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1. 发明申请

US20060049048A1 Gas sensor 审中-公开
标题翻译：气体传感器
公开(公告)号：US20060049048A1
公开(公告)日：2006-03-09
申请号：US10540561
申请日：2003-12-25
申请人： Tomonori Kondo , Shoji Kitanoya , Norihiko Nadanami , Noboru Ishida , Takafumi Oshima
发明人： Tomonori Kondo , Shoji Kitanoya , Norihiko Nadanami , Noboru Ishida , Takafumi Oshima
IPC分类号： G01N27/26
CPC分类号： G01N27/4074 , H01M8/04089 , H01M2008/1095
摘要： A gas sensor capable of reversibly and continuously measuring the concentration of a catalyst poison gas such as CO without specially needing recovering means such as a heater, and measuring the catalyst poison gas concentration without being affected by H2O concentration. The electrical circuit (15) of the gas sensor has an AC power supply (19) for applying an AC voltage between both electrodes (3), (5), an AC voltmeter (21) for measuring an AC voltage (AC effective voltage V) between the both electrodes (3), (5), and an AC ammeter (23) for measuring a current (AC effective current I) running between the both electrodes (3), (5). An impedance is determined from the AC effective voltage V and the AC effective current I generated when the AC voltage is applied to the both electrodes (3), (5). Since this impedance corresponds to the catalyst poison gas concentration, the catalyst poison gas concentration can be determined from the impedance by using a map showing the relation between the impedance and the catalyst poison gas concentration.
摘要翻译：一种气体传感器，其能够可靠地连续地测量催化剂毒气如CO的浓度，而不需要诸如加热器的回收装置，并且不受H 2 O 2的影响来测量催化剂毒气浓度浓度。气体传感器的电路（15）具有用于在两个电极（3），（5）之间施加交流电压的交流电源（19），用于测量交流电压的交流电压表（AC）（AC有效电压V （3），（5）和用于测量在两个电极（3），（5）之间运行的电流（AC有效电流I）的AC电流表（23）。根据AC有效电压V和当向两个电极（3），（5）施加AC电压时产生的AC有效电流I）确定阻抗。由于该阻抗对应于催化剂毒气浓度，所以可以通过使用示出阻抗与催化剂毒气浓度之间的关系的图来从阻抗确定催化剂毒气浓度。

2. 发明授权

US06913677B2 Hydrogen sensor 失效
标题翻译：氢传感器
公开(公告)号：US06913677B2
公开(公告)日：2005-07-05
申请号：US10242403
申请日：2002-09-13
申请人： Shoji Kitanoya , Norihiko Nadanami , Tomonori Kondo , Masaya Watanabe , Noboru Ishida
发明人： Shoji Kitanoya , Norihiko Nadanami , Tomonori Kondo , Masaya Watanabe , Noboru Ishida
IPC分类号： G01N27/416 , G01N27/407 , G01N33/00 , H01M8/04 , H01M8/10
CPC分类号： G01N27/4074 , G01N33/005
摘要： A hydrogen gas sensor is configured such that an O-ring 21 is disposed within a measurement chamber 11a in order to seal against a first support element 9a and against a proton conduction layer 1. This O-ring 21 assumes the form of a rectangular frame that surrounds a first electrode 3, and a substantially circular cross section, and is elastic, heat resistant, and durable. A first metal plate 23a and a second metal plate 23b are disposed from the outside on opposite support elements 9a and 9b, respectively. The hydrogen gas sensor of the present embodiment has a pair of right-hand and left-hand through-holes 29 formed therein so as to extend along the thickness direction thereof. Bolts 31 are inserted into the corresponding through-holes 29. By fastening the metal plates 23a and 23b from the outside by means of the bolts 31 and nuts 33, the opposite support elements 9a and 9b are fastened, thereby clamping the entire hydrogen sensor in a unitary condition.
摘要翻译：氢气传感器被配置为使得O形环21设置在测量室11a内以便密封第一支撑元件9a并抵靠质子传导层1.该O形环21呈现为围绕第一电极3的矩形框架和基本圆形的横截面，并且是弹性的，耐热的和耐用的。第一金属板23a和第二金属板23b分别从外部设置在相对的支撑元件9a和9b上。本实施方式的氢气传感器具有沿其厚度方向延伸的一对形成在其中的右侧和左侧通孔29。螺栓31插入对应的通孔29.通过螺栓31和螺母33从外部紧固金属板23a和23b，将相对的支撑元件9a和9b紧固，从而将整个氢传感器处于一体状态。

