等电位构件设置在该对端子衬垫的外侧,以封闭彼此相对的衬垫周边的至少一部分。
    • 5. 发明授权
    • Oxygen sensor
    • 氧传感器
    • US4732663A
    • 1988-03-22
    • US788142
    • 1985-10-16
    • Nobuhide KatoTakao Murase
    • Nobuhide KatoTakao Murase
    • G01N27/409G01N27/12G01N27/403G01N27/407G01N27/46
    • G01N27/4071G01N27/4062G01N27/407G01N27/4078
    • An oxygen sensor for determining an oxygen partial pressure of a measurement gas in a measurement-gas space, includes an elongate planar sensing element, a tubular protective device, and a retainer housing. The sensing element has an oxygen detecting portion adjacent to one longitudinal end thereof, and electrical terminal contacts adjacent to the other longitudinal end thereof. The tubular protective device accommodates therein the sensing element, and includes a first protective covering for protecting at least an end portion of the sensing element which is located within the measurement-gas space and exposed to the measurement gas and which includes the oxygen detecting portion. The tubular protective device further comprises a second protective covering for covering the remaining portion of the sensing element which is not exposed to the measurement gas. The tubular protective device is attached by the retainer housing to a partition wall defining the measurement-gas space. The elongate planar oxygen sensing element has a length of at least 40 mm as measured from the partition wall to the said other longitudinal end.
    • 用于确定测量气体空间中的测量气体的氧分压的氧传感器包括细长的平面感测元件,管状保护装置和保持器壳体。 感测元件具有邻近其一个纵向端的氧气检测部分,并且电气端子接触件邻近其另一个纵向端部。 管状保护装置在其中容纳感测元件,并且包括用于保护位于测量气体空间内并且暴露于测量气体并且包括氧气检测部分的感测元件的至少端部的第一保护盖。 管状保护装置还包括用于覆盖未暴露于测量气体的感测元件的剩余部分的第二保护盖。 管状保护装置通过保持器壳体附接到限定测量气体空间的分隔壁。 细长平面氧气感测元件具有从分隔壁到所述另一纵向端部测量的至少40mm的长度。
    • 6. 发明授权
    • Oxygen sensor
    • 氧传感器
    • US4591423A
    • 1986-05-27
    • US709801
    • 1985-03-08
    • Nobuhide KatoTakao Murase
    • Nobuhide KatoTakao Murase
    • F02D41/14G01N27/04G01N27/12G01N27/403G01N27/407G01N27/58
    • G01N27/4077
    • An oxyen sensor for determining an oxygen partial pressure of a measurement gas in a measurement-space, comprising (a) an elongate oxygen sensing element having an oxygen detecting portion adjacent to its one longitudinal end, (b) a first protective covering for protecting at least an end portion of the sensing element which is located within the measurement-space and exposed to the measurement gas and which includes the oxygen detecting portion; (c) a second protective covering for covering another portion of the sensing element which is not exposed to the measurement gas; and (d) a retainer housing for supporting the sensing element, and the first and second protective coverings such that the end portion of the sensing element having the detecting portion is located within the conduit. The first and second protective coverings consist of an integral protective tubing member which is supported by the retainer housing with fluid tightness therebetween and which accommodates the oxygen sensing element. The oxygen sensor may comprise an air-tight mass of an inorganic particulate material which fills a portion of a space defined by the periphery of the sensing element and the inner surface of the protective tubing member, over a predetermined length along the axis of the protective tubing member.
