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    • 4. 发明授权
    • Light-sensitive photopolymerizable composition
    • 光敏光聚合组合物
    • US4386153A
    • 1983-05-31
    • US240433
    • 1981-03-04
    • Fumiaki ShinozakiYasuo WashizawaTomoaki IkedaSho NakaoSyunichi Kondoh
    • Fumiaki ShinozakiYasuo WashizawaTomoaki IkedaSho NakaoSyunichi Kondoh
    • C08F2/00C08F2/50G03F7/031H01L21/027G03C1/68
    • G03F7/031Y10S430/12Y10S430/124
    • A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.
    • 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物,其包含(1)选自由以下的化合物组成的组中的至少一种化合物:苯并蒽酮,取代的苯并蒽酮(其取代基包括卤素原子, 至5个碳原子和具有1至5个碳原子的烷氧基),1,2-苯并蒽醌和取代的苯并蒽醌(其取代基包括卤素原子,具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基)和 (2)选自由以下通式(a)表示的4,4'-二取代氨基 - 二苯甲酮,由以下通式(b)表示的对取代氨基 - 苯甲醛衍生物, ,由以下通式(c)表示的2-(对取代氨基 - 苯基)-1,3-二氧戊环,4,4'-双(取代氨基)-N-亚苄基苯胺r (d)和由下列通式(e)表示的2- [4-(取代氨基)肉桂酰基]萘表示:(a)图像(c)(c) (e)其中R和R'可以相同或不同,表示甲基或乙基,R 0表示氢原子,羟基,-CR 1 R 2 R 3 基团,其中可以相同或不同的R 1,R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团,其中R 4表示具有1至5个碳原子的烷基 原子
    • 5. 发明授权
    • Light-sensitive ethylenically unsaturated materials containing
benzanthrones and novel sensitizers
    • 含有苯并蒽和新型敏化剂的光敏烯属不饱和物质
    • US4439515A
    • 1984-03-27
    • US484818
    • 1983-04-14
    • Fumiaki ShinozakiYasuo WashizawaTomoaki IkedaSho NakaoSyunichi Kondoh
    • Fumiaki ShinozakiYasuo WashizawaTomoaki IkedaSho NakaoSyunichi Kondoh
    • C08F2/00C08F2/50G03F7/031H01L21/027G03C1/68
    • G03F7/031Y10S430/12Y10S430/124
    • A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.
    • 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物,其包含(1)选自由以下的化合物组成的组中的至少一种化合物:苯并蒽酮,取代的苯并蒽酮(其取代基包括卤素原子, 至5个碳原子和具有1至5个碳原子的烷氧基),1,2-苯并蒽醌和取代的苯并蒽醌(其取代基包括卤素原子,具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基)和 (2)选自由以下通式(a)表示的4,4'-二取代氨基 - 二苯甲酮,由以下通式(b)表示的对取代氨基 - 苯甲醛衍生物, ,由以下通式(c)表示的2-(对取代氨基 - 苯基)-1,3-二氧戊环,4,4'-双(取代氨基)-N-亚苄基苯胺r (d)和由下列通式(e)表示的2- [4-(取代氨基)肉桂酰基]萘表示:(a)图像(c)(c) (e)其中R和R'可以相同或不同,表示甲基或乙基,R 0表示氢原子,羟基,-CR 1 R 2 R 3 基团,其中可以相同或不同的R 1,R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团,其中R 4表示具有1至5个碳原子的烷基 原子