3. 发明授权

US06764582B2 Hydrogen sensor 失效
标题翻译：氢传感器
公开(公告)号：US06764582B2
公开(公告)日：2004-07-20
申请号：US10290162
申请日：2002-11-08
申请人： Norihiko Nadanami , Shoji Kitanoya , Tomonori Kondo , Masaya Watanabe , Noboru Ishida
发明人： Norihiko Nadanami , Shoji Kitanoya , Tomonori Kondo , Masaya Watanabe , Noboru Ishida
IPC分类号： G01N27407
CPC分类号： G01N27/4074 , G01N33/005
摘要： A gas sensor suitable for measuring hydrogen concentration, including a proton conductive layer (1); a first electrode (3) and a second electrode (5) provided on the proton conductive layer (1); a gas diffusion-limiting inlet (19) provided between the first electrode (3) and a measurement gas atmosphere (6) containing hydrogen gas; and a gas diffusion-limiting outlet (21) provided between the second electrode (5) and the atmosphere (6); wherein the ratio (a/b) between the diffusion resistance (a) of the diffusion limiting portion (19) and the diffusion resistance (b) of the gas outlet portion (21) is not greater than 2.
摘要翻译：适用于测量氢浓度的气体传感器，包括质子传导层（1）; 设置在质子传导层（1）上的第一电极（3）和第二电极（5）。设置在第一电极（3）和含有氢气的测量气体气氛（6）之间的气体扩散限制入口（19）和设置在第二电极（5）和大气（6）之间的气体扩散限制出口（21）。其中所述扩散限制部分（19）的扩散阻力（a）与所述气体出口部分（21）的扩散阻力（b）之比（a / b）不大于2。

4. 发明授权

US07306712B2 Gas sensor and method for measuring gas concentration using the same 失效
标题翻译：气体传感器及使用其测量气体浓度的方法
公开(公告)号：US07306712B2
公开(公告)日：2007-12-11
申请号：US10144835
申请日：2002-05-15
申请人： Masaya Watanabe , Norihiko Nadanami , Tomonori Kondo , Ryuji Inoue , Takafumi Oshima , Noboru Ishida
发明人： Masaya Watanabe , Norihiko Nadanami , Tomonori Kondo , Ryuji Inoue , Takafumi Oshima , Noboru Ishida
IPC分类号： G01N27/407
CPC分类号： G01N33/005 , G01N27/4074 , G01N33/006
摘要： This invention provides a gas sensor including a proton-conductive polymer electrolyte layer and a method for measuring gas concentration, that are capable of measuring gas concentration at high accuracy notwithstanding the presence of water vapor.
摘要翻译：本发明提供了一种气体传感器，其包括质子传导性聚合物电解质层和气体浓度测量方法，尽管存在水蒸气，但能够高精度地测量气体浓度。

5. 发明授权

US06797151B2 CO sensor and method of measuring CO concentration 失效
标题翻译： CO传感器和测量CO浓度的方法
公开(公告)号：US06797151B2
公开(公告)日：2004-09-28
申请号：US10035248
申请日：2002-01-04
申请人： Norihiko Nadanami , Tomonori Kondo , Ryuji Inoue , Noboru Ishida , Takafumi Oshima
发明人： Norihiko Nadanami , Tomonori Kondo , Ryuji Inoue , Noboru Ishida , Takafumi Oshima
IPC分类号： G01N27407
CPC分类号： G01N27/4074 , G01N33/004
摘要： A CO sensor and a CO-concentration measurement method which enables accurate measurement of CO concentration irrespective of the hydrogen concentration of a gas under measurement. By applying a first predetermined voltage between first and second electrodes 7 and 8, hydrogen contained in a gas under measurement which has been introduced into a first measurement space 2 via a first diffusion-controlling section 1 dissociates, decomposes, or reacts with another element to generate protons. The thus-generated protons are transported from the first electrode 7 to the second electrode 8 via a first proton-conductive layer 5 or protons are transported from the second electrode 8 to the first electrode 7 via the first proton-conductive layer 5 (when the hydrogen concentration of the measurement gas is extremely low), so that the hydrogen concentration within the first measurement space 2 is controlled to a constant level. The gas under measurement having a controlled hydrogen concentration is introduced into a second measurement space 4 via a second diffusion-controlling section 3, and a second predetermined voltage is applied between third and fourth electrodes 9 and 10. The CO concentration of the gas under measurement is obtained based on current (a limiting proton current) which flows between the third and fourth electrodes 9 and 10. Alternatively, the CO concentration of the gas under measurement is obtained from electromotive force generated between the third and fourth electrodes 9 and 10.
摘要翻译：一种CO传感器和CO浓度测量方法，其能够精确测量CO浓度，而与测量的气体的氢浓度无关。通过在第一和第二电极7和8之间施加第一预定电压，通过第一扩散控制部分1被引入到第一测量空间2中的测量气体中所含的氢离子，分解或与其它元件反应产生质子。由此产生的质子经由第一质子传导层5从第一电极7传送到第二电极8，或者质子经由第一质子传导层5从第二电极8输送到第一电极7（当测量气体的氢浓度极低），使得第一测量空间2内的氢浓度被控制在一定水平。具有受控氢浓度的测量气体经由第二扩散控制部分3引入第二测量空间4，并且在第三和第四电极9和10之间施加第二预定电压。测量气体的CO浓度基于在第三和第四电极9和10之间流动的电流（限制质子电流）获得。或者，测量气体的CO浓度是从第三和第四电极9和10之间产生的电动势获得的。