    • 一种用于测量测量空间中的测量气体的氧分压的氧气传感器,包括:(a)具有与其一个纵向端相邻的氧气检测部分的细长氧气感测元件,(b)第一保护盖,用于保护 所述感测元件的至少一个端部位于所述测量空间内并且暴露于所述测量气体并且包括所述氧气检测部分; (c)用于覆盖未暴露于测量气体的感测元件的另一部分的第二保护盖; 和(d)用于支撑感测元件的保持器壳体,以及第一和第二保护罩,使得具有检测部分的感测元件的端部位于导管内。 第一和第二保护罩由整体的保护管构件组成,其由保持器壳体支撑,并且容纳氧气感测元件。 氧传感器可以包括无气体质量的无机颗粒材料,其填充由感测元件的周边和保护管构件的内表面限定的空间的一部分,沿着保护管的轴线预定长度 管件。
    • 7. 发明授权
    • Electrochemical oxygen sensor
    • 电化学氧传感器
    • US4591422A
    • 1986-05-27
    • US709803
    • 1985-03-08
    • Nobuhide KatoTakao Murase
    • Nobuhide KatoTakao Murase
    • G01N27/12F02D41/14G01N27/04G01N27/403G01N27/407G01N27/409G01N27/58
    • G01N27/4071G01N27/4077
    • An oxygen sensor includes a planar oxygen sensing element having an oxygen detecting portion located in the vicinity of one end thereof, and a protective covering encloses the sensing element to protect the detecting portion in particular. The detecting portion has an oxygen detecting member exposed to a measurement gas. The sensing element has opposite primary surfaces having a larger area than other surfaces thereof, and the detecting member is disposed on the side of one of the primary surfaces. The protective covering has apertures for allowing the measurement gas to flow through a wall of the protective covering so that the detecting member is exposed to the measurement gas. The apertures are formed through a part of the wall of the protective covering which does not face the above-indicated one primary surface of the planar sensing element.
    • 氧传感器包括具有位于其一端附近的氧检测部分的平面氧感测元件,并且保护盖包围感测元件以特别地保护检测部分。 检测部分具有暴露于测量气体的氧气检测部件。 感测元件具有相对的主表面,其面积比其他表面大,并且检测构件设置在一个主表面的一侧。 保护罩具有用于允许测量气体流过保护盖的壁的孔,使得检测构件暴露于测量气体。 孔通过防护罩的壁的一部分形成,其不面对平面感测元件的上述一个主表面。
    • 10. 发明授权
    • Method and sensing device for measuring predetermined gas component in
measurement gas
    • 用于测量测量气体中预定气体成分的方法和感测装置
    • US5763763A
    • 1998-06-09
    • US731307
    • 1996-10-15
    • Nobuhide KatoNoriyuki InaYasushi WatanabeTakao Murase
    • Nobuhide KatoNoriyuki InaYasushi WatanabeTakao Murase
    • G01N27/41G01N27/407G01N27/416G01N27/419G01N33/00G01N27/46G01N27/58
    • G01N27/4074G01N27/419G01N33/0014
    • Disclosed is a method and a sensing device capable of measuring a predetermined measurement gas component continuously and accurately with good response over a long period of time without being affected by a high oxygen concentration in a measurement gas. The measurement gas is introduced into a first processing zone. A first electrochemical pumping cell is used to lower a partial pressure of oxygen in an atmosphere thereof to a degree sufficient to control a partial pressure of oxygen in a subsequent second processing zone. The gas is introduced into the second processing zone. Oxygen in an atmosphere is pumped out by using a second electrochemical pumping cell so that the partial pressure of oxygen in the atmosphere is controlled to have a low value of partial pressure of oxygen which does not substantially affect measurement of an amount of the measurement gas component. The gas is introduced into a third processing zone. Oxygen produced by reducing or decomposing the measurement gas component is pumped out by using a third electrochemical pumping cell. The amount of the measurement gas component is determined from a detected value of a pumping current flowing through the third electrochemical pumping cell. The amount of the measurement gas component may be also determined by measuring an electromotive force by using an electrochemical sensor cell, in place of the third electrochemical pumping cell.
    • 本发明公开了一种方法和检测装置,其能够在不受测量气体中的高氧浓度的影响的情况下长时间连续准确地测量预定的测量气体成分,并具有良好的响应。 将测量气体引入第一处理区域。 第一电化学泵送电池用于将氧气在其气氛中的分压降低至足以控制随后的第二处理区域中的氧分压。 将气体引入第二处理区。 通过使用第二电化学泵送电池将大气中的氧气抽出,使得大气中的氧分压被控制为具有低的氧分压值,其基本上不影响测量气体组分的量的测量 。 将气体引入第三处理区域。 通过使用第三电化学泵送单元泵送通过还原或分解测量气体组分产生的氧气。 测量气体成分的量根据流过第三电化学泵送单元的泵浦电流的检测值来确定。 测量气体组分的量也可以通过使用电化学传感器单元来代替第三电化学泵送单元来测量电动势来确定。