6. 发明授权

US07189364B2 Hydrogen sensor 失效
标题翻译：氢传感器
公开(公告)号：US07189364B2
公开(公告)日：2007-03-13
申请号：US10119901
申请日：2002-04-11
申请人： Norihiko Nadanami , Tomonori Kondo , Masaya Watanabe , Ryuji Inoue , Noboru Ishida , Takafumi Oshima
发明人： Norihiko Nadanami , Tomonori Kondo , Masaya Watanabe , Ryuji Inoue , Noboru Ishida , Takafumi Oshima
IPC分类号： B32B5/02 , B32B27/04 , B32B27/12 , G01N27/00 , G01N7/00
CPC分类号： G01N33/005 , G01N27/4074 , Y10T436/11 , Y10T436/203332 , Y10T436/22 , Y10T436/25875
摘要： A hydrogen sensor includes a first electrode 3 and a second electrode 4 provided in contact with a proton conduction layer 2; a gas diffusion controlling portion 6 provided between a measurement gas atmosphere and the first electrode 3; and a support element (1a, 1b) for supporting the proton conduction layer 6, the first electrode 3, the second electrode 4, and the gas diffusion controlling portion 6. Hydrogen contained in a measurement gas introduced via the gas diffusion controlling portion 6 is dissociated, decomposed, or reacted by applying a voltage between the first electrode 3 and the second electrode 4 to thereby generate protons. Hydrogen concentration is obtained on the basis of a limiting current generated as a result of the generated protons being pumped out via the proton conduction layer 2 from the first electrode 3 side of the proton conduction layer to the second electrode 4 side of the proton conduction layer. Hydrogen concentration on the first electrode 2 is controlled to a partial pressure of not less than 10−12 atm, or more preferably, of not less than 3×10−12 atm and of less than 10−2 atm.
摘要翻译：氢传感器包括与质子传导层2接触而设置的第一电极3和第二电极4; 设置在测量气体气氛和第一电极3之间的气体扩散控制部分6; 以及用于支撑质子传导层6，第一电极3，第二电极4和气体扩散控制部分6的支撑元件（1a，1b）。通过气体扩散控制部分6导入的测量气体中所含的氢离子，分解或反应，通过在第一电极3和第二电极4之间施加电压从而产生质子。基于由生成的质子经由质子传导层2从质子传导层的第一电极3侧向质子传导层的第二电极4侧泵出的限制电流获得氢浓度。将第一电极2上的氢浓度控制在不低于大气压的分压，或者更优选不低于3×10 12大气压，以及小于10-2大气压。

7. 发明授权

US06344134B1 Method for measuring NOx concentration and NOx concentration sensor 有权
标题翻译： NOx浓度和NOx浓度传感器的测量方法
公开(公告)号：US06344134B1
公开(公告)日：2002-02-05
申请号：US09232001
申请日：1999-01-15
申请人： Tessho Yamada , Noboru Ishida , Toshitaka Matsuura , Yoshiro Noda , Nobuhiro Hayakawa , Norihiko Nadanami , Satoshi Sugaya , Takaki Otsuka , Masashi Ando , Takafumi Oshima
发明人： Tessho Yamada , Noboru Ishida , Toshitaka Matsuura , Yoshiro Noda , Nobuhiro Hayakawa , Norihiko Nadanami , Satoshi Sugaya , Takaki Otsuka , Masashi Ando , Takafumi Oshima
IPC分类号： G01N27407
CPC分类号： G01N27/417
摘要： An apparatus and method using a two-serial space sensor (having first and second internal spaces 2,3) for accurately measuring NOx concentration in gas, e.g., exhausted from an internal combustion engine. Both NOx (nitrogen oxide) and oxygen are forced to be partially dissociated in the first space 2 to an oxygen concentration level of 2×10−7 to 2×10−10 atm by pumping out oxygen from the first space 2. The NOx concentration is determined based on the second current measured in the second space 4 and based on the NO dissociation percentage in the first chamber which is 0.5-50%, or preferably 2-20%. The NOx measurement accuracy is further improved when the above oxygen concentration level is maintained from 2×10−8 to 2×10−9 and the temperature drift of the sensor is maintained within ±5° C. under a sensor temperature range of 700-900° C.
摘要翻译：一种使用两串联空间传感器（具有第一和第二内部空间2,3）的装置和方法，用于精确测量例如从内燃机排出的气体中的NOx浓度。通过从第一空间2中抽出氧，迫使NOx（氮氧化物）和氧在第一空间2中部分地离解为2x10-7至2×10-10大气压的氧浓度水平。基于在第二空间4中测量的第二电流，并且基于第一室中的NO解离百分比为0.5-50％，或优选2-20％。在700-900℃的传感器温度范围内，当上述氧气浓度水平保持在2×10 -8至2×10 -9，并且传感器的温度漂移保持在±5℃以内时，NOx测量精度进一步提高。

8. 发明授权

US06743352B2 Method and apparatus for correcting a gas sensor response for moisture in exhaust gas 有权
标题翻译：用于校正废气中的湿气的气体传感器响应的方法和装置
公开(公告)号：US06743352B2
公开(公告)日：2004-06-01
申请号：US10066684
申请日：2002-02-06
申请人： Masashi Ando , Noboru Ishida , Satoshi Sugaya , Takafumi Oshima , Norihiko Nadanami , Takaki Otsuka , Yoshikuni Sato , Tatsuo Okumura , Yasuhisa Kuzuya
发明人： Masashi Ando , Noboru Ishida , Satoshi Sugaya , Takafumi Oshima , Norihiko Nadanami , Takaki Otsuka , Yoshikuni Sato , Tatsuo Okumura , Yasuhisa Kuzuya
IPC分类号： G01N27407
CPC分类号： F01N3/2066 , F01N3/0842 , F01N3/0871 , F01N11/00 , F01N2550/02 , F01N2550/03 , F01N2560/026 , F01N2570/14 , F01N2610/03 , F02D41/146 , F02D41/2474 , F02D41/28 , G01N27/4175 , G01N27/419 , G01N33/0037 , Y02A50/2344 , Y02A50/245 , Y02T10/24 , Y02T10/47
摘要： A method for detecting the concentration of a specific gas (NOx) in an engine exhaust gas using a gas sensor and a process of correcting the gas sensor. According to the correcting process, the amount of moisture in the exhaust gas is estimated, then a a gas concentration detection signal output by the gas sensor on the basis of an estimated amount of moisture is corrected. Finally, the effect of the amount of moisture in the exhaust gas is removed or reduced from the detected value of gas concentration.
摘要翻译：一种使用气体传感器检测发动机排气中的特定气体（NOx）的浓度的方法和校正气体传感器的处理。根据校正处理，对废气中的水分量进行推定，校正气体传感器基于估计的水分量输出的气体浓度检测信号。最后，对湿度的影响废气从气体浓度的检测值中除去或减少。

9. 发明授权

US06375828B2 Methods and apparatus for measuring NOx gas concentration, for detecting exhaust gas concentration and for calibrating and controlling gas sensor 失效
标题翻译：用于测量NOx气体浓度的方法和装置，用于检测废气浓度和校准和控制气体传感器
公开(公告)号：US06375828B2
公开(公告)日：2002-04-23
申请号：US09045938
申请日：1998-03-23
申请人： Masashi Ando , Noboru Ishida , Satoshi Sugaya , Takafumi Oshima , Norihiko Nadanami , Takaki Otsuka , Yoshikuni Sato , Tatsuo Okumura , Yasuhisa Kuzuya
发明人： Masashi Ando , Noboru Ishida , Satoshi Sugaya , Takafumi Oshima , Norihiko Nadanami , Takaki Otsuka , Yoshikuni Sato , Tatsuo Okumura , Yasuhisa Kuzuya
IPC分类号： G01N27407
CPC分类号： F01N3/2066 , F01N3/0842 , F01N3/0871 , F01N11/00 , F01N2550/02 , F01N2550/03 , F01N2560/026 , F01N2570/14 , F01N2610/03 , F02D41/146 , F02D41/2474 , F02D41/28 , G01N27/4175 , G01N27/419 , G01N33/0037 , Y02A50/2344 , Y02A50/245 , Y02T10/24 , Y02T10/47
摘要： A nitrogen oxide concentration detector has a first measurement chamber 2 into which is introduced a measurement gas via a first diffusion resistance 1; an oxygen concentration detection electrode 7a for measuring the oxygen concentration in the measurement gas in said first measurement chamber 1; a first oxygen ion pump cell 6 for pumping out oxygen in the measurement gas from said first measurement chamber 2 based on the potential of said oxygen concentration detection electrode 7a; a second measurement chamber 8 into which the gas is introduced from said first measurement chamber 2 via a second diffusion resistance 3; and a second oxygen ion pump cell 8 having a pair of electrodes 8a,8b across which a voltage is applied to decompose NOx in the second measurement chamber 4 to pump out dissociated oxygen to cause a circuit Ip2 corresponding to the NOx concentration to flow in the second oxygen ion pump cell 8. Variation of NOx concentration is a function of variation of Ip2. The concentration obtained based on the Ip2 is corrected responsive to the oxygen concentration in the measurement gas. Particularly, a coefficient of the variation of the Ip2, gain, in said function is corrected responsive to the oxygen concentration in the measurement gas.
摘要翻译：氮氧化物浓度检测器具有通过第一扩散电阻1引入测量气体的第一测量室2; 用于测量所述第一测量室1中的测量气体中的氧浓度的氧浓度检测电极7a; 第一氧离子泵电池6，用于根据所述氧浓度检测电极7a的电位从所述第一测量室2抽出测量气体中的氧; 第二测量室8，通过第二扩散电阻3从所述第一测量室2引入气体; 以及第二氧离子泵电池8，具有一对电极8a，8b，施加电压以分解第二测量室4中的NOx，以排出解离的氧，使得与NOx浓度对应的电路Ip2流入第二氧离子泵电池8. NOx浓度的变化是Ip2变化的函数。响应于测量气体中的氧浓度校正基于Ip2获得的浓度。特别地，响应于测量气体中的氧浓度来校正所述功能中的Ip2增益的变化系数。

10. 发明授权

US06695964B1 Method and apparatus for measuring NOx gas concentration 有权
标题翻译：测量NOx气体浓度的方法和装置
公开(公告)号：US06695964B1
公开(公告)日：2004-02-24
申请号：US09588504
申请日：2000-06-07
申请人： Masashi Ando , Noboru Ishida , Satoshi Sugaya , Takafumi Oshima , Norihiko Nadanami , Takaki Ootuka , Yoshikuni Sato , Tatsuo Okumura
发明人： Masashi Ando , Noboru Ishida , Satoshi Sugaya , Takafumi Oshima , Norihiko Nadanami , Takaki Ootuka , Yoshikuni Sato , Tatsuo Okumura
IPC分类号： G01N27407
CPC分类号： G01N27/4074
摘要： Method and sensor for measuring accurate measurement of NOx concentration in an exhaust gas containing O2,H2O, CO2 and NOx and a NOx gas concentration sensor. A first oxygen pump cell sufficiently pumps out oxygen in a measurement gas such as not to decompose NOx. A pair of electrodes is provided on an inner side and an outer side of a second measurement chamber into which the gas is introduced from a first measurement chamber via a diffusion resistance. A voltage is impressed across the paired electrodes for decomposing NOx in the second measurement chamber to dissociate oxygen which causes the current to flow in a second oxygen ion pump cell. The NOx gas concentration is measured for this current. The voltage impressed across the paired electrodes of the second oxygen ion pump cell is set so as not to dissociate H2O and CO2 present in the second measurement chamber.
摘要翻译：用于测量含有O 2，H 2 O，CO 2和NO x以及NOx气体浓度传感器的废气中的NOx浓度的精确测量的方法和传感器。第一氧气泵电池在测量气体中充分抽出氧气，例如不分解NOx。一对电极设置在第二测量室的内侧和外侧，气体通过扩散阻力从第一测量室引入到该第二测量室中。在一对电极上施加电压，用于分解第二测量室中的NOx，以解离氧，这导致电流在第二氧离子泵电池中流动。测量该电流的NOx气体浓度。设置在第二氧离子泵电池的成对电极上施加的电压，以使第二测量室中不存在H 2 O和CO 2。

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